• 한국자동차공학회논문집
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• 제10권6호
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• pp.142-149
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• 2002

The frictional properties of nylon can be improved by the impregnation of lubricants like wax, oil or graphite. The inclusion of these lubricants, on the other hand, decreases the mechanical properties of nylon, such as tensile strength, hardness and impact strength. As an attempt to maximize frictional properties, while minimizing a decrease in the mechanical properties, various kinds of nylon containing 3 wt% wax and varying contents of oil or graphite were prepared. It was found that the synergy effects to improve both friction and anti-wear properties is evidenced by impregnating a combination of wax/oil or wax/graphite. The wear rate of a nylon containing 3 wt% of wax and 1.5 wt% of oil turned out to be 1/4 of that of nylon impregnated with 8 wt% wax or 8 wt% oil. The latter showed the lowest wear rate among the nylons prepared with a single lubricant. In addition, the friction coefficient of the developed nylon was found to be very similar to the nylon with 8 wt% wax only.

• 공업화학
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• 제4권4호
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• pp.791-797
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• 1993

생물공학에의 투과증발공정의 응용은 성장 중에 있다. 2단계 투과증발공정이 에탄올 발효의 분리공정에 적용되어질 수 있다. 본 논문에서는 물-에탄올의 조성이 50:50wt.%가 되는 두번째 투과분리공정을 나일론 4와 폴리비닐알코올 및 폴리아크릴산을 포함하는 나일론 4블렌드 막을 이용하여 조사하였다. 나일론 4막은 25, 30, $35^{\circ}C$에서 에탄올의 조성 변화에 따라 실험이 수행되어졌다. 나일론 4막은 물-에탄올 조성이 50 : 50wt.%에 대해 선택도 4.18 그리고 투과도 $0.69kg/m^2hr$을 얻은 반면에 5Mrad의 감마선에 의해 가교된 나일론 4-PVA 블렌드 막은 선택도 10.56, 투과도 $0.55kg/m^2hr$을 얻었다. 또한 나일론 4 막은 물-에탄올 혼합물의 공비점에서 호모폴리머 중 27.8의 높은 선택도를 얻을 수 있었다.

• 한국응용과학기술학회지
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• 제27권4호
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• pp.501-507
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• 2010

In this study, we evaluate the anti-microbiological activity of paraben in eye shadows that are composed of pigments and oil binders using various analytical methods and microbiological tests. Paraben does not show the microbiological activity properly when it was used with Nylon SP$^{(R)}$ 10, Talc RF SSA$^{(R)}$, OMC Talc AS$^{(R)}$ and $BaSO_4$. In the test of fungi, Nylon SP$^{(R)}$ 10 causes the decrease of microbiological activity regardless of the type of oil binders. The pigment of Mango violet also causes the decrease of microbiological activity when ester oil binder was used. Regardless of the type of oil binder, samples containing nylon SP 10, 0.15% of methyl paraben and 0.05% of propyl paraben had not been able to maintain microbiological activity only if the concentration of parabens were increased. Trace amounts of metal ions present in pigments reduced the activity of preservatives by inactivation of hydroxyl group of paraben. It is thought that swollen nylon SP 10 in ester oil increase the absorption or interaction of parabens and swollen nylon powder causes the inactivation of paraben.

• 폴리머
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• 제38권3호
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• pp.314-319
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• 2014

힌더드 아민기를 포함하고 있는 헤테로환을 가지며 알킬사슬 길이가 서로 다른 세 종류의 나일론 4 열안정제를 합성하였다. 힌더드 아민기를 이용하여 라디칼에 의한 열분해를 방지하고, 열안정제와 나일론 4의 아마이드기 간 수소결합을 조절하여 나일론 4의 열적 특성에 미치는 영향을 확인하였다. 안정제의 알킬사슬의 수가 4개일 때 수소결합이 가장 최적화되는 것으로 등온 TGA 결과를 통해서 확인하였다. 또한 시판중인 나일론 6의 열안정제를 사용하여 나일론 4에 대한 열안정성을 비교 실험한 결과, 합성 열안정제가 나일론 4의 열안정성을 실질적으로 향상시킨 것을 확인하였다.

• 한국염색가공학회지
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• 제26권1호
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• pp.22-31
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• 2014

This study investigated the physical properties of warm up yarns and their knitted fabrics including the dye affinity and color fastness to washing of these knitted fabrics according to the various dyeing times and temperatures on dyeing process. The results were summarized as follows. The tenacity of Nylon/PP warm-up yarn was 4g/d and breaking strain was 4.5%. The wet and dry thermal shrinkages were higher than those of PET warm-up yarn. The maximum heat flow rate(Qmax) of Nylon/PP warm-up knitted fabric was lower than that of PET warm-up knitted fabric and heat keeping rate(a) of Nylon/PP warm-up knitted fabric was higher as 47% than that of PET warm-up knitted fabric. It was shown that the shape retention and wearing comfort of Nylon/PP warm-up knitted fabric were better than those of PET warm-up knitted fabric. The dye-affinity(K/S) of Nylon/PP warm-up knitted fabric showed maximum value at the dyeing condition of 40minute or 50minute dyeing time with $80^{\circ}C$ dyeing temperature, but PET warm-up knitted fabric showed maximum value at the 30minute or 40minute with $110^{\circ}C$ dyeing temperature. Finally, the color fastness to washing of Nylon/PP warm-up knitted fabric showed good value as between 4 and 5 grade.

• 대한화학회지
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• 제23권5호
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• pp.329-337
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• 1979

국내에서 상업용으로 이용하는 여러종류의 고분자 필름들에 대한 투습도를 일정한 압력과 상대습도 하에서 측정하고 투습도의 역수를 구하여 각 필름의 방습도로 정의하였다. 실험온도 $40{\pm}1^{\circ}C$, 상대습도 $90{\pm}2%$ 하에서 시료를 24시간 방치한 후 컵방법으로 필름의 방습도를 측정한 결과 다음과 같은 순서로 감소함을 밝혔다. 연신 polypropylene (O. PP) > 고밀도 polyethylene (HDPE, Inflation) > 고밀도 polyethylene (HDPE, T-die) > 무연신 polypeopylene (C. PP) > 무연신 polyester (N. PET) > 저밀도 polyethylene (LDPE) > 연신 polyester (O.PET) > 경질 polyvinyl chloride (Rigid PVC) > 반경질 polyvinyl chloride (Semirigid PVC) > 연질 Polyvinyl chloride (Nonrigid PVC) > 연신 nylon(O.Nylon) > 무연신 nylon (N.Nylon) 또한 온도증가에 따라서 측정한 결과 방습도는 HDPE, (T-die) > C. PP > O. PET > LDPE > O. Nylon으로 감소하였고, LDPE, HDPE (T-die), C. PP, O. PET, O. Nylon 필름들의 투습활성화 에너지는 12.0, 11.1, 11.4, 11.7, 14.1 kcal/mole임을 밝혔다. 필름의 투습도는 극성증가에 따라서 증가하고 PVC 필름은 가소제 첨가에 따라서 증가하며, 필름 두께와 연신 증가에 따라서는 감소하였다. O. PP/LDPE, N.Nylon/LDPE, C.PP/LDPE이 집합필름은 단일필름보다 두께에 대한 의존성이 증가하였다.

• 한국정밀공학회지
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• 제19권3호
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• pp.114-122
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• 2002

Electric conductivities, mechanical properties and friction properties were investigated far graphite-nylon composites impregnated with oil. Specific resistivity of composites containing oil from 2% to 6% were in the range of $10^7 ~10^6 \ohm$ cm, which were applicable for anti-static purpose of composites improved by the impregnation of graphite with 2%. Improvement in the impact strength and friction properties of graphite/nylon composites was achieved by the impregnation of oil. The coefficient of friction of the composites containing graphite from 2% to 4% and oil with 2 - 4% showed much loller than that of virgin nylon. Also the abrasive wear of the oil impregnated graphite composites were decreased about 1/3 - 1/10.

• 수산해양기술연구
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• 제29권2호
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• pp.117-123
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• 1993

In order to analysis the tensile properties of the high-tech fibers for fishing gear materials. tensile strength was tested on raw materials, single yarns and netting twines(plied yarns)made of nylon, kevlar 29 and techmilon respectively. The results obtained are as follows: 1. The tensile stress and tenacity of unknotted single yarns in dry and wet conditions were 3 to 3.5 times greater in the high-tech fibers than in nylon. But the elongation of the high-tech fibers was about 15% of that in nylon. 2. The tensile strength of knotted single yarns in dry and wet conditions was arranged in order of as follows : techmilon. kelver 29, and nylon. The ratio of knot strength to tensile strength, knot efficiency, was the highest in nylon. 3. The tensile strength of unknotted netting twines in dry and wet conditions was 2.3 to 2.5 times greater in the high-tech fibers than in nylon. 4. The tensile strength of knotted netting twines in dry and wet conditions was arranged in order of as follows : techmilon, kevlar 29, nylon. The knot efficiency was the highest in nylon.

• 한국염색가공학회지
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• 제10권4호
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• pp.30-36
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• 1998

The need for the effective flame retardant finishing for synthetic fiber Is required. This paper is focussed on the analysis of physical properties of nylon 6 fabric treated with tris(2-chloroethyl) phosphate(TCEP) in comparision with the untreated fabric. In order to evaluate the flame retardance effect, limiting oxygen index and burn rate were determined. Above 20% add-on of TCEP on nylon 6 fabric, reasonable flame retardancy was observed. Thermal stability of the treated nylon 6 fabric was evaluated by TGA. It seems that TCEP acts via a condensed phase mechanism. Tenacity and moisture regain of the treated fabrics were not changed and washfastness of those was excellent.

• Elastomers and Composites
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• 제58권2호
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• pp.65-69
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• 2023

To reduce the weight of the engineering plastic Nylon 6 resin, two high-temperature foaming agents, p-toluenesulfonyl semicarbazide (PTSS) and 5-phenyltetrazole (5-PT) (0-10 phr), were added and foamed without other additives. We investigated the effects of the foaming agent type and content on the foam density (g/cm³) and percent weight reduction rate of the Nylon 6 foam, and 5-PT exhibited better foaming performance than PTSS. In the case of 5-PT, the weight reduction rate was above 36% when the blowing agent content was 1.5 phr or higher, indicating that 5-PT is an effective blowing agent for reducing the Nylon 6 foam weight. Additionally, we studied the effect of the nucleating agent Talc content (0-0.4 phr) on Nylon 6 foaming, and the nucleating agent Talc considerably reduced foaming.