• Title/Summary/Keyword: oil-absorbent

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A Study on Feasibility of Oil Separation with Oil Absorbent for Spilt Oil Recovery (흡착재에 의한 유출기름 회수용 유수분리의 가능성 연구)

  • 박외철;권병곤
    • Journal of the Korean Society of Safety
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    • v.13 no.2
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    • pp.39-44
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    • 1998
  • An experimental study on oil absorbent was conducted to investigate the feasibility of utilizing absorbents in oil separation from water-oil mixture for spilt oil recovery. Experiments included investigations of absorptivity and filtering performance of a commercial oil absorbent for different diesel oil concentrations. The measured average absorptivity of the absorbent was above 92% for oil concentrations, 5, 10, 15vo1%, that shows good absorbing performance. Filtering the oil-water mixture, however, was too slow to be used for oil separation. An absorbent baffle system was suggested for oil separation which collects oil panicles by increasing contact between the absorbent and oil particles.

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Development of Oil-Absorbent Using by Curdlan (Curdlan을 이용한 기름 흡착제의 개발에 관한 연구)

  • 이창문;이기영;최춘순;이인영
    • KSBB Journal
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    • v.16 no.2
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    • pp.216-219
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    • 2001
  • Experimental studies were carried out to develop oil-absorbent using curdlan solution or gel. Curdlan sponge was prepared by freeze drying. Surface of curdlan sponge was observed with Scanning electron microscopy(SEM). Curdlan sponge absorbed more than 9 times oil and curdlan was recovered by gellation. Curdlan solution gelled at higher temperature than 50$^{\circ}C$ and dissolved at pH 11.0 and viscosity of curdlan solution increased at 40∼50$^{\circ}C$.

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Adsorption Characteristics of Natural Powdered Oil Absorbent for Marine Oil Pollution (해양오염제거용 천연분말상 유흉착재의 흡착 특성에 관한 연구)

  • 김인수;이진석;김동근;고성정
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.7 no.1
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    • pp.7-14
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    • 2001
  • The amount of petroleum consumption has been Increased according to the industrialization and It leads to the increase of the possibility of marine oil pollution. In Korea, some countermeasures including oil skimmer, gelling agent and herding agent of oil have been used for the remediation of the pollution. However, most of them have lets of shortcomings in the application under in-situ condition, because they are sensitive to the situation such as geographical feature, the wind and the tide. In reported literature, the natural powdered oil absorbent which is made of peat moss is an effective mean to clean spilled oil from lake or coast. However, the peat moss is a natural resource which is only Produced from a specific cold weather are like Canada. This indicates that the alternative materials which is readily obtained from everywhere are needed for powdered oil absorbent. Therefore. in the study, same natural materials including pine leaves and straw are tested as the alternative materials for the absorbent. The raw materials were dried and treated by heat at various temperature during several Periods and then. shattered by a grain cracking machine. The oil sorption capacity of the prepared materials was compared according to the methods of heat treatment and their sizes. The proportion of hydrogen cyanide to combustion of the absorbents was measured to confirm their final disposal methods. The biodegradability test of the absorbents was carried our to evaluate possibility of a side pollution in the coast. In was found that the heat treatment of pine leaves enhanced the capacity of oil sorption and decreased the water sorption. The maximum oil sorption was observed for the material treated at 18$0^{\circ}C$for 60 min. The amount of hydrogen cyanide from the combustion were 0.09ml/g, 0.07ml/g for pine leaves and straw respectively meaning that the final disposal by combustion might be feasible. The amount or organic carbon extracted from pine leaves during 7 days was up to 0.015g organic carbon from one gram of pine leaves. but the degradation was as fast as for glucose. It is concluded that the pine leaves can be served as a good raw material for the powdered oil absorbent like peat moss.

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Exothermic Oil Absorbent Sheet for Low-sulfur Fuel Oil (LSFO) Spilled into Seawater in the Winter Season (동절기 해상으로 유출된 저유황 중질유 제거를 위한 발열 흡착포)

  • Park, Han-gyu;Oh, Gyung-geun;Bae, Byung-Uk;Song, Young-Chae
    • Journal of Navigation and Port Research
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    • v.46 no.4
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    • pp.297-302
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    • 2022
  • An exothermic oil absorbent sheet with calcium chloride crystals can be fabricated, by dipping a clean polypropylene fabric in calcium carbonate and hydrochloric acid solution and drying it. The exothermic oil absorbent sheet applied to the seawater surface, releases heat by the dissociation of calcium chloride. The dissociation heat liquefies the solidified low-sulfur fuel oil at a low temperature, and converts it to a state at which it can be absorbed. The optimum mole concentrations of calcium carbonate and hydrochloric acid required for the exothermic oil absorbent sheet, are 0.25 M and 0.5 M, respectively. The oil absorption capacity of the exothermic oil absorbent sheet for low sulfur fuel oil depends on the seawater temperature. But, it is highly excellent at 4.5-7.08 g/g at 10℃, the average seawater temperature during the winter in Korea. The exothermic oil absorbent sheet is an excellent alternative in absorbing low-sulfur fuel oil in winter and removing it from seawater.

Efficiency Characteristics by Mixed Absorbents for the Removal of Odor Compounds in the Wet Scrubber (습식세정탑 내 악취가스 제거를 위한 복합흡수제의 효율 특성)

  • Park, Young G.;Kim, Jeong-in
    • Applied Chemistry for Engineering
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    • v.22 no.1
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    • pp.48-55
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    • 2011
  • It was found that the absorbent mixed with 2-aminoethanol and others has been applied to remove them via chemical neutralization. The absorbent of natural second metabolites was achieved by a removal efficiency of 20~30% by itself depending on treatment conditions, but the complex absorbent mixed with 0.2% amine chemical provides the removal efficiency of over 98%. Optimal removal efficiencies have been examined against two major parameters of the temperature and pH to remove ammonia and hydrogen sulfide gases. The chemical analysis was also performed to analyze the composition of an essential oil by GC-MS. The monoterpenes in an essential oil reacted with odorous compounds by neutralization and their reaction mechanism was partially elucidated.

A Study on the Preparation of Oil Absorbent Using Waste Polyurethane (폐폴리우레탄을 이용한 오일 흡수제의 제조)

  • Kim, Hyung-Soon
    • Journal of the Korean Society of Industry Convergence
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    • v.10 no.2
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    • pp.73-80
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    • 2007
  • The preparation of oil absorbent using waste polyurethane was studied. And the effects of shape, size, and contents of waste polyurethane foam was investigated. The waste foam was treated in shape of powder, cube and bar type generated from rigid sandwich panel process. The tests for flexural strength, combustibility, and water absorptivity were carried out to investigate the mechanical and physical properties of the recycled foams. And the cell microstructure was evaluated through Scanning Electron Micrograph. The recycled foam containing powder-shaped underfilled and showed poor properties that was generated through reactivity of the resins and increasing of slurry viscosity. For the recycled foam with the cube and bar-shaped, the underfilling was caused by interference between the waste PUFs and increasing surface areas of PUF. Low cell density, non-uniformity of cell shape and size, and low adhesion of the boundary surface (new/recycled) was showed as a result of the poor properties. Considering underfilling and the properties of PUF (new/recycled), maximum recycle contents were less than 20 wt% for the powder and above 40 wt% for the cube and bar.

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Bioremediation of Crude Oil by White Rot Fungi Polyporus sp. S133

  • Kristanti, Risky Ayu;Hadibarata, Tony;Toyama, Tadashi;Tanaka, Yasuhiro;Mori, Kazuhiro
    • Journal of Microbiology and Biotechnology
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    • v.21 no.9
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    • pp.995-1000
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    • 2011
  • The bioremediation potential of crude oil by Polyporus sp. S133 pre-grown in wood meal was investigated in two separate experiment trials; liquid medium and soil. The effect of three nutrients (glucose, polypeptone, and wood meal), oxygen flow, and some absorbent on the efficiency of the process was also evaluated. Degradation of crude oil in soil was significantly increased with an addition of oxygen flow and some absorbent (kapok and pulp). The highest degradation rate of crude oil was 93% in the soil with an addition of 10% kapok. The present study clearly demonstrates that, if suitably developed, Polyporus sp. S133 could be used to remediate soil contaminated with crude oil.

Study on Effective Treatment of Waste Gases in Chung-Ju Industrial Complex with Polymeric Absorbent( II ) (고분자 담지제에 의한 청주공단내 공장배기가스의 효율적 처리기술에 관한 연구( II ) - 고분자 담지제의 흡착실험을 중심으로 -)

  • 이상혁;이영순;전종한
    • Journal of the Korean Society of Safety
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    • v.8 no.1
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    • pp.29-34
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    • 1993
  • Two major hazardous gases. SOx and NOx. are emissioned from fossile fuels. SOx has been removed when oil is refined but NOx hasn't. So NOx is very serious problem in air pollution now There are several technologies to remove NOx. e.g. cooling method. scrubbers method. combustion method, polymer membrane method and adsorbent methods. Polymer membrane and adsorbent methods have good economic merit in removal systems of low content hazard gases. Traditional absorbents are porous silicas, aluminas. active carbon and zeolites. But these absorbents act only physisorption which has less removal performance than chemisorption. In this study. polymeric absorbent which has chemisorption as well as physisorption was analyzed about chemical structure and experimented about optimum operation conditions. The results showed that the chemical structure of the polymeric absorbent was expected as polystyrene having -N-CH$_2$COOH absorbent was revealed about 310$m^2$/g. The molar ratio of absored NO to charged NO in absorption experiments was shown 60% of the polymeric absorbent and 45% of zeolite absorbent at 3$0^{\circ}C$.

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Shelf-life Extension of Yukwa (oil puffed rice cake) by $O_2$ Preventive Packing (유과 저장성 향상을 위한 산소 차단 포장시험)

  • Shin, Dong-Hwa;Choi, Ung
    • Korean Journal of Food Science and Technology
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    • v.25 no.3
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    • pp.243-246
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    • 1993
  • For extending the shelf-life of Yukwa (oil puffed rice cake) which is one of the most favorable Korean traditional rice snack, the Yukwa was packed in $O_2$ preventive container and substituted the air with $N_2$ gas or packed with $O_2$ absorbent (ageless sachet). The quality of Yukwa stored at $35^{\circ}C$ was evaluated by POV, AV and TBA including sensory evaluation. The POV of oil in Yukwa of $N_2$ substitute pack and absorbent sachet included were 5.3 and 11.9 meq/kg, respectively, while no packing (control) was 195.5 meq/kg after 90 days storage at $35^{\circ}C$. AV and TBA were also same trend but the gap with the control was not so big. The Yukwa, $N_2$ gas substituted, was better in quality than absorbent treatment in sensory evaluation and no difference was detected in quality of 90 days storage Yukwa at $35^{\circ}C$ with 15 days. The main reason for lower sensory score of absorbent treatment was that the $O_2$ absorbent also absorbed the flavor component of Yukwa.

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Effects of Properties of Raw Materials on Biodiesel Production (바이오디젤 생산에 미치는 원료 특성의 영향)

  • Jeong, Gwi-Taek;Park, Seok-Hwan;Park, Jae-Hee;Park, Don-Hee
    • KSBB Journal
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    • v.23 no.4
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    • pp.335-339
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    • 2008
  • Biodiesel is an alternative and renewable energy source, which is hoped to reduce global dependence on petroleum and environmental problem. Biodiesel produced from a variety of oil sources such as vegetable oil, animal fat and waste oils, and has properties similar to those associated with petro-diesel, including cetane number, volumetric heating value, flash point, viscosity and so on. In this study, we investigate the effect of quality of raw materials on alkali-catalyzed transesterification for producing of biodiesel. The increase of content of free fatty acid and water in oil were caused the sharp decrease of conversion yield. Also, the low purity of methanol in reactant was inhibited the reaction rate. In the case of addition of sodium sulfate as absorbent to prepare catalyst solution, the content of fatty acid methyl ester in product was increased more about 1.6% than that of control. However, the addition of zeolite, sodium chloride and sodium sulfate as absorbent in reactant to remove water generated from reaction did not show any enhancement in the reaction yield. This result may provide useful information with regard to the choice and preparation of raw materials for more economic and efficient biodiesel production.