• Title/Summary/Keyword: one-step separation

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Removal of PVC from Mixed Plastic Waste by Combination of Air Classification and Centrifugal Process (풍력(風力) 및 습식비중(濕式比重) 선별(選別)에 의한 혼합(混合)폐플라스틱 종말품(終末品)으로부터 PVC 제거(除去)에 관한 연구(硏究))

  • Choi, Woo-Zin;Yoo, Jae-Myung
    • Resources Recycling
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    • v.16 no.5
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    • pp.71-76
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    • 2007
  • The mixed plastic waste generated from households after hand-picking and/or mechanical sorting processes amounts to 1,750,000 ton in 2006, and most of these waste are finally end up with landfill and/or incineration due to the lacks of separation technologies and economical reasons. The mixed plastic wastes can not be used as raw materials for chemical and/or thermal recycling processes because of their high content of PVC(upto 4.0 wt.%). In the present research, gravity separation system has been developed to remove PVC from the mixed plastic waste and to recover the PO-type plastics. This system mainly consists of air classification, magnetic separation, one-step crushing, feeding system at fixed rate and wet-type gravity separation system. The gravity system based on centrifugal separation has been developed at capacity of 0.5 ton/h and it consists of mixing, precleaning, separation, dewatering, recovery system and wastewater treatment system, etc. The main objective of this process is to achieve high separation efficiency of polyolefins with less than 0.3 wt.% PVC content and less than 10% moisture content in the final products. In addition, a crushing unit of with 8 rotor system is also developed to improve the crushing efficiency of soft-type plastics. The system with a capacity of 1.0 ton/h is developed and operational results are presented.

The analysis of alkaline earth metal and its alloy by using of cation exchanger (양이온교환수지에 의한 알칼리 토금속 및 합금의 분리정량)

  • Myon-Yong Park;Byong Cho Lee;Kee Chae Park
    • Journal of the Korean Chemical Society
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    • v.15 no.2
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    • pp.45-48
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    • 1971
  • The various eluents have been used for the separations of alkaline earth metals by elutions through cation exchange resin column by many investigators. We find, the mixed solution of 1M HAc and 1M NaAc (pH 4.75) is the best eluent for this purpose, becouse the one step elution through 7cm Dowex 50w${\times}$8(100~200mesh) resin column with this eluent, gives the quantitative separation. When 2M NaAc is used as a eluent Sr(II) and Ba(II) is separated easily without any contamination of Mg(II) andCa(II). The Ca-Pb alloy which is composed of Cu, Ca, Sr, Ba and abundance of Pb metal is separated quantitatively into its components by the two step elution with 0.3M HAc + 0.3M NaAc(PH 4.75) and 0.5M HAc + 0.5M NaAc(PH 4.75) as eluents through 10cm resin column.

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Hybrid between Inorganic Material and Biological Photosystem1 for Light Energy Application

  • Kim, Yeong-Hye;Nam, Gi-Tae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.272-272
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    • 2013
  • The attractive features of photosynthetic reaction center proteins for energy application make them useful in solar energy conversion to hydrogen fuel or electrical energy. Almost unity charge separation quantum yield and its rapid speed of ~1ns, absorbance region in visible light (480~740 nm) and high proportion of photosynthetically active solar energy of 48.5% allowed photosystem1 to exploited as a bio-material for photo-energy devices. Directionality of photosystem1 in electron transfer can solve main problem in two-step water splitting process where back reaction deteriorates the overall efficiency. In the study, photosystem1 was extracted from spinach and the photo-induced excited electron in the reaction center was utilized in various field of light energy application. First, hydrogen evolving system realized by photodeposition of platinum at the end of the electron transfer chain, with combining specific semiconductor to oxidize water in the first step of Z-scheme. The evaluation by gas-chromatography demonstrated hydrogen evolution through the system. For the further application of photoelectrical material on electrode, photosystem1 have been controlled by copper ion, which is expected to assemble photosystem in specific orientation followed by maximized photoelectrical ability of film. The research proposed concrete methods for combining natural protein and artificial materials in one system and suggested possibility of designing interface between biological and inorganic materials.

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Optimization of KOGAS DME Process From Demonstration Long-Term Test (KOGAS DME 공정의 실증 시험을 통한 최적화 기술개발)

  • Chung, Jongtae;Cho, Wonjun;Baek, Youngsoon;Lee, Changha
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.5
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    • pp.559-571
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    • 2012
  • Dimethyl ether (DME) is a new clean fuel as an environmentally-benign energy resource. DME can be manufactured from various energy sources including natural gas, coal, and biomass. In addition to its environmentally friendly properties, DME has similar characteristics to those of LPG. The aim of this article is to represent the development of new DME process with KOGAS's own technologies. KOGAS has investigated and developed new innovative DME synthesis process from synthesis gas in gaseous phase fixed bed reactor. DME has been traditionally produced by the dehydration of methanol which is produced from syngas, a product of natural gas reforming. This traditional process is thus called the two-step method of preparing DME. However, DME can also be manufactured directly from syngas (single-step). The single-step method needs only one reactor for the synthesis of DME, instead of two for the two-step process. It can also alleviate the thermodynamic limitations associated with the synthesis of methanol, by converting the produced methanol into DME, thereby potentially enhancing the overall conversion of syngas into DME. KOGAS had launched the 10 ton/day DME demonstration plant project in 2004 at Incheon KOGAS LNG terminal. In the mid of 2008, KOGAS had finished the construction of this plant and has successively finished the demonstration plant operation. And since 2008, we have established the basic design of commercial plant which can produce 3,000 ton/day DME.

Accuracy of one-step automated orthodontic diagnosis model using a convolutional neural network and lateral cephalogram images with different qualities obtained from nationwide multi-hospitals

  • Yim, Sunjin;Kim, Sungchul;Kim, Inhwan;Park, Jae-Woo;Cho, Jin-Hyoung;Hong, Mihee;Kang, Kyung-Hwa;Kim, Minji;Kim, Su-Jung;Kim, Yoon-Ji;Kim, Young Ho;Lim, Sung-Hoon;Sung, Sang Jin;Kim, Namkug;Baek, Seung-Hak
    • The korean journal of orthodontics
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    • v.52 no.1
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    • pp.3-19
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    • 2022
  • Objective: The purpose of this study was to investigate the accuracy of one-step automated orthodontic diagnosis of skeletodental discrepancies using a convolutional neural network (CNN) and lateral cephalogram images with different qualities from nationwide multi-hospitals. Methods: Among 2,174 lateral cephalograms, 1,993 cephalograms from two hospitals were used for training and internal test sets and 181 cephalograms from eight other hospitals were used for an external test set. They were divided into three classification groups according to anteroposterior skeletal discrepancies (Class I, II, and III), vertical skeletal discrepancies (normodivergent, hypodivergent, and hyperdivergent patterns), and vertical dental discrepancies (normal overbite, deep bite, and open bite) as a gold standard. Pre-trained DenseNet-169 was used as a CNN classifier model. Diagnostic performance was evaluated by receiver operating characteristic (ROC) analysis, t-stochastic neighbor embedding (t-SNE), and gradient-weighted class activation mapping (Grad-CAM). Results: In the ROC analysis, the mean area under the curve and the mean accuracy of all classifications were high with both internal and external test sets (all, > 0.89 and > 0.80). In the t-SNE analysis, our model succeeded in creating good separation between three classification groups. Grad-CAM figures showed differences in the location and size of the focus areas between three classification groups in each diagnosis. Conclusions: Since the accuracy of our model was validated with both internal and external test sets, it shows the possible usefulness of a one-step automated orthodontic diagnosis tool using a CNN model. However, it still needs technical improvement in terms of classifying vertical dental discrepancies.

Simultaneous determination of betaine and choline using derivatization by HPLC with UV detection (HPLC-UV검출방법으로 유도체화를 통한 비테인과 콜린의 동시분석)

  • Rhee, Insook;Paeng, Ki-Jung
    • Analytical Science and Technology
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    • v.28 no.2
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    • pp.112-116
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    • 2015
  • Extraction of quaternary ammonium compounds (choline and betaine) from plant samples (spinach) using ion exchange resin (AG1, OH form) is a very simple and inexpensive approach. However, it is very hard to determine amounts of choline and betaine simultaneously using high-performance liquid chromatography-ultraviolet (HPLC-UV) detection. Unlike choline, betaine has low molar absorptivity in UV-visible (UV-Vis) region, which makes it difficult to carry out UV-Vis detection of betaine. The mixture of quaternary ammonium compounds (choline and betaine) was derivatized using 2-bromo acetophenone as a derivatizing agent. As a result, choline did not react with the derivatizing agent, whereas betaine formed a betaine derivative. This betaine derivative exhibited detectable UV absorption with baseline separation between choline and the betaine derivative. Thus, with this method, choline and betaine can be determined simultaneously by using the HPLCUV method through one-step derivatization, which is an easy, sensitive, and reliable method.

NUMERICAL STUDY ON THE WAKE OF A SINGLE MICRO VORTEX GENERATOR (Single micro Vortex Generator의 후류에 대한 수치적 연구)

  • Kim, G.H.;Park, S.O.
    • 한국전산유체공학회:학술대회논문집
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    • 2011.05a
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    • pp.494-499
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    • 2011
  • One of the devices to prevent separated flow over a wing or a flap at high angle of attack is a vortex generator. In the present work, we numerically study the flow around a low-profile or micro vortex generator whose height is less than local boundary layer thickness which can delay separation with a minimum drag penalty owing to its very small wetted surface area. As a first step toward a parametric study to efficiently design this MVG flow control system, we simulate the flow around a single MVG on a flat plate. For the simulation, we employ OpenFOAM with Launder-Sharma ${\kappa}$-epsilon model. The analysis results are validated by comparing with experimental results of a rectangular MVG at an angle of attack of 10 degrees whose height is 20% of local boundary layer. Important results and aspects of this numerical study are discussed. We also simulate the flow around rectangular, triangular and trapezoidal MVGs and the results are compared

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Separation of Non-covalently Functionalized Graphene Nanoplatelets via Salting-out Process (염석법을 이용한 비공유 기능기화된 그래핀 나노플레이트렛의 분리 공정 연구)

  • Kim, Joonhui;Yoo, Sung Chan;Cha, Jaemin;Ryu, Hojin;Hong, Soon Hyung
    • Composites Research
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    • v.32 no.3
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    • pp.134-140
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    • 2019
  • Graphene nanoplatelets (GNP), one of the graphene derivatives is famous as the most proper candidate for industrial applications. However, current performance of GNPs as reinforcing filler in composites is limited by their agglomeration and physicochemical heterogeneity. Herein, an approach to produce non-covalently functionalized GNPs (F-GNPs) is reported which possesses potential to be extended as the industrial level of mass production. The one-step functionalization process uses melamine, a low-cost chemical, to prevent agglomeration and dispersion in polar solvents. Furthermore, a purification strategy called salting-out process based on differences in the dispersibility of the individual F-GNP flakes is reported to separate F-GNPs. The functionalization and separation process developed in this paper provides a strategy to use GNPs at the industrial level in composite applications.

Synthesis, Morphology and Permeation Properties of poly(dimethyl siloxane)-poly(1-vinyl-2-pyrrolidinone) Comb Copolymer (폴리디메틸실록산-폴리비닐피롤리돈 빗살 공중합체 합성, 모폴로지 및 투과성질)

  • Patel, Rajkumar;Park, Jung Tae;Park, Min Su;Kim, Jong Hak
    • Membrane Journal
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    • v.27 no.6
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    • pp.499-505
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    • 2017
  • The increasing number of natural disasters resulting from anthropogenic greenhouse gas emissions has prompted the development of a gas separation membrane. Carbon dioxide ($CO_2$) is the main cause of global warming. Organic polymeric membranes with inherent flexibility are good candidates for use in gas separation membranes and poly(dimethyl siloxane)(PDMS) specifically is a promising material due to its inherently high $CO_2$ diffusivity. In addition, poly(vinyl pyrrolidine)(PVP) is a polymer with high $CO_2$ solubility that could be incorporated into a gas separation membrane. In this study, poly(dimethyl siloxane)-poly(vinyl pyrrolidine)(PDMS-PVP) comb copolymers with different compositions were synthesized under mild conditions via a simple one step free radical polymerization. The copolymerization of PDMS and PVP was characterized by FTIR. The morphology and thermal behavior of the produced polymers were characterized by transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). Composite membranes composed of PDMS-PVP on a microporous polysulfone substrate layer were prepared and their $CO_2$ separation properties were subsequently studied. The $CO_2$ permeance and $CO_2/N_2$ selectivity through the PDMS-PVP composite membrane reached 140.6 GPU and 12.0, respectively.

A Study on the Innovative Scheme of the Public IT Project Ordering and Receiving Systems (공공 IT 프로젝트 수발주 제도의 개선방안 연구)

  • Oh, Jong-Woo;No, Gyu-Seong;Kim, Sin-Pyo
    • Journal of Digital Convergence
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    • v.4 no.2
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    • pp.97-108
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    • 2006
  • The purpose of this study is to generate a proper regulation improvement direction of the public If project contract law through the current four contract methods and three methods of the awarding party of a contract method. The research method for this paper is derived from the written materials of the present public IT project contract law. Two problems have been processed in order to produce the results: the current contract methods and the awarding party of a contract method. The current contract methods consist of a competition contract, a private contract, and a supply methodology contract, The methods of the awarding party of a contract display a qualified evaluation regulation, the 2nd step competition bid, a standard cost separation tender, and a contract by a negotiation. The results exhibit that the general competition contract consists of four improvement items. The contract by a negotiation contains five improvement items. The group private contract has one improvement item. And the private contract includes one improvement item. These results implicate that the current public IT project contract law demands better improvement work for the ubiquitous Korea.

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