• 한국염색가공학회지
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• 제28권4호
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• pp.231-238
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• 2016

We investigated the evolution of crystal formation as a function of drawing ratio in poly(1,4-diaminobutane-co-adipic acid-co-${\varepsilon}$-caprolactam-co-diethylenetriamine)(nylon 466T) copolymer formed by four monomers, i.e 1,4-diaminobutane, adipic acid, ${\varepsilon}$-caprolactam, diethylenetriamine(DETA), using synchrotron X-ray scattering measurement. In case of pristine(as spun) nylon 466T fiber, it was consisted with unoriented nylon $6{\alpha}$ and unoriented nylon $46{\alpha}$ phases. As increase the drawing ratio, unoriented nylon $6{\alpha}$ was transformed to oriented ${\gamma}$ phase, while unoriented nylon $46{\alpha}$ changed to oriented $46{\alpha}$ phase. The effect of the addition of DETA was not observed in the pristine fibers. However, DETA affected to restrict the formation of crystals at the maximum drawing condition, and as a result it had a role to increase the moisture regain.

• 폴리머
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• 제27권3호
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• pp.201-209
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• 2003

나일론의 종류에 따른 분쇄형 탄소 섬유/나일론 복합재료의 직류 및 교류 전도도, 그리고 전자기파 차폐 효율을 조사하였다. 탄소 섬유의 함량이 약 7 vol%에서 전도도가 급격하게 증가하는 percolation 전이가 관찰되었다. 나일론 46을 기저 수지로 하였을 경우 더욱 높은 전기 전도도를 나타냈으며, 계면 결합제의 적용 여부에 따라 전도도의 차이가 발생하였다. 온도증가에 따라 전도도가 증가하는 negative temperature coefficient 현상을 나타냈으며, percolation 전후의 탄소 섬유 함량에서의 주파수에 따른 전도기구를 완화와 공진 현상으로 각각 달리 설명할 수 있었다. 회로망 분석기를 통하여 측정한 전자기파 차폐 효율은 전도도 및 탄소 섬유의 함량에 따라 증가하였으며, 높은 전도도 영역에서의 전자기파 차폐 효율은 반사에 의한 차폐가 지배적이었다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.419-419
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• 2012

We fabricated the Polyamide 4,6 (PA46) thin film using Adipoyl chloride and 1,4-butadiamine. PA46 film was grown at $70^{\circ}C$ by Molecular Layer Deposition (MLD) method. MLD is sequential and self-terminating fabrication method for organic thin film. The growth rate of PA46 is $3.5{\acute{\AA}}$ cycle. The thickness of PA46 film was measured by Ellipsometer. Surface morphology of this film was investigated by Atomic Force Microscopy (AFM) and roughness is directly proportional to number of growing cycles.

• 한국항공우주학회지
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• 제46권10호
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• pp.867-875
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• 2018

종래의 큐브위성용 나일론선 절단방식 태양전지판 구속분리장치는 단순히 패널 평면상에 나일론선을 체결함에 따른 취약한 구속력으로 인해 태양전지판 면적이 증가함에 따라 발사하중에 대한 구조 건전성 확보에 한계가 존재한다. 본 연구에서는 전술한 종래 분리장치의 한계점 극복을 위해 Ball & Socket 접속부가 반영된 별도의 타원형 브라켓을 적용하여 높은 구속력, 전개 및 평면 방향 동시구속 및 체결작업의 용이성 등의 장점을 갖는 6U 큐브위성용 태양전지판 구속분리장치를 제안하였다. 상기 구속분리장치의 설계 방향성 파악을 위해 큐브위성용 태양전지판 조립체에 대한 발사하중을 고려한 구조해석을 실시하였다. 또한, 상이한 온도조건에서의 나일론선 두께 및 체결횟수에 따른 기능시험을 수행하여 제안된 구속분리장치의 유효성을 검증하였다.

• 대한화학회지
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• 제17권1호
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• pp.40-46
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• 1973

Nylon 6 의 후중합 반응을 질소흐름, 밀봉 및 감압의 세조건하에서 행하였다. 각 조건에 있어서 점도와 중합물의 감량은 반응온도 및 반응시간에 따라 증가하였고, 같은 반응온도에서의 점도는 감압, 밀봉, 질소흐름의 순서로 증가하였다. 후중합의 activation energy는 10.5kcal/mole로 계산되었다

• 한국식품조리과학회지
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• 제19권4호
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• pp.439-446
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• 2003

This study was performed to investigate the change in the chemical components of red pepper powder using different packaging materials and various storage conditions. Red pepper powders with 11 and 15% initial moisture content were packed with five different materials and stored at different temperatures (0, 20, and 30 C) for a one year period. Over the storage period, each combination was periodically sampled, and examined for composition changes. The five packaging materials were: linear low density polyethylene(LLDPE), nylon/LLDPE(Ny/LLDPE), saran coated ethylene vinyl acetate copolymer/linear low density polyethylene(B650), nylon/Tie/nylon/ethylene-vinyl alcohol copolymer/nylon/Tie/LLDPE(RDX-2787) and oriented polypropylene/alumimum/LLDPE(OPP/Al/LLDPE), and the three storage conditions were (28.3${\pm}$1.0)$^{\circ}C$ with (15.5${\pm}$2.8)% relative humidity, (18.6${\pm}$0.5)$^{\circ}C$ with (46.6${\pm}$4.9)% RH, and (0${\pm}$2)$^{\circ}C$ with (80${\pm}$10)% RH, respectively. The moisture contents of all samples changed according to the relative storage humidity, except those of the samples packed with OPP/Al/LLDPE, which remained constant throughout the storage period. The capsaicinoids content of the red pepper powder did not change significantly for 6 months, but gradually decreased after that until about 85% of the original amount remained at the final stage of storage. The ASTA color values of all samples decreased gradually throughout the storage period. The higher the storage temperature, the more severe the deterioration. The color deterioration seemed greatly related to the existence of oxygen, as the deterioration was especially severe in the samples packed with LLDPE and B650, where the oxygen transmission rate were highest among the five packaging materials.

• 대한가정학회지
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• 제46권9호
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• pp.1-6
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• 2008

홍화 황색소와 홍색소로 염색을 한 나일론 직물에 자외선을 조사 한 후 시료들의 염착량과 색채변화, 표면 특성 변화와 인장 강도 변화를 측정한 결과는 다음과 같다. 1. 색소의 종류에 상관없이 자외선 조사시간 증가에 따라 염착량이 감소되었다 그러나 홍색 소보다는 황색소로 염색한 시료들의 자외선 조사 28일 후의 염착량 보유율이 더욱 낮았다. 2. 색채변화의 경우, 황색소로 염색한 시료들은 $L^*$은 증가하고 $a^*$와 $b^*$는 감소하였으며, H/VC, ${\Delta}E$등 색채 전반에 퇴색이 나타났다. 홍색소로 염색한 시료들 도 자외선 조사 시간 증가에 따라 $L^*$은 증가하고 $a^*$는 감소하였으며, $b^*$는 증가하였고, H/VC, ${\Delta}E$등 색채 전반에 퇴색이 나타났다. 그러나 홍색소와 황색 소로 염색한 나일론 직물 시료의 조사 28일 후의 색차는 황색소가 더욱 낮아 나일론 직물에는 황색소가 자외선에 대한 견뢰도가 더욱 높은 것으로 보인다. 3. 자외선 조사 시간에 따른 표면 특성 변화의 결과, 색소의 종류와 상관없이 조사 28일 후 모든 시료들에서 심한 손상을 관찰할 수 있었다. 4. 자외선 조사 시간에 따른 인장 강도 변화 결과, 모든 종류의 시료에서 자외선 조사 시간 증가에 따른 강도의 손실을 알 수 있었다. 그러나 홍색소보다는 황 색소로 염색한 나일론 직물 시료들의 인장 강도 보유율이 상대적으로 높은 것으로 나타났다.

• 수산해양기술연구
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• 제46권3호
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• pp.257-264
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• 2010

In order to improve the breaking strength and elongation of Polybutylene succinate (PBS) monofilament, the monofilament was produced by blending PBS and Polybutlyne adipate-co-terephthalate (PBAT). The PBS/PBAT blend monofilament was prepared by the melt spinning system, and the weight ratios of the compositions of PBS/PBAT was 100/0, 95/5, 90/10 and 85/15, respectively. The breaking strength, elongation, softness and crystallization of PBS/PBAT blend monofilament were analyzed by using a tensionmeter, softness measurement, X-ray diffractometer in the both dry and wet conditions. The PBS/PBAT blend monofilaments were spun in the take-up velocity of 1.19m/sec under the drawing ratio of 6.8:1 condition. The production volumes of PBS/PBAT blend monofilaments showed 20% less than that of Nylon. The breaking strength of PBS/PBAT blend monofilaments were decreased as PBAT contents increased, while elongation and softness were increased. In case of PBAT content were over 5%, the breaking strength, elongation and softness of PBS/PBAT blend monofilaments were not shown to increase in spite of increasing in PBAT contents. Based on these results, it was possible to make the monofilaments with the maximized physical properties when the PBAT contents at 5%.

• Asian-Australasian Journal of Animal Sciences
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• 제12권7호
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• pp.1054-1062
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• 1999

The effects of dry roasting whole faba beans (WFB) and whole lupin seeds (WLS) at 110, 130 or $150{^{\circ}C}$ for 15, 30 or 45 min on rumen (RDCP%), estimated intestinal (IDCP%) and total tract disappearance of CP (TDCP%) and intestinal availability (IARUCP%) of rumen undegraded CP (RUCP%) were determined. The RDCP values were estimated by in sacco technique by incubating nylon bags for 8, 12 and 24 h in the rumen of dairy cows. The IDCP and IARUCP values were estimated using a sequence of ruminal incubation, in vitro incubation in acid-pepsin for 1 h and then in pancreatin for 24 h of three-step in vitro procedure technique. Dry roasting at 130 and $150^{\circ}C$ decreased RDCP with correspondingly increasing IDCP. The IDCP value generally increased from 12.3(raw) to 8.6, 14.8 and 39.6% (WFB) and from 28.3 (raw) to 33.7, 36.2 and 56.2% (WLS) at 8 h rumen incubation; from 2.9 (raw) to 2.9, 4.6 and 23.3% (WFB) and from 19.6 (raw) to 19.0, 24.0 and 46.6% (WLS) at 12 h rumen incubation; from 1.3 (raw) to 1.9, 1.7 and 11.0% (WFB) and from 4.4 (raw) to 4.2, 10.7 and 36.7% (WLS) at 12 h rumen incubation as the temperatures rose to 110, 130 and $150{^{\circ}C}$ respectively. The TDCP values were always high and increased by time in the rumen, the average values of which were 97.9, 96.6; 99.2, 96.9 and 99.6, 98.7% for WFB and WLS, respectively, at 8, 12 and 24 h rumen incubation. But within the same retention time, TDCP was generally unchanged. The average IARUCP increased from 87.3 (raw) to 87.4, 88.7 and 92.0% (WFB); from 87.6 (raw) to 88.9, 91.5 and 93.0% (WLS) at roasting temperatures of 110, 130 and $150{^{\circ}C}$, respectively. It was concluded that dry roasting can shift the digestion of CP from rumen to the lower gastrointestinal tract without depressing the digestion of RUCP. The best processing condition in this study was dry roasting at $150{^{\circ}C}$ for 45 min in terms of effects on the disappearances and availability of CP. Research data on intestinal availability of individual amino acids need to be further investigated.

• 수산해양기술연구
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• 제46권4호
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• pp.281-291
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• 2010

To estimate the mesh selectivity of monofilament and multifilament gill net for Marbled sole, Pleuronectes yokohamae, the field testes were carried out 12 times with five different mesh sizes (86.6, 101.0, 121.2, 137.7, 151.5mm) in the western sea of Korea, 2007-2009. The master curve of selectivity was estimated by the extended Kitahara's method. In the field testes, the total number of species and catch were 26 and 987, respectively. The catch number of marbled sole was 728 and occupied 73.8% in total catch. The optimum values of l/m for 1.0 of retention probability in monofilament and multifilament gill net were estimated 0.288 and 0.307, respectively and l/m was estimated to be 0.189, 0.203, 0.213, 0.222 and 0.230 in case of monofilament gill net and 0.171, 0.191, 0.205, 0.216 and 0.227 in case of multifilament gill net when the retention probability were 0.1, 0.2, 0.3, 0.4 and 0.5, respectively. The 0.5 selection range of multifilament gill net was wider about 1.5 times than that of monofilament gill net according as multifilament gill net was 0.216 and monofilament gill net was 0.148. So the multifilament gill net has a low selectivity than that of the monofilament gill net. To estimate the optimum mesh size on first maturity length 19.5cm of marbled sole, the retention probability value of 0.1 was adopted in consideration of using the gill net for marbled sole at present. The optimum mesh size were estimated to be 103.2mm and 114.0mm in monofilament gill net and multifilament gill net, respectively, on first maturity length 19.5cm of marbled sole.