• Title/Summary/Keyword: open-circuit

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Electrochemical properties of AZ31, AZ61 magnesium alloy electrodes for eco-friendly Magnesium-air battery (친환경 마그네슘-공기 전지용 AZ31, AZ61 마그네슘 합금 전극의 전기화학적 특성)

  • Choi, Weon-Kyung
    • Journal of the Korea Convergence Society
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    • v.12 no.5
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    • pp.17-22
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    • 2021
  • Eco-friendly magnesium-air battery is a kind of metal-air battery known as a primary battery with a very high theoretical discharge capacity. This battery is also called a metal-fuel cell from the viewpoint of using oxygen in the atmosphere as a cathode active material and magnesium alloy as a fuel. Since battery performance is determined by the properties of the magnesium alloy used as a anode, more research and development of the magnesium alloy electrode as a anode material are required in order to commercialize it as a high-performance battery. In this study, the commercialized magnesium alloys(AZ31, AZ61) were selected and then electrochemical measurements and discharge test were conducted. Electrochemical properties of magnesium alloys were investigated by OCP changes, Tafel parameters and CV measurement, and the feasibilities of AZ61 alloy with excellent discharge capacity(1410mAhg-1) as electrode materials were evaluated through CC discharge experiments.

Mo,Cu-doped CeO2 as Anode Material of Solid Oxide Fuel Cells (SOFCs) using Syngas as Fuel

  • Diaz-Aburto, Isaac;Hidalgo, Jacqueline;Fuentes-Mendoza, Eliana;Gonzalez-Poggini, Sergio;Estay, Humberto;Colet-Lagrille, Melanie
    • Journal of Electrochemical Science and Technology
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    • v.12 no.2
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    • pp.246-256
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    • 2021
  • Mo,Cu-doped CeO2 (CMCuO) nanopowders were synthesized by the nitrate-fuel combustion method aiming to improve the electrical and electrochemical properties of its Mo-doped CeO2 (CMO) parent by the addition of copper. An electrical conductivity of ca. 1.22·10-2 S cm-1 was measured in air at 800℃ for CMCuO, which is nearly 10 times higher than that reported for CMO. This increase was associated with the inclusion of copper into the crystal lattice of ceria and the presence of Cu and Cu2O as secondary phases in the CMCuO structure, which also could explain the increase in the charge transfer activities of the CMCuO based anode for the hydrogen and carbon monoxide electro-oxidation processes compared to the CMO based anode. A maximum power density of ca. 120 mW cm-2 was measured using a CMCuO based anode in a solid oxide fuel cell (SOFC) with YSZ electrolyte and LSM-YSZ cathode operating at 800℃ with humidified syngas as fuel, which is comparable to the power output reported for other SOFCs with anodes containing copper. An increase in the area specific resistance of the SOFC was observed after ca. 10 hours of operation under cycling open circuit voltage and polarization conditions, which was attributed to the anode delamination caused by the reduction of the Cu2O secondary phase contained in its microstructure. Therefore, the addition of a more electroactive phase for hydrogen oxidation is suggested to confer long-term stability to the CMCuO based anode.

Hot Firing Test of a Quadrature NEA SSD9103S1 Configuration

  • Ja-Chun, Koo;Hee-Sung, Park;Max, Guba
    • International Journal of Aerospace System Engineering
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    • v.9 no.2
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    • pp.1-9
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    • 2022
  • The NEA release mechanism is used to provide restraint and release functions with low shock for critical deployment operations on solar arrays after launch. The GK3 solar array consists of 2 wings and 6 hold down points per panel. The NEA SSD9103S1 is a part of the GK3 solar array hold-down and release mechanism. Each NEA unit is equipped with two Z-diodes which provide power to a NEA unit connected in series after actuation of the fuse wire. This paper presents the hot firing test results of a quadrature NEA SSD9103S1 configuration. One output powers a maximum of 4 NEA SSD9103S1 units simultaneously. The necessary actuation pulse duration has been determined to meet margin requirement for thermal energy of minimum 4. Actuation thermal energy difference is about 6.6% between each half of two fired serial NEAs. Thermal energy margin at worst case is minimum 5.9 in case of an actuation pulse duration of 500 ms. Two series Zener impedance depend on current applied has been characterized by an additional actuation after all fuse wires are open circuit. Total number of actuation commands to the GK3 NEA unit reduce drastically from 24 in case of single NEA configuration down to 8 in case of parallel and quadrature NEA configurations. It can be accommodated by the existing HP2U Pyro design without any impact.

Effect of Pseudomonas aeruginosa Strain ZK Biofilm on the Mechanical and Corrosion Behavior of 316L Stainless Steel and α-brass

  • Farooq, A.;Zubair, M.;Wadood, H.Z.;Deen, K.M.
    • Journal of Electrochemical Science and Technology
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    • v.12 no.4
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    • pp.431-439
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    • 2021
  • This research work aims to investigate the effect of the aerobic bacterium, Pseudomonas aeruginosa on the mechanical and electrochemical properties of the 316L stainless steel and α-brass. These properties of both the alloys were determined after 7 days of exposure to the controlled and inoculated media at 37℃. The microstructural and electrochemical test results revealed the deleterious effects of Pseudomonas aeruginosa. After exposure to the inoculated medium, the scanning electron microscopy (SEM) results showed the larger pitting and formation of relatively dense biofilm on α-brass compared to 316L stainless steel. The tensile strength and hardness of 316L stainless steel were slightly affected after exposure to the controlled and inoculated media. After exposure to the controlled medium and inoculated media, the tensile strength of the α-brass was least affected but a significant decrease in the hardness (from 165 HV to 124 HV) was observed due to the severe attack induced by the Pseudomonas aeruginosa. Similarly, the open-circuit potential of the 316L stainless steel in the inoculated medium was measured to be less active (-410 mV vs Ag/AgCl) than α-brass (-550 mV vs Ag/AgCl). In the inoculated medium, potentiodynamic polarization curves confirmed the severe attack of Pseudomonas aeruginosa on α-brass (7.15 × 10-2 mm/year) compared to 316L stainless steel which registered a corrosion rate of 5.14 × 10-4 mm/year.

Experimental Implementation of a Cableless Seismic Data Acquisition Module Using Arduino (아두이노를 활용한 무선 탄성파 자료취득 모듈 구현 실험)

  • Chanil Kim;Sangin Cho;Sukjoon Pyun
    • Geophysics and Geophysical Exploration
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    • v.26 no.3
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    • pp.103-113
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    • 2023
  • In the oil and gas exploration market, various cableless seismic systems have been developed as an alternative to improve data acquisition efficiency. However, developing such equipment at a small scale for academic research is not available owing to highly priced commercial products. Fortunately, building and experimenting with open-source hardware enable the academic utilization of cableless seismic equipment with relatively low cost. This study aims to develop a cableless seismic acquisition module using Arduino. A cableless seismic system requires the combination of signal sensing, simple pre-processing, and data storage in a single device. A conventional geophone is used as the sensor that detects the seismic wave signal. In addition, it is connected to an Arduino circuit that plays a role in implementing the processing and storing module for the detected signals. Three main functions are implemented in the Arduino module: preprocessing, A/D conversion, and data storage. The developed single-channel module can acquire a common receiver gather from multiple source experiments.

Evaluation of Initial Operation Stability of Hydrogen-Fueled, Low-Temperature Solid Oxide Fuel Cell with Sputtered Ni Thin-Film Anode (스퍼터링 니켈박막 연료극 적용 수소공급 저온 세라믹 연료전지의 초기작동 안정성 평가)

  • SANGHOON JI;WEONJAE KIM;SANGJONG HAN;HYANGYOUN CHANG;NARI PARK;MISEON KIM;SUNGWON KANG;HYUNMAN LIM;JINHONG JUNG;KWANGHO AHN;MIRATUL MAGHFIROH;SUK WON CHA
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.6
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    • pp.743-748
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    • 2022
  • The initial operation stability of hydrogen-fueled, solid oxide fuel cell with Ni thin-film anode fabricated by direct current sputtering was evaluated in terms of electrochemical properties such as peak power density, open circuit voltage, overpotential, and alternating current impedance at 500℃. Hydrogen and air were used as anode fuel and cathode fuel, respectively.

Effect of Ag Alloying on Device Performance of Flexible CIGSe Thin-film Solar Cells Using Stainless Steel Substrates

  • Awet Mana Amare;Inchan Hwang;Inyoung Jeong;Joo Hyung Park;Jin Gi An;Soomin Song;Young-Joo Eo;Ara Cho;Jun-Sik Cho;Seung Kyu Ahn;Jinsu Yoo;SeJin Ahn;Jihye Gwak;Hyun-wook Park;Jae Ho Yun;Kihwan Kim;Donghyeop Shin
    • Current Photovoltaic Research
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    • v.11 no.1
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    • pp.8-12
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    • 2023
  • In this work, we investigated the thickness of Ag precursor layer to improve the performance of flexible CIGSe solar cells grown on stainless steel (STS) substrates through three-stage co-evaporation with Ga grading followed by alkali treatments. The small amount of incorporated Ag in CIGSe films showed enhancement in the grain size and device efficiency. With an optimal 6 nm-thick Ag layer, the best cell on the STS substrate yielded more than 16%, which is comparable to the soda-lime glass (SLG) substrate. Thus, the addition of controlled Ag combined with alkali post-deposition treatment (PDT) led to increased open-circuit voltage (VOC), accompanied by the increased built-in potential as confirmed by capacitance-voltage (C-V) measurements. It is related to a reduction of charge recombination at the depletion region. The results suggest that Ag alloying and alkali PDT are essential for producing highly efficient flexible CIGSe solar cells.

Review of the Silicon Oxide and Polysilicon Layer as the Passivated Contacts for TOPCon Solar Cells

  • Mengmeng Chu;Muhammad Quddamah Khokhar;Hasnain Yousuf;Xinyi Fan;Seungyong Han;Youngkuk Kim;Suresh Kumar Dhungel;Junsin Yi
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.3
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    • pp.233-240
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    • 2023
  • p-type Tunnel Oxide Passivating Contacts (TOPCon) solar cell is fabricated with a poly-Si/SiOx structure. It simultaneously achieves surface passivation and enhances the carriers' selective collection, which is a promising technology for conventional solar cells. The quality of passivation is depended on the quality of the tunnel oxide layer at the interface with the c-Si wafer, which is affected by the bond of SiO formed during the subsequent annealing process. The highest cell efficiency reported to date for the laboratory scale has increased to 26.1%, fabricated by the Institute for Solar Energy Research. The cells used a p-type float zone silicon with an interdigitated back contact (IBC) structure that fabricates poly-Si and SiOx layer achieves the highest implied open-circuit voltage (iVoc) is 750 mV, and the highest level of edge passivation is 40%. This review presents an overview of p-type TOPCon technologies, including the ultra-thin silicon oxide layer (SiOx) and poly-silicon layer (poly-Si), as well as the advancement of the SiOx and poly-Si layers. Subsequently, the limitations of improving efficiency are discussed in detail. Consequently, it is expected to provide a basis for the simplification of industrial mass production.

Analysis of Characteristics and Internal Resistance of Seawater Secondary Battery according to its Usage Environment (해수이차전지의 사용 환경에 따른 특성 및 내부 저항 분석)

  • Seung-pyo Kang;Jang-mok Kim;Hyun-jun Cho
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.29 no.2
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    • pp.223-229
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    • 2023
  • Seawater batteries are next-generation secondary batteries that use seawater as a cathode. They utilize marine resources to provide competitive prices, high eco-friendliness, and a structure suitable for marine applications. Based on these advantages, pouch types and prismatic types have been studied and developed assuming natural seawater exposure. However, because of the electrical characteristics of the secondary battery, its capacity and internal resistance vary depending on the use environment. These characteristics are not only utilized for predicting the life of a battery but also have a direct effect on the capacity and power suitable for a specific situation. Therefore, the internal resistance was analyzed in this study by measuring the capacity depending on the seawater battery use environment and the state-of-charge-open-circuit-voltage measurement method.

Corrosion resistance assessment of nickel-titanium endodontic files with and without heat treatment

  • Tatiana Dias Costa;Elison da Fonseca e Silva;Paula Liparini Caetano ;Marcio Jose da Silva Campos ;Leandro Marques Resende ;Andre Guimaraes Machado;Antonio Marcio Resende do, Carmo
    • Restorative Dentistry and Endodontics
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    • v.46 no.1
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    • pp.6.1-6.10
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    • 2021
  • Objectives: The aim of this study was to evaluate the corrosion resistance of heat-treated (Reciproc and WaveOne) and non-heat-treated (ProTaper and Mtwo) superelastic nickel-titanium endodontic files when immersed in a 5.25% sodium hypochlorite solution. Materials and Methods: Anodic polarization curves were obtained with potential sweeps that began at the open circuit potential or corrosion potential (Ecorr). The pitting potential (Epit) was identified on the anodic polarization curve as the potential at which a sudden increase in current was observed. The micromorphology of the 28 tested files was analyzed before and after the electrochemical assay using scanning electron microscope (SEM). The data were analyzed using 1-way analysis of variance with the post hoc Bonferroni test (for Ecorr) and the Student t-test for independent samples (for Epit). Results: The mean Ecorr values were 0.506 V for ProTaper, 0.348 V for Mtwo, 0.542 V for Reciproc, and 0.321 V for WaveOne files. Only WaveOne and Protaper files exhibited pitting corrosion, with Epit values of 0.879 V and 0.904 V, respectively. On the SEM images of the ProTaper and WaveOne files, cavities suggestive of pitting corrosion were detected. Conclusions: Signs of corrosion were observed in both heat-treated and non-heat-treated files. Of the evaluated files, WaveOne (a heat-treated file) and ProTaper (a non-heat-treated file) exhibited the lowest corrosion resistance.