• Title/Summary/Keyword: optimal mixture ratio

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Study on separation process of tri-cresyl phosphate by reaction of $POCl_3$ with mixed cresol (혼성 Cresol과 $POCl_3$의 반응에 의한 tri-Cresyl Phosphate의 분리공정 연구)

  • 김장규;원성호;양승남;이상석;김남기
    • Journal of the Korean Society of Safety
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    • v.13 no.2
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    • pp.109-115
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    • 1998
  • Tri-cresyl phosphate(TCP) was synthesized by reaction of phosphorus chloride with mixed cresol(mixture of m-cresol, p-cresol, and others) in the presence of $AlCl_3$. Some of unwanted products and unreactants colored TCP. In order to separate TCP from these, vaccume distillation was carried twice, but colorless TCP could not be producted. Separation of unwanted materials by 2% NaOH solution was introduced before first and second distillation and optimal separation conditions such as NaOH concentration, mixing volume ratio, mixing time, and rpm were investigated for new batch separation and production of colorless TCP Optimal conditions were 2% NaOH solution, 35% mixing volume ratio of 2% NaOH solution, 1.5 hours of mixing time, and 20 rpm.

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Color Fastness of Digital Textile Printing on Silk Fabrics - The effect of the mixed pre-treatment agent (디지털 프린팅 견직물의 색상 변화 및 견뢰도 - 혼합 전처리제의 영향)

  • Jeong, Dong-Seok;Chun, Tae-Il
    • Fashion & Textile Research Journal
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    • v.15 no.5
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    • pp.808-814
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    • 2013
  • In this study, The mixture of three kinds of pre-treatment agents, Carboxymethyl cellulose sodium salt(CMC), Sodium alginate and Dextrin, have been prepared for the better coloration of digital textile printing. To get sharpness of outline during digital printing process, the optimal formulation is the CMC and Sodium alginate mixture 1:1 ratio by volume. Cyan, Yellow, and Black colours are excellent on the Sodium alginate mixtures. But, Magenta is excellent in the CMC and Dextrin mixture. Sharpness and printability are closely related to viscosity of the mixture. The most optimal sharpness of outline achieved with a consideration of coloring, and field operations account for production when the viscosity of the mixed pre-treatment agent approximately is 10~13 cSt. Change in shade and staining of wash fastness for all the treated samples with the mixtures rated 4-5 grade. Both dry rubbing fastness to shade change and staining are good in the treated samples, whereas wet rubbing fastness rated 2-3 grade. To improve wet rubbing fastness, the Sodium alginate and Dextrine mixture, which rated 3-4 grade for Black color, is applicable. With exception of 3 rating to black color, Light fastness is 4 rating for the remaining three colors in the regardless of treatment condition and mixing of the pre-treatment agent. Dry cleaning fastness of all samples are also 4-5 rating.

A Study on Improvement of the Physical Properties of 4 Component Working Fluid in Gas Fired Absorption Chillers (가스흡수식 냉방기용 4성분계 작동매체의 물성 향상 연구)

  • Baek, Young-Soon;Oh, Young-Sam;Lee, Yong-Won;Park, Dal-Ryung;Koo, Ki-Kap
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.400-406
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    • 1999
  • In an effort to obtain high efficiency in gas fired absorption chillers, a new working fluid has been developed with thc addition of the component of $LiNO_3$, LiCl and LiI to the conventional solution of $LiBr-H_2O$. The solubility and vapor pressure of the 4 component working fluid developed in this work were measured and compared to the results of $LiBr-H_2O$ solution. It was observed that there exists an optimal mole ratio of the inorganic salts in terms of solubility. The mole ratio of LiBr, $LiNO_3$ and LiCl was found to be around 5:1:1~2 in the $LiBr-LiNO_3-LiCl-H_2O$ mixture, and in the case of $LiBr-LiO_3-Lil-H_2O$ and $LiBr-Lil-LiCl-H_2O$ mixtures, the mole ratio of LiBr, $LiNO_3$ and Lil/ LiBr, LiI and LiCl were found to be around 5:1:1 and 5:1:0.5~1 respectively. The vapor pressure of the 4 component working fluid of the optimal mole ratio was increascd with adding the component of $LiNO_3$, LiCl and LiI except for $LiBr-LiNO_3-LiCl-H_2O$ mixture. The absorption capacity of $LiBr-LiNO_3-LiCl-H_2O$ mixture was obtained higher than that of $LiBr-H_2O$ mixture.

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Plasma spectroscopy aimed at quantifying the flame equivalence ratio (화염의 정성적 당량비 측정을 위한 Plasma Diagnostics에 관한 연구)

  • Lee, SeokHwan;Yoh, Jai-ick
    • 한국연소학회:학술대회논문집
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    • 2013.06a
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    • pp.99-101
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    • 2013
  • The equivalence ratio is measured by LIBS(Laser-induced Breakdown spectroscopy) in hydrocarbon flame and high temperature (${\sim}3200^{\circ}C$) oxyhydrogen flame, where a stoichiometric mixture of hydrogen and oxygen is produced from water through electrolysis. The ratio of the hydrogen and oxygen (H/O) atomic lines intensities is used for quantitatively determining the quivalence ratio. laser energy is evaluated for determining the optimal condition for plasma diagnostics. The minimum laser energy for generating plasma in a laminar premixed hydrocarbon flame was about 70 mJ, whereas oxyhydrogen flame. consequently the irradiated spot of a lower density in high temperature oxyhydrogen flame gave rise to bigger plasma in size, thus limiting the spatial resolution of the LIBS measurement.

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Preparation of Diacylglycerol from Lard by Enzymatic Glycerolysis and Its Compositional Characteristics

  • Diao, Xiaoqin;Guan, Haining;Kong, Baohua;Zhao, Xinxin
    • Food Science of Animal Resources
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    • v.37 no.6
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    • pp.813-822
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    • 2017
  • The aim of this study was to prepare diacylglycerol (DAG) by enzymatic glycerolysis of lard. The effects of reaction parameters such as lipase type, reaction temperature, enzyme amount, substrate molar ratio (lard/glycerol), reaction time, and magnetic stirring speed were investigated. Lipozyme RMIM was found to be a more active biocatalyst than Novozym 435, and the optimal reaction conditions were 14:100 (W/W) of enzyme to lard substrate ratio, 1:1 of lard to glycerol molar ratio, and 500 rpm magnetic stirring speed. The reaction mixture was first incubated at $65^{\circ}C$ for 2 h and then transferred to $45^{\circ}C$ for 8 h. At the optimum reaction conditions, the conversion rate of triacylglycerol (TAG) and the content of DAG in the reaction mixture reached 76.26% and 61.76%, respectively, and the DAG content in purified glycerolized lard was 82.03% by molecular distillation. The distribution of fatty acids and Fourier transform infrared spectra in glycerolized lard samples were similar to those in lard samples. The results revealed that enzymatic glycerolysis and molecular distillation can be used to prepare more highly purified DAG from lard.

Optimization of Ingredient Mixing Ratio for Preparation of Sponge Cake with Bamboo (Pseudosasa japonica Makino) Leaves Powder (대나무잎 가루를 첨가한 스펀지 케이크 재료 혼합비율의 최적화)

  • Park, Jung-Eun;Jeong, Heung-Do;Jang, Myung-Sook
    • Korean journal of food and cookery science
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    • v.25 no.3
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    • pp.317-329
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    • 2009
  • In the study, we determined the optimal ingredient mixing ratio for the preparation of sponge cake containing bamboo (Pseudosasa japonica Makino) leaves. This experiment was designed in according with the D-optimal design of mixture design, which involved 14 experimental points including 4 replicates for three independent variables (sugar 110${\sim}$129%, bamboo leaves 3${\sim}$8%, oil 10${\sim}$25%). The results the F-test, specific gravity, volume and color values (L, a, b) decided a linear model, while the viscosity, hardness and sensory characteristics (color, smell, taste, texture and overall acceptance) decided a quadratic model. The results of our fitness analysis demonstrated that in all characteristic, the probabilities were significant within 0.05%; thus, the models were accepted as appropriate. The response surface and trace plot results demonstrated that increasing amounts of added bamboo leaves induced a reduction in brightness, and increasing redness and yellowness. In addition, increasing amounts of bamboo leaves caused increases in hardness, and thus the softness of the cake decreased. And as the level of added oil increased, softness increased. Cake samples received low sensory evaluation scores when sugar, bamboo leaves, and oil were added above their optimal levels. In the numeric optimization, the optimal ingredient amounts were 121.36% sugar, 4.96% bamboo leaves, and 15.69% oil. The above results demonstrate the feasibility of adding bamboo leaves to sponge cake, and therefore, a bamboo leaves as a functional food.

Optimization of Mixing Ratio to Improve Antioxidant Activity of Aged Garlic with Pine Needle Using Response Surface Methodology

  • Park, Jae-Hee;Shin, Eunji;Park, Eunju
    • Preventive Nutrition and Food Science
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    • v.22 no.3
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    • pp.241-245
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    • 2017
  • Aged garlic has been reported to possess beneficial pharmacological activities, including anti-stress and anti-fatigue properties, and to exert protective effects on the cardiovascular system and liver. Pine needles are widely used in folk medicine and as food additives owing to their pharmacological properties such as anti-aging and anti-inflammatory effects. It has long been known that combining certain phytochemicals with other phenols or organic acids can produce synergistic effects. Therefore, the purpose of this study was to develop an optimal formula of aged garlic with added pine needle powder for improved antioxidant activity using the statistical technique of response surface methodology. The antioxidant activities of aged garlic mixed with pine needle powder were confirmed by measuring oxygen radical absorbance capacity and total polyphenol content. An optimized antioxidant formula was identified that contained 5.08 g aged garlic and 1.97 g pine needle powder. The antioxidant activities of the mixture prepared using this optimal formula were significantly higher than the predicted values according to an additive model. Hence, this study confirms that the addition of pine needle powder to aged garlic can improve its antioxidant activity. This study demonstrated an optimal mixing ratio to produce an aged garlic product with improved functionality through the addition of pine needle powder that could be successfully employed by the food industry to prepare functional foods.

Video Based Pedestrian Height Estimation Using Winer Optimization (위너 최적화 기법을 이용한 영상기반 보행자 키 추정)

  • Jeon, Sang Hee;Song, Jong Kwan;Park, Jang Sik;Yoon, Byung Woo
    • Journal of Korea Multimedia Society
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    • v.19 no.2
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    • pp.264-270
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    • 2016
  • In this paper, we proposed a method which can detect pedestrians from CCTV video and estimate the height of the detected objects. We separate the foreground using Gaussian mixture model and the pedestrian is detected using the conditions such as the width-height ratio and the size of the candidate objects. In order to obtain the optimal model for estimating the height of pedestrian, we get many training data from the pedestrian whose height is known. Using these training data, we designed optimal Wiener height estimator and used to estimate the height of pedestrians. The height of the pedestrian at various distance is estimated and the accuracy is evaluated. In the experimental results, proposed method shows that it can estimate the height of pedestrian for various positions effectively.

Optimum Mixture Proportion of Self-Compacting Concrete Considering Packing Factor of Aggregate and Fine Aggregate Volume Ratio (골재 채움율과 잔골재 용적비를 고려한 자기충전형 콘크리트의 최적배합)

  • 최연왕;정문영;정지승;문대중;안성일
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.549-554
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    • 2002
  • In Powder System, SCC demands high dosage of superplasticizer and a lage amout of powder for suitable fluidity and viscosity. Okamura's method of most representative mixing design method in SCC of Powder-System is unfavorable economically because of using a large amount of powder. In addition, many ready-mixed concrete plants do not use his mix design method and procedure due to complexity for practical application. Therefore, Nan Su proposed more simple mix design method than Okamura's. It had an advantage in simplicity in practical application and required a smaller amount of powders compared with Okamura's method. This paper proposed an optimal mixture proportion of SCC with consideration of Nan Su's method. The new and modified mix design method required a smaller amount of powder than that of Nan Su's. To check the properties of SCC, considered with the requirements specified by the Japanese Society of Civil Engineering.(JSCE)

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Effects of Combustion Chamber Shape on the Stratified Combustion of a GDI Engine (직접분사식 가솔린엔진의 연소실 형상이 성층화 연소에 미치는 영향)

  • 송재원;김미로;조한승;여진구;조남효
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.1
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    • pp.67-75
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    • 2002
  • A study to investigate the influence of combustion chamber shape, especially piston top face configuration, on the combustion stability is presented with CFD analysis and single cylinder GDI engine test. Initial configuration of the piston bowl was designed with CFD analysis and further parametric studies of the design factors on the piston top face were carried out through the single cylinder GDI engine test. It was found that both the geometry of piston top face and the compression ratio have great influences on the combustion stability. Of interest is that the design factors of the GDI piston to prevent mixture diffusion out of the piston bowl have important roles for the stable combustion at the stratified mixture condition. Also the relationship between spray impingement and flow pattern in a GDI piston bowl should be considered to design an optimal bowl configuration for stable stratified combustion.