• Journal of the Korea Institute of Building Construction
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• v.18 no.5
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• pp.429-437
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• 2018

The aim of the research is to analyze a feasibility of rapid evaluation method for cement fineness by the relation analysis between density measurement using hydrometer and fineness of ordinary Portland cement. Additionally, based on the commercially available cement product, relation between a series of fundamental properties of cement mortar and fineness of cement powder was analyzed. As an experimental result, the actually measured fineness value of cement powder showed a good correlation with the fineness value obtained by hydrometer while there was poor correlation with the fineness value on specification. Especially, the density measurement in three minutes showed the closest relation with cement powder fineness, thus rapid quality evaluation of cement powder can be possible by using the regression equation obtained from the three minutes density measurement. Additionally, there was a high relation between cement powder fineness with a fundamental properties of the cement mortar such as fluidity, air content, setting time, and strength development.

• Journal of the Korean Ceramic Society
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• v.42 no.11 s.282
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• pp.737-742
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• 2005

Rheological properties of ordinary portland cement (OPC) containing metakaoline (MK), granulated blast furnace slag (GBS) and polycarboxylate type superplasticizer (PCA) were investigated using a mini-slump test, sedimentation test and viscometer. Fluidity of cement pastes containing MK (OPC-MK, OPC-MK-GBS systems) with PCA were higher than those of the cement pastes without MK(OPC, OPC-GBS systems). Colloid suspensions with $0.1\%$ PCA were changed from stable sedimentation behaviors to flocculation behaviors in the OPC-MK, OPC-GBS and OPC-MK-GBS systems. The colloid suspensions showed stable sedimentation behaviors with PCA greater than $0.2\%$. The OPC system showed shear thinning behavior. However, the other systems showed weak shear thinning behaviors with PCA. Rheological properties of cement pastes were improved when MK and GBS were contained together. The rheological properties of OPC-MK, OPC-GBS and OPC-MK-GBS systems were improved by PCA added greater than $0.2\%$.

• Journal of the Korean Ceramic Society
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• v.51 no.2
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• pp.82-87
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• 2014

Due to the revised Korean standard KS L 5201 for Ordinary Portland Cement (OPC), the use of mixed cement has grown from 5% to 10%. This study investigates the hydration behavior of $C_3A$, asit is a cement mixture that is more commonly used than granulated blast furnace slag or limestone alone. Paste samples were prepared with either granulated blast furnace slag or limestone alone. Each sample was compared with the widely used Rietveld method with a cement mixture containing blast furnace slag or limestone. The hydration behavior of $C_3A$ in each OPC sample was assessed and results were analyzed. Granulated blast furnace slag promotes a high initial level of ettringite, but as the days passed, it promotes an increase in monosulfate, leading to cracks and expansion due to the penetration of sulfates in the solution. However, when limestone is added to the mixture, a transformation of ettringite to monosulfate occurs in the presence of the $CaCO_3$ in the limestone. It is considered that this produces hemi-carbonate and mono-carbonate and thus maintains the ettringite level.

• Journal of the Korean GEO-environmental Society
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• v.25 no.5
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• pp.15-19
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• 2024

This study aimed to develop high-efficiency grouting techniques under deep-depth conditions by experimentally verifying the applicability of various injection materials. Particle size analysis and injection model experiments were conducted with Ordinary Portland Cement (OPC) and Micro Cement (MC) to evaluate the injection performance of each material. Using Barton's Cubic Network theory, the rock fracture spacing was calculated for domestic deep-depth standards, specifically below 40 meters underground. The analysis of particle size passability under selected conditions showed that MC could pass through the rock fracture gaps, while OPC could not. According to the results of the injection model experiments using experimental devices and area calculation software, OPC failed in injection due to its larger particle size, whereas MC was capable of injection even under high-viscosity conditions. Based on these findings, the study quantitatively and visually derived the applicability of grouting materials under deep-depth conditions, and high-viscosity MC material is expected to be effective for waterproofing enhancement in deep-depth rock fracture surfaces.

• Journal of Urban Science
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• v.11 no.1
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• pp.21-28
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• 2022

Raman spectroscopy is effective to investigate functional groups via molecular vibration. The technique offers the structural information of compounds including subtle changes in the chemical composition of local atomic coordination without critical damage. Thus, the effect of carbonation on the hydration characteristics of Portland cement under pre-curing conditions for carbonation was investigated via Raman spectroscopy in the present study. Gaseous CO₂ was injected within 60 seconds, and the reaction time was varied from 0 minute to 90 minutes. The test results indicated that the Ca/Si ratio of C-S-H reduced immediately after mixing and then the C-S-H with a relatively high Ca/Si ratio coexisted as the reaction time increased. The calcium carbonates formed in the present study included calcite and amorphous calcium carbonates. The test results via Raman spectroscopy provide valuable information about the carbonation characteristics of OPC under pre-curing conditions for carbonation.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.04a
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• pp.184-185
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• 2022

This study researched the effect of graphene nanoribbons (0.05 wt%) on cement-based materials' mechanical and electrical properties. The results were compared with the ordinary Portland cement (OPC) paste and OPC paste with the same content of carbon nanotubes. The experiment results showed that after curing for 28 days, the compressive and splitting tensile strength of the sample with graphene nanoribbons were increased by 17.8% and 6.6% compared to OPC paste, and its reinforced effect for cement-based materials was superior to carbon nanotubes. Besides, due to the excellent electrical properties of graphene nanoribbons, the sample reinforced by graphene nanoribbons had a lower electrical resistivity (135.5 Ω·m) than OPC paste (418.5 Ω·m) and paste with carbon nanotubes (175.5 Ω·m). This proved the promising application of graphene nanoribbons on cement-based materials.

• Journal of the Korean Ceramic Society
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• v.36 no.5
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• pp.539-546
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• 1999

Absorbent polymer-cement composites were fabricated by the semi-powder mixing OPC(ordinary Portland cement) with an absorbent polymer. The effects of absorbent polymer on the mechanical properties and the hydration characteristics were observed and the polymer-cement interaction also discussed. Absorbent polymer-cement composites showed the value of total porosity of 8vol% the value of 28 days flexural strength was up to 280 Kgf/cm2 in the case of absorbent polymer-cement composite at 1 wt% absorbent polymer content and microstructure of absorbent polymer-cement composite has been observed more dense than that of OPC paste. Accordingly the permeability of compositewas improved and so the moisture resistance was also increased. Adding polymer did not retard the hydration of OPC. It was considered from the results of IR(infrared) analysis that the functional group of absorbent polymer would be changed from unidentate to bidentate during by the hydration of cement minerals.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.217-220
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• 2001

Due to the tendency of increase in demolished-concrete produced by alteration and deterioration of concrete structures, recycling of those demolished-concrete is necessary to solve the exhaustion of natural aggregate, in order to save resources and protect environment, especially being want of resources in Korea. For this purpose, concrete made with the pozzolanic cement and recycled aggregate was tested for compressive and tensile strength. The pozzolanic cement was a mixture of OPC(Ordinary Portland Cement) and pozzolans such as fly ash, other siliceous materials and early rapid hardening cement(ERC). It was found that the compressive strength of the pozzolanic cement was enhanced when 0.75% of ERC was dozed, as compared with OPC mortar. It was also shown that compressive and tensile strength of concrete with recycled aggregate and pozzolanic cement were higher than those of concrete with crushed stones and OPC. It was concluded that the pozzolanic cement influenced on the increase of concrete strengths with recycled aggregate.

• Journal of the Korean Ceramic Society
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• v.55 no.3
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• pp.224-229
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• 2018

OPC production requires high calorific value and emits a large amount of $CO_2$ through decarbonation of limestone, accounting for about 7% of $CO_2$ emissions. To reduce $CO_2$ emissions during the Ordinary Portland Cement (OPC) production process, there is a method of reducing the consumption of cement or lower temperature calcination for OPC product. In this study, for energy consumption reduction, we prepared Hauyne-belite cement by calcination at a low temperature compared to that used for OPC and studied the early hydration properties of the synthesized Hauyne-belite cement. We set the ratios of Hauyne and belite to 8 : 2, 5 : 5 and 3 : 7. For the hydration properties of the synthesized Hauyne-belite cement, we tested heat of hydration of paste and the compressive strength of mortar, using XRD and SEM for analysis of hydrates. As for our results, the temperature for optimum synthesis of Hauyne-belite is $1,250^{\circ}C$. Compressive strength of synthesized Hauyne-belite cement is lower than that of OPC, but it is confirmed that compressive strength of synthesized Hauyne-belite cement with mixing in of some other materials can be similar to that of OPC.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2016.10a
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• pp.100-101
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• 2016

The fineness degree of Ordinary Portland Cement (OPC henceforth) usually used in Korea's construction sites, is designated as over 2,800㎠/g. But the higher the fineness, the surface area of hydration reaction on water increases as well, resulting in large early age strength and high-intensity; so the trend is to prefer a high degree of fineness. But from a pore-space filling perspective, fine-particled cement is not always beneficial to intensity. Therefore in this study artificial modifications were given to cement fineness to analyze the effect of various fineness changes on the liquidity, air quantity and intensity of lean mixture cement mortar. As a result, the greater the degree of fineness, the better the cement was, with fine particle+OPC having the most satisfactory results due to consecutive particle distribution.