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Effect of Initial Toluene Concentration on the Photooxidation of Toluene-NOx-Air Mixture -II. Aerosol Formation and Growth (초기 톨루엔 농도가 톨루엔- NOx-공기 혼합물의 광산화 반응에 미치는 영향 - II. 입자상 물질의 생성 및 성장)

  • Lee Young-Mee;Bae Gwi-Nam;Lee Seung-Bok;Kim Min-Cheol;Moon Kil-Choo
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.1
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    • pp.27-38
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    • 2005
  • An experimental investigation of the gas-phase photooxidation of toluene-NO$_{x}$-air mixtures at sub-ppm concentrations has been carried out in a 6.9 ㎥, indoor smog chamber irradiated by blacklights. Measured parameters in the toluene-NO$_{x}$ experiments included aerosol, $O_3$, NO, NO$_2$, NO$_{x}$ CO, SO$_2$ toluene, and air temperature. The initial toluene concentration ranged from 225 ppb to 991 ppb and the initial concentration ratio of toluene/NO$_{x}$ in ppbC/ppb was in the range of 5~20. It was found that the variation of aerosol number concentration with irradiation time caused by the photooxidation of toluene-NO$_{x}$-air mixtures depended on the initial toluene concentration for similar concentration ratio of toluene/NO$_{x}$. The dependency of initial toluene concentration on the photooxidation of toluene-NO$_{x}$-air mixtures for toluene/NO$_{x}$= 5~6 seemed to be opposite to that for toluene/NO$_{x}$=10~11. The maximum number concentration of aerosols formed by photooxidation and the aerosol yield depended on both initial toluene concentration and initial concentration ratio of toluene/NO$_{x}$. In this study, the aerosol yield, defined as aerosol formed per unit toluene consumed, was found to be 0.01~0.16.und to be 0.01~0.16.

Adsorption Properties of Paint Mixed with Powdered Activated Carbon According to the Number of Coatings (분말활성탄을 혼합한 도료의 도장횟수에 따른 흡착 특성)

  • Choi, Byung-Cheol;Kyoung, In-Soo;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.25-26
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    • 2021
  • Due to COVID-19, the spread of non-face-to-face culture is increasing the time spent indoors. Accordingly, it is necessary to reduce indoor air pollutants. Also, among building materials, there are paints. As the number of coatings increases, the coating film becomes thick, and there is a risk of cracking and falling off. Therefore, this study is to examine the adsorption properties of indoor air pollutants according to the number of coatings of a paint mixed with powdered activated carbon. In the experimental plan, the addition ratio of powdered activated carbon was selected as 30%, and the number of coatings was selected as primcoating, second coat, and finishing coat, and the concentration of formaldehyde and volatile organic compounds were measured. As a result, as the number of coatings increased, the concentration of formaldehyde and volatile organic compounds tended to decrease. This is considered to be due to the fact that not only the physical adsorption acted by the internal pores of the powdered activated carbon, but also because a lot of powdered activated carbon was present on the painted surface as the coating film was formed. However, since it is judged that there is an error in the concentration due to the inflow of external air as the chamber cover is opened to put the test object in the adsorption test process, it is considered that the experimental method needs to be supplemented.

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CO concentration distribution in a tunnel model closed at left end side using CFD

  • Peng, Lu;Lee, Yong-Ho
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.3
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    • pp.282-290
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    • 2013
  • A primary air pollutant as an indicator of air quality released from incomplete combustion is Carbon monoxide. A study of the distributions of CO concentration with no heat source in a tunnel model closed at left end side is simulated with a commercial CFD code. The tunnel model is used to investigate the CO concentration distributions at three Reynolds numbers of 990, 1970, and 3290. which are computed by the inlet velocities of 0.3, 0.6 and 1.0 m/s. The CFD predictive approaches can be useful for a better design to analyze the distributions of CO concentrations. In the case of the tunnel model closed at left end side alone, the concentration changes of x/H=-5 and -2.5 have the similar laminar characteristics like the case of the tunnel model closed at both end sides expecially at low values of Reynolds number. Irregular average CO concentration variations at Re=1790 are considered that the transition from laminar to turbulent flow occurs even in three different tunnel models.

The Effect of Oxygen and Carbon Dioxide Concentration on Soot Formation in Nonpremixed Flames Using Time Resolved LII Technique

  • Oh, Kwang-Chul;Shin, Hyun-Dong
    • Journal of Mechanical Science and Technology
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    • v.19 no.11
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    • pp.2068-2076
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    • 2005
  • The influence of oxygen concentration and CO$_{2}$ as diluent in oxidizer side on soot characteristics was studied by Laser Induced Incandescence, Time Resolved LII and Transmission Electron Microscopy photography in non-premixed co flowing flames. Through the comparison of TEM photographs and the decay rate of LII signal, suitable two delay times of TIRE-LII method and signal sensitivity ($\Delta$S$_{TIRE-LII/) were determined. The effects of O$_{2}$ and CO$_{2}$ as diluent in oxidizer side on soot formation are investigated with these calibrated techniques. The O$_{2}$+CO$_{2}$, N$_{2}$, and [Ar+CO$_{2}$] mixture in co-flow were used to isolate CO2 effects systematically. The number concentration of primary particle and soot volume fraction abruptly decrease by the addition of CO$_{2}$ to the co-flow. This suppression is resulted from the short residence time in inception region because of the late nucleation and the decrease of surface growth distance by the low flame temperature due to the higher thermal capacity and the chemical change of CO$_{2}$ including thermal dissociation. As the oxygen concentration increases, the number concentration of soot particles at the inception region increases and thus this increase of nucleation enhances the growth of soot particle.

Effect of light intensity on the ozone formation and the aerosol number concentration of ambient air in Seoul (광도가 서울 대기의 오존 생성 및 에어로졸 수 농도에 미치는 영향)

  • Bae, Gwi-Nam;Park, Ju-Yeon;Kim, Min Cheol;Lee, Seung-Bok;Moon, Kil-Choo;Kim, Yong Pyo
    • Particle and aerosol research
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    • v.4 no.1
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    • pp.9-20
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    • 2008
  • The effect of light intensity on the ozone formation and the aerosol number concentration during the photochemical reactions of ambient air was investigated in an indoor smog chamber. The smog chamber consists of a housing, 64 blacklights, and a $2.5-m^3$ reaction bag made of Teflon film. The bag was filled with the unfiltered ambient air in Seoul from January 10 to March 18, 2002. In this work, the photolysis rate of $NO_2$, $k_1$ was used as an index of light intensity. Three levels of light intensity were controlled by changing the number of blacklights turned on among 64 blacklights: $0.29min^{-1}$ (50%), $0.44min^{-1}$ (75%), $0.57min^{-1}$ (100%). The ozone concentration increased rapidly within 10 minutes after irradiation irrespective of light intensity, thereafter it increased linearly during the irradiation. The ozone production rate seems to be dependent on both the light intensity and the quality of ambient air introduced into the reaction bag. The change in aerosol number concentration also depended on both the light intensity and the ambient air quality, especially aerosol size distribution. Based on the initial ambient aerosol size distributions, the photochemical potential for aerosol formation and growth is classified into two cases. One is the case showing aerosol formation and growth processes, and the other is the case showing no apparent change in particle size distribution.

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Analysis of characteristics of sediment transport in sewers by densimetric Froude number (밀도프루드수에 의한 하수관로 침전물 이송 특성 분석)

  • Park, Kyoohong;Lee, Taehoon;Yu, Soonyu;Kang, Byongjun;Hyun, Kirim
    • Journal of Korean Society of Water and Wastewater
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    • v.34 no.1
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    • pp.45-52
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    • 2020
  • Even though sewers have been conventionally designed to prevent from sediment deposition using a specified minimum velocity or shear stress at a particular depth of flow or with a particular frequency of occurrence, it was appreciated that these methods do not consider the characteristics and concentration of the sediment and the specific hydraulic conditions of the sewer with sediment. In this study, a densimetric Froude number formula was suggested considering particle diameter and volumetric concentration of the sediment as well as flow depth and flowrate, based on several domestic field inspections, which was compared with other formulas proposed by previous investigators. When the sediment concentration was not considered, the calibration coefficient of 0.125-1.5 to the densimetric Froude numbers of this study was needed to obtain the similar ones with previous investigators'. For the densimetric Froude number formula obtained with consideration of sediment concentration, the exponent value of term Cv was almost the same as that of previous results and that of d50/Rh was similar for Fr < 2.2.

Analysis of High Volume Slit Type Two-Stage Virtual Impactor for Particle Size Classification (특정크기 입자농축을 위한 대유량 슬릿형 2단 가상충돌기의 성능분석)

  • 박성호;김상수;오명도
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.1
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    • pp.285-291
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    • 1991
  • A two-stage slit type virtual impactor based on the concept of the single stage virtual impactor has been designed, fabricated, and evaluated for the purpose of concentrating the suspended particles in the air with the size range of 1.8-4.5 .mu.m and handling large flow volume. Monodisperse methylene blue particles have been generated with vibrating orifice aerosol generator (VOAG). The separation efficiency and concentration efficiency have been measured by the UV-visible absorption spectrometry. Previous study for a single stage virtual impactor were used to determine the design parameters such as 50% cut-off sizes and dimensions of the two stage virtual impactor. The separation efficiency curve and 50% cut-off Stokes number(cut-off sizes) are not sensitive to the nozzle Reynolds number, but sensitive to the ratio between the minor flow rate and the total flow rate, The measured concentration efficiency was compared with the maximum concentration efficiency determined by the separation efficiencies of the first and the second stages. The differences between the measured and the maximum concentration efficiencies result from the wall loss due to the deposited particles on the internal walls inside the impactor.

A Study on the Relationships of the Menstrual Blood Loss, Iron Nutriture, and the Pregnancy History in Married Korean Women (한국인(韓國人) 기혼여성(旣婚女性)의 출산역(出産歷)에 따른 월경혈손실양(月經血損失量) 변화(變化)와 철분영양상태(鐵分營養狀態)에 관한 연구(硏究))

  • Tchai, Bum-Suk;Han, Jung-Ho;Nam, Soon-Joo
    • Journal of Nutrition and Health
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    • v.15 no.4
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    • pp.249-257
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    • 1982
  • The aim of this study was to observe the relationships between the amount of menstrual blood loss (MBL) and age, parity, number of pregnancy and induced abortion, and the iron nutriture in married Korean women. Fifty-one healthy women aged 26 to 48 years were tested for their MBL, hemoglobin(Hb) concentration, hematocrit (Hct) value, mean corpuscular hemoglobin concentration (MCHC), serum iron and ferritin concentrations. The results of this study are summarized as follows : 1) The mean value and standard error of mean of the MBL was $32.0{\pm}3.94ml$, and the range of MBL was 3.8-127.2 ml for total subjects. Maximum number (23.5%) of the subjects fell in the group with MBL of 10-l9ml, while 17.7% showed MBL above 50m1. 2) There were no statistically significant differences on the mean amount of MBL between the age groups 25-48 years. 3) The mean amount of MBL in 1-2 and 3-4 para groups were 28.5 and 36.1 ml, respectively, but the difference between two groups was not significant 4) It was observed that the mean amount of MBL was gradually decreased as the number of pregnancy and induced abortion were increased, but the significance was not observed. 5) The mean values of Hb concentration, MCHC and serum iron concentration were slightly decreased in subjects with MBL of more than 50ml but the statistical significance was not observed. The mean of Hct value was not influenced by the amount of MBL. While serum ferritin concentrations were markedly decreased and the prevalence rate of anemia was markedly increased as the amount of MBL was increased. There was significant difference (P<0.05) between the mean amount of MBL with respect to the serum ferritin concentration.

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Development of Target-Controlled Infusion system in Plasma Concentration. PART2: Design and Evaluation (혈중 목표 농도 자동 조절기(TCI) 개발 PART2: 시스템 구현 및 평가)

  • 안재목
    • Journal of Biomedical Engineering Research
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    • v.24 no.1
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    • pp.45-53
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    • 2003
  • Based on the 4-compartmental pharmacokinetic model developed in PART1, target-controlled infusion(TCI) pump system was designed and evaluated. The TCI system consists of digital board including microcontroller and digital signal process(DSP), analog board, motor-driven actuator, user friendly interface, power management and controller. It provides two modes according to the drugs: plasma target concentration and effect target concentration. Anaesthetist controls the depth of anaesthesia for patients by adjusting the required concentration to maintain both plasma and effect site in drug concentration. The data estimated in DSP include infusion rate, initial load dose, and rotation number of motor encoder. During TCI operation, plasma concentration. effect site concentration, awaken concentration, context-sensitive decrement time and system error information are displayed in real time. Li-ion battery guarantees above 2 hours without power line failure. For high reliability of the system, two microprocessors were used to perform independent functions for both pharmacokinetic algorithm and motor control strategy.

Nano-particles emission characteristics of GDI vehicles using Engine Exhaust Particle Sizer (Engine Exhaust Particle Sizer를 통한 GDI 자동차에서 발생하는 나노미세입자 배출특성 분석)

  • Jang, Jihwan;Lee, Jongtae;Kim, Kijoon;Kim, Jeongsoo;Park, Sungwook
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.95-96
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    • 2014
  • In this study, the nano-particle emitted from Gasoline Direct Injection(GDI) vehicles was measured using the Engine Exhaust Particle Sizer(EEPS) on a chassis dynamometer. In addition, driving mode were divided into cold start mode(CVS-75, NEDC) and hot start mode(NIER-6, NIER-9) to evaluated the characteristics in the various operating conditions. The Particle Number(PN) concentration was analyzed for various driving patterns, i.e., acceleration, deceleration, idling, cruising and the phases of mode. In a result, Total concentration of PN for size was concentrated from 50 to 100 nm and acceleration represents the highest concentration among the driving pattern. It is believed that the increases quantity of fuel, and mixture will be richer than other patterns.

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