• Title/Summary/Keyword: optical anisotropy

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Photoisomerization and Photo-induced Optical Anisotropy of Polymethacrylate Containing Aminonitroazobenzene

  • Park, Dong-Hoon;Cho, Kang-Jin
    • Fibers and Polymers
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    • v.2 no.1
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    • pp.123-130
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    • 2001
  • Photoresponsive side chain copolymer and homopolymer containing an aminonitroazobenzene were synthesized for studying photoisomerization behavior and photo-induced anisotropy. Trans-to-cis photoisomerization was observed under the exposure of a circularly polarized visible light with UV-Vis absorption spectroscopy. Reorientation of polar azobenzene molecules induced optical anisotropy under a linearly polarized light at 532nm. Polarized absorption spectroscopy was employed to investigate the anisotropy of the polymer film during irradiationg of the excitation light. Layers of two photosensitive polymers were used for aligning liquid crystal(LC) molecules instead of one of the rubbed polyimide layers in the conventional twisted nematic cell. For producing homogeneous alignment of a nematic LC molecule, a linearly polarized light was exposed to the films of two polymers. The stability of the LC alignment upon the linearly polarized light exposure was also studied.

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Estimation of the Anisotropy Magnitude in Amorphous $As_40Ge_{10}S_{35}Se_{15}$ Thin Films by an Interference Method (간섭방법을 이용한 비정질 $As_40Ge_{10}S_{35}Se_{15}$ 박막에서의 광유기 이방성 크기 측정)

  • 전진영;박수호;이현용;정홍배
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.9
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    • pp.746-751
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    • 1998
  • There are several methods capable of determining he magnitude of optical anisotropy, such as spectrometric ellipsometry and polarized light reflectometry. The interference method is estimated to be no influence of surface scattering. The magnitude of anisotropy is a-As/sub 40/Ge/sub 10/S/sub 35/Se/sub 15/ thin film is analyzed by the reflection interference analysis method based on the difference depending on a phase of s- and p-polarized light. The theoretically analyzed value is compared with the result obtained by the measured technique.

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Photo-alignment of Low-molecular Mass Nematic Liquid Crystals on Photochemically Bifunctional Chalcone-epoxy Film by Irradiation of a Linearly Polarized UV Light

  • Choi, Dong-Hoon;Cha, Young-Kwan
    • Bulletin of the Korean Chemical Society
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    • v.23 no.4
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    • pp.587-592
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    • 2002
  • Photocrosslinkable chalcone-epoxy compound comprising 1,3-bis-(4-hydroxy-phenyl)-propenone was synthe-sized for fabricating the photo-alignment layer of liquid crystals. Chalcone group was introduced into the main chain unit of the epoxy oligomer. We observed a photodimerization behavior and an optical anisotropy of this material by irradiation of a linearly polarized UV(LP-UV) light. With a trace amount of cationic photoinitiator (TRS-HFA), polymerization of epoxy groups was also conducted at the similar wavelength range used for photodimerization. Linearly polarized UV irradiation on the chalcone-epoxy films with cationic photoinitiator induced optical anisotropy of the film and the resultant film can be used for alignment layers for low molecular weight nematic liquid crystals.

Ellipsometric Characterization of Rubbed Polyimide Alignment Layer in Relation with Distribution of Liquid Crystal Molecules in Twisted Nematic Cell

  • Cho, Sung Yong;Park, Sang Uk;Yang, Sung Mo;Kim, Sang Youl
    • Current Optics and Photonics
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    • v.2 no.2
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    • pp.185-194
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    • 2018
  • Ultra-small optical anisotropy of a rubbed polyimide (PI) alignment layer is quantitatively characterized using the improved reflection ellipsometer. Twisted nematic (TN) cells are fabricated using the rubbed PIs of known surface anisotropy as alignment layers. Distribution of liquid crystal (LC) molecules in the TN cell is characterized using transmission ellipsometry. The retardation of the rubbed PI surface increases as rubbing strength increases. The tilt angle of the optic axis of the rubbed PI surface decreases as rubbing strength especially as the angular speed of the rubbing roller increases. Pretilt angle of LC molecules in the TN cell shows strong correlation with tilt angle of the optic axis of the rubbed PI surface. Both the apparent order parameter and the effective twist angle of the LC molecules in the TN cell decrease as the pretilt angle of LC molecules increases.

X-ray scattering study on the electric field-induced interfacial magnetic anisotropy modulation at CoFeB / MgO interfaces

  • Song, Kyung Mee;Kim, Dong-Ok;Kim, Jae-Sung;Lee, Dong Ryeol;Choi, Jun Woo
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1212-1217
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    • 2018
  • The electric field-induced modifications of magnetic anisotropy in CoFeB/MgO systems are studied using X-ray resonant magnetic scattering and magneto-optical Kerr effect. Voltage dependent changes of the magnetic anisotropy of -12.7 fJ/Vm and -8.32 fJ/Vm are observed for Ta/CoFeB/MgO and Hf/CoFeB/MgO systems, respectively. This implies that the interfacial perpendicular magnetic anisotropy is reduced (enhanced) when electron density is increased (decreased). X-ray resonant magnetic scattering measurements reveal that the small in-plane magnetic component of the remanent state of CoFeB/MgO systems with weak magnetic anisotropy changes depending on the applied voltage leading to modification of the magnetic anisotropy at the CoFeB/MgO interface.

Ellipsometric Expressions for Two Uniaxially Anisotropic Layers Coated on a Multilayered Substrate (두개의 단축이방성 박막이 있는 다층박막 시료의 타원식)

  • Kim, Sang Youl
    • Korean Journal of Optics and Photonics
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    • v.26 no.2
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    • pp.115-120
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    • 2015
  • Explicit expressions are derived for the effective reflection coefficients of obliquely incident light on a multilayered substrate coated with two uniaxially anisotropic films. Based on these reflection coefficients, ellipsometric constants are obtained as function of the tilt and azimuthal angles of the optical axes of the uniaxial films. Explicit expressions are provided, which can be used to separate the effects of surface anisotropy for anisotropic film from that of its bulk anisotropy, so that these expressions may be utilized in characterizing the surface anisotropy of alignment layers.

Origin of Optical Bounce during switching in the FFS Mode using a LC with Positive Dielectric Anisotropy (유전율이 양인 액정을 이용한 FFS모드의 스위칭시 Optical Bounce 발생 원인에 관한 연구)

  • Ha, Kyung-Su;Jung, Jun-Ho;Kim, Min-Su;Lee, Seung-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.04a
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    • pp.63-64
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    • 2009
  • Optical bounce during switching in the fringe field switching (FFS) mode using a liquid crystal (LC) with positive dielectric anisotropy has been observed. According to the analysis, it occurs at two positions which are center and edge of the pixel electrode, which decreases decaying response time. The former is major and mainly associated with increase in twist angle instantaneously during switching off resulted from decrease in tilt angle near by LC molecules at center. This paper discusses the origin of such optical bounces.

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Photoinduced Anisotropy and Reorientation of Anisotropic Axis in Amorphous $As_2S_3$ Thin Film (비정질 $As_2S_3$ 박막의 광유도 비등방성과 비등방축의 가역성)

  • 김향균
    • Proceedings of the Optical Society of Korea Conference
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    • 1990.02a
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    • pp.162-166
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    • 1990
  • Photoinduced anisotropy (PIA) in amorphous As2S3 (a-As2S3 ) thin film, deposited by vacuum evaporation, is investigated. PIA is induced by linearly polarized Ar+ laser beam (λ=514.5nm) and probed by weak Ar+ laser (λ=514.5nm) and He-Ne laser (λ=632.8nm) beam through the crossed analyzer. Keeping pump beam intensity constantly, rotation of pump beam polarization direction induces reorientation phenomina of anisotropic axis. Introducing directional factor into simplified 3-level system, which is used to analyze photodarkening phenomina, an analytical expression of PIA is derived. Temporal behavior of PIAand its reorientation phenomina are investigated andcompared with theory. In the experiment pump beam intensity is 100mW/$\textrm{cm}^2$ and thickness of a-As2S3 thin film is 3${\mu}{\textrm}{m}$. In those condition, time constant of photoinduced anisotropy obtained by method of least square curve fitting is 4.0$\times$10-2sec-1. The time constant of PIA we obtained is larger than that of photodarkening, 2.8$\times$10-2sec-1.

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