• Title/Summary/Keyword: organic acid mixtures

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The Study of Physical Properties for the Organic Compounds and their Binary Mixture according to Molecular Connectivity Method (Molecular Connectivity法을 이용한 有機化合物과 二成分 混合物에 對한 物理化學的 性質에 關한 硏究 (Ⅱ))

  • Ui-Rak Kim;Kyung-Sub Min;Myung-Jae Lee;Sang-Hae Kim;Bong-Jin Jeong
    • Journal of the Korean Chemical Society
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    • v.36 no.4
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    • pp.485-495
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    • 1992
  • The viscosities of organic compounds (alcohols, acetates, alkanes, acids, substituted $NH_2$) in liquid states, gas states and the binary mixtures of n-alkane / 1-chloroalkane were calculated by molecular modeling techniques. The molecular descriptors of molecular modeling technique are Molecular connectivity indices, Wiener indices and ad hoc descriptors, which can encode the information of compound properties about the effect of size, branching, cyclization, unsaturation, heteroatom content, polarizability, and so on. The successful results among method have been Molecular connectivity indices, binary mixtures of n-alkane / 1-chloroalkane, Wiener indices for gas state and ad hoc descriptor for liquid states. Also we obtained the regression equations for viscosities using molecular modeling indices for gas, liquid states and binary mixtures of n-alkane / 1-chloroalkane. The calculated viscosity values for organic compounds are in good agreement with experimental results.

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Studies on the Preparation of Yogurt from Milk and Sweet Potato or Pumpkin (고구마와 호박을 첨가한 요구르트 제조에 관한 연구)

  • Shin, Yong-Seo;Lee, Kap-Sang;Kim, Dong-Han
    • Korean Journal of Food Science and Technology
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    • v.25 no.6
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    • pp.666-671
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    • 1993
  • Mixtures (total solid content: 15%) prepared with whole milk added with skim milk powder and/or sweet potato and/or pumpkin were fermented with 0.205% gelatin, 2% sugar and yogurt bacteria. The fermented mixtures (curd yogurt) were evaluated for acid production (pH, titratable acidity), number of viable cell, sensory property and keeping quality. The acid production of all mixtures remarkably increased for the first 12 hours and there is no significant difference among the mixtures. The lactic acid bacteria counts in the all products after 24 hours incubation were above $6.4{\times}10^{9}cfu/ml$. In organic acids, the mixture added with skim milk powder was higher ratio of lactic acid content to total acidity than those added with sweet potato and/or pumpkin. The sensory score of mixture containing sweet potato was best but curd yogurt containing pumpkin reduced the sensory property. When each mixtures were kept at $5^{\circ}C$ for 15 days, pH, titratable acidity, and number of viable tells of yogurt were not changed.

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The Molecular Complexes (ⅩI). The Complexes of Toluidines and N-Methyltoluidines with Iodine in Carbon Tetrachloride$^*$

  • Lee, Dong-Choo;Lee, Ki-Chang
    • Bulletin of the Korean Chemical Society
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    • v.1 no.3
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    • pp.101-104
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    • 1980
  • A sequential copolypeptide with repeating unit sequences, in which a glycyl residue is flanked progressively by two ${\gamma}$-benzyl-L-glutamyl residues, has been synthesized by poymerizing p-nitrophenyl ester of ${\gamma}$-benzyl-L-glutamyl-${\gamma}$ -benzyl-L-gutamyl-glycine. Polymers obtained were characterized by viscosity and infra-red spectral data. The highest molecular weight obtained was 21,000. Molecular conformation in solid state was found to be a mixed form of and |${\beta}$-structure. Polymers obtained were insoluble in the most of the organic solvents except in a strong acid like dichloroacetic acid, but in binary mixtures of solvents such as dichloroacetic acid-ethylene dichloride or dichloroacetic acid-chloroform, they were soluble within certain ranges of solvent compositions.

Silage from Agricultural By-products in Thailand: Processing and Storage

  • Suksombat, W.;Lounglawan, P.
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.4
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    • pp.473-478
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    • 2004
  • Processing and storage of the silage from agricultural by-products were studied in two experiments. The first experiment was conducted to investigate the chemical composition and degradability of various silages with varying ensiling times. The experiment was a 5$\times$3 factorial design, completely randomized, with factor A as the different formulated mixtures by varying level of urea addition (0, 0.5, 1.0, 1.5 and 2.0%) and factor B as the time of ensiling. Chemical composition changed little with time and varied only slightly with levels of urea in the mixtures. Dry matter (DM) degradability increased with increasing cassava levels while crude protein degradability and pH level increased with increasing urea addition. By using 'Flieg point', which relates to organic acid yields, there were no significant difference among ensiled mixtures and times of ensiling. Therefore it can be concluded that the 5th silage formulation is the most appropriate since its DM and crude protein (CP) degradability were highest. The second experiment was carried out to determine the quality of the 5th silage mixtures (from the previous trial) after being stored for up to 6 months. The experiment was a complete randomized design with samples taken at monthly intervals up to 6 months and subjected to laboratory and degradability analyses. The results showed no significant (p>0.05) difference in chemical composition except for increased neutral detergent fiber and acid detergent fiber percentage in association with increasing storage time. There were no significant (p>0.05) differences in 'Flieg point' among times of storage. In conclusion, this experiment showed that the silage from agricultural by-products can be stored for more than 6 months.

Bacterial Biocontrol of Sprouts through Ethanol and Organic Acids (새싹채소 오염세균의 에탄올과 유기산에 의한 제어)

  • Cho, Sung-Kyung;Park, Jong-Hyun
    • The Korean Journal of Food And Nutrition
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    • v.25 no.1
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    • pp.149-155
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    • 2012
  • Although bacterial outbreaks from ready-to-eat foods such as sprouts have increased, the information on microbial biocontrol by means of sanitizers is limited. Twenty sprouts of red cabbage, baby radish, alfalfa, and broccoli each were collected from the wholesale markets in Seoul. Ethanol and organic acids including acetic acid, citric acid, and lactic acid were used to control the amount of mesophilic bacteria and Bacillus cereus. Sanitizer mixtures of ethanol and organic acids showed a remarkable reduction of viable counts and, in particular, the sanitizer mixture comprised of 20% ethanol and 1% lactic acid seemed to be best by a reduction of 7~8 log CFU/g on the sprouts after a 10 minute exposure. At the same time, the sanitizer comprised of 20% ethanol and 1% lactic acid showed the same reduction for Escherichia coli, Salmonella typhimurium, B. cereus, Staphylococcus aureus, and Enterococcus faecalis, with more effect toward the Gram-negative bacteria. Sensory evaluation by texture, browning, off-flavour, and overall acceptability seemed better just after treatment when compared to one day after treatment with the sanitizer. Therefore, the sanitizers of ethanol-organic acid might be an effective means to control the bacterial contamination of sprouts in palce of sodium hypochloric acid.

Analysis of specific character of environment-friendly material-produced rice

  • Heo, Kyu-Hong;Cho, Sun-Sik;Seo, Pil-Dae;Rico, Cyren;Bequillo, Irvin;Kang, Mi-Young;Lee, Sang-Chul
    • Proceedings of the Korean Society of Organic Agriculture Conference
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    • 2009.12a
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    • pp.314-314
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    • 2009
  • The effects of mixtures of each of rice hull charcoal and wood charcoal with pyroligneous acid on the cultivation and antioxidant activities of rice were investigated. Results of the total phenolic compounds, DPPH radical electron-donating ability and xanthine oxidase stress activity analyses revealed that the environment-friendly materials increased the total antioxidant capacity in rice. In the case of palatability of rice, total amylose blue value and starch-I2color reaction analyses, data showed that environment-friendly materials generally decreased the amylose content of rice. Also, the environment-friendly materials improved the rice endosperm quality.

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Effects of Dietary Supplementation of Organic Acid and Antibiotics Mixture on Growth Performances and Blood Metabolites in Growing Pigs (사료내 유기산제 및 항생제의 혼합첨가가 육성돈의 성장과 혈액성상에 미치는 영향)

  • Lee, Cheol-Ho;Jo, Ik-Hwan;Shon, Joong-Cheon;Lee, Sung-Hoon
    • Korean Journal of Organic Agriculture
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    • v.17 no.2
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    • pp.237-251
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    • 2009
  • This study was carried out to evaluate the effect of replacing antibiotics by organic acid mixture on growth performances and blood metabolites in growing pigs. Twenty-five crossbred pigs (Large White${\times}$Landrace) at the age of 79 days were fed five different diets by supplementing organic acid mixture and chlortetracycline. The experimental diets were consisted of diets without antibiotics supplementation (control), diets added 100mg/kg of chlortetracycline to control diet (T1), diets added 100mg/kg of chlortetracycline and 0.1% of $Acidomix^{(R)}$ (comprising formic acid 25%, sorbic acid 10%, fumaric acid 10%) to control diet (T2), diets added 0.1% of $Acidomix^{(R)}$ to control diet (T3), and diets added 0.3% of $Acidomix^{(R)}$ to control diet (T4). The changes in feed conversion ratio, average daily gain and blood metabolites were investigated. Twenty-five pigs were allotted to five treatments with five replications of each and the experiment was conducted on the basis of complete randomized design for 6 weeks. Average daily gain was significantly (p<0.05) different between T4 and control diets. All treatments including diets added $Acidomix^{(R)}$ and chlortetracycline were slightly higher than control diets. The feed intakes did not show a significant difference between the control and other treatments, and did not give change in feed intake by the addition of $Acidomix^{(R)}$. No differences on feed conversion ratio among treatments were observed but T4 and T3 treatments showed lower value than other treatments. The concentrations of blood urea nitrogen, total cholesterol and triglyceride were significantly (p<0.05) different among treatments, but their values were within the normal range representing that effects on blood profile by organic acid or antibiotics supplementation were not found. The results from this study indicated that adding chlortetracycline or organic acid mixtures to diets showed tendency to improve average daily gain and feed conversion ratio in growing pigs. These results showed that antibiotics could be replaced by organic acid mixture in growing pig diets, leading to stimulated growth and improved feed conversion ratio.

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Changes in Molecular Weight of Dissolved Organic Matter by Photodegradation and their Subsequent Effects on Disinfection By-Product Formation Potential (광분해에 의한 용존 유기물질의 분자량 변화가 소독부산물 생성능에 미치는 영향)

  • Lim, Jung-Hee;Hur, Jin
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.11
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    • pp.769-775
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    • 2013
  • UV-induced transformations in the characteristics of dissolved organic matter (DOM) and the subsequent effects on the disinfection by-product formation potential (DBPFP) were investigated using the mixtures of the two humic substances with different sources, and two different size fractions of Suwannee River fulvic acid (SRFA). 7 day-photodegradation resulted in the decrease of specific ultraviolet absorbance (SUVA) of the mixtures as well as the specific DBPFP. After the irradiation, however, higher specific DBPFP values were consistently observed at the same range of the SUVA values. This suggests that non UV-absorbing components, generated by the UV-irradiation, may contribute to the formation of DBPs. Two different molecular size fractions of SRFA showed dissimilar responses to photodegradation. The behavior was also influenced by the types of the DBPs generated. Higher levels of trihalomethenes (THMs) were formed per organic carbon for the high molecular fraction compared to the low molecular fraction, whereas no differences were found in the formation of haloacetic acids (HAAs) between the two different size fractions. The formation of the two types of DBPs also differed by the irradiation times. Specific formation potential of THMs consistently increased upon the irradiation, whereas HAAs showed the initial increase followed by the decrease in their specific formation potential.

Stripping of Fe(III) from the Loaded Mixture of D2EHPA and TBP with Sulfuric Acid Containing Reducing Agents

  • Liu, Yang;Nam, Sang-Ho;Lee, Manseung
    • Bulletin of the Korean Chemical Society
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    • v.35 no.7
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    • pp.2109-2113
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    • 2014
  • Solvent extraction of Fe(III) from chloride solution by using a mixture of D2EHPA (Di-(2-ethylhexyl)-phosphoric acid) and TBP (Tri-butyl phosphate) and the reductive stripping of Fe(III) from the loaded organic were investigated. Quantitative extraction of Fe(III) from the solution (Fe concentration = 90 g/L) was accomplished in two cross-current extraction stages by using the mixture of D2EHPA and TBP. In order to facilitate the stripping efficiency, a reductive stripping method was employed by using $H_2SO_3$ or $Na_2SO_3$ as a reducing agent. The addition of $H_2SO_4$ into reducing agents led to improvement in the stripping efficiency while high concentration acid would suppress it. Both of the mixtures of $H_2SO_4+H_2SO_3$ and $H_2SO_4+Na_2SO_3$ showed good efficiency for the stripping of Fe(III), while the latter was recommended as the stripping solution based on the economics and experimental condition.

Evaluation of Feed Value for Cow Manure-Sawdust Mixtures Fermented by a Fungal Mycelium of Formitella flaxinea (Formitella flaxinea에 의하여 발효된 우분-톱밥 배양물의 사료가치 평가)

  • Kim, Yong-Kook
    • Journal of the Korea Organic Resources Recycling Association
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    • v.14 no.1
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    • pp.103-111
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    • 2006
  • Fresh dairy cow manure was mixed with dried sawdust at the following moisture contents and manure: sawdust ratios: 50% and 57:43 ($\underline{M50}$), 55% and 64:36 ($\underline{M55}$), 60% and 70:30 ($\underline{M60}$), 65% and 76:24 ($\underline{M65}$), 70% and 83:17 ($\underline{M70}$) 75% and 90:10($\underline{M75}$) and 80% and 96:04($\underline{M80}$). The mixtures were fermented by a fungal mycelium of Fomitella flaxinea for 2wk at 29 C to recycle cow manure along with sawdust and fungal mycelium as a ruminant feedstuff. Chemical composition and in vitro rumen dry matter digestibilities of fermented mixtures were compared with unfermented mixture. The crude protein contents of mixtures were not changed by fermentation with fungal mycelium. Neutral detergent fiber contents of 4WK fermented mixtures (90.6, 85.3, 80.4, and 76.4% for $\underline{M50}$, $\underline{M60}$, $\underline{M70}$ and $\underline{M80}$, respectively were lower (P<0.05) than those of unfermented mixtures (91.1, 89.9, 84.3, and 79.4%). However, acid detergent fiber contents of fermented mixtures (73.8, 68.9, 65.3, and 58.0%) were higher (P<0.05) than those unfermented mixtures (70.2, 67.8, 61.7, and 56.3%). In vitro rumen dry matter digestibilities of fermented mixtures for four weeks(49.4, 36.8, 28.6, and 22.3% for $\underline{M50}$, $\underline{M60}$, $\underline{M70}$ and $\underline{M80}$) were higher than those of unfermented mixtures(34.1, 27.5, 20.6, and 15.4%) (P<0.05).

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