• Title/Summary/Keyword: organic content

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Performance and Emission Comparisons of a SI Engine Fueled by Syngas with Varying Hydrogen Content (합성가스 연료의 수소 함량 변화가 SI 엔진의 연소특성에 주는 영향)

  • Park, Seung-Hyun;Lee, Sun-Youp;Park, Cheol-Woong;Lee, Jang-Hee
    • Journal of the Korean Institute of Gas
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    • v.15 no.2
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    • pp.63-68
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    • 2011
  • As an effective utilization of biomass, organic wastes and coal, attention has been made to use syngas to a reciprocating engine to generate power. However, significant component variation of syngas depending upon origin and gasification conditions, and its lower heating value than that of LPG and CNG can create difficulties in stable engine operation. Thus it is necessary to address these issues in order to successfully develop power generation engines. As a primary step to resolve these problems, effects of H2 content variation in syngas on engine performance and emission characteristics were discussed in this study. The results show that as H2 % in syngas increases, more stable combustion was achieved with retarded MBT spark timing and engine efficiency becomes maximum with syngas of 10% H2. In addition, NOx emission increased while THC emission decreased as H2 % rises in the syngas.

Preparation of Hard Coating Solutions with High Refractive Index for Polycarbonate Sheet by the Sol-Gel Method (Sol-Gel 법에 의한 Polycarbonate 시트에 적용 가능한 고굴절률을 보이는 하드코팅 용액의 제조)

  • Cheong, Il Yeop;Cho, Kyung In;Cheong, Sang Hyuk;Park, Hyo Nam;Song, Ki Chang
    • Korean Chemical Engineering Research
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    • v.45 no.4
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    • pp.335-339
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    • 2007
  • In order to overcome the problem of poor hardness of transparent polycarbonate (PC) sheets, organic-inorganic hybrid hard coating solutions, which show a high refractive index above 1.58, were made by the sol-gel method. These hybrid coating solutions were obtained from mixture of titanium tetraisopropoxide (TTIP), and (3-glycidoxypropyl)trimethoxysilane (GPTMS). The PC sheets were spin-coated, and cured at $120^{\circ}C$ for 2 hr. Change of refractive index in the range of 1.53-1.61 was obtained by varying the GPTMS content. The refractive index of the coated film decreased with increasing the GPTMS content, while the pencil hardness of the coated film was found to increase with increasing the GPTMS content.

Effect of "CellCaSi" recycling Coal Fly Ash on Soil Amendment and the growth of Turfgrass in Golf Course (석탄회를 재활용한 '셀카시'의 토양 개량과 골프 코스 잔디 생육에 대한 효과)

  • 이상재;허근영;정운익
    • Asian Journal of Turfgrass Science
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    • v.13 no.4
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    • pp.191-200
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    • 1999
  • The objective of this study was to improve the recycling rate of coal ash fly, industrial waste. This study was conducted to analyze the physico-chemical properties of \"CellCaSi\" and clarify the effects on the growth of Kentucky bluegrass(Poa pratensis L.) and creeping bentgrass(Agrostis paulstris Huds \"Penncross\") and the chemical properties of soil, which was cellular calcium silicate reproduced by coal ash fly. A field assay was carried out in Young-Pyong Golf Course. The results were as follows. 1. The main chemical composition of CellCaSi was $SiO_2$(45~55%) and CaO(25~35), which was 70~90% of total weight. CellCaSi showed pH 8~9. Bulk density of CellCaSi was 0.35~0.45g/㎤. Water content of CellCaSi was 52.5~67.5%. 2. In the applied plots, leaf width, grass density per $1\textrm{cm}^2$, rhizome number and length per plant, and root number per plant of Kentucky bluegrass(Poa pratensis L.) and creeping bentgrass(Agrostis paulstris Huds \"Penncross\") showed increasing tendency compared with the control. The application of CellCaSi increased the growth of turfgrasses. Their visual quality on hardness, grass shoot density per $1\textrm{cm}^2$ and root growth was very good. And, their visual quality on rhizome growth was good. 3. After the application of CellCaSi, pH, CEC, Ex-cation of the applied soil showed increasing tendency with the little range, $SiO_2$content increasing tendency considerably, and organic matter content decreasing tendency compared with the control.ncy compared with the control.

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Manufacturing of Calcium Binding Peptide using Sericin Hydrolysate and Its Bioavailability in Calcium Deficient Rat (실크 세리신 단백질 가수분해물을 이용한 유기 칼슘제의 제조 및 칼슘 결핍 쥐에서의 생체 이용률)

  • Cho, Hye-Jin;Lee, Hyun-Sun;Jung, Eun-Young;Suh, Hyung-Joo
    • Journal of the East Asian Society of Dietary Life
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    • v.20 no.5
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    • pp.680-686
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    • 2010
  • Silk sericin protein was hydrolyzed by seven proteolytic enzymes in order to examine the effectiveness of the hydrolysates in binding calcium. The amino acid nitrogen content of hydrolysates from Flavourzyme was higher than that for other enzymes, and its calcium binding capacity showed a dose-dependent increase. We examined the effects of calcium binding peptide from sericin hydolysates on the bioavailability of Ca-deficient rats. Three-week-old male rats were fed an Ca-deficient diet for three weeks. Rats were divided into four groups (DD: non-treated group on calcium deficient diet; DD+MC: milk-calcium treated group; DD+OC: organic calcium made using sericin hydolysates; and DD+IC: inorganic calcium ($CaCl_2$). After oral administration of calcium supplements for one week, the calcium content of the serum and liver were significantly higher in DD+OC ($101.7{\mu}g$/mL and $49.3{\mu}g$/mL) and DD+MC ($83.6{\mu}g$/mL and $42.8{\mu}g$/mL) than DD ($86.3{\mu}g$/mL and $43.4{\mu}g$/mL). The alkaline phosphatase (ALP) content in the treated groups was significantly lower than DD, but no significant difference among groups was shown. Aspartate aminotransferase (AST) levels did not show any significant difference between groups. Alanine aminotransferase (ALT) levels were significantly reduced compared to the DD group. In conclusion, binding calcium to peptides from sericin hydrolysates seems to improve its bioavailability, and to hasten the cure of calcium deficiency in experimental rats.

The Effects of Skin Contact Time and Suspended Solid on The White Wine Quality (Skin Contact와 Suspended Solid가 백포도주 품질에 미치는 영향)

  • Rho, Tae-Uk;Kim, Chanjo;Sung, Chang;Moon, Youngja;Kim, Bong-Nan;Oh, Manjin
    • Korean Journal of Agricultural Science
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    • v.24 no.2
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    • pp.290-297
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    • 1997
  • Danored is considered as the most favorable grape variety for national wine manufacturing in terms of sugar, organic acid contents, annual production amount, as well as quality control convenience after harvest. This study was canied out to know the influence of suspended solid(SS) and skin contact time(SCT) with Danored variety on the white wine quality. The results are summarized as follows; 1. Suspended solid and skin contact time did not greatly influence on the chemical composition of Danored juice. But skin contact time provided slightly increaseness to the content of phenol compounds 2. Suspended solid accelerated fermentation rate of white wine manufacturing. Although the content of suspended solid are less amount than 0.3% in must, wine fermentation was completed to dryness in concentration of sugar. 3. When the content of suspended solid was around 3%, higher alcohol in white wine was increased by the 20%. This result is relatively small increasement compared to the other reported results. 4. Because Danored contained less amount of phenol compounds comparison with other grape varieties, browning capacity in white wine was much favorable to quite low concentration. Especially, phenolic compounds was decreased remarkably as one of fermentation characteristics of Danored variety. 5. As a result of sensory evaluation, wine quality was A-1> B-1> A-2> B-2 in its favorable ranking orders. It was so concluded that A-1 might be the most acceptable one from this study.

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Synthesis and characterization of poly(vinyl-alcohol)-poly(β-cyclodextrin) copolymer membranes for aniline extraction

  • Oughlis-Hammache, F.;Skiba, M.;Hallouard, F.;Moulahcene, L.;Kebiche-Senhadji, O.;Benamor, M.;Lahiani-Skiba, M.
    • Membrane and Water Treatment
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    • v.7 no.3
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    • pp.223-240
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    • 2016
  • In this study, poly(vinyl-alcohol) and water insoluble ${\beta}$-cyclodextrin polymer (${\beta}$-CDP) cross-linked with citric acid, have been used as macrocyclic carrier in the preparation of polymer inclusion membranes (PIMs) for aniline (as molecule model) extraction from aqueous media. The obtained membranes were firstly characterized by X-ray diffraction, Fourier transform infrared and water swelling test. The transport of aniline was studied in a two-compartment transport cell under various experimental conditions, such as carrier content in the membranes, stirring rate and initial aniline concentration. The kinetic study was performed and the kinetic parameters were calculated as rate constant (k), permeability coefficient (P) and flux (J). These first results demonstrated the utility of such polymeric membranes for environmental decontamination of toxic organic molecules like aniline. Predictive modeling of transport flux through these materials was then studied using design of experiments; the design chosen was a two level full factorial design $2^k$. An empirical correlation between aniline transport flux and independent variables (Poly ${\beta}$-CD membrane content, agitation speed and initial aniline concentration) was successfully obtained. Statistical analysis showed that initial aniline concentration of the solution was the most important parameter in the study domain. The model revealed the existence of a strong interaction between the Poly ${\beta}$-CD membrane content and the stirring speed of the source solution. The good agreement between the model and the experimental transport data confirms the model's validity.

Comparison of Productivity of Various Silage Corn Varieties II. Chemical composition and nutrient yield of different part of silage corns (Silage용 옥수수의 품종별 생산성 비교 Il. 옥수수 부위별 조성분 함량 및 영양소 생산성)

  • 김병호;문여황;신정남
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.12 no.3
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    • pp.185-192
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    • 1992
  • This experiment was conducted to compare the productivity of five silage corn varieties. Corn varieties were Pioneer 3144(P 3144), 3160(P 3160), 3282(P 3282), 3352(P 3352) and Suweon 19(S 19) and were seeded on May 2 and harvested on August 15. Ratios of stalk, leaf and ear, chemical composition and yields of nutrients were investigated in respective corn part. Experimental design was accepted by Latin square arrangement with five replicates and each plot had twenty two plants. The results obtained were as follows: 1. Crude portein, crude ash and nitrogen free extract(NFE) contents of whole plant ranged from 6.32 to 7.18%, 5.16 to 7.43% and 52.62 to 57.90%, respectively, and there were no significant(P>.Ol) differences between varieties. Crude protein and NFE content were the highest in ear between corn parts. 2. Crude fiber conent of whole plant ranged from 18.98 % to 24.01 %, and was the highest in suweon 19 and the lowest in P 3352(P<.01). Crude fiber content was the highest in stem and the lowest in ear, However, crude fat content(2.03-3.66 %) vice versa. 3. Yields of organic matter, crude protein, crude fat, NFE and TDN per 10a were the greatest(P< .01) in P 3282, however crude fiber yield was the highest(P<.Ol) in P 3352. 4. Ratios of different part to total dry matter yield ranged from 12.7 %(P 3352) to 17.8 %(P 3160) for leaf, 44.5(P 3352) to 66.9 %(P 3160) for stem and husks, and 16.9 %(P 3282) to 42.8 %(P 3352) for ear, and there were significant differences between corn varieties(P<.Ol). Consequently, P 3352 has the greatest nutrient yields, particularly by ear, and P 3282 has a great nutrient yield by stem. This result suggested that could be appear a better character of silage corn by hybridization of this two corn varieties.

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Manufacturing and Characterization of PVDF/TiO2 Composite Nano Web with Improved β-phase (β-phase가 향상된 PVDF/TiO2 Nano Web 제조 및 특성 분석)

  • Bae, Sung Jun;Kim, Il Jin;Lee, Jae Yeon;Sur, Suk-Hun;Choi, Pil Jun;Sim, Jae Hak;Lee, Seung Geol;Ko, Jae Wang
    • Textile Coloration and Finishing
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    • v.32 no.3
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    • pp.167-175
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    • 2020
  • In this study, the optimum conditions for manufacturing PVDF nano web according to various electrospinning conditions such as solution concentration and applied voltage conditions were confirmed. The optimum spinning conditions were studied by analyzing the changes in the radioactivity of PVDF/TiO2 nano web according to the TiO2 content and the content of β-phase closely related to the piezoelectric properties under established conditions. As a result, it was confirmed that the concentration of the spinning solution was 20 wt%, the applied voltage was 25 kV, and the TiO2 content was 5 phr. PVDF nano web and PVDF/TiO2 nano web were observed morphologies through Scanning Electron Microscope(SEM) analysis. Formation of β-phase by electrospinning was confirmed by Fourier transform infrared spectroscopy(FT-IR) and X-ray Diffractometer(XRD), and the effect of the trapped nano web structure on the piezoelectric properties was investigated.

Characteristics of Chemical Contents of Horizontal Spray Salts from Deep Ocean Water (수평 분무식 해양심층수 소금의 성분 특성)

  • MOON Deok-Soo;KIM Hyun-Ju;SHIN Phil-Kwon;JUNG Dong-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.38 no.1
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    • pp.65-69
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    • 2005
  • We have developed a new method of manufacturing salts by horizontal spray drying technique, using the concentrated deep ocean water after desalination processes. We studied the chemical characteristics of the spray-dried salts. Sodium content in the spray salts is $28.4\%$, which is $10-30\%$ lower than that of bay salts, bamboo salts and boiling salts $(32-38.2\%)$. However, the contents of magnesium, potassium and calcium of the spray salts are 2.5 times, 3 times and 4.5 times higher relative to those of bay salts, respectively. On the one hand, sulfur content in spray salts is 14 times lower than those of bay salts, which is caused by their volatilization during spray and vaporization of the concentrated seawater. Enrichment factors of Mg (0.8), K (0.9) and Ca (1.0) in the spray salts are relatively higher than those in bay salt (0.2-0.3), bamboo salt (0.15-0.4) and boiled salt (0.4-0.7), respectively. On the contrary, enrichment factor of sulfur in spray salts is observed to be 0.07, which is considerably lower than those in other salts (0.3-0.7). It means that the minerals like Mg, K and Ca can be well conserved from seawater to salts through spray drying techniques, while volatile elements like sulfur, lead, mercury and organic compounds can be easily removed from seawater via spray and heating processes.

Microstructure and Hardness of Titanium Aluminide/Carbide Composite Coatings Prepared by Reactive Spray Method (반응성 스프레이방법으로 제작한 티타늄 알루미나이드/탄화물 복합박막의 미세조직과 경도)

  • Han, Chang-Suk;Jin, Sung-Yooun
    • Korean Journal of Materials Research
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    • v.30 no.7
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    • pp.350-358
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    • 2020
  • A variety of composite powders having different aluminum and carbon contents are prepared using various organic solvents having different amounts of carbon atoms in unit volume as ball milling agents for titanium and aluminum ball milling. The effects of substrate temperature and post-heat treatment on the texture and hardness of the coating are investigated by spraying with this reduced pressure plasma spray. The aluminum part of the composite powder evaporates during spraying, so that the film aluminum content is 30.9 mass%~37.4 mass% and the carbon content is 0.64 mass%~1.69 mass%. The main constituent phase of the coating formed on the water-cooled substrate is a non-planar α2 phase, obtained by supersaturated carbon regardless of the alloy composition. When these films are heat-treated at 1123 K, the main constituent phase becomes γ phase, and fine Ti2AlC precipitates to increase the film hardness. However, when heat treatment is performed at a higher temperature, the hardness is lowered. The main constitutional phase of the coating formed on the preheated substrate is an equilibrium gamma phase, and fine Ti2AlC precipitates. The hardness of this coating is much higher than the hardness of the coating in the sprayed state formed on the water-cooled substrate. When hot pressing is applied to the coating, the porosity decreases but hardness also decreases because Ti2AlC grows. The amount of Ti2AlC in the hot-pressed film is 4.9 vol% to 15.3 vol%, depending on the carbon content of the film.