• Title/Summary/Keyword: one bath two step method

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Studies on the One Bath Two Step Dyeing of Wool/Cationized Cotton Blends with Acid Dye/Reactive Dye (양모/카티온화 면 혼방품의 산성염료/반응성염료에 의한 1욕2단 염색에 관한 연구)

  • 성우경;이춘길;권오경
    • Textile Coloration and Finishing
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    • v.11 no.2
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    • pp.46-54
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    • 1999
  • The conventional dyeing of wool/cotton blends involves a two bath two step method, i.e., after dyeing of the wool component with acid dyes in an acidic dyebath at $100^\circ{C}$, the dyeing of the cotton component with reactive dyes in an alkaline dyebath is performed. In order to overcome the disadvantage of the conventional two bath two step dyeing method of wool/cotton blends, it had prompted significant effort to the development of the one bath dyeing method which can accomplish savings in time, energy and water usage. To improve dyeing property of wool/cotton blends, cotton component was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. This study was carried out to investigate dyeing possibilities of wool/cationized cotton blends with acid dye/reactive dye by one bath two step method.

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The One Bath One Step Dyeing of Cationized Nylon/Viscose Rayon Mixture Fabrics With Acid Dyes and Reactive Dyes (산성염료와 반응성염료에 의한 카티온화 나일론/비스코스레이온 교직물의 1욕1단 염색)

  • Sung, Woo-Kyung
    • Fashion & Textile Research Journal
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    • v.7 no.3
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    • pp.339-345
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    • 2005
  • It is difficult to dye nylon/viscose rayon mixture fabrics by one-bath one-step dyeing method, because acid dyes and reactive dyes require acidic dyebath for adsorption and alkaline dyebath for fixation respectively. In order to overcome the disadvantage of the conventional two bath two step dyeing method of nylon/viscose rayon mixture fabric, it was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. The pretreated nylon/viscose rayon mixture fabrics produced cationized fabrics that could be dyed with acid dyes and reactive dyes under neutral condition. This study was carried out to investigate dyeing possibilities, surface reflectance spectra and color characteristics of cationized nylon/viscose rayon mixture fabrics with acid dyes and reactive dyes in a non-electrolytic and neutral dyebath by one bath one step dyeing method.

A Study on the One Bath Two Step Dyeing of Wool/Cationized Cotton Blends With Acid Dye/Direct Dye (양모/카티온화 면 혼방품의 산성염료/직접염료에 의한 1욕2단 염색에 관한 연구)

  • Sung, Woo-Kyung;Lee, Choon-Gil
    • Fashion & Textile Research Journal
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    • v.3 no.2
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    • pp.168-173
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    • 2001
  • In order to overcome the disadvantage of the conventional two bath dyeing method of wool/cotton blends, it had prompted significant effort to the development of the one bath dyeing method which can accomplish savings in energy, water usage and time. To improve the dyeability of cotton toward direct dyes in a non-electrolytic and acidic dyebath, cotton component was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. This study was carried out to investigate almost equal color strength between wool component and cationized cotton component when wool/cationized cotton blends was dyed with acid dye/direct dye by the one bath two step method in a non-electrolytic and acidic dyebath.

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A Study on the One Bath Two Step Dyeing of Nylon/ Cationized Cotton Blends with Acid Dye/Direct Dye (나일론/카티온화 면 혼방품의 산성염료/직접염료에 의한 1욕 2단 염색에 관한 연구)

  • 성우경
    • Textile Coloration and Finishing
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    • v.12 no.1
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    • pp.44-51
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    • 2000
  • The conventional one bath exhaust dyeing system of nylon]/cotton blends with acid dye/direct dye involves a lot of neutral salt which affect dyeability of acid dyes. Because of conventional one bath exhaust dyeing system of nylonl/cotton blends with acid dye/direct dye needs acid dyes adjusted at a neutral liquor, suitable acid dye is limited. To improve dyeing property of nylon/cotton blends, cotton component was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. This study was carried out to investigate dyeing possibilities of nylon/cationized cotton blends with acid dye/direct dye in a non-neutral salt dyebath by one bath two step method. The concentration of direct dye was 1.0%, 0.7%, 0.3%o.w.f. respectively at a non, 1%, 3%owf of reserving agent for being almost equal color strength between nylon and 3% cationized cotton when nylon/3% cationized cotton blends was dyed with acid dye/direct dye at concentration of acid dye(1%o.w.f.) by one bath two step method.

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The Disperse Dyeing of Polyester/Cotton Blend Using a Hetero-bifunctional Bridge Compound(II) (이반응형 브릿지 화합물을 이용한 폴리에스테르/면 복합소재의 단일분산염료 일욕염색(II))

  • Kim, Mi-Kyung;Yoon, Seok-Han;Kim, Tae-Kyeong;Yoon, Nam-Sik
    • Textile Coloration and Finishing
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    • v.19 no.1 s.92
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    • pp.1-11
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    • 2007
  • Dyeing of polyester/cotton blends is usually carried out through the two-bath or one-bath two-step dyeing method using proper disperse dyes and reactive dyes for each fiber. However, the dyeing requires relatively long and complicated procedure as well as there are some problems such as lower dyeability. In the present study, new one-bath one-step dyeing process was investigated using disperse dyes having amino groups and hetero-bifunctional bridge compound(DBDCBS) including dichloro-s-triazinyl groups and ${\alpha},{\beta}$-dibromopropionylamido groups to improve the dyeability of cotton component in polyester/cotton blends. And the one-bath dyeing properties of polyester/cotton blends was evaluated by various dyeing conditions such as pH, temperature and dye concentration, The optimum dyeing condition was pH 4 and $110-120^{\circ}C$. Color fastness were relatively good because of the colvalent bond formation between DBDCBS-reacted cotton fiber and disperse dye.

Flame-Retardant and Water-Repellent Finishing of Automobile Indoor Fabrics (자동차 내장용 직물의 난연 및 발수가공)

  • 박병기;이방원;김환철;김학용
    • Textile Coloration and Finishing
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    • v.11 no.5
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    • pp.7-12
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    • 1999
  • The objective of this study is to apply water repellent and flame retardant finishes simultaneously to the fabric used for automobile. Both two step and one step methods were tried to apply the finishing agent to the fabric. In the two step method, water repellent agent was treated first, and flame retardant agent was applied next. The reverse finishing process was also attempted. In the one step method, flame retardant agent and water repellent agent treated to the fabric in one bath. The results of two step method revealed that the finishing effect was better when the water repellent agent was treated first than when flame retardant agent was treated first. In one step method, fluoro water repellent agent was superior to silicon water repellent agent.

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Studies on the Synthesis of Bisphenol Sulfonate Polymers and Their Staining Resist Effect in the Dyeing of Nylon/Cotton Union (Ⅱ) (Bisphenol sulfone산계 고분자의 합성 및 나일론 오염방지성에 관한 연구 (Ⅱ))

  • Choe, Yeong Ju;Song, Seung Jong;Yun, Nam Sik
    • Textile Coloration and Finishing
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    • v.13 no.2
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    • pp.1-1
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    • 2001
  • In the Previous studies, we reported about the synthesis of poly[3-methylence-3-methylenesodiumbisulfite-bis(4-hydroxypheny)sulfone] (PMSBPS) and their effect on the staining of direct dye on nylon in the dyeing of nylon/cotton union. The results showed that PMSBPS have good staining resist effect on nylon in the dyeing of nylon/cotton union. In this study, the staining resist effects of PMSBPS in varied dyeing process and method were investigated, and the fastness to washing, light, and rubbing of the deed N/C unions was tested. The results are as follows ; 1. In the two bath two step method, the staining of direct dye on nylon was decreased with the concentration of PMSBPS, and the fastness to washing, light, and rubbing of the dyed N/C unions were increased by addition of PMSBPS. 2. In the one bath two step method, optimun concentration of PMSBPS was 4% 0.w.f..

Studies on the Synthesis of Bisphenol Sulfonate Polymers and Their Staining Resist Effect in the Dyeing of Nylon/cotton Union ( II ) (Bisphenol sulforn산계 고분자의 합성 및 나일론 오염방지성에 관한 연구 (II))

  • 최영주;송승종;윤남식
    • Textile Coloration and Finishing
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    • v.13 no.2
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    • pp.87-92
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    • 2001
  • In the Previous studies, we reported about the synthesis of poly(3-methylence-3-methylenesodiumbisulfite-bis(4-hydroxypheny )sulfone] (PMSBPS ) and their effect on the staining of direct dye on nylon in the dyeing of nylon/cotton union. The results shoved that PMSBPS have good staining resist effect on nylon in the dyeing of nylon/cotton union. In this study, the staining resist effects of PMSBPS in varied dyeing process and method were investigated, and the fastness to washing, light, and rubbing of the deed N/C unions was tested. The results are as follows , 1. In the two bath two step method, the staining of direct dye on nylon was decreased with the concentration of PMSBPS, and the fastness to washing, light, and rubbing of the dyed N/C unions were increased by addition of PMSBPS. 2. In the one bath two step method, optimun concentration of PMSBPS was 4% 0.w.f..

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A Study on the Dyeing Method of Silk/Polyester Blend Fabrics (견/Polyester 혼방직물의 염색에 관한 연구)

  • Park, Hyun-Tea;Song, Mi-Kyoung;Kim, Gong-Ju
    • Textile Coloration and Finishing
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    • v.3 no.2
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    • pp.16-24
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    • 1991
  • The textile fabric have the functions of sanitation, decoration, wearing style and washing in the practical use. Among various texitle fiber, silk has less utilities than synthetic fiber in practical use although silk has good benefits of the high quality. Thus no textile fiber, neither natural nor synthetic, has all the functions. In this sence, many blend yarns have been improved various functions of fabric. However, this has been disturbed with the problem of dyeing, especially in the case of blend fabric of silk. In this study, we dyed silk/PET blend fabric in one step useing one bath dyeing method by acid dyes/disperse dyes. The results of the experiments can be summarized as follows; 1) Yellow index of silk fabric treated at $130^{\circ}C$ increased about 7.8 (color difference 4.5 NBS) and whiteness decrease about 5%. 2) Both elongation and tensile strength of silk fabric treated at $130^{\circ}C$ of pH 5-6 decreased about 10% and tensile strength of silk spun yarn treated at $60^{\circ}C$ of pH 10 have little changed. 3) While silk/PET blend frbric dyeing, silk soiling of disperse dyes causes from difference of dyeing rate and degree of silk soiling with dyes. 4) Fastness and soiling of silk/PET blend fabric dyed by one bath dyeing method of acid dyes/disperse dyes was same as two bath dyeing method.

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Photovoltaic Performence of Dye-sensitized Solar Cells using ZnO nanostructures (ZnO 나노구조체를 이용한 염료감응형 태양전지의 광전효율)

  • Lee, JeongGwan;Cheon, JongHun;Kim, NaRee;Kim, JaeHong
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.90.1-90.1
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    • 2010
  • Due to the rapidly diminishing energy sources and higher energy production cost, the interest in dye-sensitized solar cells (DSSCs) has been increasing dramatically in recent years. A typical DSSC is constructed of wide band gap semiconductor electrode such as $TiO_2$ or ZnO that are anchored by light-harvesting sensitizer dyes and surrounded by a liquid electrolyte with a iodide ion/triiodide ion redox couple. DSSCs based on one-dimensional nano-structures, such as ZnO nanorods, have been recently attracting increasing attention due to their excellent electrical conductivity, high optical transmittance, diverse and abundant configurations, direct band gap, absence of toxicity, large exiton binding energy, etc. However, solar-to-electrical conversion performances of DSSCs composed of ZnO n-type photo electrode compared with that of $TiO_2$ are not satisfactory. An important reason for the low photovoltaic performance is the dissolution of $Zn^{2+}$ by the adsorption of acidic dye followed by the formation of agglomerates with dye molecules which could block the I-diffusion pathway into the dye molecule on the ZnO surface. In this paper, we prepared the DSSC with the ZnO electrode using the chemical bath deposition (CBD) method under low temperature condition (< $100^{\circ}C$). It was demonstrated that the ZnO seed layers played an important role on the formation of the ZnO nanostructures using CBD. To achieve truly low-temperature growth of the ZnO nanostructures on the substrates, a two-step method was developed and optimized in the present work. Firstly, ZnO seed layer was prepared on the FTO substrate through the spin-coating method. Secondly, the deposited ZnO seed substrate was immersed into an aqueous solution of 0.25M zinc nitrate hexahydrate and 0.25M hexamethylenetetramine at $90^{\circ}C$ for hydrothermal reaction several times.

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