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검색결과 543건 처리시간 0.023초

Preparation and Characterization of Palladium Nanoparticles Supported on Nickel Hexacyanoferrate for Fuel Cell Application

  • Choi, Kwang-Hyun;Shokouhimehr, Mohammadreza;Kang, Yun Sik;Chung, Dong Young;Chung, Young-Hoon;Ahn, Minjeh;Sung, Yung-Eun
    • Bulletin of the Korean Chemical Society
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    • 제34권4호
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    • pp.1195-1198
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    • 2013
  • Nickel hexacyanoferrate supported palladium nanoparticles (Pd-NiHCF NPs) were synthesized and studied for oxygen reduction reactions in direct methanol fuel cell. The NiHCF support was readily synthesized by a comixing of $Ni(OCOCH_3)_2$ and equimolar $K_3[Fe(CN)_6]$ solution into DI water under rigorous stirring. After the preparation of NiHCF support, Pd NPs were loaded on NiHCF via L-ascorbic acid reduction method at $80^{\circ}C$. Pd-NiHCF NPs were electrochemically active for oxygen reduction reaction in 0.1 M $HClO_4$ solution. X-ray absorption near edge structure analysis was conducted to measure the white line intensity of Pd-NiHCF to verify the OH adsorption. As a comparison, carbon supported Pd NPs exhibited same white line intensity. This study provides a general synthetic approach to easily load Pd NPs on porous coordination polymers such as NiHCF and can provide further light to load Pd based alloy NPs on NiHCF framework.

한국성인 정상교합자와 부정교합자의 연조직 측모에 관한 두부방사선 계측학적 비교연구 (A CEPHALOMETRIC COMPARATIVE STUDY ON SOFT TISSUE PROFILE BETWEEN NORMAL OCCLUSION AND MALOCCLUSION IN KOREAN ADULTS)

  • 강홍구;윤태호
    • 대한심미치과학회지
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    • 제4권1호
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    • pp.23-36
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    • 1995
  • The purpose of this artic1e is to compare soft tissue profiles between Korean adults with normal occ1usion and malocclusin and to identify the differences between them. The subjects of this cephalometric study were 40 males with normal occlusion(Group 1), 27 females with normal occlusion(Group 2), 28 adults with Angle's Class II malocclusion(Group 3) and 41 adults with Angle's Class III malocclusion(Group 4). The results of this study were as follows ; 1) People with Angle's Class II malocclusion had tendency to have more labial tipping of lower teeth than people with normal occ1usion. Through NOA angle measurement, it was determined that people with Angle's Class II malocclusion had more protruding midface than people with normal occlusion and people with Angle's Class III malocclusion had retruding midface. 2) Through Powell's esthetic triangle analysis, it was determined that people with Angle's Class II malocclusion had retruding chin and protruding nose. 3) No significant differences between people with normal occlusion and maloclusion could be identified by measuring soft tissue profile angle basis of S-NS plane. 4) There were significant differences between groups with normal occlusion and malocclusion by measuring Facial convexity angle(Significance level 99%). 5) By measuring the distance between each landmark basis of N-Pog plane, People with Angle's Class II malocclusion were identified as having more protruding midface, but there were no significant differences between people with normal occlusion and Angle's Class III malocclusion. 6) By measuring the vertical dimension of the face, it was determined that the lower facial height was higher than the upper facial height in all groups, particularly in group with Angle's Class III malocclusion. 7) By measuring the lips basis of E-line and S-line, it was determined that people with Angle's Class III malocclusion had more, protruding lower lips than people with normal occlusion, while people with normal occlusion, while people with Angle's Class II malocclusion had more protruding upper lips. By measuring the distance between the superior sulcus and inferior sulcus basis of H-line, people with Angle's Class II malocclusion had thicker upper lips than the other's.

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전력계통 사고구간 판정을 위한 Commectionist Expert System (A Connectionist Expert System for Fault Diagnosis of Power System)

  • 김광호;박종근
    • 대한전기학회논문지
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    • 제41권4호
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    • pp.331-338
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    • 1992
  • The application of Connectionist expert system using neural network to fault diagnosis of power system is presented and compared with rule-based expert system. Also, the merits of Connectionist model using neural network is presented. In this paper, the neural network for fault diagnosis is hierarchically composed by 3 neural network classes. The whole power system is divided into subsystems, the neural networks (Class II) which take charge of each subsystem and the neural network (Class III) which connects subsystems are composed. Every section of power system is classified into one of the typical sections which can be applied with same diagnosis rules, as line-section, bus-section, transformer-section. For each typical section, only one neural network (Class I) is composed. As the proposed model has hierarchical structure, the great reduction of learning structure is achieved. With parallel distributed processing, we show the possibility of on-line fault diagnosis.

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Equivariant vector bundle structures on real line bundles

  • Shu, Dong-Youp
    • 대한수학회논문집
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    • 제11권1호
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    • pp.259-263
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    • 1996
  • Let G be a topological group and X a G space. For a given nonequivariant vector bundle over X there does not always exist a G equivariant vector bundle structure. In this paper we find some sufficient conditions for nonequivariant real line bundles to have G equivariant vector bundle structures.

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초등학교 재량활동시간에 라인트레이서를 이용한 C프로그래밍 학습모형 (A C-Programming Learning Model Using a Line Tracer in Discretionary Activity Hours in Elementary Schools)

  • 문외식
    • 정보교육학회논문지
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    • 제15권4호
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    • pp.603-612
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    • 2011
  • 최근 IT 및 융합기술 발달로 로봇이 컴퓨터를 대신하여 문제해결력, 알고리즘향상 학습을 위한 새로운 창의성교구로 각광을 받고 있다. 본 연구에서는 초등학교 고학년생이 재량활동시간에 라인트레이서를 이용하여 프로그래밍학습을 할 수 있도록 교육과정(12차시분)을 제안하고 성공 가능성을 평가하기 위해 차시별 학습결과물 중심으로 성취수준을 평가하였다. 결과로서, 실행오류의 분석을 통해 라인트레이서를 이용한 프로그래밍 학습이 컴퓨터프로그래밍 학습에 비해 창의성요소가 우수함을 확인하였다. 또한, 라인트레이서를 이용한 프로그래밍학습 방법은 컴퓨터를 대신할 새로운 창의성 학습도구로 성공할 수 있는 가능성을 확인하였다.

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교사의 면대면 수업과 사이버 가정 학습의 학습 효과 비교 - 중학교 기술 가정 교과의 '청소년과 소비 생활' 단원을 중심으로 - (Comparison of Learning Effect between Cyber Home Study and Teacher's Lecture in Class - Focusing on the Unit of 'Consumer Life for Youth' in Middle School Technology.Home Economics Subject -)

  • 이혜란;이연숙
    • 한국가정과교육학회지
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    • 제21권2호
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    • pp.139-158
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    • 2009
  • 본 연구는 청소년 소비자교육을 위한 사이버 가정 학습 교수-학습 과정안을 개발하여 사이버 가정학습을 실시 한 후 이의 학습효과를 교사의 면대면 수업과 비교하기 위하여 시도 되었다. 이에 청소년 소비자 교육의 교수-학습 과정안은 현행 7차 교육과정의 중학교 2학년 기술 가정 교과의 대단원 '자원 관리와 환경'에서 중단원 '청소년과 소비 생활'에 기초를 두어 학교에서 학습하게 되는 학교 소비자 교육 내용에 맞게 구성되었다. 사이버 가정 학습을 진행하기 위하여 '소비자 교육'이라는 강좌를 연구자가 개설하고, "중학교 2학년 기술 가정"에 해당하는 강좌에서 청소년 소비자 교육과 관련된 '청소년과 소비 행동', '소비자 정보의 활용', '합리적인 소비생활', '소비자 문제의 발생과 해결'의 4차시 강좌를 선정하였다. 사이버 가정학습 학습 강좌는 학습안내$\rightarrow$학습활동$\rightarrow$평가하기$\rightarrow$분기$\rightarrow$정리하기 의 5단계로 구성되어 있으며, 매체의 화면 구성은 에니메이션과 동영상을 통하여 제시되었다. 학습 효과를 비교하기 위해 중학교 2학년 남 여 학생을 100명을 대상으로 실험집단에게는 사이버 가정 학습을 이수하도록하고, 통제 집단에게는 오프라인 상의 교사의 면대면 수업을 실시한 후 공변량 분석과 대응표본 t 검증을 하였는데, 전체 소비자 태도와 일부를 제외한 소비자태도 하위 영역과 소비자 교육에 관한 지식 에서 유의미한 수업 효과를 보였고, 각 학습방법만의 고유한 학습 효과 또한 전체 소비자 태도와 일부를 제외한 소비자태도 하위 영역에서 유의미한 영향을 미쳤다. 교사의 면대면 강의식 수업이 사이버 가정 학습보다 소비자태도와 지식을 향상 시키는데 보다 효율적으로 나타나 사이버 가정학습은 교사의 면대면 수업을 보조할 수 있는 역할을 할 수 있도록 교수 설계를 하는 것이 바람직하다고 할 수 있다.

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전력회사 계통에 22kV급 초전도 케이블 도입을 위한 적용 개소 고찰 (A Study on the Application of 22kV class Superconducting Cable in Utility Network)

  • 김종율;윤재영;이승렬
    • 한국초전도ㆍ저온공학회논문지
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    • 제5권2호
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    • pp.20-29
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    • 2003
  • As power systems grow more complex and power demands increase, the need of underground transmission system is increasing gradually. But it is very difficult and high in cost to construct new ducts and/or tunnels for power cables in metropolitan areas. HTS (High Temperature Superconducting) cable can carry very high current densities with strongly reduced conductor loss and allow high power transmission at reduced voltage. Therefore HTS cable can transfer more power to be moved in existing ducts, which means very large economical and environmental benefits. A development project for a 22kV class HTS cable is ongoing at a research centers, and the cable manufacturer in Korea. In this paper, we carried out investigation for application of 22kV class HTS cable in Korean utility networks. The results show that the HTS cable is applicable to replace IPB in pumping-up power plant, withdrawal line in distributed generation, withdrawal line in complex power plant, and conventional under ground cable. Finally, as the cost of HTS wire and refrigeration drops, the technical and economical potential of HTS cable is evaluated positively.

22.9kV 혼합배전선로의 뇌과전압 해석 및 중성선 유기 전압 해석 (Analysis of Lighting Overvoltage and Induced Voltage of Neutral Line on the 22.9kV Combined Distribution Line)

  • 홍동석;이종범
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 하계학술대회 논문집 A
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    • pp.510-512
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    • 2000
  • This paper describes the voltage induced at neutral line and the proper location of lightning arrester in combined 22.9 kV class distribution line jointed overhead line and cable each other Modeling is established in ATP Draw to perform simulation. Simulated distribution line at this paper consists of distribution line 4.2km and underground distribution line 2km. Overvoltage and induced voltage are analyzed at several point of combined line. Analysis results was compared to select the best point to install arrester. Such analysis technology will be applied to obtaining capacity and location of arrester in the similar combined distribution line.

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배전용 S2급 차단기의 차단 성능평가 시험법에 관한 연구 (Study on interrupting test method for class S2 circuit breaker of distribution system)

  • 박병락;조만영;김진석;신희상;김재철
    • 조명전기설비학회논문지
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    • 제25권8호
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    • pp.132-139
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    • 2011
  • Technical requirements for medium voltage class circuit breaker were harmonized by IEC and IEEE, and IEC newly adopted the requirements for class S2 circuit-breaker for overhead-line with the ratings of high-frequency TRV(Transient Recovery Voltage), which IEEE already adopted. Under these circumstances, KERI(Korea Electrotechnology Research Institute) studied testing technologies and facilities, which enable to perform interrupting capacity tests for class S2 circuit-breaker. As results, KERI could carry out interrupting capacity tests for medium voltage class circuit breaker rated up to 3-phase 52[kV] 40[kA], which satisfies the IEC standard.

Round robin analysis to investigate sensitivity of analysis results to finite element elastic-plastic analysis variables for nuclear safety class 1 components under severe seismic load

  • Kim, Jun-Young;Lee, Jong Min;Park, Jun Geun;Kim, Jong-Sung;Cho, Min Ki;Ahn, Sang Won;Koo, Gyeong-Hoi;Lee, Bong Hee;Huh, Nam-Su;Kim, Yun-Jae;Kim, Jong-In;Nam, Il-Kwun
    • Nuclear Engineering and Technology
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    • 제54권1호
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    • pp.343-356
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    • 2022
  • As a part of round robin analysis to develop a finite element elastic-plastic seismic analysis procedure for nuclear safety class 1 components, a series of parametric analyses was carried out on the simulated pressurizer surge line system model to investigate sensitivity of the analysis results to finite element analysis variables. The analysis on the surge line system model considered dynamic effect due to the seismic load corresponding to PGA 0.6 g and elastic-plastic material behavior based on the Chaboche combined hardening model. From the parametric analysis results, it was found that strains such as accumulated equivalent plastic strain and equivalent plastic strain are more sensitive to the analysis variables than von Mises effect stress. The parametric analysis results also identified that finite element density and ovalization option in the elbow elements have more significant effect on the analysis results than the other variables.