• Title/Summary/Keyword: non-uniformly

Search Result 340, Processing Time 0.027 seconds

The effects of Nafion$^{(R)}$ ionomer content in dual catalyst layer on the performances of PEMFC MEAs

  • Kim, Kun-Ho;Jeon, Yoo-Taek
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2011.05a
    • /
    • pp.95.2-95.2
    • /
    • 2011
  • In order to achieve high performance and low cost for commercial applications, the development of membrane electrode assemblies (MEA), in which the electrochemical reactions actually occur, must be optimized. Expensive platinum is currently used as an electrochemical catalyst due to its high activity. Although various platinum alloys and non-platinum catalysts are under development, their stabilities and catalytic activities, especially in terms of the oxygen reduction (ORR), render them currently unsuitable for practical use. Therefore, it is important to decrease platinum loading by optimizing the catalysts and electrode microstructure. In this study, we prepared several different MEAs (non-uniform Nafion$^{(R)}$ ionomer loading electrode) which have dual catalyst layers to find the optimal Nafion$^{(R)}$ ionomer distribution in the electrodes. We changed Nafion$^{(R)}$ ionomer content in the layers to find the ideal composition of the binder and Pt/C in the electrode. For MEAs with various ionomer contents in the anodes and cathodes, the electrochemical activity (activation overpotential) and the mass transport properties (concentration overpotential) were analyzed and correlated with the single cell performance. The dual catalyst layers MEA showed higher cell performance than uniformly fabricated MEA, especially at the high current density region.

  • PDF

Employing Al Etch Stop Layer for Nb-based SNS Josephson Junction Fabrication Process (Al 식각정지층을 이용한 Nb-based SNS 조셉슨 접합의 제조공정)

  • Choi, J.S.;Park, J.H.;Song, W.;Chong, Y.
    • Progress in Superconductivity
    • /
    • v.12 no.2
    • /
    • pp.114-117
    • /
    • 2011
  • We report our efforts on the development of Nb-based non-hysteretic Josephson junction fabrication process for quantu device applications. By adopting and modifying the existing Nb-aluminum oxide tunnel junction process, we develop a process for non-hysteretic Josephson junction circuits using metal-silicide as metallic barrier material. We use sputter deposition of Nb and $MoSi_2$, PECVD deposition of silicon oxide as insulator material, and ICP-RIE for metal and oxide etch. The advantage of the metal-silicide barrier in the Nb junction process is that it can be etched in $SF_6$ RIE together with Nb electrode. In order to define a junction area precisely and uniformly, end-point detection for the RIE process is critical. In this paper, we employed thin Al layer for the etch stop, and optimized the etch condition. We have successfully demonstrated that the etch stop properties of the inserted Al layer give a uniform etch profile and a precise thickness control of the base electrode in Nb trilayer junctions.

Effects of Initial Slug Design on the Earring of a Rectangular Battery Case During Impact Extrusion (충격압출 공정에서 초기 슬러그 디자인이 사각 배터리 케이스의 이어링에 미치는 영향 분석)

  • Lim, J. H.;Choi, S.;Chung, W. J.;Shin, J. H.;Lee, J.
    • Transactions of Materials Processing
    • /
    • v.24 no.6
    • /
    • pp.425-430
    • /
    • 2015
  • In the current paper, the effects of initial slug design on the earring of an Al rectangular battery case manufactured by impact extrusion were studied. During impact extrusion, non-uniform metal flow between the long and the short sides of the battery case leads to earring, which is subsequently trimmed. Process parameters such as friction, aspect ratio of the battery case, the die shape and the forming temperature tend to induce earring because they cause greater non-uniform metal flow. Large aspect ratio of the battery case and high friction between slug and die can greatly affect the earring of a rectangular battery case. To make a rectangular battery case without earring, it is necessary to control metal flow uniformly during impact extrusion. One of the ways to reduce the earring is to control the metal flow of slug at the initial upsetting stage. To analyze the effects of the initial slug design on earring, FE analysis was conducted using DEFORM 3D. Two types of initial slug designs were evaluated where volume was removed along either the width or thickness directions. The results show that the initial slug design can be effective in adjusting the uniformity of metal flow.

A Study on Forced Convective Boiling Heat Transfer of Non-Azeotropic Refrigerant Mixture R134a/R123 Inside Horizontal Smooth Tube (수평 전열관내 비공비 혼합냉매 R134a/R123의 강제대류비등 열전달에 관한 연구)

  • Lim, Tae-Woo;Han, Kyu-Il
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.27 no.3
    • /
    • pp.381-388
    • /
    • 2003
  • An experimental study was carried out to measure the heat transfer coefficient in flow boiling to mixtures of HFC-l34a and HCFC-123 in a uniformly heated horizontal tube. Tests were run at a pressure of 0.6 MPa and in the ranges of heat flux 1-50 kw/$m^2$, vapor quality 0-100 % and mass velocity 150-600 kg/$m^2$s. Heat transfer coefficients of mixture were less than the interpolated values between pure fluids both in the low quality region where the nucleate boiling is dominant and in the high quality region where the convective evaporation is dominant. Measured data of heat transfer are compared to a few available correlations proposed for mixtures. The correlation of Jung et. al. satisfactorily predicted the present data, but the data in lower quality was overpredicted and underpredicted the high quality data. The correlation of Kandlikar considerably underpredicted most of the data. and showed the mean deviation of 35.1%.

An Experimental Study on the Non-Uniform Flow Distribution in the Windbox of an Oil-Fired Boiler (유류 연소 발전용 보일러에서 공기 공급 계통의 불균일성에 관한 실험적 연구)

  • Go, Young-Gun;Kim, Young-Zoo;Choi, Sang-Min
    • Journal of the Korean Society of Combustion
    • /
    • v.11 no.1
    • /
    • pp.1-10
    • /
    • 2006
  • Oil-fired power plant usually uses several burners and combustion air is supplied to each burner through the complicated duct which is called windbox. A windbox should be designed to supply combustion air to each burner uniformly but, due to the complicated duct shape, flow distribution in the windbox is unbalanced and non-uniform supplies of combustion air are induced by these unbalanced flows in the windbox. These flow patterns tend to make flame unstable, increase the formation of pollutants and lower the overall combustion efficiency. To prevent these disadvantages, flow patterns in the windbox should be investigated for the uniform flow distribution. In this study, computational simulation method was used to investigate the flow distribution in a windbox and measured the velocities at the exit of burners in a real windbox and model tests to compare with CFD results. The results show two significant flow patterns. One is that the flow rates of each burner are different from each other and this means that all burners operate in different conditions of air to fuel ratio. The other is that the flow distribution at the exit of each burner is not axi-symmetric although the burner shape is axi-symmetric. Additionally some modifications of windbox shape and installation of baffles were proposed to make the uniform flow in the windox.

  • PDF

Study on the Improvement of the Fastness of Dyeing for Environmentally Synthetic Suede Using Silica Particles (실리카 입자를 활용한 친환경 인조스웨이드의 견뢰도 향상에 관한 연구)

  • Lee, Hye Mi;Kim, Ah Rong;Kim, Dae Geun
    • Textile Coloration and Finishing
    • /
    • v.30 no.4
    • /
    • pp.275-287
    • /
    • 2018
  • In recent years, research on the development of eco-friendly synthetic suede based on water-dispersed polyurethane resin and non-fluorine water repellent has been conducted. Synthetic suede has a problem that the fastness to dyeing is greatly lowered after the water-repellent processing at a high temperature of $160^{\circ}C$ because the polyester is dyed with a disperse dye. Therefore, in this study, silica was added to water-dispersed polyurethane resin to improve dye fastness. To distribute the $PUD-SiO_2$ mixture evenly in the water-dispersed polyurethane resin, sufficient stirring was done for a period of time. When the $PUD-SiO_2$ mixture(PUD 1-5%) is applied to the substrate, it is confirmed through SEM that the mixture is uniformly applied without particle condensation. The results showed that silica with a diameter of 4~12nm and BET of $200{\sim}380g/m^2$ had the ability to improve dispersibility and fastness.

EFFECTS OF RADIATION AND HEAT GENERATION ON MHD AND PARABOLIC MOTION ON CASSON FLUIDS FLOW THROUGH A ROTATING POROUS MEDIUM IN A VERTICAL PLATE

  • J. PRAKASH;A. SELVARAJ
    • Journal of applied mathematics & informatics
    • /
    • v.42 no.3
    • /
    • pp.607-623
    • /
    • 2024
  • This article studies the effects of heat generation/absorption and thermal radiation on the unsteady magnetohydrodynamic (MHD) Casson fluid flow past a vertical plate through rotating porous medium with constant temperature and mass diffusion. It is assumed that the plate temperature and concentration level are raised uniformly. For finding the exact solution, a set of non-dimensional partial differential equations is solved analytically using the Laplace transform technique. The influence of various non-dimensional parameters on the velocity are discussed, including the effects of the magnetic parameter M, heat generation/absorption Q, thermal radiation parameter R, Prandtl number Pr, Schmidt number Sc, permeability of porous medium parameter, Casson fluid parameter γ, on velocity, temperature, and concentration profiles, which are discussed through several figures. It is found that velocity, temperature, and concentration profiles in the case of heat generation parameter Q, Casson fluid parameter γ, thermal Grashof number Gr, mass Grashof number Gc, Permeability Porous medium parameter K, and time t have retarding effects. It is also seen that the magnetic field M, Thermal Radiation parameter R, Prandtl field Pr, Schmidt number Sc have reverse effects on it.

Memory Access Behavior of Embedded Java Virtual Machine in Energy Viewpoint (에너지 관점에서 임베디드 자바가상기계의 메모리 접근 형태)

  • Yang Heejae
    • The KIPS Transactions:PartA
    • /
    • v.12A no.3 s.93
    • /
    • pp.223-228
    • /
    • 2005
  • Several researchers have pointed out that the energy consumption in memory takes a dominant fraction on the energy budget of a whole embedded system. This applies to the embedded Java virtual machine tn, and to develop a more energy-efficient JVM it is absolutely necessary to optimize the energy usage in Jana memory. In this paper we have analyzed the logical memory access pattern in JVM as it executes numerous number of bytecode instructions while running a Java program. The access pattern gives us an insight how to design and select a suitable memory technology for Java memory. We present the memory access pattern for the three logical data spaces of JVM: heap, operand stack, and local variable array. The result saws that operand stack is accessed most frequently and uniformly, whereas heap used least frequently and non-uniformly among the three. Both heap and local variable array are accessed mostly in read-only fashion, but no remarkable difference is found between read and write operations for operand stack usage.

Fabrication and Evaluation of Machinability of Diamond Particle Electroplating Tool for Cover-Glass Edge Machining (커버 글래스 엣지 가공을 위한 다이아몬드 입자 전착 공구 제작 및 가공성 평가)

  • Kim, Byung-Chan;Yoon, Ho-Sub;Cho, Myeong-Woo
    • Design & Manufacturing
    • /
    • v.11 no.1
    • /
    • pp.1-6
    • /
    • 2017
  • In these days, due to generalization of using smart mobile phone and wearable device such as smart watch, demand of Cover-glass and touch screen panel for protecting display increases. With increasing the demand of Cover-glass, slimming technique is promising for weight lightening, zero bezel. Cover-glass produced by this technique is required to decreasing thickness with increase strength. In the Cover-glass manufacturing process, mechanical processing and chemical processing has improve in the strength. Generally, Diamond electrodeposition wheel is used in mechanical process. Reinforced glass with the characteristics of the brittle and high hardness was manufactured by using a diamond electrodeposition wheel. At this time, Because of surface of the tool present non-uniform distribution of diamond particle, it has generate Loading of wheel and it has been decrease life of grinding tool, efficiency of grinding, quality and shape accuracy of workpiece. Thus Research is needed to controling particle distribution of diamond electrodeposition wheel uniformly. And it is necessary to study micro hole machining such as proximity senser hole, speaker hole positioned Cover-glass. Reinforced glass with the characteristics of the brittle and high hardness is difficult to machining. Processing of reinforced glass have generated wear of tool, micro cracks. Also, it is decreasing shape accuracy. In this paper, We conducted a study on how to control particle distribution uniformly about the diamond tool manufactured using elecetodeposition processing. It analyzed the factors that affect the arrangement of the particles in the electrodeposition process by design of experiment. And There is produced the grinding tool, which derives an optimum deposition conditions, for processing Cover-glass edge and the machinability was evaluated.

Fast Search with Data-Oriented Multi-Index Hashing for Multimedia Data

  • Ma, Yanping;Zou, Hailin;Xie, Hongtao;Su, Qingtang
    • KSII Transactions on Internet and Information Systems (TIIS)
    • /
    • v.9 no.7
    • /
    • pp.2599-2613
    • /
    • 2015
  • Multi-index hashing (MIH) is the state-of-the-art method for indexing binary codes, as it di-vides long codes into substrings and builds multiple hash tables. However, MIH is based on the dataset codes uniform distribution assumption, and will lose efficiency in dealing with non-uniformly distributed codes. Besides, there are lots of results sharing the same Hamming distance to a query, which makes the distance measure ambiguous. In this paper, we propose a data-oriented multi-index hashing method (DOMIH). We first compute the covariance ma-trix of bits and learn adaptive projection vector for each binary substring. Instead of using substrings as direct indices into hash tables, we project them with corresponding projection vectors to generate new indices. With adaptive projection, the indices in each hash table are near uniformly distributed. Then with covariance matrix, we propose a ranking method for the binary codes. By assigning different bit-level weights to different bits, the returned bina-ry codes are ranked at a finer-grained binary code level. Experiments conducted on reference large scale datasets show that compared to MIH the time performance of DOMIH can be improved by 36.9%-87.4%, and the search accuracy can be improved by 22.2%. To pinpoint the potential of DOMIH, we further use near-duplicate image retrieval as examples to show the applications and the good performance of our method.