• Title/Summary/Keyword: organic content

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Chemical Vapor Deposition of Ga2O3 Thin Films on Si Substrates

  • Kim, Doo-Hyun;Yoo, Seung-Ho;Chung, Taek-Mo;An, Ki-Seok;Yoo, Hee-Soo;Kim, Yun-Soo
    • Bulletin of the Korean Chemical Society
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    • v.23 no.2
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    • pp.225-228
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    • 2002
  • Amorphous $Ga_2O_3$ films have been grown on Si(100) substrates by metal organic chemical vapor deposition (MOCVD) using gallium isopropoxide, $Ga(O^iPr)_3$, as single precursor. Deposition was carried out in the substrate temperature range 400-800 $^{\circ}C$. X-ray photoelectron spectroscopy (XPS) analysis revealed deposition of stoichiometric $Ga_2O_3$ thin films at 500-600 $^{\circ}C$. XPS depth profiling by $Ar^+$ ion sputtering indicated that carbon contamination exists mostly in the surface region with less than 3.5% content in the film. Microscopic images of the films by scanning electron microscopy (SEM) and atomic force microscopy (AFM) showed formation of grains of approximately 20-40 nm in size on the film surfaces. The root-mean-square surface roughness from an AFM image was ${\sim}10{\AA}$. The interfacial layer of the $Ga_2O_3$/Si was measured to be ${\sim}35{\AA}$ thick by cross-sectional transmission electron microscopy (TEM). From the analysis of gaseous products of the CVD reaction by gas chromatography-mass spectrometry (GC-MS), an effort was made to explain the CVD mechanism.

Preparation and Properties of Regenerated Composite Fibers made from Styela Clava Tunics/PVA Blending(I) (미더덕 껍질과 PVA를 혼합한 재료로부터 제조한 복합섬유의 제법과 성질(I))

  • Jung, Young-Jin;An, Byung-Jae;Kim, Hong-Sung;Choi, Hae-Wook;Lee, Eon-Pil;Lee, Jae-Ho;Kim, Han-Do;Park, Soo-Min;Kim, Sung-Dong
    • Textile Coloration and Finishing
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    • v.20 no.2
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    • pp.1-8
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    • 2008
  • Regenerated composite fibers are prepared from solution(styela clava tunics /poly vinyl alchol) using N-methylmorpholine-N-oxide(NMMO)/water(87/13)(wt/wt) as a solvent by dry-wet spinning. The chemical cellulose (94%, ${\alpha}$-cellulose content) used for this study is extracted from styela clava tunics (SCT, Midduck), which are treated in chemical process and mechanical grinding. The structure and physical properties of regenerated composite fibers were investigated through IR-spetra, DSC, TGA and SEM. The optimal blend ratio of SCT/PVA for spinning solution was 70/30 and the total weight was 4% concentrations in NMMO/water solvent system. The fiber density, moisture contents and the degree of swelling were $1.5(g/cm^3)$ 10.2(%) and 365(%), respectively. The crystallinity index of composite fibers are decreased as the PVA contents increased. Thermal decomposition of composite fibers took place in two stages at around $250^{\circ}C$ and $550^{\circ}C$. The best thermal stability was obtained with 30% PVA contents.

Quality Characteristics of Yanggeng added with Pesticide Free Wild Grape (Vitis amurensis) Juice (무농약 산머루 즙을 첨가한 양갱의 품질특성)

  • Kang, Chang-Soo
    • Korean Journal of Organic Agriculture
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    • v.23 no.2
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    • pp.301-309
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    • 2015
  • This study was performed to investigate the quality characteristics of Yanggeng added wild grape (Vitis amurensis) juice. The yanggeng was prepared with pesticide-free wild grape juice, agar, sugar and salt. The yanggeng was made with various levels (0, 50, 100, 150, 200 g of wild grape juice in yanggeng, respectively) based on the total weight of water. It was estimated on Hunter's color value, texture profile analysis, and sensory characteristics of the Yanggeng. As the content of wild grape juice increased, The lightness (L) and yellowness (b) decreased and redness (a) increased. In texture profile analysis, hardness was increased; however, springiness, cohesiveness, gumminess and chewiness decreased with increasing levels of wild grape juice. The results of the sensory evaluation indicated that the Yanggeng containing the 150 g level of wild grape juice showed the highest preference scores in terms of color, taste, texture, flavor and overall acceptance. These results show that the yanggeng containing 150 g of wild grape juice is the better.

Influence the Fruit Quality of 'Campbell early' Grape according to Inoculation time of Kluyvera sp. CL2 (Kluyvera sp. CL2 처리시기가 포도 '캠벨얼리' 과실품질에 미치는 영향)

  • Lee, Seok-Ho;Song, Myung-Kyu;Kim, Seung-Duck;Choi, Won-Ho;Lee, Yoon-Sang;Hong, Seong-Taek;Kim, Hyun-Joo
    • Korean Journal of Organic Agriculture
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    • v.23 no.2
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    • pp.291-299
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    • 2015
  • This study aimed to investigate the effect of inoculation time of phosphate- solubilizing Kluyvera sp. CL2 on fruit quality in cultivation of Campbell early' grape. When phosphate-solubilizing strain was treated at the stone-hardening stage, soil phosphorous increased, exchangeable cations such as K, Ca and Mg also increased. Soil pH was not changed severely due to the soil buffer capacity. Water soluble phosphate concentrations did not decrease heavily up to 20 days after inoculation. When this strain was treated at the berry-softening stage, soil phosphate solubilization ratio was high, cluster weight and sugar content also increased. Both anthocyanin contents and Hunter's values were seen to be significant when inoculation times were stone-hardening stage and berry-softening stage, in particular, increase of Hunter's value a resulted in the improvement of coloration. From these results, we could find that the inoculation of phosphate-solubilizing Kluyvera sp. CL2 at berry-softening stage was the most effective in improvement of fruit productivity and quality in cultivation of'Campbell early' grape.

Effect of protected Methionine and Lysine on Milk yield and Composition in Holstein Dairy Cow under Different Dietary Crude Protein Levels : Meta-analysis (사료 내 수준별 조단백질 조건에서 보호메티오닌과 보호라이신의 사료첨가 급여가 착유우유생산성 및 유성분에 미치는 영향 : 메타분석)

  • Choi, Nag-Jin
    • Korean Journal of Organic Agriculture
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    • v.24 no.4
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    • pp.957-967
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    • 2016
  • The present study was conducted to investigate effect of dietary protected amino acid on milk yield and composition in dairy cow using meta-analysis. Total 21 research papers were employed in analysis, and mixed model was used for the analysis of effects. Effect of protected methionine (PM) and combination of protected methionine and lysine (PML) were investigated under two different levels of dietary crude protein (CP, <18% and >18%). For performance of dairy cow, milk yield, milk composition including milk fat and protein content and yield and 4% FCM (fat corrected milk) production were used for analysis. In case of milk yield, a trend of increment was found at PM supplementation at low CP (P=0.055). However, the effect of PM at high CP was detected as not significant (P>0.05). In case of milk protein, inclusion of PM at low CP showed significant decrement (P<0.05). However, there was no significant effect of MP on milk protein at high CP (P>0.05). Supplementation of MP at high CP level showed significant increment of milk fat (P<0.05). MP supplementation represented significant increment of 4% FCM production (P<0.05) regardless of dietary CP levels. Effects of PML on milk yield and composition at both of low and high dietary CP were not significant in this study. However, it seem to be that there was a possible positive effect of MPL application at high dietary CP on performance of dairy cow.

Persistence of Salmonella enterica, Escherichia coli O157:H7, and Listeria monocytogenes in Soil, Liquid Manure Amended Soil, and Liquid Manure

  • Jung, Kyu-Seok;Kim, Min-Ha;Heu, Sung-Gi;Roh, Eun-Jung;Lee, Dong-Hwan;Lim, Jeong-A;Ryu, Jae-Gee;Kim, Kye-Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.6
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    • pp.432-436
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    • 2014
  • While searching for healthier diets, people became more attentive to agricultural organic products. However, organic foods may be more susceptible to microbiological contamination because of the use of livestock manure compost and liquid manure, potential sources of pathogenic bacteria. This study was undertaken to investigate the persistence of Salmonella enterica, Escherichia coli O157:H7, and Listeria monocytogenes in soil, liquid manure amended soil, and liquid manure. Loamy soil, liquid manure amended soil, and liquid manure were inoculated with S. enterica, E. coli O157:H7, and L. monocytogenes. Samples were incubated in consistent moisture content at $25^{\circ}C$. Samples had been periodically collected during 120 days depending on the given conditions. S. enterica and E. coli O157:H7 survived over 120 days in loamy soil and over 60 days in liquid manure amended soil, respectively. L. monocytogenes decreased faster than other pathogens in soil. S. enterica, E. coli O157:H7, and L. monocytogenes survived for up to 5 days in liquid manure. S. enterica and E. coli O157:H7 in soil decreased by 2 to $2.5log\;CFU\;g^{-1}$ for 120 days. S. enterica and E. coli O157:H7 in liquid manure amended soil decreased slowly for 21 days. However, S. enterica, E. coli O157:H7, and L. monocytogenes sharply decreased after 21 days. S. enterica, E. coli O157:H7, and L. monocytogenes in soil increased by 0.5 to $1.0log\;CFU\;g^{-1}$ for 7 days. Foodborne pathogens in soil and liquid manure amended soil gradually decreased over time.

Effect of Carbonized Wastewoods on Soil Improvement(2) (목질폐잔재 탄화물의 토양개량 효과(2))

  • Shin, Chang-Seob;Kim, Byung-Ro
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.6
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    • pp.21-28
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    • 2006
  • This study was carried out to examine the effect of soil improvement according to the shape of charcoal and the kind of carbonized tree species. As the results, all of the seedlings of Thuja occidentalis and Aesculus turbinata grew better in the charcoal-treated soil than the non-treated soil. In case of powder charcoal, Thuja occidentalis seedlings grew up best in the soil treated with powder charcoal of Pinus koraiensis and then grew well in order of Larix leptolepis > particle board > Quercus acutissima. In case of granulated charcoal, the seedlings grew well in order of the granulated charcoal of Larix leptolepis > particle board > Pinus koraiensis. It was analyzed that the soil porosity and the organic matter content were mo re in the charcoal -treated soil than the non-treated soil also. It is inferred that because the aeration property and the absorption of organic matter were increased in the root zone, the growth of seedlings was better in the char-coal-treated soil.

Preparation and Characteristics of Silicone Modified Polyacrylic Hybrid Elastomer (실리콘 변성 폴리아크릴졔 Hybrid Elastomer의 제조와 그 특성)

  • Lee, Byoung-Chul;Kang, Doo-Whan
    • Polymer(Korea)
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    • v.31 no.1
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    • pp.86-91
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    • 2007
  • Polydimethylsiloxane branched HEMA (SH) was Prepared by reacting polydimethylsilorane prepolymer and 2-hydroxyethyl methacrylate (HEMA). Polyacrylate modified Polyorganosiloxane (SMPA) was prepared by polymerization of methacrylic acid(MA), allyl glycidyl ether(AGE), aminopro- pyltrimethoxysilane (APTS), and SH. Their structures were confirmed by the measurement of FTIR and $^1H-NMR$ and thermal properties of SMPA were studied from TGA. Residual weight of SMPA at $400^{\circ}C$ increased according to increasing content of the APTS to 63 from 55%. SMPA sealant was prepared by adding additives, such as viscosity increasing agent, crosslinking agent, and fillers. Adhesion characteristics of SMPA-3 sealant was determined to be maximum load elongation, 2.01 %, and break load elongation, 2.28%. Adhesion characteristics for SMPA sealant prepared from SMPA-3 were better than those for SMPA sealant prepared from SMPA-1 and SMPA-2.

Preparation and Properties of Regenerated Composite Fibers made from Styela Clava Tunics/PVA Blending( II) (미더덕 껍질과 PVA를 혼합한 재료로부터 제조한 복합섬유의 제법과 성질(II))

  • Jung, Young-Jin;An, Byung-Jae;Kim, Hong-Sung;Choi, Hae-Wook;Lee, Eon-Pil;Lee, Jae-Ho;Kim, Han-Do;Park, Soo-Min;Kim, Sung-Dong
    • Textile Coloration and Finishing
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    • v.20 no.3
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    • pp.31-38
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    • 2008
  • Regenerated composite fibers were prepared from solution of styela clava tunics(SC) and poly vinyl alchol(PVA) using N-methylmorpholine-N-oxide(NMMO)/water(87/13)(wt%/wt%) as a solvent by dry jet-wet spinning. Structure and physical properties of regenerated composite fibers were investigated through birefrngence, x-ray diffratograms, tenacity, fibrillation and SEM. Optimal blend ratio of SC/PVA for mechanical properties of composite fibers was 70/30 and total weight was 4wt% concentrations in NMMO/$H_2O$ solvent system. Crystallinity index of composite fibers were decreased as the PVA contents increased. Fibrillation of $10{\sim}20wt%$ PVA blended fibers were occurred less than pure SC fiber. Shape of composite fibers were a circle cross section within 10wt% PVA content. But the cross section of fibers were changed as crushed flat with the PVA contents increased.

Pervaporation Separation of Trace Dicholoromethane from Water Using Fluorinated Polysiloxaneimide do Membranes (불소계 폴리실록산이미드 공중합체막을 이용한 저농도 Dichloromethane 수용액의 투과증발)

  • Kim, Jeong-Hoon;Chang, Bong-Jun;Lee, Soo-Bok
    • Membrane Journal
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    • v.17 no.3
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    • pp.184-190
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    • 2007
  • This study reports on the pervaporation separation of a volatile organic compound(VOC), dichloromethane(DCM) from water using fluorinated copolysiloxaneimide membranes. The copolysiloxaneimide membranes were prepared from 4,4'-(hexafluoroisopropylidene)diphthalic anhydride(6FDA) and two diamines(polysiloxane diamine(SIDA), 2-(perfluorohexyl)ethyl-3,5-diaminobenzene(PFDAB)). By varying the ratio of flexible polysiloxane diamine(SIDA)/rigid fluorinated aromatic diamine(PFDAB) from 0/100 to 100/0 mol%, five copolysiloxaneimide membranes were prepared success- fully. The pervaporation properties of DCM/water were examined in terms of two diamine monomer ratio at room temperature and the feed composition of 0.05 wt% in water. It was found that the increase in SIDA content led to high permeation flux and pervaporation selectivity towards DCM by the enhanced sorption/sorption selectivity and diffusion coefficient/diffusion selectivity due to the increased hydrophobicity and fractional free volume.