• 대한화학회지
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• 제34권4호
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• pp.331-339
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• 1990

cis-diamminedichloroplatinum (II)에서 아민리간드가 변화할 때, 항암성과 백금원자의 전자구조 사이의 관계를 연구하였고, 또 이러한 착물과 DNA base인 1-methylcytosine의 상호작용에 대한 메카니즘을 알기 위해서 백금(II)착물들을 분자궤도함수론적으로 연구하였다. 그 결과, 백금착물에서 중심금속의 atomic charge가 항암성에 영향을 미치고 있음을 알았다. 또한 백금착물과 1-methylcytosine의 결합은 리간드에서 금속원자로 전하이동을 하였고, 이 때 Pt(II)의 6p-orbital이 중요한 하고 있음을 발견한다. Pt-N3결합성은 $\alpha$ 와 $\pi$ 성분을 포함하고 있으며, 실험한 값과 비교할 때 비교할 때 항암성이 큰 백금착물일수록 Pt-N3 결합이 강하게 형성하고 있었다.

• 산업경영시스템학회지
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• 제39권1호
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• pp.98-104
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• 2016

With the development of modern science and technology, weapon systems such as tanks, submarines, combat planes, radar are also dramatically advanced. Among these weapon systems, the ballistic missile, one of the asymmetric forces, could be considered as a very economical means to attack the core facilities of the other country in order to achieve the strategic goals of the country during the war. Because of the current ballistic missile threat from the North Korea, establishing a missile defense (MD) system becomes one of the major national defense issues. This study focused on the optimization of air defense artillery units' deployment for effective ballistic missile defense. To optimize the deployment of the units, firstly this study examined the possibility of defense, according to the presence of orbital coordinates of ballistic missiles in the limited defense range of air defense artillery units. This constraint on the defense range is originated from the characteristics of anti-ballistic missiles (ABMs) such as PATRIOT. Secondly, this study proposed the optimized mathematical model considering the total covering problem of binary integer programming, as an optimal deployment of air defense artillery units for defending every core defense facility with the least number of such units. Finally, numerical experiments were conducted to show how the suggested approach works. Assuming the current state of the Korean peninsula, the study arbitrarily set ballistic missile bases of the North Korea and core defense facilities of the South Korea. Under these conditions, numerical experiments were executed by utilizing MATLAB R2010a of the MathWorks, Inc.

• 한국발생생물학회지:발생과생식
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• 제20권2호
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• pp.65-79
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• 2016

We observed the osteological development of larval and juvenile red spotted grouper (Epinephelus akaara) in order to generate data for the assessment of skeletal deformities and to inform phylogenetic systematics research. Larvae and juveniles were obtained from a aquafarm in Muan-gun, Jeolla-namdo Province, Korea. The average water temperature at the time of breeding was $23.0^{\circ}C$ and average water salinity was 33.0 psu. Freshly hatched fish larvae had not undergone any ossification, but ossification of the parasphenoid bone, which forms the base of the cranium, occurred as the juveniles reached an average body length (BL) of 2.49 mm. At the same time, ossification of the preopercle and opercle occurred in the operculum, and ossification of the maxilla, which forms the upper jaw, and the dentary bones, which form the lower jaw, began. In addition, ossification of the vertebra occurred by formation of 7 vertebral centra and the neural spine in the abdominal vertebra. When the juveniles reached an average (BL) of 5.22 mm, ossification of the nasal, lateral ethmoid, and alisphenoid bones occurred in the cranium; ossification of the endopterygoid and metapterygoid bones began in the palatine region; and ossification of the hypohyal and interhyal bones occurred in the hyoid arch. At an average (BL) of 20.9 mm, ossification of the basisphenoid bone in the cranium and the suborbital bone in the orbital region occurred. Ossification of the vertebra then occurred by the formation of long pairs of ribs from the third to the ninth abdominal vertebrae, completing osteological development.

• 천문학회보
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• 제35권2호
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• pp.65.2-65.2
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• 2010

We present four new transits of the planetary system TrES-3 observed between 2009 May and 2010 June. Among those, the third transit by itself indicates possible evidence for brightness disturbance, which could originate from a starspot or an overlapping double transit. A total of 107 transit times, including our measurements, were used to determine the improved ephemeris with a transit epoch of $2454185.910950\pm0.000073$ HJED (Heliocentric Julian Ephemeris Date) and an orbital period of $1.30618698\pm0.00000016$ d. We analyzed the transit light curves using the JKTEBOP code and adopting the quadratic limb-darkening law. In order to derive the physical properties of the TrES-3 system, the transit parameters are combined with the empirical relations from eclipsing binary stars and stellar evolutionary models, respectively. The stellar mass and radius obtained from a calibration using $T_{eff}$, log $\rho$ and [Fe/H] are in good agreement with those from the isochrone analysis within the uncertainties. We found that the exoplanet TrES-3b has a mass of $1.93\pm0.07\;M_{Jup}$, a radius of $1.30\pm0.04\;R_{Jup}$, a surface gravity of $28.2\pm1.1\;m\;s^{-1}$, a density of $0.82\pm0.06\;\rho_{Jup}$, and an equilibrium temperature of $1641\pm23K$.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.432.2-432.2
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• 2014

Recently, colloidal core/shell type quantum dots lighting-emitting diodes (QDLEDs) have been extensively studied and developed for the future of optoelectronic applications. In the work, we fabricate an inverted CdSe/ZnS quantum dot (QD) based light-emitting diodes (QDLED)[1]. In order to reduce work function of indium tin oxide (ITO) electrode for inverted structure, a very thin (<10 nm) polyethylenimine ethoxylated (PEIE) is used as surface modifier[2] instead of conventional metal oxide electron injection layer. The PEIE layer substantially reduces the work function of ITO electrodes which is estimated to be 3.08 eV by ultraviolet photoemission spectroscopy (UPS). From transmission electron microscopy (TEM) study, CdSe/ZnS QDs are uniformly distributed and formed by a monolayer on PEIE layer. In this inverted QD LED, two kinds of hybrid organic materials, [poly (9,9-di-n-octyl-fluorene-alt-benzothiadiazolo)(F8BT) + poly(N,N'-bis (4-butylphenyl)-N,N'-bis(phenyl)benzidine (poly-TPD)] and [4,4'-N,N'-dicarbazole-biphenyl (CBP) + poly-TPD], were adopted as hole transport layer having high highest occupied molecular orbital (HOMO) level for improving hole transport ability. At a low-operating voltage of 8 V, the device emits orange and red spectral radiation with high brightness up to 2450 and 1420 cd/m2, and luminance efficacy of 1.4 cd/A and 0.89 cd/A, respectively, at 7 V applied bias. Also, the carrier transport mechanisms for the QD LEDs are described by using several models to fit the experimental I-V data.

• 한국통신학회논문지
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• 제35권9C호
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• pp.729-734
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• 2010

지상국과 위성트랜스폰더 사이의 통신의 초기 단계에서 궤도 운행 중인 위성과 지상국과의 도플러 효과에 의한 주파수 편이와 신호의 상태의 파악을 위해 지상국에서는 변조되지 않은 상향링크 반송파(up-link carrier) 신호의 주파수를 일정한 범위와 속도로 sweeping하며 송신한다. 위성트랜스폰더는 수신된 상향링크 반송파를 획득(acquisition) 및 추적(tracking)하며, 그 상태를 지상국에 송신하여 지상국과의 통신을 초기화 하게 된다. 이러한 과정의 제어를 위해서 위성 수신부는 수신된 반송파 신호에 대한 다양한 분석이 필요하다. 본 논문에서는 위성트랜스폰더의 반송파 복원 루프 상태와 상향링크 신호 상태를 확인하고, 수신부 동작의 제어를 위해 사용할 수 있는 SNR 추정 알고리즘을 제안하고, 이에 따른 수신부 동작 제어 방안을 제시하였다. 제안된 알고리즘은 수신된 상향링크 반송파를 기저대역 극좌표계로 변환하여 각성분만의 통계로부터 SNR을 추정하고, 수신부 제어에 필요한 상태 변수를 파악하므로, AGC(Auto Gain Controller) 정보를 이용하여 신호의 상태를 파악하는 기존의 아날로그 방식에 비해 매우 간단히 구현될 수 있다. 제안된 SNR 추정 및 제어 상태 추출 결과는 모의실험을 통해 그 유효성을 입증하였다.

• Journal of Trauma and Injury
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• 제22권1호
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• pp.18-23
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• 2009

Purpose: In this study, we retrospectively investigated the medical records of patients with facial fractures and suspected cranial injuries in order to determine if there was any relationship between various facial fracture patterns and cranial injuries. Methods: Medical records were reviewed to identify patients diagnosed with facial fractures who underwent cranial computed tomography (CT) scans. Records were reviewed for gender, age, injury mechanism, facial fracture pattern, and presence or absence of cranial injuries. Facial fracture patterns were classified as isolated fractures (tripod, zygomatic arch, maxilla, orbit, and mandible), combined fractures, or total fractures. Cranial injuries included skull fractures, traumatic subarachnoid hemorrhages, subdural hemorrhages, epidural hemorrhages, and contusional hemorrhages. All cranial injuries were established by using cranial CT scans, and these kinds of cranial injuries were defined radiologically-proven cranial injuries (RPCIs). We evaluated the relationship between each pattern of facial fractures and the incidence of RPCIs. Results: Of 132 eligible patients with facial fractures who underwent cranial CT scans, a total of 27 (20.5%) patients had RPCIs associated with facial fractures. Falls and slips were the most common causes of the fractures (31.8%), followed by assaults and motor vehicle accidents (MVAs). One hundred one (76.5%) patients had isolated facial fractures, and 31 (23.5%) patients had combined facial fractures. Fractures were found most commonly in the orbital and maxillary bones. Patients with isolated maxillary fractures had a lower incidence of RPCIs than those with total mandibular fractures. RPCIs frequently accompanied combined facial fractures. Conclusion: Combined facial fractures had a significant positive correlation with RPCIs. This means that facial fractures caused by stronger or multidirectional external force are likely to be accompanied by cranial injuries.

• Applied Biological Chemistry
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• 제32권2호
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• pp.170-177
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• 1989

2개의 m-methyl group이 치환된 m-xylyl N-methylcarbamates(MXNMC)가 비치환된 phenyl N-methylcarbamates(PNMC)보다 높은 살충작용을 나타내는 이유를 알아보기 위하여 이들 두 유도체들이 확장 $H\ddot{u}ckel$(EHT) 이론에 따른 분자궤도(MO) 이론과 회귀 및 자유에너지 관계(LFER) 분석에 의하여 연구되었다. 가장 안정한 입체구조는 phenyl group이 N-methylcarbamyl group의 면에 대하여 수직(${\theta}=90^{\circ}$)인 형태(Z,Z)이었으며, 회귀분석은 $pI_{50}$ 상수들과 meta-위치 및 m-methyl group의 수소원자 하전과 LUMO에너지의 계산된 MO량을 변수로 취했을 경우가 가장 좋은 상관관계를 나타내었다. Carbamylation 반응에 관한 LFER분석 결과, PNMC에서는 공명(R)-효과(40%)보다 장 (F) 효과(60%)가 약간 컸으나(F>R), MXNMC의 경우에는 R-효과(98.6%)가 F-효과(1.4%)보다 월등히 큰 값($R{\gg}F$)을 보였다. 이와 같은 사실로부터 MXNMC의 살충작용이 증진되는 것은 m-dimethyl group에 의한 hyperconjugation의 결과라고 믿어진다.

• 한국표면공학회지
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• 제53권3호
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• pp.124-129
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• 2020

This study is for the development of high temperature ALD SiO₂ film process, optimized for gap-fill process in manufacturing memory products, using a space-divided PE-ALD system equipped with an independent control dual plasma system and orbital moving unit. Space divided PE-ALD System has high productivity, and various applications can be applied according to Top Lid Design. But space divided ALD system has a limitation to realize concentric deposition map due to process influence due to disk rotation. In order to solve this problem, we developed an orbit rotation moving unit in which disk and wafer. Also we used Independent dual plasma system to enhance thin film properties. Improve productivity and film density for gap-fill process by having deposition and surface treatment in one cycle. Optimize deposition process for gap-fill patterns with different depths by utilizing our independently controlled dual plasma system to insert N₂and/or He plasma during surface treatment, Provide void-free gap-fill process for high aspect ratio gap-fill patterns (up to 50:1) with convex curvature by adjusting deposition and surface treatment recipe in a cycle.

• 천문학회보
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• 제36권2호
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• pp.141.1-141.1
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• 2011

New CCD BVR light curves of BD And are presented. Our light curves with nearly equal depths for both primary and secondary eclipses show well-defined photometric waves outside eclipse for all of BVR bandpasses. The orbital period is greatly revised as $0.^d92580519$ which is twice longer than that known previously. Sixteen timings from our observations and thirteen ones from the SuperWASP measurements were calculated. All available timings over 76 years, including ours, were analyzed to figure out the dynamical behavior of the system. It was found that the recent CCD O-C residuals varied in a cyclical way with a period of $9.^y18$ and a semi-amplitude of $0.^d0046$. The secondary period of $9.^y18$ is the most shortest one among those which have been ever found in the short period RS CVn binary stars. The periodic variation most likely arises from the light-travel time effect due to a low-mass ($m_3{\sim}0.88\;M_{\odot}$) tertiary companion moving in an orbit with an large eccentricity ($e_3$=0.70) and a low inclination ($i_3{\sim}28^{\circ}$). The Applegate mechanism could not operate properly in both components because the model parameters require too much large luminosity changes of ${\Delta}L/L_{p,s}$ > 10. The new light curves were synthesized using the 2003 version of Wilson-Divinney code. It was found useful to model two huge spots on the surface of the hotter star and a third-light in order to minimize the residuals from the observations. Astronomical basic parameters were deduced from our photometric solution.