• Transactions of the Korean Society of Automotive Engineers
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• v.14 no.5
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• pp.32-38
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• 2006

Currently, due to the serious world-wide air pollution by substances emitted from vehicles, emission control is enforced more firmly and it is expected that the regulation requirements for emission will become more severe. A new concept combustion technology that can reduce the NOx and PM in relation to combustion is urgently required. Due to such social requirement, technologically advanced countries are making efforts to develop an environment-friendly vehicle engine at the nation-wide level in order to respond to the reinforced emission control. As a core combustion technology among new combustion technologies for the next generation engine, the homogenous charge compression ignition(HCCI) is expanding its application range by adopting multiple combustion mode, catalyst, direct fuel injection and partially premixed combustion. This study used a 2-staged injection method in order to apply the HCCI combustion method without significantly altering engine specifications in the aspect of multiple combustion mode and practicality by referring to the results of studies on the HCCI engine. In addition, this study confirmed the possibility of securing optimum fuel economy emission reduction in the IMEP 8bar range(which could not be achieved with existing partially premixed combustion) through forced charging, exhaust gas recirculation(EGR), compression ratio change and application of DOC catalyst.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.36 no.1
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• pp.1-5
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• 2003

This study was carried out to prepare the depolymerized alginates by physical treatment processing with organic acids. The applied physical treatment methods were autoclaving, microwaving, and ultrasonicating, Among several physical depolymerization methods, autoclaving treatment was the most effective for hydrolyzing the alginate to low molecular compounds such as oligosaccharides. Citrate was most effective catalyst in hydrolyzing alginate to some oligosaccharides among organic acids. An acceptable autoclaving conditions for hydrolyzing alginate to oligosaccharides were to treat at $110^{\circ}C$ for 90 min and $120^{\circ}C$ for 60 min, respectively. The maximum depolymerization percentage produced by autoclaving was $56.8\%$. The depolymerized alginates prepared by autoclaving at $110^{\circ}C\;and\;120^{\circ}C$ has oligosaccharides of $3\~4 $and $7\~8$ species, respectively. The optimum condition for alginate oligosaccarides was autoclaving treatment with $0.5\%$ citrate solution at $120^{\circ}C$ for 90 min.

• Applied Chemistry for Engineering
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• v.33 no.1
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• pp.64-70
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• 2022

In this study, an experiment was performed by adding Sb during NH3-selective catalytic reduction (NH₃-SCR) while varying calcination temperatures from 400 to 700 ℃ to improve the low temperature denitrification efficiency of VWTi catalyst. As a result, VWSbTi(500) and VWSbTi(600) catalysts corresponding to Sb calcination temperatures of 500~600 ℃ showed the best denitrification performance at low temperatures below 300 ℃. BET, XRD, Raman, XPS, H₂-TPR, and NH₃-TPD analyses were performed In order to confirm physicochemical properties according to the calcination temperature. In the case of VWSbTi(500) and VWSbTi(600), an acid site increased with the generation of W=O species, and superb activity at low temperatures was exhibited due to the excellent redox characteristics and increase in electron density of tungsten. Furthermore, in the case of VWSbTi(700), as the crystalline V₂O₅ structure was formed, the denitrification efficiency decreased. Thus the optimum calcination temperature during Sb addition process was confirmed.

• Korean Journal of Materials Research
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• v.32 no.3
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• pp.125-131
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• 2022

Effect of sulfation processes on the physicochemical properties of ZrO₂ and TiO₂ nanoparticles were thoroughly investigated. SO₄/ZrO₂ and SO₄/TiO₂ catalysts were synthesized to identify the acidity character of each. The wet impregnation method of ZrO₂ and TiO₂ nanoparticles was employed using H2SO₄ with various concentrations of 0.5, 0.75, and 1 M, followed by calcination at 400, 500, and 600 ℃ to obtain optimum conditions of the catalyst synthesis process. The highest total acidity was found when using 1 M SO₄/ZrO₂-500 and 1 M SO₄/TiO₂-500 catalysts, with total acidity values of 2.642 and 6.920 mmol/g, respectively. Sulfation increases titania particles via agglomeration. In contrast, sulfation did not practically change the size of zirconia particles. The sulfation process causes color of both catalyst particles to brighten due to the presence of sulfate. There was a decrease in surface area and pore volume of catalysts after sulfation; the materials' mesoporous structural properties were confirmed. The 1 M SO₄/ZrO₂ and 1 M SO₄/TiO₂ catalysts calcined at 500 ℃ are the best candidate heterogeneous acid catalysts synthesized in thus work.

• Journal of Hydrogen and New Energy
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• v.33 no.1
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• pp.38-46
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• 2022

Two different gas diffusion layers having noticeable differences in micro-porous layer's (MPL's) crack were studied as a substrate for the gas diffusion electrode (GDE) with different binder/carbon (B/C) ratios in high-temperature polymer electrolyte fuel cell (Ht-PEMFC). As a result, the performance defined as the voltage at 0.2 A/cm² and maximum power density from the single cells using GDEs from H23 C2 and SGL38 BC with different B/C ratios were compared. GDEs from H23 C2 showed a proportional increase of the voltage with the binder content on the other hand GDEs from SGL38 BC displayed a proportional decline of the voltage to the binder content. It was revealed that MPL crack influences the structure of catalyst layer in GDEs as well as affects the RC_athode which is in close connection with the Ht-PEMFC performance.

• Korean Chemical Engineering Research
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• v.61 no.4
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• pp.591-597
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• 2023

Pakistan depends heavily on imports for its fuel requirements. In this experiment, catalytic pyrolysis of a blend of feedstock's consisting of date seed, wheat straw, and corn cob was conducted in a fixed bed reactor to produce oil that can be used as an alternative fuel. The main focus was to emphasize the outcome of important variables on the produced oil. The effects of operating conditions on the yield of bio-oil were studied by changing temperature (350-500 ℃), heating rate (10, 15, 20 ℃/min), and particle size (1, 2, 3 mm). Moreover, ZnO was used as a catalyst in the process. First, the thermal degradation of the feedstock was investigated by TGA and DTG analysis at 10 ℃/min of different particle sizes of 1, 2, and 3mm from a temperature range of 0 to 1000 ℃. The optimum temperature was found to be 450 ℃ for maximum degradation, and the oil yield was indicated to be around 37%. It was deduced from the experiment that the maximum production of bio-oil was 32.21% at a temperature of 450 ℃, a particle size of 1mm, and a heating rate of 15 ℃/min. When using the catalyst under the same operating conditions, the bio-oil production increased to 41.05%. The heating value of the produced oil was 22 MJ/kg compared to low-quality biodiesel oil, which could be used as a fuel.

• Journal of the Korean Institute of Gas
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• v.5 no.1
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• pp.45-51
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• 2001

Catalytic combustion is the environmental-friendly technology, which has been applied to a variety of areas for industrial and domestic use in recent years. Accordingly, this study performed the development of the catalytic manufacturing technology for the high temperature and of the catalytic combustor in priority, which were aimed to be aimed to a commercialized condensing boiler. Palladium(Pd) of a noble meta] was used as a catalyst for the high temperature and supported on $alumina(Al_{2}O_{3})\;and\;zirconia(ZrO_2)$ in constant weight ratio. Activity of Pd catalysts is compared and analysed in the catalytic combustion of natural gas. The ratio of $Pd/Al_{2}O_{3}\;=\;4$ was found to be better than any other weight ratios in activity and durability. The performance examination of catalysts and of combustion through the plate-type combustor made it possible to be developed the cylindrical-type combustor which has increased combustion area. Catalytic combustion condensing boiler of 25,000 kcal/hr class was also developed, which had the optimum combustion condition at the no221e of 5.95mm and the orifice of 21mm. This condition was determined through the performance experiments of catalytic combustion condensing boiler to which the cylindrical-type catalytic combustor was applied.

• Resources Recycling
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• v.13 no.5
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• pp.28-36
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• 2004

The extraction of platinum group metals such as Pt, Pd and Rh from spent automobile catalyst has been investigated by leaching in HCl solutions using $HNO_3$ or NaOCl as a oxidant. The effect of type and amount of oxidant, reaction time and pulp density on the extraction of platinum group metals was examined. Platinum group metals were recovered by the cementation method using aluminum as a reducing agent. The extraction ratio was higher when NaOCl was used as a oxidant. The optimum leaching conditions were obtained to be: HCl 8 M, the amount of NaOCl 1.4 mole, leaching temperature $90^{\circ}C$, leaching time 180 minutes, pulp density 400g/L. Under the optimum conditions, the extraction of Pt, Pd and Rh were 96.1%, 93.6% and 77.3%, respectively. With the addition of 2.0g of aluminum which corresponds to 28 equivalent the reduction were 98% for Pt. 98.8% for Pd and 65.3% for Rh, respectively.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.1 no.2
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• pp.57-62
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• 2000

The photocatalytic degradation of trichloroethylene(TCE) in water on various types of$TiO_2$ was studied. Surface properties of $TiO_2$were characterized by XRD, SEM, and BET in our previous work(23) . $TiO_2$from Aldrich has 100$\%$pure anatase, TiO$_2$from KIER has 100$\%$ pure rutile structure, and P25-TiO$_2$from Degussa has mixed structure of anatase(75$\%$) and rutile(25$\%$) . Firstly, optimum conditions for TCE degradation were examined in this study. Results showed that optimum loading amount of catalyst was 0.1 wt% and recirculation flow rate of mixture(distilled water and TCE) was 200 cc/min. Secondly, the effect of $TiO_2$structure on TCE degradation was examined. Results revealed that anatase structure generally has better photocatalytic activity than rutile structure. Especially, mixed structure(Degussa P25-$TiO_2$) has the highest activity due to small particle size and large specific surface area.

• Applied Chemistry for Engineering
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• v.17 no.6
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• pp.619-624
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• 2006

This study was performed to investigate the formation process of calcium sulfate ${\alpha}$-hemihydrate from FGD gypsum produced at thermal power plant burning bituminous coal. The experimental results showed that calcium sulfate $\alpha$-hemihydrate with a large aspect ratio was produced in the temperature range of $120^{\circ}C$ and $140^{\circ}C$ in the absence of additives through dissolution-recrystallization mechanism. It was also observed that addition of Na-succinate as a catalyst changed crystal shape from acicular to prismatic, resulting in decreased water/powder ratio down to 33%. Optimum concentration of Na-succinate was 20mM. It was confirmed that the optimum moulding pressure and moisture content of moulded body from FGD gypsum were $30kg_f/cm^2$ and between 10% and 15% respectively, which prevent moulded body from collapsing and maximize the capillary effect by given pore volume while autoclaving.