• Elastomers and Composites
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• v.40 no.1
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• pp.3-11
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• 2005

The ruling kinetics of epoxy resins with 3 different kinds or alkenylsuccinic anhydride (ASA) having C-8, C-12, and C-16 pendant side chain length with two different catalysts was studied by using differential scanning calorimetry (DSC). Nonisothermal and isoconversional method has been used for characterizing the effect of the pendant side chain length in the curing process. Results or nonisothermal method showed that there was no significant difference in the effect of the pendant side chain length of ASA. But isoconversional analysis showed that the value of the activation energy for the initiation reaction or C-8, C-12, and C-16 were $61.7{\sim}57.7kJ/mol$, $63.0{\sim}57.3 kJ/mol$, and $130.4{\sim}94.2 kJ/mol$, respectively, depending on the catalyst used. The values of activation energy for the initiation is different as reported value of 20 kJ/mol which indicating the difference in the effect of the pendant side chain length of ASA in the initial stage of the reaction.

• Korean Chemical Engineering Research
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• v.56 no.5
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• pp.725-731
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• 2018

The effects of catalysts addition on the carbonization reaction of biomass have been studied in a thermogravimetric analyzer (TGA). The sample biomasses were Bamboo and Pine. The catalysts tested were K, Zn metal compounds. The carbonization reactions were tested in the nonisothermal condition from the room temperature to $850^{\circ}C$ at a heating rate $1{\sim}10^{\circ}C/min$ on the flowing of $N_2$ purge gases. Also, the effects of catalyst on the torrefaction were tested in the temperature condition of 220, 250, $280^{\circ}C$ at 30 min. Combustion characteristic for the torrefied catalyst biomass were studied in the nonisothermal conditions of $200{\sim}850^{\circ}C$. As the results, the initial decomposition temperatures of the volatile matters ($T_i$) and the temperature of maximum reaction rate ($T_{max}$) were decreased with increasing the catalyst amounts in the sample biomass. The char amounts remained after carbonization at $400^{\circ}C$ increased with the catalyst amounts. Therefore catalysts addition can be decreased the energy for carbonization process and improved the heating value of product char. The catalysts reduced the optimum torrefaction conditions from $250^{\circ}C$ to $220^{\circ}C$. The torrefied catalyst biomass have lower activated energy from 46.5~58.7 kJ/mol to 25.1~27.0 kJ/mol in the nonisothermal combustion reaction.

• Proceedings of the Korean Fiber Society Conference
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• 1994.10a
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• pp.75-75
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• 1994

• Transactions of the Korean Society of Automotive Engineers
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• v.4 no.1
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• pp.187-197
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• 1996

Many investigations have been made to determine the pressure drop and heat transfer characteristics for single phase flow in tape generated swirl flow. But few studies have been carried out to investigate the heat transfer in two component, two phase swirl flow with non-boiling. An experimental study has been conducted to determine the effects of tape twist ratios on two phase convective heat transfer coefficients, pressure drop, and void fraction distribution in a non-boiling, air-water, two phase flow. The flow conditions were both swirl and non swirl flows. The internal diameter of the test section is 42.5mm. The tape twist ratios of pitch to diameter ratio varied from 4.0 to 10.6. The heating conditions were isothermal and nonisothermal. The flow patterns identified with experiments were bubbly, bubbly-slug, slug, and slug-annular flow in up-flow. This study has concluded that no significant difference in void fraction distribution were observed both isothermal and nonisothermal conditions, the pressure drop for two phase flow with twisted tape swirler increase as the tape twist ratio decrease, and that values of two phase heat transfer coefficient increase when the tape twist ratio decreases.

• The Korean Journal of Rheology
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• v.1 no.1
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• pp.46-53
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• 1989

유한요소법을 이용하여 애뉼라다이 팽창현상을 수치 해석학적으로 분석하였다. 이보 고는 계속적인 연구의 일부로써 비탄성 비뉴토니안 유체인 지수법칙형의 유체에 대한 모사 이다. 이지수법칙형의 유체는 간단하나 고분자 공정 연구에 많이 쓰이는 구성식으로써, 분석 결과는 환형압축체의 두께는 지수법칙 지수에 비례하여 증가하였다. 높은 전단응력 감소유 체의 경우 두께는 증가하지 않고 감소하였다. 비등온 유체 및 여러 다른 형태의 압출형에 대한 수치해석 결과도 예시하였다.

• Structural Engineering and Mechanics
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• v.26 no.4
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• pp.393-408
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• 2007

The effects of material nonhomogeneity and nonisothermal conditions on the stress response of pressurized tubes are assessed by virtue of a computational model. The modulus of elasticity, the Poisson's ratio, the yield strength, and the coefficient of thermal expansion, are assumed to vary nonlinearly in the tube. A logarithmic temperature distribution within the tube is proposed. Under these conditions, it is shown that the stress states and the magnitudes of response variables are affected significantly by both the material nonhomogeneity and the existence of the radial temperature gradient.

• 제어로봇시스템학회:학술대회논문집
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• 1986.10a
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• pp.232-237
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• 1986

Theoretical studies are performed for a nonisothermal CFSTR in which consecutive reactions take place. The local dynamic stability of an unstable steady state is investigated with relation to variations in the controller gain when the temperature is subjected to a proportional control. The control has significant in fluences upon the stability of the high temperature steady state as well as that of the intermediate steady state.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 1997.10a
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• pp.138-141
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• 1997

CFM(Cast Forge Method) is widely used in manufacturing industry to produce aluminium parts with good mechanical properties and low production cost. CFM is the process which produces a final products by forging from the initial billet by casting. The study on this paper covers the automatic design method which finds a pertinent shape for initial billet using Fast Fourier Transform, low-pass frequency filtering and FEM simulation of the nonisothermal forging process by DEFORM. These works will give us an information to enhance the low strength of a aluminium casting.

• Proceedings of the Korean Society of Rheology Conference
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• 2006.06a
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• pp.89-92
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• 2006

• Journal of the Korean Ceramic Society
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• v.24 no.5
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• pp.417-422
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• 1987

Kinetic studies were made on the thermal decomposition of hydrated magnesium aluminum double sulfate by a nonisothermal TG method. Thermal analyses of the dehydration of tricosahydrate showed that the reaction proceeded via decahydrate to the anhydrous MgAl2(SO4)4 in the range 50$^{\circ}$to 400$^{\circ}C$. Decomposition of MgAl2(SO4)4 occurred as the two-step between 650$^{\circ}$ and 970$^{\circ}C$. Dehydration of MgAl2(SO4)4$.$23H2O and a 2D diffusion controlled with an activation energy of 16.6kcal/mole, respectively. MgAl2(SO4)4 fitted the contracting volume model with an activation energy of 10.5kcal/mole, and MgSO4 fitted a contracting area model with an activation of 4.5kcal/mole.