• Title/Summary/Keyword: ordering temperature

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Nano-structure and Magnetic Properties of FePd Superlattice Thin Film (FePd 인공격자박막의 나노구조 및 자기적 특성)

  • Kang, J.G.;Chung, I.S.;Koo, J.W.;Koh, J.H.;Koo, S.M.;Nam, S.M.;Ha, J.G.
    • Journal of the Korean Magnetics Society
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    • v.18 no.5
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    • pp.190-194
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    • 2008
  • Epitaxial $L1_0$ FePd (001) thin films were successfully manufactured by sputtering deposition method. The structure and magnetic properties of FePd thin films were characterized as a function of Fe compositions. It was found that the long-range ordering parameter had a maximum for the stoichiometric composition, whereas the magnetic anisotropy had a maximum as the Fe content is decreased to slightly above the stoichiometric composition. This indicates that the stoichiometry is directly contributed to the chemical ordering and the magnetic anisotropy. These results imply that nonstoichiometric FePd compositions, with a slight excess of Pd, may in fact be preferred for applications that require high magnetic anisotropy.

The Mossbauer Spectra Changes Due to the Jahn-Teller Distortion in Sulphur Spinel $Co_{0.95}Fe_{0.05}Cr_2S_4$ (유화 Spinel $Co_{0.95}Fe_{0.05}Cr_2S_4$에서 Jahn - Teller Distortion에 의한 Mossbauer 공명 흡수선의 변화에 관한 연구)

  • 서정철;이민용;고영복
    • Journal of the Korean Magnetics Society
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    • v.7 no.5
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    • pp.225-231
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    • 1997
  • Sulphur Spinel $Co_{0.95}Fe_{0.05}Cr_2S_4$ has been studied with Mossbauer Spectroscopy between 4.2 K and room temperature. The $Fe^{2+}$ ion in a tetrahedral site is the Jahn-Teller active and the dynamic Jahn-Teller distortion starts below the magnetic ordering temperature. The distortion cause a quadrupole shift to appear which increases with decreasing temperature. The magnetic hyperfine field has a maximum at 100 k and then decreases with decreasing temperature. The magnitude of the interaction ratio R between the electric quadrupole and magnetic dipole interaction increases from 0 near the magnetic ordering temperature to 5.4 at 4.2 K. The optimum values of 0, the polar angle of the magnetic hyperfine field with respect to the principle axis of the electric field gradient (EFG) remains zero and the asymmetry of the EFG n is about 0.25. The simulations of Mossbauer spectra coincidence with the experimental results.

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A Report on the ESR and Magnetic Structure of BixCa1-xMnO3 (x=0.15, 0.22)

  • Na, S.H.;Kim, J.W.;Choi, S.N.;Park, J.W.
    • Journal of Magnetics
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    • v.11 no.2
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    • pp.95-97
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    • 2006
  • The electron spin resonance signals of $Bi_xCa_{1-x}MnO_3$ have been acquired for two samples of x=0.15 and 0.22. ESR signal of the sample of x=0.15 clearly shows signal shape change into Dysonian with g-value shift at around 165 K so that the charge ordering temperature can be identified. The general features of ESR signal of the two samples well correlate with magnetic susceptibility measurement and also confirm the validity of former investigations.

Magnetic Ordering in (1-x)BaTiO3-xLaFeO3 Solid Solutions

  • Rajagukguk, R.;Shin, D.G.;Lee, B.W.
    • Journal of Magnetics
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    • v.16 no.2
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    • pp.101-103
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    • 2011
  • Solid solutions between $BaTiO_3$ and $LaFeO_3$ have been prepared through a solid state reaction method. The X-ray diffraction results reveal that $Ba_{1-x}La_xTi_{1-x}Fe_xO_3$ ($0.1\;{\leq}\;x\;{\leq}\;0.7$) compounds have a cubic structure, whereas the parent material $BaTiO_3$ has a tetragonal structure. The magnetization measurements indicate that the materials have a magnetic ordering at room temperature and the magnetic properties of the solid solutions depending on the doping amount of $LaFeO_3$. The origin of magnetic behaviors is believed to be from $Fe^{3+}$ ions.

Construction of the Reliable Quick Response System of Chinese Fashion Distribution (중국 패션유통업의 신뢰성 있는 신속대응형 시스템 구축)

  • Lian Ren-Chun;Lee Chang-Ho
    • Journal of the Korea Safety Management & Science
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    • v.7 no.5
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    • pp.233-241
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    • 2005
  • The most important thing in the garments enterprises is fast reaction. Expecially in the China has both many population and large territory, so each region of China, for instance, northeast, northwest, huanan, huabei, has various climate and considerably different temperature. As a result China garments enterprises require different clothes at the same time. This study build a reliable market-response process as a sub module of SCM that lay emphasis on production and sale cope with specific character of China. This process build a information chain including manufacture-planning, manufacture-ordering, production, arrivals of goods, distribution, sale, sale-evaluation, cross shipment, supplement shipment, and ordering popular goods and similar products. As a result of those, the focused points of this process are real time data gathering and various analysis of data, so it can be possible supporting more faster and more accurate market decision making system and our proposed goal is accomplishment of management profit.

Two-dimensional Supramolecular Ordering via Hydrogen and Halogen Bondings

  • Yoon, Jong-Keon;Kim, Ho-Won;Jeon, Jeong-Heum;Kahng, Se-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.11-11
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    • 2010
  • Supramolecualr ordering has been actively studied due to it's possible applications to the fabrication processes of nano-electronic devices. Van der Waals interaction and hydrogen bonding are frequently studied mechanisms for various molecular structures based on non-uniform charge distributions. Halogen atoms in molecules can have electrostatic interactions with similar strength. Big halogen atoms have strong non-uniform charge distributions. To study molecular orderings formed by hydrogen and halogen interactions, we chose a molecular system containing oxygen, hydrogen, and bromine atoms, a bromo-quinone. A two-dimensional molecular network was studied on Au(111) using a low-temperature scanning tunneling microscope. Bromo-quinonemolecules form self-assembled square grids having windmill structures. Their molecular orderings, chiral structures, and defects are explained in terms of hydrogen and halogen interactions.

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Synthesis, Crystal Structure, and Magnetic Properties of $RbV_2SeO_7$ as Compared with $KV_2SeO_7$

  • 김윤현;권영욱;이규석
    • Bulletin of the Korean Chemical Society
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    • v.17 no.12
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    • pp.1123-1127
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    • 1996
  • Crystalline compound RbV2SeO7, a Rb analogue of KV2SeO7, was synthesized from a hydrothermal reaction of V2O5, V2O3, SeO2, and Rb2CO3 in the mole ratio 3: 1: 15: 6 (in millimoles) at 230℃. RbV2SeO7 crystallizes in an orthorhombic space group Pnma (No. 62) with a=18.444(8), b=5.415(3), c=7.070(4) Å, Z=8. The two structures of KV2SeO7 and RbV2SeO7 are almost the same except that bond lengths in the latter are slightly longer than in the former. The magnetic susceptibility measurement for RbV2SeO7 in the temperature range 4-300 K showed an antiferromagnetic ordering with TN=45 K, higher than that for KV2SeO7 of 27 K. The origin of the magnetic coupling and the different ordering temperatures in the two phases are discussed in relation to the crystal structures.

Emission of Spin-polarized Light in Nitride-based Spin LEDs with Room-temperature Ferromagnetic (Ga,Mn)N Layer (상온 강자성 (Ga,Mn)N 박막을 이용한 질화물계 스핀 발광소자의 스핀편극된 빛의 발광)

  • Ham, Moon-Ho;Myoung, Jae-Min
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.11
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    • pp.1056-1060
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    • 2005
  • We investigated the fabrication and characteristics of the nitride-based spin-polarized LEDs with room-temperature ferromagnetic (Ga,Mn)N layer as a spin injection source. The (Ga,Mn)N thin films having room-temperature ferromagnetic ordering were found to exhibit the negative MR and anomalous Hall resistance up to room temperature, revealing the existence of spin-polarized electrons in (Ga,Mn)N films at room temperature. The electrical characteristics in the spin LEDs did not degraded in spite of the insertion of the (Ga,Mn)N layer into the LED structure. In EL spectra of the spin LEDs, it is confirmed that the devices produce intense EL emission at 7 K as well as room temperature. These results are expected to open up new opportunities to realize room-temperature operating semiconductor spintronic devices.

Structural Properties of $Ba(Zn_{1/3}Ta_{2/3})O_3$[BZT] Ceramics with Sintering Temperature (소결온도에 따른 $Ba(Zn_{1/3}Ta_{2/3})O_3$[BZT] 세라믹스의 구조적 특성)

  • Lee, Sang-Chul;Kim, Ji-Hoon;Kim, Kang;Lee, Sung-Gap;Lee, Young-Hie
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04b
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    • pp.76-79
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    • 2000
  • The $Ba(Zn_{1/3}Ta_{2/3})O_3$ ceramics were prepared by conventional mixed oxide method. The structural properties of the BZT ceramics with the sintering temperature were investigated by XRD, SEM. The BZT ceramics have a complex-perovskite structure. The BZT ceramics sintered at $1550^{\circ}C$ had a superstructure plane of BZT(100). Increasing the sintering temperature, the bulk density and ordering were increased. The bulk density of the BZT ceramics sintered at $1550^{\circ}C$ was $7.50[g/cm^3]$. Increasing the sintering temperature, the average grain size were increased and pore were decreased.

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Relaxation Characteristic of the Disordered Lead Scandium Niobate

  • Kim, Yeon Jung
    • Applied Science and Convergence Technology
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    • v.24 no.3
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    • pp.47-52
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    • 2015
  • The correlation between admittance and dielectric spectroscopy of dielectric relaxation in lead scandium noibate, have been investigated. Lead scandium niobate, with composition $PbSc_{0.5}Nb_{0.5}O_3$, was prepared by conventional solid state synthesis. Conductance Y'(G), susceptance Y"(B) and capacitance C of lead scandium niobate as a function of frequency and temperature were measured. From the temperature-dependence of RLC circuit, insight into physical significance of the dielectric properties of lead scandium niobate is obtained. The relative strong frequency dependent of dielectric properties in lead scandium niobate is observed, and the phase transition occurred at a broad temperature region. Also, the value of critical exponent ${\gamma}$=1.6 showed on heating process. The long relaxation times part enlarged diffuse by conductivity effects with increasing temperature, and the ordering between $Sc^{3+}$ and $Nb^{5+}$ in PSN influences complex admittance and dielectric properties. Confirmed the typical characteristic of lead-type relaxor in the Raman spectra of lead scandium niobate and major ranges are between 400 and $900cm^{-1}$.