• Title/Summary/Keyword: optimum pressure

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Growth of Large Area BSTO Thin Films using Pulsed Laser Deposition (펄스레이저 증착법을 이용한 대면적 BSTO 박막의 성장)

  • Kang, Dae-Won;Kwak, Min-Hwan;Kang, Seong-Beom;Paek, Mun-Cheol;Choi, Sang-Kuk;Kim, Sung-Il;Ryu, Han-Cheol;Kim, Ji-Seon;Jeong, Se-Young;Chung, Dong-Chul;Kang, Kwang-Yong;Lee, Beong-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.249-249
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    • 2009
  • We have grown large area BSTO($(Ba_{1-x}Sr_x)TiO_3$) thin films (x=0.4) on 2 inch diameter MgO (001) single crystal substrates using a pulse laser deposition(PLD) system. Substrate temperature and oxygen pressure in the deposition chamber, and the laser optics for ablating a target have been controlled to obtain the uniform thickness and preferred orientation of the films. Results of x-ray diffraction and rocking curve analysis revealed that the BSTO films were grown on MgO substrates with a preferred orientation (002), and the full width half maximum of the rocking curve was measured to be 0.86 degree at optimum condition. Roughness of the films have been measured to be $3.42{\AA}$ rms by using atomic force microscopy. We have successfully deposited the large area BSTO thin films of $4000{\AA}$ thickness on 50 mm diameter MgO substrates.

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Preparation of Porous K2Ti6O13 Whisker Preform by Spark Plasma Sintering (방전 플라즈마 소결법에 의한 다공성 육티탄산 칼륨 휘스커 프리폼의 제조)

  • Lee, Chang-Hun;Cho, Dong-Choul;Cho, Won-Seung;Lee, Chi-Hwan
    • Journal of the Korean Ceramic Society
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    • v.39 no.12
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    • pp.1197-1202
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    • 2002
  • In order to develope the porous $K_2Ti_6O_13$ whisker preform with good strength, the pore characteristics and compressive strength were investigated as a function of spark plasma sintering temperature. As a result, high porous whisker preform were successfully fabricated by sintering at 900∼950${\circ}C$ for 10 min under a pressure of 40 MPa, heating rate of 50${\circ}C$/min and on-off pulse type of 12:2. The whisker preform prepared under above optimum condition showed relatively high compressive strength of 174∼266 MPa, despite of high porosity ranging from 15% to 37%. This improvement in strength was considered to be mainly due to the spark-plasma discharges and the self-heating action between whiskers. The compressive strength of whisker preform, fabricated at sintering temperature less than 900${\circ}C$, showed 80∼100 MPa. This is low strength level less than one half times compared with whisker preform fabricated at 900∼950${\circ}C$. The whisker preform fabricated at 1000${\circ}C$ showed the highest compressive strength of 523 MPa, but resulted in low porosity of ∼5%. Based on above results, it was considered that spark plasma sintering was an effective method for developing high strength and porosity of whisker preform.

Characterization to flammable gas $\alpha$-$Fa_{2}O_{3}/SnO_{2}$ system thin film fabricated by APCVD (APCVD법에 위해 제조된 $\alpha$-$Fa_{2}O_{3}/SnO_{2}$계 박막의 가연성 가스 감지 특성 평가)

  • 심성은;이세훈;최성철
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.2
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    • pp.105-110
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    • 2000
  • The $\alpha$-$Fa_{2}O_{3}/SnO_{2}$ thin film gas sensor was fabricated by APCVD and heat treated. The gas sensitivity to flammable gases ($CH_4$, $H_2$, LPG) was measured. This device was to heat treatment at $400^{\circ}C$, $450^{\circ}C$, $500^{\circ}C$, $550^{\circ}C$, $600^{\circ}C$ for 2 h to enhance the gas sensitivity. The heat treated device at $500^{\circ}C$ for 2 h had the best properties and especially it shows high sensitivity to H2 gas. The sensitivity to gases was studied in the temperature range from lOoC to $300^{\circ}C$ in order to find the optimum detection temperature. In the range of detection from 500 ppm to 10,000 ppm at $175^{\circ}C$ the fabricated device showed that the gas sensitivity to $H_2$ was from 62%~76% and to $CH_4$ was from 16 %~58% and to LPG was from 8%~37 %. The sensitivity difference between heat treated device and as fabricated one was about 10 8 The long-term stability to LPG at 1,000 ppm was converged to sensitivity of 30 %.

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A Study on Advance Rate under the Operating Conditions of EPB Shield TBM Based on TBM Operation Data (현장 굴진자료 분석에 의한 토압식 쉴드 TBM의 운전조건과 굴진속도 연구)

  • An, Man Sun;Lim, Kwang-Su;Kim, Kyong Ju
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.6D
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    • pp.839-848
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    • 2011
  • TBM (Tunnel Boring Machine) tunnel should be carry out with the adopted machine until the end of excavation because of impossibility of replacement or modification of machine. Observation of the face of the tunnel is difficult, especially in EPB(Earth Pressure Balance) shield TBM, predict changes in the ground condition with analyzing data, collected during the excavation, and it should be reflected in construction. Until recently, subjects of studies on TBM are mainly the determination of machine and the development of advance rate prediction model, according to the characteristics of ground which is the target of excavation. However, study focused on the estimation of ground conditions and the improvement in operational methods using excavation data of TBM equipment, the principal of the excavation, has been done not so much. This study examine the variances in advance rate depending on changes in operating conditions and evaluate the optimal operating conditions of adopt machine, using working data obtained from EPB shield TBM project. The result of this study is suggested as follows. First, cutter head RPM and total thrust force are biggest influences on advance rate, Second, it is recommended for proper advance rate that total thrust force is controlled while optimum cutter head RPM is kept, Third, according to the increasing trend of total thrust force, the changes in ground conditions can be predicted, the appropriate operating conditions can be determined.

Absorption Characteristics of Sulfur Dioxide in Jet Bubbling Reactor (가스분사반응기에서의 SO2 흡수 특성)

  • Choi, Byung-Sun;Park, Seung-Soo;Kim, Yung-whan
    • Applied Chemistry for Engineering
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    • v.5 no.5
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    • pp.836-842
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    • 1994
  • The optimum design conditions of gas sparger pipe and the effects of operating variables on $SO_2$ removal efficiency have been examined in Jet Bubbling Reactor. Geometry of gas sparser pipe of Jet Bubbling Reactor is a very important factor to obtain a effective gas-liquid contact. Test results revealed that Reynolds numbers at sparger and slot have to be kept greater than 12,000 identically at a given gas velocity. $SO_2$ removal efficiency was a function of ${\Delta}P$, pH, inlet $SO_2$ concentration and particle size of limestone and was more sensitive to the change of ${\Delta}P$ than to the changes of others. The ${\Delta}P$ of at least 230mmAq must be maintained to acheive the above 90% $SO_2$ removal at pH of 4.0 which is considered as adequate operating pH. Higher $SO_2$ removal efficiency was obtained even at lower pH ranges, which resulted from the complete oxidation of the absorbed $SO_2$ to sulfates by adding air and consequently from the reduction of $SO_2$ equillibrium partial pressure in the gas-liquid interface The 99.5% of the limestone utilization was attained in pH range from 3.0 to 5.0 with regardless to the particle size of limestone employed.

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The Performance Evaluation of Blended Fertilizers as Draw Solution in Forward Osmosis Desalination (유도용액으로 혼합비료를 사용한 정삼투식 해수담수화에서 혼합비료의 성능평가)

  • Kim, Seung-Geon;Lee, Ho-Won
    • Membrane Journal
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    • v.28 no.1
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    • pp.45-54
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    • 2018
  • This study is to find the optimum draw solution in fertilizer-drawn forward osmosis desalination. Considering osmotic pressure, solubility, and pH, 20 blended fertilizers were screened. Their performance were evaluated in terms of pure water permeate flux, reverse solute flux, and specific reverse solute flux for nitrogen, phosphorus, and potassium. The pure water permeate flux of blended fertilizers including KCl were relatively higher. The reverse solute flux and specific reverse solute flux for nitrogen of blended fertilizers containing ${NO_3}^-$ ion were relatively higher than those of the nitrate ion-free draw solution. Those for phosphorus, and potassium of blended fertilizers including $NH_4H_2PO_4$, and $KNO_3$ were relatively higher than those of the phosphorus-free, and potassium-free draw solution, respectively. The blended fertilizer of $NH_4H_2PO_4$ and KCl contains all of nitrogen, phosphorus and potassium which are essential elements of fertilizer, and has the relatively high water permeation flux and the low reverse solute flux for nitrogen, phosphorus, and potassium. Therefore, it is the most effective draw solution for fertilizer-drawn forward osmosis desalination.

Transpiration Modelling and Verification in Greenhouse Tomato (온실재배 토마토의 증산모델 개발 및 검증)

  • 이변우
    • Journal of Bio-Environment Control
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    • v.6 no.3
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    • pp.205-215
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    • 1997
  • An accurate transpiration model for greenhouse tomato crop, which is liable to transpiration depression and yield loss because of low solar radiation and high humidity, could be an efficient tool for the optimum control of greenhouse climate and for the optimization of Irrigation scheduling. The purpose of this study was to develop transpiration model of greenhouse tomato and to carry out the experimental verification. The formulas to calculate the canopy transpiration and temperature simultaneously were derived from the energy balance of canopy. Transpiration and microclimate variables such as net radiation, solar radiation, humidity, canopy and air temperature, etc. were simultaneously measured to estimate parameters of model equations and to verify the suggested model. Leaf boundary layer resistance was calculated as a function of Nusselt number and stomatal diffusive resistance was parameterized by solar radiation and leaf-air vapor pressure deficit. The equation for stomatal diffusive resistance could explain more than 80% of its variation and the calculated stomatal diffusive resistance showed good agreements with the measured values in situations independent of which the constants of the equation were estimated. The canopy net radiation calculated by Stanghellini's model with slight modification agreed well with the measured values. The present transpiration model, into which afore-mentioned component equations were assembled, was found to predict the canopy temperature, instantaneous and daily transpiration with considerable accuracy in greenhouse climates.

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Optimizing Cooking Condition of Short Grain Rice Containing Sea-tangle Patch (다시마밥 제조조건의 최적화)

  • Shin, Eun-Soo;Lee, Jin-Hwa;Park, Kyong-Tae;Ryu, Hong-Soo;Jang, Dae-Heung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.10
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    • pp.1726-1734
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    • 2004
  • Response surface methodology on sensory evaluation was used to optimize cooking condition of cooked short grain rice (CSR) and cooked short grain rice containing grainy sea-tangle patch (CSTR). Texture profile analysis and nutritional evaluation were also performed. For maximizing overall acceptability, it can be predicted sea-tangle patch 14%, added water 1.67 times of rice and sea-tangle amount and steeping time 47 min as optimum cooking conditions from sensory evaluation conducted by the forties panelist. Hardness of pressure cooked short grain rice containing grainy sea-tangle patch (CSTR) were lower than cooked short grain rice (CSR), but it showed similar as CSR in adhesiveness, chewiness and higher in springiness and cohesiveness. In addition CSTR was delayed retrogradation compared with CSR. The nutritional Quality of CSTR showed higher level in total dietary fiber, protein, ash than CSR, but lower in protein digestibility, C-PER, gelatinization degree compared with CSR.

Characteristics of Transparent Conductive Tin Oxide Thin Films on PET Substrate Prepared by ECR-MOCVD (PET 기판상에 ECR 화학증착법에 의해 제조된 SnO2 투명도전막의 특성)

  • Kim, Yun Seok;Jeon, Bup Ju;Ju, Jeh Beck;Sohn, Tae Won;Lee, Joong Kee
    • Korean Chemical Engineering Research
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    • v.43 no.1
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    • pp.85-91
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    • 2005
  • $SnO_2$ films were prepared at room temperature under a $(CH_3)_4Sn-H_2-O_2$ atmosphere in order to obtain transparent conductive polymer by using ECR-MOCVD (Electron Cyclotron resonance -Metal Organic Chemical Vapor Deposition) system. The electrical properties of the films were investigated as function of process parameters such as deposition time, microwave power, magnetic current power, magnet/showering/substrate distance and working pressure. An increase in microwave power and magnetic current power brought on $SnO_2$ film formation with low electric resistivity. On the other hand, the effects of process parameters described above on optical properties were insignificant in the range of our experimental scope. The transmittance and reflectance of the films prepared by the ECR-MOCVD exhibited their average values of 93-98% at wave length range of 380-780 nm and 0.1-0.5%, respectively. The grain size of the $SnO_2$ films that are also insensitive with the process parameters were in the range of 20-50 nm. On the basis of experimental data obtained in the present study, electrical resistivity of $7.5{\times}10^{-3}ohm{\cdot}cm$, transmittance of 93%, and reflectance of 0.2% can be taken as optimum values.

Determination of Water Retention Characteristics of Organic and Inorganic Substrates for Horticulture by European Standard Method (유럽표준배지분석법에 의한 원예용 유기·무기성 배지의 수분보유특성)

  • Kang, Ji-Young;Park, Soon-Nam;Lee, Hyun-Haeng;Kim, Kye-Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.37 no.2
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    • pp.55-58
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    • 2004
  • The objective of this study was to get information about water retention characteristics of horticultural substrates used in Korea determined by European standard method. Water retention curves were prepared at water volume (v/v, %) in relation to -10 cm, -50 cm, -100 cm water pressure head. Water retention curves showed different properties depending upon the type, the place of origin, particle size, and manufacturing processes of substrates. Peat and coir had easily available water content in the range of 30-40% and showed high water holding capacity, water buffering capacity, and aeration for plant growth. However, bark, sawdust and rice hull showed low water holding capacity about below 10%. The easily available water content of perlite and clay ball was low about 0.1-13.8%, whereas that of vermiculite and rockwool granulate was high about 25.9-52.0%. Understanding water retention characteristics of growing substrates is very important in cstablisliing optimum condition for plant growth. Further study on water retention curves for more substrates, mixture and growing media is needed.