• Title/Summary/Keyword: oil contamination

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Shearing Conditions on the Interface of a Spherical Water Drop Sinking in Silicone Oil

  • Uemura, Tomomasa;Yamauchi, Makoto
    • Journal of Mechanical Science and Technology
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    • v.15 no.12
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    • pp.1845-1852
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    • 2001
  • This paper deals with the experiment to obtain quantitative information about conditions of the interface between a water drop and surrounding oil. Velocity distributions in very close region of the interface are measured by introducing a new illumination technique and a telecentric lens. It enables precise measurements of velocity distributions in the close region to the interface. Although the measured velocity distributions exhibit strong influence from the solid wall of an experimental tube, the coincidence of inner and outside velocities on the interface is clearly confirmed for the clean interface. The shearing stresses on the interface, which are proportional to the velocity gradient normal to the interface, clearly show conditions of contaminated interface, which can be divided into two parts. From front stagnation point to somewhere near a separation point, the distribution of shearing stresses is well coincide with that of the Hadamard's analytical solution, while the distribution on the latter part of the interface sows quite different feature, which is supposed to be strongly influenced by contamination of the surface.

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Extraction Characteristics and Quantitational Methods for Total Petroleum Hydrocarbons in Soil

  • Jeon, Chi-Wan;Lee, Jung-Hwa;Song, Kyung-Sun;Lee, Sang-Hak;Lee, Jung-Min
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.119-122
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    • 2003
  • Quantitation methods of total petroleum hydrocarbons to determinate oil contaminated level in soil were discussed. Extraction characteristics of several pretreatment methods and practical detection limit and reappearances in gas chromatography/mass spectrometry. with each pretreatment method were investigated. The obtained results showed that the newly adopted quantitation method and mechanical shaking extraction method using methanol with extraction solvent are more practical and applicable to real sample than the conventional methods. In applying these methods to gasoline, kerosene, fuel oil which are major source of soil contamination, the practical quantitation limit and % relative standard deviation was able to determine with range of 2.5 - 10 ppm, 5 - 7 %.

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The Contamination Characteristics of BTEX and TPH Components in Silty Soils with the Oil Leakage Event from Point Source (점오염원 형태의 유류누출 사건에 의한 실트질 토양층에서 BTEX와 TPH 성분의 오염도 연구)

  • Kang, Dong-Hwan;Chung, Sang-Yong;Go, Dong-Ho
    • The Journal of Engineering Geology
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    • v.16 no.4 s.50
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    • pp.393-402
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    • 2006
  • The contamination characteristics of BTEX and TPH components in silty soils with the oil leakage event from point source were studied. The over ratios of three soil pollution standard for TPH component were $1.5{\sim}1.7$ times higher than that of BTEX component. The mean and maximum values of BTEX and TPH components with sample points were B-zone > A-zone > C-zone, and the highest concentrations were measured at $1{\sim}2m$ depth below surface. BTEX and TPH components were increased with linear distance in zone within 120 m and 80 m from point source. For the zone more than 120 m, BTEX and TPH concentrations were under soil pollution standard. The cutoff values of indicator kriging using BTEX and TPH components were defined as confirmative limit, warn- ing limit and counterplan limit. The variograms of indicator-transformed data were selected linear model. The contamination ranges of BTEX and TPH components using confirmative limit and warning limit were estimated similar, but the contamination range of those using counterplan limit was much reduced. The maximum contamination probabilities were estimated by probability maps usinB confirmative limit, warning limit and counterplan limit. The maximum contamination probabilities with three soil pollution standard were estimated 26%, 26% and 13% for BTEX component, and 44%, 38% and 26% for TPH component.

Treatability Study on Oil-Contaminated Soils for Bioremediation Application (유류오염토양의 생물적용기술 적용타당성 검토)

  • Lee, Yeon-Hui;Seol, Mi-Jin;O, Yeong-Suk
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.578-581
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    • 2001
  • A treatability study was conducted using a hydrocarbon-contaminated soil for the oPtimization of bioremediation strategy best fit to a given set of contamination. The applicability of nutrients, biosurfactant, and oil-degrading microorganisms were examined by monitoring $CO_2$ evolution and oil degradation The addition of inorganic nutrients in the form of slow released fertilizer accelerated the initial rate of $CO_2$ evolution by a factor of 3. The application of oil-degrading microorganisms did not significantly increased $CO_2$ evolution or biodegradation efficiency. Application of a commercial biosurfactant was most effect in terms of the total $CO_2$ evolution and the oil degradation rate. The results indicate that $CO_2$ evolution measurement was found to be a simple and reliable countermeasure of crude oil hydrocarbon mineralization for the rapid determination of the best-fit bioremediation strategy.

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Effectiveness of Antimicrobial Starch Coating Containing Thyme Oil against Salmonella, Listeria, Campylobacter, and Pseudomonas on Chicken Breast Meat

  • Goswami, Namita;Han, Jung-Hoon;Holley, Richard A.
    • Food Science and Biotechnology
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    • v.18 no.2
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    • pp.425-431
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    • 2009
  • Antimicrobial coating on chicken carcasses may reduce the effects of cross-contamination and improve product shelf-life and safety. Thyme oil was mixed at 0.5%(v/v) with a pre-gelatinized pea starch coating solution. The coating solution was spread on chicken breast meat after inoculation with selected spoilage and pathogenic bacteria. After inoculation, the chicken meats were packaged in plastic bags and stored at $4^{\circ}C$. During 12 day storage, total aerobic bacteria, lactic acid bacteria, and inoculated organisms were counted at 4 day intervals. Thyme oil treatments reduced the viability of Salmonella as well as the growth of Listeria and Pseudomonas by 2 log CFU/g, and appeared to eliminate inoculated Campylobacter during storage. The addition of thyme oil increased the viscosity of the pre-gelatinized pea starch solution. The results suggested that thyme oil inclusion in an edible starch coating may be a satisfactory delivery system to enhance the safety of processed fresh meat.

Development of a Cold Rolling Oil with Lubricity and Mill Cleanness Property (윤활성 및 압연기 청정성을 겸비한 냉간 압연유의 개발)

  • 한석영;송교봉;이준정
    • Tribology and Lubricants
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    • v.13 no.2
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    • pp.74-81
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    • 1997
  • The purpose of this study is to develop a cold rolling oil with lubricity and mill cleanness property under the rolling conditions of high reduction ratio and high rolling speed. Six kinds of oil samples were blended. Evaluation of lubricity and anti-seizuro property of the samples were carried out with a laboratory scale rolling mill, where the contact conditions between work roll and strip are very close to actual cold rolling mill. Laboratory evaluation for dispersion, contamination, anti-oil stain property and residual carbon, etc. were carried out with several testers such as longterm circulation tester, Coulter counter and Conradson tester. A new high speed cold rolling oil with good lubricity and mill cleanness property was developed compared with the previously developed rolling oil.

The Effectiveness of the Dispersant Use during the "Deepwater Horizon" Incident -REVIEW of the Proceedings from 2011 International Oil Spill Conference- (미국 멕시코만 기름유출사고에서 본 유처리제 사용의 효용성 고찰)

  • Cho, Hyun-Jin;Ha, Chang-Woo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.1
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    • pp.61-65
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    • 2012
  • Once oil has spilled, oil spill responders use a variety of countermeasures to reduce the adverse effects of spilled oil on the environment. Mechanical methods of containment and recovery are preferred as the first response when the use of other methods fail or are ineffective. In these cases, the application of oil dispersants shall be use only as a last resort. While effectiveness of dispersants in removing oil form the sea surface is proven, the use of dispersants is controlled in almost all countries due to the toxicity of their active agents and the dispersed oil on the marine environment. However, according to reports, after dispersant application, no significant toxicity to fish or shrimp was observed in the field-collected samples. Moreover, the results also indicate that dispersant-oil mixtures are generally no more toxic to the aquatic test species than oil alone. During the Deepwater Horizon Incident, dispersants were applied to floating oil and injected into the oil plume at depth. These decisions were carefully considered by state and federal agencies, as well as BP, to prevent as much oil as possible from reaching sensitive shoreline habitats. Net Environmental Benefit Analysis for dispersant use assumed that dispersants appear to prevent long-term contamination resulting absence of oil in the substrate and will benefit marine wildlife by decreasing the risk of significant contamination to feathers or fur. Further study to use dispersants with scientific baseline is needed for our maritime environment which consistently threaten huge oil spill incidents occurrence.

Phytoremediation potential of indigenous Ghanaian grass and grass-like species grown on used motor oil contaminated soils

  • Akutam, Abednego;Pappoe, Alexander Nii Moi;Armah, Frederick Ato;Enu-Kwesi, Lewis
    • Journal of Ecology and Environment
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    • v.37 no.2
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    • pp.41-51
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    • 2014
  • This study investigated the ability of Bothriochloa bladhii (Retz.) S.T. Blake (Poaceae), Cyperus ligularis L. (Cyperaceae), Commelina erecta L. (Commelinaceae), Mariscus umbellatus (Rottb.) Vahl (Cyperaceae), Fimbistylis miliacea L. (Cyperaceae) and Torulinium odoratum L. (Cyperaceae) to clean up various levels of used motor oil (UMO) contaminated soils. The plants were grown in 2 kg garden soils treated to 0%, 1%, 5% and 10% levels of UMO contamination. The plant growth parameters, chlorophyll contents and dry weight of test plants were measured. The phytoremediation ability of these test plants were assessed by measuring the uptake of hydrocarbons in terms of total hydrocarbon content (THC) as well as their percentage degradation values. There was significant (P < 0.05) reduction in leaf chlorophyll contents and dry weights of the test plant species planted in UMO contaminated soils. THC as well as the percentage uptake (or degradation) of hydrocarbons were both lowest in C. ligularis but highest in T. odoratum in all cases. The phytoremediation potential of test plants was highest in soils contaminated with 5% UMO. Based on the results of this study, all test plants with the exception of C. ligularis were potentially capable of undertaking phytoremediation. However, B. bladhii and T. odoratum proved most effective in the uptake and degradation of UMO.

Oil Absorption Effects of Organic Porous Materials (유기 다공성 소재의 흡유 효과)

  • Kang, Young-Goo;Han, Sang-Bum
    • Journal of the Korean Society of Safety
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    • v.21 no.1 s.73
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    • pp.86-91
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    • 2006
  • Oil spills caused by the accidents have been occurred from house and factory waste, grounded tanker, the rupture of storage tank and oil pipelines, the deterioration of various industrial facilities, etc. Many oil spills result in contamination of shorelines and workplace. Fire and explosion may happen from these spills. There are several technologies used for clean-up application, which include use of oil dispersing agents, absorbents, solidifiers, booms and skimmers by physical, chemical, and biological methods. Methods for oil spill clean-up operation are classified into the absorption type, gel type and self-swelling type. Porous materials with oil absorptive properties are classified into micropore, mesopore, and macropore depending on their pore sizes. Recently, new porous materials with smaller size have been developed, but the selective oil absorption in water-in-oil interface demonstrates the macro pore size. In this study oil absorption effects were evaluated using the organic porous materials with a complex function of gel type and swelling type. Samples were subjected to analysis by FT-IR spectroscopy and were characterized in terms of gel formation and morphologies. Oil sorption capacity, pressure retention force and gel strength were also measured. From these results, the physicochemical reactivity before and after gelation was verified and the industrial applications of clean-up operation were suggested.

The Interpretation of Petroleum Species from Contaminated Soil by Complex Oil (복합유류 토양오염에 따른 유종 해석)

  • Lim, Young-Kwan;Kim, Ji-Yeon;Kim, Wan-Sik;Lee, Jeong-Min
    • Journal of Soil and Groundwater Environment
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    • v.24 no.1
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    • pp.17-23
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    • 2019
  • Clean soil environment is of crucial importance to sustain lives of ecosystem and humans. With rapid industrialization, there has been a great increase of soil contamination by accidental releases of petroleum products. In general, soil remediation is an expensive and time-consuming process as compared to cleanup of water and air. Moreover, determining the source and responsible parties of soil pollution often turns into legal conflicts and that further delay the cleanup process of contaminated sites. In practice, total petroleum hydrocarbon (TPH) analysis has been employed to determine the petroleum species and to track down the responsible polluters. However, this approach often suffers from differentiating similar TPH species. In this study, we analyzed TPH chromatogram patterns of 24 domestic petroleum products in specific carbon ranges (${\sim}C_{10}$, $C_{10}-C_{12}$, $C_{12}-C_{36}$, and $C_{36}{\sim}$) and the fractional changes of THP ratio in the mixture products of gasoline, kerosene and diesel. The proposed TPH analysis method in this study could serve as a useful tool to better analyze the petroleum species in soils contaminated with complex oil mixtures, and ultimately be used to identify the polluters of soil.