• Title/Summary/Keyword: optimum dosage

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Research on the factors affecting the development of shrinkage cracks of rammed earth buildings

  • Zhao, Xiang;Cai, Hengli;Zhou, Tiegang;Liu, Ling;Ding, Yijie
    • Earthquakes and Structures
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    • v.20 no.4
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    • pp.365-375
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    • 2021
  • Rammed earth (RE) buildings have existed all over the world for thousands of years, and have gained increasing attention because of its sustainable advantages, however, the shrinkage cracks reduce its bearing capacity and seriously affect its durability and applicability. In this study, the shrinkage cracks test was carried out to investigate the effects of initial water content, proportion of sand and gravel, compaction degree, thickness and the additives (polypropylene fiber, cement and sodium silicate) of shrinkage cracks in RE buildings, ten groups of RE samples were prepared and dried outdoors to crack. Four quantitative parameters of geometrical structure of crack patterns were used to evaluate the development of cracks. The results show that the specimens cracking behavior and the geometrical structure of crack patterns are significantly influenced by these considered factors. The formation of crack can be accelerated with the increase of initial water content and thickness of specimen, while restricted with the increase of the compaction degree and the proportion of sand and gravel. Moreover, the addition of 1% polypropylene fiber, 10% cement and 0.5 volume ratio sodium silicate can significantly restrain the form and development of cracks. In RE construction, these factors should be considered comprehensively to prevent the harm caused by shrinkage cracks. Further works should be carried out to obtain the optimum dosage of the additives, which can benefit the construction of RE buildings in future.

Separation of cadmium and chromium heavy metals from industrial wastewater by using Ni-Zn nanoferrites

  • Thakur, Atul;Punia, Pinki;Dhar, Rakesh;Aggarwal, R.K.;Thakur, Preeti
    • Advances in nano research
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    • v.12 no.5
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    • pp.457-465
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    • 2022
  • The potentials of NixZn1-xFe2O4 (x = 0.0, 0.2, 0.4, 0.6, 0.8 and 1.0) nanoadsorbents were investigated for removal of Cd and Cr from contaminated water from an electroplating industry in Himachal Pradesh, India. Optimal values were recorded under batch adsorption experiments performed to remove dissolved heavy metal ions from industrial wastewater. The specific surface area (SSA) of nanoadsorbents perceived to vary in a range 35.75-45.29 cm2/g and was calculated from the XRD data. The influence of two operating parameters, contact time and dopant (Ni) concentration was also investigated at pH ~7 with optimum dosage. Kinetic studies were conducted within a time range of 2-10 min with rapid adsorption of cadmium and chromium ions onto Ni0.2Zn0.8Fe2O4 nanoadsorbents. Pseudo-second-order kinetic model was observed to be well fitted with the adsorption data that confirmed the only existence of chemisorption throughout the adsorption process. The maximum adsorption efficiency values observed for Cd and Cr were 51.4 mg/g and 40.12 mg/g, respectively for different compositions of prepared series of nanoadsorbents. The removal percentage of Cd and Cr was found to vary in a range of 47.7%-95.25% and 21%-50% respectively. The prepared series of nanoferrite found to be suitable enough for adsorption of both heavy metal ions.

Effect of the Gonadotropin-Releasing Hormone (GnRH) on Induction of Maturation in White-Spotted Bambooshark Chiloscyllium plagiosum (성 성숙 자극호르몬방출호르몬(GnRH) 투여를 이용한 백점얼룩상어 (Chiloscyllium plagiosum)의 성 성숙 유도에 관한 연구)

  • Ki-hyuk Kim;Ji-min Jeon;Hye-na Moon;Jin Namgung;In-kyu Yeo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.56 no.3
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    • pp.309-314
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    • 2023
  • Shark populations are constantly decreasing owing to environmental destruction and overfishing; thus, sharks are now at risk of extinction, with 30.5% of species classified as endangered on the International Union for Conservation of Nature's Red List. Sharks are apex predators and keystone species in balancing the marine food chain; their extinction would create an imbalance in the entire marine ecosystem. Assisted reproductive technology is a last resort for protecting animals facing extinction. Here, as a proactive effort toward building a hormone-induced artificial insemination protocol for endangered wild sharks, we identified the possibility of germ cell maturation by administration of GnRH, a commercially produced synthetic salmon gonadotropin-releasing hormone, and calculated its optimum dosage and injection timing. The experiment was conducted on one shark species, Chiloscyllium plagiosum. Injections were administered in 24 h intervals to C. plagiosum females, and 0.2 mL/kg+0.2 mL/kg were the optimal doses. These doses effectively induced maturation and, and ovulation, and oocyte release. Our results confirm that GnRH is a suitable tool for shark hormone-induced artificial insemination and indicate that this method may facilitate the conservation of endangered shark species.

Evaluation of Ozone Application for Drinking Water Treatment Process Using DAF (DAF를 이용한 정수처리 공정에서의 오존 적용성 평가)

  • Kang, Tae-Hee;Oh, Byung-Soo;Cheong, Youn-Cheong;Kwon, Soon-Buhm;Sohn, Byeong-Yong;Kang, Joon-Wun
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.6
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    • pp.567-572
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    • 2005
  • In this study, a lab-scale test was performed to apply the ozone process in drinking water treatment plant using dissolved ai, flotation(DAF). The kinetic study on the ozone decay and hydroxyl(OH) radical formation was investigated by several parameters, such as I.D(Instantaneous ozone demand), $k_c$(ozone decomposition rate), ozone-Ct and OH radical-Ct. Ozonation of several target waters, such as raw water, DAF treated water and filtrate, was conducted to select the optimum position and dosage of ozone process. The highest value of Ozone-Ct and OH radical-Ct was observed at DAF treated water at initial run time($0{\sim}30\;min$). From the results of ozonation, the intermediate ozonation was proposed as the optimum position and the effective dose of ozone was determined to be $1{\sim}2\;mg/L$.

The Effect of Isoproturon on Herbicidal Properties, Crop Injury and Yield in Barley and Wheat Cultivation (맥작(麥作)에 있어서 Isoproturon의 살초특성(殺草特性)과 약해(藥害) 및 수량(收量)에 미치는 영향(影響))

  • Ryang, Y.S.;Kim, J.S.;Han, S.S.;Ryang, H.S.
    • Korean Journal of Weed Science
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    • v.2 no.2
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    • pp.152-159
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    • 1982
  • To investigate the effect of isoproturon (N,N-dimethyl-N-4-isopropyl phenyl urea) on weed-killing, crop injury and yield of barley, several experiments were conducted by application time, dosage, cultivars and soil texture. For the effective control of weeds the optimum application time was foliage application after winter. Alopecurus aequalis SOBOL was effectively controlled when isoproturon should be applied at three to four leaf-stage and most annual broad-leave weeds emerged through winter and spring could be controlled when applied even at five to six leaf-stage. But among the broad-leave weeds Vicia amoena Fisch. was resistant to isoproturn. The optimum application rate of isoproturon was 240g-300g/10a (prod.). Among 11 cultivars of barley and wheat, phytotoxicity of Olmil, Jokwang and Rye was slighter than that of the other cultivars when isoproturon was treated by foliage application after winter. At the time of foliage application after winter, the variation of phytotoxicity and effectiveness was a little despite the difference of soil texture and the grain yield of barley was higher in the plots treated 240-300g/10a than in other treated plots.

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Struvite Crystallization of Swine Wastewater using Bittern (간수를 이용한 축산폐수의 struvite 결정화)

  • Ryu, Hong-Duck;Kim, Tae-Su;Park, Hyoung-Soon;Lee, Sang-Ill
    • Journal of Korean Society on Water Environment
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    • v.23 no.1
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    • pp.138-143
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    • 2007
  • This study goes in for the observation of the characteristics of nitrogen removal from swine wastewater by struvite crystallization. In addition, the struvite formation potential in supernatants after struvite crystallization was investigated. In the study for nitrogen removal by struvite crystallization, the effects of pH and molar ratio of magnesium (Mg) injected using bittern as Mg source were investigated. Also, the potential of struvite formation in the supernatant with amount of Mg added was carefully observed. As the results, the optimum pH in the removal of nitrogen was 8.8 and sludge volume was increased as pH was raised from 7 to 12 under the condition that the molar ratio of $Mg^{2+}$ to ${NH_4}^+$-N to ${PO_4}^{3-}$-P was 1:1:1. An optimum removal efficiency of ammonia-N was observed at 1 molar ratio of Mg to ${NH_4}^+$-N, showing no further increase at over 1 molar ratio and dramatical deterioration at under 1 molar ratio. However, the sludge volume was increased by increasing the molar ratio of Mg. In the experiments for the potential of struvite formation in the supernatants, initial -log([$Mg^{2+}$][${NH_4}^+$][${PO_4}^{3-}$]) value was much lower than $pK_{sp}$ and gradually reached $pK_{sp}$ at 2 days, as the molar ratio of Mg increased over 1.2. At 31 days, -log([$Mg^{2+}$][${NH_4}^+$][${PO_4}^{3-}$]) value was returned to the initial value. In addition, the supernatants had a potential precipitation of hydroxylapatite due to calcium contained in bittern, $K_2Mg(SO_4)_3$ and $K_3Na(SO_4)_2$ resulting from the decrease of sodium and potassium in supernatants formed after struvite crystallization as times go by. Based on the results, it appears that some retention time and proper dosage of Mg may be needed for the prevention of scale in pipe line.

Optimizing Coagulation Conditions of Magnetic based Ballast Using Response Surface Methodology (반응표면분석법을 이용한 자성기반 가중응집제의 응집조건 최적화)

  • Lee, Jinsil;Park, Seongjun;Kim, Jong-Oh
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.12
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    • pp.689-697
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    • 2017
  • As a fundamental study to apply the new flocculation method using ballast in water treatment process, the optimal conditions for general and ballast coagulant dosage, and pH, which are known to have a significant influence, were derived by response surface methodology. Poly aluminum chloride (PAC) and magnetite ballast were used as a general coagulant and ballast, respectively. Coagulation experiments were performed by jar-tester using the kaolin based synthetic water. The effects of three independent variables (pH, PAC, and ballast) on response variables (turbidity removal rate and average settling velocity of flocs) and the optimum condition of independent variables to induce the optimum flocculation were obtained by 17 experimental conditions designed by Box-Behnken procedure. After performing experiments, the quadratic regression model was derived for each of response variables, and the response surface analysis was conducted to explore the correlation between independent variables and response variables. The $R^2$ values for the turbidity removal rate and the average settling velocity were 0.9909 and 0.8295, respectively. The optimal conditions of independent variables were 7.4 of pH, 38 mg/L of PAC and 1,000 mg/L of ballast. Under these conditions, the turbidity removal rate was more than 97% and the average settling velocity exceeded 35 m/h.

Characteristics of Heat Stable Salts Treatment Using Anion Exchange Resins in CO2 Absorption Process (음이온교환수지를 이용한 CO2 흡수 공정시 발생하는 열안정성염 처리 특성)

  • Park, Kyung-Bin;Cho, Jun-Hyoung;Jeon, Soo-Bin;Lim, You-Young;OH, Kwang-Joong
    • Clean Technology
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    • v.21 no.1
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    • pp.22-32
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    • 2015
  • In this study, we studied the characteristics of ion exchange for treatment of HSS (heat stable salts) which cause performance reduction in CO2 gas capture amine solution using anion exchange resins. The optimum HSS removal efficiency, 96.1% was obtained when using strong base anion exchange resin SAR10 at dosage 0.05 g/mL, 316 K, pH 12 and the best resin regeneration efficiency, 78.8% was obtained using NaOH solution of 3 M at 316 K. The adsorption data were described well by the Freundlich model and the sorption intensity(n) was 2.0951 lying within the range of favorable adsorption. The adsorption selectivity coefficients were increased by increasing valences and size of ion and desorption selectivity coefficients showed a contradictory tendency to adsorption selectivity coefficients. By continuous HSS removal experiments, 13.3 BV of HSS contaminated solution was effectively treated and the optimum NaOH solution consumption was 5.2 BV to regenerate resins.

A Study on the Dye-Wastewater Treatment by Fenton and Photo-Fenton Oxidation Process (Fenton 및 Photo-Fenton 산화공정을 이용한 염색 폐수의 처리에 관한 연구)

  • 조일형;고영림;이소진;이홍근;조경덕
    • Journal of Environmental Health Sciences
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    • v.26 no.4
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    • pp.29-37
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    • 2000
  • Fenton’s oxidation process is one of the most commonly applied processes to the wastewater which cannot be treated by conventional biological treatment processes. However, it is necessary to minimize the cost of Fenton’s oxidation treatment by modifying the treatment processes or other means of chemical treatment. So, as a method for the chemical oxidation of biorefractory or nonbiodegradable organic pollutants, the Photo-Fenton-Reaction which utilizes iron(11)salt. $H_2O$$_2$ and UV-light simultaneously has been proprosed. Therfore, the purpose of this study is to test a removal efficiency of dye-wastewater and treatment cost with Fenton’s and Photo-Fenton’s oxidation process. The Fe(11)/$H_2O$$_2$ reagent is referred to as the fenton’s reagent. which produces hydroxy radicals by the interaction of Fe(11) with $H_2O$$_2$. In this exoeriment, the main results are as followed; 1. The Fenton oxidation was most efficient in the pH range of 3-5. The optimal condition for initial reaction pH was 3.5 for the high CO $D_{Cr}$ & TOC-removal efficiency. 2. The removal efficiency of TOC and CO $D_{Cr}$ increased up to the molar ration between ferrate and hydrogen peroxide 0.2:1, but above that ratio removal efficiency hardly increased. 3. The highest removal efficiency of TOC and CO $D_{Cr}$ were showed when the mole ration of ferrate to hydrogen peroxide was 0.2:3.4. 4. Without pretreatment process, photo-fenton oxidation which was not absorbed UV light was not different to fenton oxidation. 5. And Fenton oxidtion with pretreatment process was similar to Fenton oxidation in the absence of coagulation, the proper dosage of F $e^{2+}$: $H_2O$$_2$ was 0.2:1 for the optimal removal efficiency of TOC or CO $D_{Cr}$ .6. Also, TOC & CO $D_{Cr}$ removal efficiency in the photo-fenton oxidation with pretreatment was increased when UV light intensity enhanced.7. Optimum light intensity in the range from 0 to 1200 W/$m^2$ showed that UV-intensity with 1200W/$m^2$ was the optimum condition, when F $e_{2+}$:$H_2O$$_2$ ratio for the highest decomposition was 0.2:2.5.EX>$_2$ ratio for the highest decomposition was 0.2:2.5.

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Pretreatment Condition in the Full Scale Dissolved Air Flotation Process Using a DAF Pump (DAF 펌프를 이용한 실규모 용존공기부상 공정의 전처리 조건)

  • Lee, Chang-Han;An, Dae-Myung;Kim, Seong-Soo;Cho, Seok-Ho;Ahn, Kab-Hwan
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.1
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    • pp.58-63
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    • 2009
  • Dissolved air flotation (DAF) process is generally considered more effective than sedimentation process in raw water containing algae, humus materials, and low density particles. This study presents the treatment efficiencies by the coagulation and flocculation conditions at a drinking water treatment plant using a laboratory tester and the full scale DAF pump system. The full scale DAF pump system (F-DAF) in this study had a capacity of 5,000 $m^3$/d and a hydraulic surface loading of 10 m/hr. F-DAF in D drinking water treatment plant was continuously operated to determine the operational performance and pretreatment (mixing and coagulation) conditions. Results in the laboratory experiment showed that the optimum coagulant (PSO-M) doses required to 2.7~4.5 mL/$m^3$/NTU with raw water turbidity from 13.8 NTU to 56.3 NTU. F-DAF in the optimum coagulant dosage could be operated in effluent turbidity of 1 NTU or below for a month.