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Chemical Compositions and Lead Isotope Ratios of Some Glass Beads from Seokga-tap, Gyeongju

  • Kang, Hyung-Tae;Yun, Eun-Young
    • Conservation and Restoration of Cultural Heritage
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    • v.1 no.1
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    • pp.3-8
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    • 2012
  • Chemical compositions and lead isotope ratios for four glass bead samples of Seokga-tap were analyzed and the results were organized. Among 4 glass beads found in the Seokga-tap, 3 pieces were lead glass. Manufacturing method was to firstly grind pebbles finely and mix lead ore to be melt at $740{\sim}760^{\circ}C$. The mixed ratio of silica and lead was 3:7. Moreover, The evaluation on the lead isotope ratio indicated that two lead glass pieces used lead ore from northern Korea. One piece has the direction of southern Korea lead ore, but it requires a further review. One glass bead of Seokga-tap was brown and it was potash lead glass ($K_2O-PbO-SiO_2$) System. The mixed ratio was approximately 50:10:40 for silica, natural saltpeter, and lead, respectively. Lead isotope ratio data fell within the lead ore from northern China. Therefore, it was concluded that potash lead glass found in the Seokga-tap was produced in northern area of China at the end of $10^{th}$ century and transferred to the Seokga-tap.

Heat Characteristic Analysis of Stacking Type HTS Current Lead (적층형 고온초전도 전류도입선의 열 특성 해석)

  • 두호익;임성우;홍세은;윤기웅;한병성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.628-631
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    • 2001
  • Current lead is one of the first proposed devices for the application of High Temperature-Superconductor(HTSC). The current lead provides high current for electrical machine using superconductor from room temperature. Its characteristics that is zero resistance and low heat transfer rate under critical temperature lead to research for the replacement of existing current lead with HTSC. In this paper, we investigated the temperature distributions of stacking type and rod type current lead with each cross-section area and length using Nastran program and compared each temperature distribution. It is obtained from this paper that stacking type current lead has flat temperature gradient and than rod type one and more stable operation as current lead is closely related with its cross-section area and length.

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Corrosion behavior of refractory metals in liquid lead at 1000 ℃ for 1000 h

  • Xiao, Zunqi;Liu, Jing;Jiang, Zhizhong;Luo, Lin
    • Nuclear Engineering and Technology
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    • v.54 no.6
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    • pp.1954-1961
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    • 2022
  • Lead-based fast reactor (LFR) has become one of the most promising reactors for Generation IV nuclear systems. A developing trend of LFR is high efficiency, along with operation temperatures up to 800 ℃ or even higher. One of key issues in the high-efficiency LFR is corrosion of cladding materials with lead at high temperatures. In this study, corrosion behavior of some refractory metals (Nb, Nb521, and Mo-0.5La) was investigated in static lead at 1000 ℃ for 1000 h. The results showed that Nb and Nb521 exhibited an intense dissolution corrosion with obvious lead penetration after corrosion, and lead penetration extended along the grain boundaries of the specimens. Furthermore, Nb521 showed a better corrosion resistance than that of Nb as a result of the elements of W and Mo included in Nb521. Mo-0.5La showed much better corrosion resistance than that of Nb and Nb521, and no lead penetration could be observed. However, an etched morphology appeared on the surface of Mo-0.5La, indicating the occurrence of corrosion to a certain degree. The results indicate that Mo-0.5La is compatible with lead up to 1000 ℃. While Nb and Nb alloys might be not compatible with lead for high-efficiency LFR at such high temperatures.

An investigation of lead absorption in an electric accumulator factory with the use of personal samplers

  • Williams M.K.;King E.;Walford Joan
    • 대한예방의학회:학술대회논문집
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    • 1994.02a
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    • pp.561-575
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    • 1994
  • Williams, M K., King, E., and Walford, Joan (1969). Brit. J. industr. Med., 26, 202-216. An investigation of lead absorption in an electric accumulator factory with the use of personal samplers. Thirty-nine lead workers and controls, in stable conditions of exposure, each wore personal lead-in-air samplers daily for two weeks. During the second week samples for blood lead, urinary lead, urinary coproporphyrin, urinary $\gamma$-aminolevulinic acid (ALA), the punctate basophil count, and haemoglobin were taken daily. Duplicate estimations were made on one day. The lead exposures of men doing almost identical jobs differed by ratios of up to four to one. This could be attributed on y to personal differences in working habits. The correlation coefficients and regression equations of the biochemical tests with lead-in-air and with each other were determined. The mean values and $95\%$ confidence limits of single determinations of some of the biochemical tests corresponding to the two commonly accepted TLVs of lead-in-air (0-20 and 0-15 mg./$m^{3}$) were calculated from the regression equations. For each biochemical test the variation due to analytical error, the variation from day to day within subjects and the residual variation about the regression on lead-in-air were calculated. Previous estimates of the latter are not known. Excessive confidence may be placed in an index of exposure due to its low coefficient of variation within subjects unless the coefficient of variation between subjects about regression is taken into account. The correction for specific gravity of estimations of lead and ALA in spot samples of urine was found to reduce slightly the residual variation between subjects about the regression on lead-in-air and to increase the correlations with lead-in-air and with the other biochemical tests, but these changes were not statistically significant. The modified method used for estimating blood lead and urinary lead is described and validated.

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A Study on Characteristics of Charging and Discharging for Lead Storage Batteries in Series (직렬 연결된 납축전지의 충방전 전압 특성 연구)

  • Moon, Chae-Joo;Jin, Jong-Soo;Seo, Dong-Choon;Jung, Kwen-Sung;Kim, Tae-Gon;Kim, Young-Gu
    • 한국태양에너지학회:학술대회논문집
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    • 2008.04a
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    • pp.75-79
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    • 2008
  • To control the lead storage batteries it is necessary to consider the characteristics of each battery connected in series. In this study, the charging and discharging characteristics of sealed lead storage batteries 12V/1.2A was investigated one by one through experiments. The results of the experiment shows that one should consider the state of each battery to prevent overcharge or deep discharge. Also, we designed an equipment to measure battery voltages simultaneously using micro-controller. This equipment will be useful for monitoring batteries at PV generation system.

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Blood Lead Level and Intelligence among Children (정상 소아들의 혈중 연 농도와 지능지수와의 관련성)

  • Lee, Duk-Hee;Lee, Yong-Hwan;Kim, Jin-Ha;Park, In-Geun;Han, Tae-Young;Jang, She-Han
    • Journal of Preventive Medicine and Public Health
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    • v.28 no.2 s.50
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    • pp.373-385
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    • 1995
  • The association between blood lead of children and Intelligent Quotient(I.Q) was investigated in a sample of 100 boys and girls aged $6\sim8$ years from one primary school within an industrial area of Pusan. The trained undergraduates in school of public health administered an 1.0. test one by one. Parents answered a questionnaire on demographic, perinatal and socioeconomic variables. Atomic Absorbtion Spectrophotometer was used to determine blood lead levels. The geometric mean of blood lead value was $7.99{\mu}g/dl$. In total children, there was no significant relationship between blood lead level and I.Q. But in the children who were born of gestational age of less than 38 weeks, children with higher levels of blood lead performed more poorly on I.Q test with correlation coefficient from -0.68 to -0.71. But, the children who were born of gestational age of 38 weeks and more were same as total children. These results suggest that exposure to low levels of lead in the children who were born premature probably may result in impaired intelligent development. But, We think that more profound study should be performed with sufficient numbers of subjects.

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A Study on the Additive of Positive Paste in Lead Acid Battery (납축전지 양극 Paste 첨가제에 관한 연구)

  • Jeong, Soon-Wook;Ku, Bon-Keun
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.2
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    • pp.196-201
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    • 2010
  • The influence of red lead($Pb_3O_4$) to curing and formation reaction properties when it was added in positive material of lead acid battery for vehicle use has been investigated. At the results, it was confirmed that the addition of red lead led 4BS crystal size to be smaller and increased the rates of 4BS formation and Pb consumption. Consequently the curing time was shortened to half compared with that of red lead-free one. In addition to this, the lead acid battery prepared by adding red lead showed 14% higher efficiency at the life cycle test than that without red lead.

Removal Characteristics of Lead by Immobilizing Agents and Immobilized Seaweed (고정화제와 고정화된 해조류에 의한 납의 제거 특성)

  • 이학성;서정호;서근학
    • Journal of Environmental Health Sciences
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    • v.27 no.1
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    • pp.83-87
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    • 2001
  • In this study, the characteristics of lead removal by PVA and alginate bead which used widely as immobilizing agents were investigated, and the difference of removal amounts between pure PVA/alginate bead and Sargassum thunbergii immobilized bead was studied. All PVA beads, pure and S. thunbergii immobilized, reached an equilibrium state in about 1 hour, and S. thunbergii immobilized bead adsorbed more lead than pure one. But in the case of alginate beads, they needed much time, about 5 hours, to reach an equilibrium state, and adsorbed lead four times higher than PVA beads. Therefore, it was considered that alginate beads had more mass transfer resistance and function groups which adsorb lead such as hydroxyl, carboxyl and etc. than PVA bead. To examine the continuous usage of alginate beads, the process of adsorption/desorption of lead was conducted repeatedly. As the process proceeded, the amounts of lead adsorption decrease, so it was indicated that the non-desorbed lead from alginate bead at first adsorption/desorption process remained constantly.

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The Effect of Occupational Health Service on the Improvement of Worker’s Health in a Lead Using Industry (모연취급 사업장에서의 산업보건사업이 근로자 건강증진에 미치는 효과)

  • Lee, Byeong-Guk;Lee, Gwang-Muk;An, Gyu-Dong
    • 산업보건소식
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    • no.46
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    • pp.3-13
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    • 1987
  • For the purpose of investigating the effect of occupational health service in terms of environmental control and health provision of workers on the improvement of worker's health, authors analysed the data of environmental measurement and health check-up of one lead using industry who started his investment to environmental improvement from 1980. Six hundred million won was invested for environmental improvement from 1980 to 1986. This investment brought about apparent improvement of working conditions of all of the workplaces from mean concentration of lead in air over 0.15mg/$m^3$ 1981 to mean concentration of lead in air less than 0.15mg/$m^3$. Environmental control reduced mean blood lead level from 51.2 $\pm$ 11.5ug/이 in 1983 to 39.2 $\pm$ 16.0ug/dl in 1986, and delta-aminolevulinic acid concentration 3.15 $\pm$ 2.1mg/l in 1982 to 1.96 $\pm$ 1. 7mg/l in 1986, respectively. Blood ZPP levels were decreased from 76.1 $\pm$ 58.9ug/dl in 1983 to 42.23 $\pm$ 30.3ug/dl in 1986. If 150ug/dl of blood ZPP is considered as unacceptable limit of lead intoxication, more than 10 percent of workers belonged to this category in 1983, but only 0.5 of workers showed their blood ZPP level over the 150ug/dl in 1986 It was observed that no workers whose work duration were less than one year showed their blood ZPP level over 100ug/dl, but there were high percentages of lead workers with high blood ZPP (over 150 ug/dl) who were working in uncontrolled had working condition and whose work duration were less than one year.

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Development and Performance Comparison of Silicon Mixed Shielding Material (실리콘 혼합 차폐체의 개발과 성능비교)

  • Hoi-Woun Jeong;Jung-Whan Min
    • Journal of radiological science and technology
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    • v.46 no.3
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    • pp.187-195
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    • 2023
  • A shield was made by mixing materials such as bismuth(Bi) and barium(Ba) with silicon to evaluate its shielding ability. Bismuth was made into a shield by mixing a bismuth oxide(Bi2O3) colloidal solution and a silicon base and applied to a fibrous fabric, and barium was made by mixing lead oxide(PbO) and barium sulfate(BaSO4) with a silicon curing agent and solidifying it to make a shield. The test was conducted according to the lead equivalent test method for X-ray protective products of the Korean Industrial Standard. The experiment was conducted by increasing the shielding body one by one from the test condition of 60 kVp, 200 mA, 0.1sec and 100 kVp, 200 mA, 0.1 sec. At 60 kVp, 2 lead oxide-barium sulfate shields, 2 bismuth oxide 1.5 mm shields, and 5 bismuth oxide 0.3 mm shields showed shielding ability equal to or higher than that of lead 0.5 mm. At 100 kVp, 2 lead oxide-barium sulfate shields and 2 bismuth oxide 1.5 mm shields showed shielding ability equal to or higher than that of lead 0.5 mm. It was confirmed that when using 2 pieces of lead oxide-barium sulfate and 1.5 mm of bismuth oxide, respectively, it has shielding ability equivalent to that of lead. Bismuth oxide and lead oxide-barium sulfate are lightweight and have excellent shielding ability, thus they have excellent properties to be used as an apron for radiation protection or other shielding materials.