• Journal of Korean Society of Environmental Engineers
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• v.27 no.10
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• pp.1043-1051
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• 2005

In this stduy, adsorption and transport characteristics of Fe in the soil were investigated using convection-dispersion local equilibrium sorption model and two-site non-equilibrium sorption model. In batch experiments with different Fe concentration, characteristics of Fe adsorption was investigated using Freundlich and linear isotherm. Column experiments with different flow rate, organic matter content md Fe concentration were also carried out. We measured Fe concentrations in injection-liquid and in effluent, and then applied them to CXTFIT program. As a result of column experiments, some parameters(D, R, ${\beta}$, ${\omega}$) used in two-site non-equilibrium adsorption model were obtained. Characteristics of Fe transport were analyzed using the parameters(D, R, ${\beta}$, ${\omega}$) obtained from the CXTFIT program, Consequently, characteristics of Fe transport in the soil were predicted through two-site non-equilibrium adsorption model.

• Journal of Energy Engineering
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• v.2 no.1
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• pp.54-67
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• 1993

Two turbulent reaction models of the premixed CC1$_4$/CH$_4$/air mixture are successfully incorporated in a 3-dimensional computer program and is applied for Dow Chemical incinerator equipped with two main off-center burners. The first reaction model is fast chemistry model(model 1), in which chemical reaction is governed by the turbulent mixing itself. And the second one is nonequilibrium model(model 2), where the effect of the chemical kinetics due to the presence of CC1$_4$is considered by the incorporation of the burning velocity data of CC1$_4$. The second model not only shows the flame inhibition trend due to the presence CC1$_4$compound, but also predicts qualitatively the vortical stratification of the CC1$_4$concentration appeared experimentally at the kiln exit. Other comparisions of two models are made in detail.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.30 no.7
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• pp.90-97
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• 2002

Wall slip models are essential to the study of nonequilibrium gas transport in rarefied and microscale condition that can be found in gas flows associated with aerospace vehicle, propulsion system, and MEMS. The Maxwell slip model has been used for this type of problem, but it has difficulty in defining the so-called accommodation coefficient and has not been very effective in numerical implementation. In the present study, on the basis of Langmuir's theory of the adsorption of gases on metals, a physical slip model is developed. The concept of the accommodation coefficient and the difference of gas particles are clearly explained in the new model. It turned out that the Langmuir model recovers the Maxwell model in the first-order approximation. The new models are also applied to various situations including internal flow in a microchannel. Issues of validation of models are treated by comparing analytic results with experiment.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.32 no.9
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• pp.740-753
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• 2008

The conventional Split Hopkinson Pressure Bar (C-SHPB) technique with aluminum pressure bars to achieve a closer impedance match between the pressure bars and the specimen materials such as hot temperature degraded POM (Poly Oxy Methylene) and PP (Poly Propylene) to obtain more distinguishable experimental signals is used to obtain a dynamic behavior of material deformation under a high strain rate loading condition. An experimental modification with Pulse shaper is introduced to reduce the nonequilibrium on the dynamic material response during a short test period to increase the rise time of the incident pulse for two polymeric materials. For the dynamic stress strain curve obtained from SHPB experiment under high strain rate, the Johnson-Cook model is applied as a constitutive equation, and we verify the applicability of this constitutive equation to the probabilistic reliability estimation method. The methodology to estimate the reliability using the probabilistic method such as the FORM and the SORM has been proposed, after compose the limit state function using Johnson-Cook model. It is found that the failure probability estimated by using the SORM is more reliable than those of the FORM, and the failure probability increases with the increase of applied stress. Moreover, it is noted that the parameters of Johnson-Cook model such as A and n, and applied stress affect the failure probability more than the other random variables according to the sensitivity analysis.

• Proceedings of the KSME Conference
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• 2001.06e
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• pp.299-304
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• 2001

The current study describes experimental and computational work on the passive control of the steady and unsteady condensation shock waves, which are generated in a transonic nozzle. The bleed slots are installed on the contoured wall of the transonic nozzle in order to control the magnitude of the condensation shock wave and its oscillations. For computations, a droplet growth equation is incorporated into the two-dimensional Navier-Stokes equation systems. Computations are carried out using a third-order MUSCL type TVD finite-difference scheme with a second-order tractional time step. Baldwin-Lomax turbulence model is employed to close the governing equations. An experiment using an indraft transonic wind tunnel is made to validate the computational results. The current computations represented well the experimental flows. From both the experimental and computational results it is found that the magnitude of the condensation shock wave in the bleed slotted nozzle is significantly reduced, compared with no passive control of solid wall. The oscillations of the condensation shock wave are successfully suppressed by a bleed slot system.

• 한국전산유체공학회:학술대회논문집
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• 1995.10a
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• pp.160-168
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• 1995

This paper describes computational efforts on the various energy and environmental problems using Patankar's SIMPLE method. The specific problems included in this study are : pollutant and flammable material dispersions in open and confined areas, aerator-induced flow in a lake for DO(dissolved oxygen) concentration, primary clarifier for water and waste water treatment, hood ventilation in workplace, cyclone and LNG combustors and Dow chlorination reactor. A control-volume based finite-difference method is employed together with the power-law scheme. The pressure-velocity coupling is resolved by the use of the revised version of SIMPLE, says SIMPLER and SIMPLEC. The Reynolds stresses are closed using the standard or the RNG $k-{\varepsilon}$ models. Turbulent reaction is modeled using two fast chemistry methods such as eddy breakup and conserved scalar models. Further, a nonequilibrium model is developed for the application of the chlorination process in the Dow reactor. Other important empirical models and physical insights appeared in this study are presented and discussed in a brief note. The computational method developed in this study is considered, in general, as a viable tool for the design and determination of the optimal condition of various engineering system of interest.

• Journal of computational fluids engineering
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• v.2 no.1
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• pp.93-108
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• 1997

This paper describes several computational results on the various energy and environmental problems using Patankar's SIMPLE method. The specific problems included in this study are : pollutant and flammable material dispersions in open and confined areas, buoyancy-driven flow in a lake, primary clarifier for water and waste water treatment, hood ventilation in workplace. cyclone combustor and Dow chlorination reactor. A control-volume based finite-difference method is employed together with the power-law scheme. The pressure-velocity coupling is resolved by the use of the revised version of SIMPLE, says SIMPLER and SIMPLEC. The Reynolds stresses are closed using the standard or RNG κ-ε models. A nonequilibrium turbulent reaction model is developed for the application of the chlorination process in the Dow thermal reactor. Other important empirical models and physical insights appeared in this study are presented and discussed in a brief note. The computational method developed in this study is considered, in general, as a viable tool for the design and determination of the optimal operating condition of various environmental engineering system of interest.

• Proceedings of the KSME Conference
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• 2002.08a
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• pp.161-164
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• 2002

In the present study, a passive control method, using the porous wall and cavity system, is applied to the shock wave/boundary layer interactions in transonic moist air flow. The two-dimensional, unsteady, compressible Navier-Stokes equations, which are fully coupled with a droplet growth equation, are solved by the third-order MUSCL type TVD finite difference scheme. Baldwind-Lomax turbulence model is employed to close the governing equations. In order to investigate the effectiveness of the present control method, the total pressure losses of the flow and the time-dependent behaviour of shock motions are analyzed in detail. The computed results show that the present passive control method considerably reduces the total pressure losses due to the shock/boundary layer interaction in transonic moist air flow and suppresses the unsteady shock wave motions over the airfoil, as well. It is also found that the location of the porous ventilation significantly influences the control effectiveness.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.05c
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• pp.143-147
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• 2001

Ferromagnetism in manganese compound semiconductors open prospects for tailoring magnetic and spin-related phenomena in semiconductors with a precision specific to III-V compounds. Also it addresses a question about the origin of the magnetic interactions that lead to a Curie temperature(Tc) as high as 110 K for a manganese concentration of just 5%. Zener's model of ferromagnetism, originally suggested for transition metals in 1950, can explain Tc of $Ga_{1-x}Mn_x$ As and that of its IT-VI counterpart $Zn_{1-x}Mn_x$ Te and is used to predict materials with Tc exceeding room temperature, an important step toward semiconductor electronics that use both charge and spin. In this article, we present not only the experimental result but calculated Curie temperature by RKKY interaction. The problem in making III-V semiconductor has been the low solubility of magnetic elements, such as manganese, in the compound, since the magnetic effects are roughly proportional to the concentration of the magnetic ions. Low solubility of magnetic elements was overcome by low-temperature nonequilibrium MBE{molecular beam epitaxy) growth, and ferromagnetic (Ga,Mn)As was realized. Magnetotransport measurements revealed that the magnetic transition temperature can be as high as 110 K for a small manganese concentration.

• Journal of Korean Society of Water and Wastewater
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• v.33 no.2
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• pp.131-140
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• 2019

This study used a packed column reactor and a horizontal flow mesh reactor to examine the removal of copper ions from aqueous solutions using pine bark, a natural adsorbent prepared from Korean red pine (Pinus densiflora). Both equilibrium and nonequilibrium adsorption experiments were conducted on copper ion concentrations of 10mg/L, and the removals of copper ions at equilibrium were close to 95%. Adsorption of copper ions could be well described by both the Langmuir and Freundlich adsorption isotherms. The bark was treated with nitric acid to enhance efficiency of copper removal, and sorption capacity was improved by about 48% at equilibrium; mechanisms such as ion exchange and chelation may have been involved in the sorption process. A pseudo second-order kinetic model described the kinetic behavior of the copper ion adsorption onto the bark. Regeneration with nitric acid resulted in extended use of spent bark in the packed column. The horizontal flow mesh reactor allowed approximately 80% removal efficiency, demonstrating its operational flexibility and the potential for its practical use as a bark filter reactor.