• Title/Summary/Keyword: opal-A

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2-Dimensional inverse opal structured VO2 thin film for selective reflectance adjustment

  • Lee, Yulhee;Yu, Jung-Hoon;Nam, Sang-Hun;Seo, Hyeon Jin;Hwang, Ki-Hwan;Kim, Minha;Lee, Jaehyeong;Boo, Jin-Hyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.410.1-410.1
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    • 2016
  • Vanadium dioxide ($VO_2$) is a well-known material that exhibits a metal-semiconductor transition at 340 K, with drastic change of transmittance at NIR region. However, $VO_2$ based thermochromics accompany with low visible transmittance value and unfavorable color (brownish yellow). Herein, we demonstrate the adjustment of visible transmittance of $VO_2$ thin film by nanosphere template assisted patterning process using sol-gel method. 2-Dimenstional honeycomb shape was varied as function of diameter of nanosphere and coating conditions. The morphological geometry of the films was investigated by FE-SEM and AFM. Result shows that inversed shape of nanosphere was formed clearly and pattern width was altered according to the bead size. This structure creates the geometrical blank area from the position of nanosphere which improves the optical transmittance at the visible region. Moreover, such patterned $VO_2$ thin film not only maintains the optical switching efficiency, but also generate the gorgeous scattering effect which presumably support the glazing application.

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Visualization of 2-Phase Flow at Heat Pipe using Neutron Imaging Technique (중성자 영상법을 이용한 Heat Pipe 내의 이상유동 가시화)

  • Kim, TaeJoo;Park, SuJi;Kim, JongYul;Doh, SeungWoo
    • Journal of the Korean Society of Visualization
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    • v.14 no.3
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    • pp.15-21
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    • 2016
  • The circular and flat heat pipe were experimentally investigated by using neutron imaging technique. This experimental study was performed at the DINGO of OPAL research reactor, Australia. The diameter of the circular heat pipe is 10 mm and the dimension of flat is $10(width){\times}3(thickness)mm2$, respectively. We used the distilled water as a coolant. The coolant distributions and 2-phase flow patterns were measured under heating conditions. Experimental results show that neutron imaging technique is a good tool to visualize the 2-phase flow and phenomena in the heat pipe. The coolant distributions and 2-phase flow patterns depend on installation posture of the heat pipe and volume ratio of the coolant. Finally, it was discussed to calculate the void fraction by neutron imaging technique.

Particle Flux in the Eastern Bransfield Strait in 1999, Antarctica

  • Kim, Dong-Seon;Kim, Dong-Yup;Shim, Jeong-Hee;Kang, Sung-Ho;Kang, Young-Chul
    • Ocean and Polar Research
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    • v.23 no.4
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    • pp.395-400
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    • 2001
  • A time-series sediment trap was deployed at 1,034 m water depth in the eastern Bransfield Strait from December 25, 1998 to December 24, 1999. About 99 % of total mass fluxes were observed during the austral summer and fall (January, February, and March). The annual total mass flux was $49.2g\;m^{-2}$. Biogenic materials including biogenic silica, organic matter, and carbonate accounted for about 67% of total particle flux, and lithogenic materials contributed about 29%. Biogenic silica was the most dominant (42% of the total flux) in these components. The next most important biogenic component was organic matter, comprising 24% of total mass flux. Calcium carbonate contributed a small fraction of total mass flux, only 0.6%. The annual organic carbon flux was $5.2g\;C\;m^{-2}$ at 1,034m water depth. The annual primary production was estimated to be $21.6g\;C\;m^{-2}$ at the sediment trap site, which seems to be highly underestimated. About 5.5% of the surface water production of organic carbon sinks below 1,034m water depth.

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The Effect on the Mathematical Creativity and Disposition by the Open-ended Learning Activity Approach (개방형 학습활동이 수학적 창의력 및 수학적 성향에 미치는 효과)

  • Beak, Jong-Suk;Ryu, Sung-Rim
    • The Mathematical Education
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    • v.47 no.2
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    • pp.135-154
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    • 2008
  • The purpose of this study is to help to improve the method of math teaching by analysing how learner-centered teaching method offsets mathematical creativity and mathematical disposition. For this purpose, research questions are established as follows; (1) Mathematical creativity between open-ended learning activity approach(OLAA) and general classroom-based instruction(GCI) shows any difference? (2) Mathematical disposition between OLAA and GCI shows any difference? The results obtained through this study were as follows: (1) There was significant difference between OLAA group and CCI group in mathematical creativity. This means that open-ended learning activity approach was generally more effective in improving mathematical creativity than general classroom-based instruction. (2) There was no significant difference between OLAA group and GCI group in mathematical disposition. But the average scores of mathematical disposition except mathematical confidence improved a little. So we can say that open-ended learning activity approach brought an positive influence on students' mathematical disposition. The results obtained in this study suggest that the OLAA can be used to cultivate the children's mathematical creativity and disposition. Therefore, I suggest that teachers should use the OLAA to improve the children's mathematical creativity and disposition.

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Fabrication of Three-dimensionally Ordered Macroporous Electrode Materials by Using PMMA Template (PMMA 구를 주형으로 이용한 3DOM 전극 구조체의 제조)

  • Seo Kyoung Soo;Jung Ha-Kyun;Son Yongkeun
    • Korean Journal of Materials Research
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    • v.14 no.8
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    • pp.587-594
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    • 2004
  • Three-dimensionally ordered macroporous (3DOM) structures of the $LiCoO_2$ electrode materials for Li secondary batteries were fabricated by using the close-packed arrays of PMMA spheres served as templates. In order to successfully fabricate the cathode materials with highly ordered array form, the metal citrates were applied to new precursors. The precursor/template composites were prepared by the infiltration with metal citrate precursors into the voids of template. By removing the PMMA templates, then, the inverse opal structures with the uniform pores of narrow size distribution were resulted. It was confirmed that the 3DOM $LiCoO_2$ material is to take a single phase of rocksalt (R3m) structure. In addition, 3DOM $LiNiO_2$ and $LiMn_{2}O_4$ cathode materials were fabricated using an identical preparation procedure. Also, the morphology of the 3DOM cathode materials calcined at $500^{\circ}C\;to\;700^{\circ}C$ was observed by scanning electron microscope.

ANALYSIS OF ADHESIVE TAPE ACTIVATION DURING REACTOR FLUX MEASUREMENTS

  • Bignell, Lindsey Jordan;Smith, Michael Leslie;Alexiev, Dimitri;Hashemi-Nezhad, Seyed Reza
    • Nuclear Engineering and Technology
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    • v.40 no.1
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    • pp.93-98
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    • 2008
  • Several adhesive tapes have been studied in terms of their suitability for securing gold wires into positions for neutron flux measurements in the reactor core and irradiation facilities surrounding the core of the Open Pool Australian Light water (OPAL) reactor. Gamma ray spectrometry has been performed on each irradiated tape in order to identify and quantify activated components. Numerous metallic impurities have been identified in all tapes. Calculations relating to both the effective neutron shielding properties of the tapes and the error in measurement of the $^{198}Au$ activity caused by superfluous activity due to residual tape have been made. The most important identified effects were the prolonged cooling times required before safe enough levels of radioactivity to allow handling were reached, and extra activity caused by residual tape when measured with an ionisation chamber. Knowledge of the most suitable tape can allow a minimal contribution due to these effects, and the use of gamma spectrometry in preference to ionisation chamber measurements of the flux wires is shown to make all systematic errors due to the tape completely negligible.

Sedimentary Excess Barium from a Core of the Northwest Pacific Ocean: Geochemical Proxy

  • Suk, Bong-Chool;Park, Chan-Hong;Taira, Asahiko;Hyun, Sang-Min
    • Journal of the korean society of oceanography
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    • v.35 no.2
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    • pp.98-108
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    • 2000
  • A geochemical study on a hemipelagic core sediment taken from the northwest Pacific Ocean (eastern edge of the Shikoku Basin) was conducted to use of excess barium (Ba(ex)) for evaluate the paleoceano-graphic changes. Also, the excursion of sedimentary Ba(ex) was compared with those of biogenic opal, carbonate and organic carbon content in the sediment during the last glacial and interglacial periods. The calculated Ba(ex) derived from the major and minor element shows a distinctive glacial-interglacial variations, and the mass accumulation rate (MAR) of Ba(ex) shows coincident variations with the MARs of biogenic fractions. Especially, strong positive correlation (r$^2$=0.85) between the MAR of Ba(ex) and the MAR of biogenic carbonate is recognized. Based on the strong positive correlation(r$^2$=0.85) between the MAR of Ba(ex) and the MAR of carbonate content, we estimated the degree of carbonate dissolution rate during the glacial and interglacial periods. Assuming the proportional variation and the refractory nature of barium exist between two factors, the variation of index Ca/Ba ratio in sediment indicates the degree of carbonate dissolution. Sedimentary Ca/Ba ratios index clearly show a striking fluctuation between the glacial and interglacial periods with higher positive correlation during glacial and lower correlation during interglacial. This fact indicates enhanced carbonate dissolution during interglacial period. Thus, the sedimentary Ca/Ba ratio in sedimentary records can be used as one of the useful tools for estimation of the relative degree of carbonate dissolution. The excursion of Ba(ex) and the sedimentary Ca/Ba ratio follows the typical pacific carbonate dissolution type(enhanced dissolution during interglacial and reduced dissolution during glacial time) as suggested by previous work (e.g., Wu et al., 1990). Variation in sedimentary Ca/Ba ratio thus strongly supports that glacial-interglacial fluctuation in carbonate dissolution has been prevailed in the northwest Pacific Ocean.

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Paleoclimatic Reconstruction in the Central Great Plains Using Environmental Magnetism and Stable Isotope (자성과 동위원소를 이용한 중부대평원의 고기후 복원)

  • Kyeong Park
    • Journal of the Korean Geographical Society
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    • v.33 no.3
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    • pp.377-394
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    • 1998
  • The magnetic record of loess deposits may be one of the most detailed and useful records of Quatermary climate change on the continents. Stratigraphic variations of magnetic parameters define alternating zones of high and low concentrations of magnetic minerals. All the concentration-sensitive magnetic parameters show an increase within the interstadial Gilman Canyon Formation and interglacial Brady soil and a systematic decrease within the Wisconsinan Peoria loess. The influence of climate change on magnetic records is confirmed by a high correlation between the magnetic parameters and biological proxies. Rock magnetic data appear to be better correlated with temperature-sensitive biological proxies than does a precipitation-sensitive index such as the aridity index derived from opal phytoliths. Simultaneous, higher resolution sampling of magnetic and biological proxies proved to be a better sampling tactic, and enhanced the feasibility of rock magnetic parameters as independent climate proxies.

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Selection of Suitable Aggregates for Long-term Stability of Concrete (콘크리트 장기 안정성을 위한 골재의 선택)

  • Yang, Dong-Yoon;Lee, Dong-Young
    • Economic and Environmental Geology
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    • v.28 no.5
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    • pp.519-525
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    • 1995
  • Recently, there have been several cases of serious accidents on concrete structure resulting from rapid deterioration of concrete strength. On the view point of long term stability of concrete, deterioration of concrete strength is mostly due to chemical reaction between alkali and reactive aggregates (alkali-aggreagte reaction; AAR) in concrete rather than a problem of execution. For long-term stability of concrete, concrete aggregates must be carefully selected. Some of rocks used for concrete aggregates contain deleterious minerals reactive to alkali components in concrete. Most of AAR result from chemical reaction between alkali components and reactive silica minerals in aggregates (so called alkali-silica reaction; ASR). The silica minerals are as follows; quartz with seriously distorted lattice structure, volcanic glass, chalcedony, opal, cristobalite, tridymite, etc. ASR may cause expansion and cracks, further collapse in concrete structure, in a few years. In case of crushed aggregates, only a part of rock mass without reactive minerals must be produced in aggregates mine after thorough examination of the distribution of rocks with reactive minerals. In case of natural aggregates, the total content of reactive minerals must be calculated, if, the content is more than 20%, the rate should be lower by mixing other non-reactive crushed- or natural aggregates. If it is obliged to use concrete aggregates all containing deleterious minerals in a discrete area, they must be used with low alkali cement Even if it is low quality in the chemical properties, aggregates with suitable range in the physical properties can be utilized as the aggregate of other purposes.

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Soft-Start Open Circuit Voltage and Constant Current Sequence Control of 2.5[kW] HID Search Lamp for Ship (선박용 2.5[kW] HID 탐사등의 Soft-Start 방식에 의한 개방회로 전압과 점등전류 순차 제어)

  • Park, Noh-Sik;Kwon, Soon-Jae;Lee, Dong-Hee
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.8
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    • pp.45-51
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    • 2008
  • HID(High Intensity Discharge) search lamp for shipment requires a high open circuit and output current compare than vehicle. This paper presents a soft-start open circuit voltage and constant current sequence control method for 2.5[kW] HID search lamp. The proposed method controls the opal circuit voltage and discharge current of HID lamp according to ignition signal with a simple 8-bit micro-processor and PWM device. For the stable control of lamp, micro-processor checks the output voltage and current. And the checked signals are compared with ignition signal and changes the control mode for stable operation. An ignition signal and micro-processor change the control mode from open circuit voltage contort to constant current control. The proposed control scheme is verified from experimental tests of 2.5[kW] HID search lamp for shipment.