• Title/Summary/Keyword: observed structural behavior

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The Effects of Deposition Conditions on Deposition Rate and Crystallinity of ZnO Thin Films Deposited by PECVD (PECVD를 이용한 ZnO박막 증착시 증착 변수가 증착속도 및 결정 구조에 미치는 영향)

  • Kim, Yeong-Jin;Kim, Hyeong-Jun
    • Korean Journal of Materials Research
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    • v.4 no.1
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    • pp.90-96
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    • 1994
  • ZnO thin films were deposited using Diethylzinc and $N_{2}O$ gas by plasma enhanced CVD (PECVD) at low substrate temperatures below $300^{\circ}C$. The effect of deposition parameters on the growth rate and the structural properties was determined at various deposition conditions. Crystallized ZnO thin films were successfully deposited even at $150^{\circ}C$ of substrate temperature. Above $200^{\circ}C$ c-axis oriented ZnO thin films, of which a standard deviation of X-ray rocking curve was less than $6^{\circ}$. were deposited on glass substrates. The variation of deposition rate showed different trends depending on substrate temperature and rf-input power. According to the deposition rate behavior as a function of substrate temperature, the transition points were observed resulting from crystallization of ZnO thin films. The activation energies for the deposition of ZnO thin films were 3.1KJ/mol and 1.9KJ/mol for the rf powers of 200W and 250W, respectively.

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Preparation of Semi-solid Fibroin Gel and its Flow Property (반고형 피브로인 단백질 겔의 제조 및 유동특성)

  • Hur, Won;Lee, Shin-Young
    • KSBB Journal
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    • v.24 no.6
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    • pp.563-569
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    • 2009
  • Fibroin is an insoluble structural protein from Bombyx mori. It can be solubilized by dissolving in a hot $CaCl_2$ solution and subsequent dialysis. The aqueous solution is unstable and a transition from aqueous fibroin molecules rich in random coil is undergo to one rich in $\beta$-sheet content, resulting in hydrogelation. However, fibroin gel is so fragile and plastic that its mechanical property should be reformed for various applications. In this report, a semi-solid form of fibroin gel was prepared using glycerol and ethanol and was investigated to analyze their flow properties. A fibroin gel with 80% glycerol showed pseudoplastic and thixotropic properties. The square root of its yield stress varied linearly with fibroin concentration and it extrapolated to zero shear stress at 0.2% fibroin. A fibroin gel with 40% ethanol was shown to be highly thixotropic but its shear-thinning behavior was only observed above a certain level of shear rate. Its pseudoplasticity was restored by a high rate of shear stress.

An Experimental Study on the Prediction of Yield Load Using Ring Analysis Method in Circular Tubular X-Type Cross Sections (링해석법에 의한 X형 강관 격점부의 항복하중 예측에 관한 실험적 연구)

  • Park, Il Min;Na, Seon Hong
    • Journal of Korean Society of Steel Construction
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    • v.11 no.1 s.38
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    • pp.43-54
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    • 1999
  • The divergence connection between steel circular tubes is widely used in such structures as factory facilities, steel circular hollow section truss, and off-shore tower. Steel circular hollow section (SCHS) have close section, and it makes their per-unit production expense higher than open sectioned products like L-shape, H-shape steels, but the sectional resistance of SCHS against vertical compression and torsion is very high. Despite the structural merits of SCHS, however, many engineers dislike to use them in their design because of uncertainty regarding the stress distribution and deformation behavior at their connections. Therefore, this thesis dealt with X-type connections, the most common forms of connection, and studied their load-deformation relationship. It observed how to show the load-deformation relationship at steel circular tube connections according to the diameter-thickness ratio (D/T) of the chord and diameter of branch-diameter of chord ratio (d/D) and suggested prediction yield load using by ring analysis method.

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Weighted Integral Method for an Estimation of Displacement COV of Laminated Composite Plates (복합적층판의 변위 변동계수 산정을 위한 가중적분법)

  • Noh, Hyuk-Chun
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.1 no.2
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    • pp.29-35
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    • 2010
  • In addition to the Young's modulus, the Poisson's ratio is also at the center of attention in the field stochastic finite element analysis since the parameters play an important role in determining structural behavior. Accordingly, the sole effect of this parameter on the response variability is of importance from the perspective of estimation of uncertain response. To this end, a formulation to determine the response variability in laminate composite plates due to the spatial randomness of Poisson's ratio is suggested. The independent contributions of random Poisson's ratiocan be captured in terms of sub-matrices which include the effect of the random parameter in the same order, which can be attained by using the Taylor's series expansion about the mean of the parameter. In order to validate the adequacy of the proposed formulation, several example analyses are performed, and then the results are compared with Monte Carlo simulation (MCS). A good agreement between the suggested scheme and MCS is observed showing the adequacy of the scheme.

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Particle Stabilized Wet Foam to Prepare SiO2-SiC Porous Ceramics by Colloidal Processing

  • Bhaskar, Subhasree;Park, Jung Gyu;Han, In Sub;Lee, Mi Jai;Lim, Tae Young;Kim, Ik Jin
    • Journal of the Korean Ceramic Society
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    • v.52 no.6
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    • pp.455-461
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    • 2015
  • Porous ceramics with tailored pore size and shape are promising materials for the realization of a number of functional and structural properties. A novel method has been reported for the investigation of the role of SiC in the formation of $SiO_2$ foams by colloidal wet processing. Within a suitable pH range of 9.9 ~ 10.5 $SiO_2$, particles were partially hydrophobized using hexylamine as an amphiphile. Different mole ratios of the SiC solution were added to the surface modified $SiO_2$ suspension. The contact angle was found to be around $73^{\circ}$, with an adsorption free energy $6.8{\times}10^{-12}J$. The Laplace pressure of about 1.25 ~ 1.6 mPa was found to correspond to a wet foam stability of about 80 ~ 85%. The mechanical and thermal properties were analyzed for the sintered ceramics, with the highest compressive load observed at the mole ratio of 1:1.75. Hertzian indentations are used to evaluate the damage behavior under constrained loading conditions of $SiO_2$-SiC porous ceramics.

Evaluation of Axial Strains of Reinforced Concrete Columns (철근콘크리트 기둥의 축방향 변형률 평가)

  • Lee, Jung-Yoon;Kim, Min-Ok;Kim, Hyung-Beom
    • Journal of the Korea Concrete Institute
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    • v.25 no.1
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    • pp.19-28
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    • 2013
  • The longitudinal axial strain in the plastic hinge region of reinforced concrete (RC) columns influences on the structural behavior of RC structures subjected to reversed cyclic loading. This strain decreases the effective compressive strength of concrete and increases the lateral displacements between stories by causing the elongation of member length. This paper investigated the effects of the axial force on the elongation of a RC member by using a sectional analysis of RC members. The analytical and experimental results indicated that the axial force decreased the axial strain in the plastic hinge region of RC columns. In this study, a model was proposed to predict the axial strain of RC columns. The proposed model considering the effects of axial force ratio consisted of three path types ; Path 1-loading region, Path 2-unloading region, and Path 3-reversing cyclic loading region. The axal strains predicted by the proposed model were compared with the test results of RC columns with various axial force ratios, and agreed reasonably with the observed longitudinal strains.

$\beta$-Alanine Induced Down-Regulation of the Taurine Transporter Activity in the Human Colon Carcinoma Cell Line (HT-29) (인체 소장상피세포주 모델(HT-29)에서 $\beta$-알라닌이 타우린수송체 활성에 미치는 영향)

  • 박태선;윤미영;정한나;이해미
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.30 no.2
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    • pp.314-319
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    • 2001
  • In the present study, effects of $\beta$-alanine, a known taurine antagonist for its structural similarity, on the adaptive regulation and kinetic behavior of the taurine transporter were investigated in the HT-29, human colon carcinoma cell line. Pretreatment of the cell with $\beta$-alanine(10mM) for varying periods from 3 to 30 hrs significantly reduced the taurine uptake compared to the value for control cells. This decrease in the taurine transporter activity was dependent on the incubation time with $\beta$-alanine, and the maximal down-regulation of the transporter activity was observed in cells pretreated with $\beta$-alanine for 24 hrs (25% of the control value, p<0.01). The taurine transporter appears to bind exclusively with $\beta$-alanine in the HT-29 cells since the same concentration of $\alpha$-alanine added in the culture medium for 24 hrs did not influence the taurine uptake. Kinetic analyses of the taurine transporter activity was performed in the HT-29 cell line with varying taurine concentration (5~60$\mu$M) in the uptake medium. Active taurine uptake was significantly lower in $\beta$-alanine pretreated cells compared to the value for control cells in the range of taurine concentration used in the experiment (p<0.001). The cells pretreated with $\beta$-alanine showed a 50% lower maximal velocity (Vmax, 1.7$\pm$2.0 nmole.mg $protein^{-1}$.$30min^{-1}$), and a 99% higher Michaelis constant (Km, 40.3$\pm$7.6$\mu$M) than the control values (3.3$\pm$1.9 nmole.mg $protein^{-1}$.$30min^{-1}$, and 20.3$\pm$2.1$\mu$M, respectively). These results on kinetic data suggest that $\beta$-alanine induced down-regulation of the taurine transporter activity was associated with decreases in both maximal velocity and affinity of the transporter.

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Effect of N2 flow rate on growth and photoluminescence properties of GaN nanorods grown by using molecular beam epitaxy (분자선 에피택시를 이용하여 GaN 나노로드를 성장시 구조 및 광학적인 특성에 미치는 N2의 양의 효과)

  • Park, Y.S.
    • Journal of the Korean Vacuum Society
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    • v.16 no.4
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    • pp.298-304
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    • 2007
  • We have studied the effect of $N_2$ flow rate on the structural and optical properties of GaN nanorods grown on (111) Si substrates by radio-frequency plasma-assisted molecular-beam epitaxy. The hexagonal shape nanorods with lateral diameters from 80 to 190 nm with increasing $N_2$ flow rate from 1.1 to 2.0 sccm are obtained. However, the ratio of length (thickness) and compact region increases with increasing $N_2$ flow rate up to 1.7 sccm and then saturate. From the photoluminescence, free exciton transition is clearly observed for GaN nanorods with low $N_2$ flow rate. And the PL peak energies are blue-shifted with decreasing diameter of the GaN nanorods due to size effect. Temperature-dependent photoluminescence spectra for the nanorods with $N_2$ flow rate of 1.7 sccm show an abnormal behavior like "S-shape" with increasing temperature.

A Study on the Precipitation Behavior of Carbide Particle in L12-type Intermetallic Compound Ni3Al (L12형 금속간화합물 Ni3Al중에 탄화물입자의 석출거동에 관한 연구)

  • Han, Chang-Suk;Koo, Kyung-Wan;Oh, Dong-Cheol
    • Korean Journal of Materials Research
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    • v.16 no.4
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    • pp.241-247
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    • 2006
  • Structural studies have been performed on precipitation hardening discovered in $L1_2-ordered\;Ni_3(Al,Cr)$ containing 0.2 to 3.0 mol% of carbon using transmission electron microscopy (TEM). Fine octahedral precipitates of $M_{23}C_6$ appeared in the matrix by aging at temperatures around 973 K after solution treatment at 1423 K. TEM examination revealed that the $M_{23}C_6$ phase and the matrix lattices have a cube-cube orientation relationship and keep partial atomic matching at the {111} interface. After prolonged aging or by aging at higher temperatures, the $M_{23}C_6$ precipitates then adopt a rod-like morphology elongated parallel to the <100> directions. Deformation at temperature below 973 K, typical Orowan loops were observed surrounding the $M_{23}C_6$ particles. At higher deformation temperatures, the Orowan loops disappeared and the morphology of dislocations at the particle-matrix interfaces suggested the existence of attractive interaction between dislocations and particles. The change of the interaction modes between dislocation and particles with increasing deformation temperature can be considered as a result of strain relaxation at the interface between matrix and particles.

An Addition Effect of Amine and Cethyl Trimethyl Ammonium Bromide on Alkali-treatment of Polyester (폴리에스테르직물의 수산화나트륨 처리시 아민과 CTAB의 첨가효과)

  • Lee Jung Soon;Ryu Hyo Seon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.16 no.3 s.43
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    • pp.335-344
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    • 1992
  • This study was conducted to investigate the influence of addition of cetyl trimethyl ammo­nium bromide (CTAB), and amine [ethylamine (EA) or ethylene diamine (EDA)] to aqueous sodium hydroxide (NaOH) solution on polyester alkaline hydrolysis, The experimental vari­ables such as CTAB concentration, EA or EDA concentration, NaOH concentration, tempera­ture and time were compared, and the changes in physical and chemical properties of alkaline­hydrolyzed PET fabrics depending on their treated conditions were measured, The results are as follows: 1. By adding CTAB and amine in aqueous NaOH solution, increasing effect on weight loss of PET fabrics was obtained in simultaneous addition of CTAB and EDA, but not in CTAB and EA. 2. By adding CTAB & EDA simultaneously, increasing effect on weight loss was obtained regardless of EDA concentration, time and temperature, and it was more effective at lower NaOH concentration. :l. The increase of void space (or irregularly grooved surface), of softness, of wickability, of dyeability on PET fabric, and the decrease of tensile strength, of molecular weight were observed according to the weight loss on the PET fabrics. These changes were equal to all alkaline-hydrolyzed PET fabrics regardless of addition of CTAB and amine. l. There was little changes on crystallinity, thermal behavior when PET fiber was treated with ,aqueous NaOH solution with CTAB and EDA. These results supported that increasing effect on weight loss take place without inducing of fine structural change of PET fibers.

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