• Title/Summary/Keyword: non-thermal process

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The thermal impedance spectroscopy on Li-ion batteries using heat-pulse response analysis

  • Barsoukov Evgenij;Jang Jee Hwan;Lee Hosull
    • 한국전기화학회:학술대회논문집
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    • 2001.11a
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    • pp.145-161
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    • 2001
  • Novel characterization of thermal properties of a battery has been introduced by defining its frequency-dependent thermal impedance function. Thermal impedance function can be approximated as a thermal impedance spectrum by analyzing experimental temperature transient which is related to the thermal impedance function through Laplace transformation. In order to obtain temperature transient, a process has been devised to generate external heat pulse with heating wire and to measure the response of battery. This process is used to study several commercial Li-ion batteries of cylindrical type. The thermal impedance measurements have been performed using potentionstat/galvanostate controlled digital signal processor, which is more commonly available than flow-meter usually applied for thermal property measurements. Thermal impedance spectra obtained for batteries produced by different manufactures are found to differ considerably. Comparison of spectra at different states of charge indicates independence of thermal impedance on charging state of battery. It is shown that thermal impedance spectrum can be used to obtain simultaneously thermal capacity and thermal conductivity of battery by non-linear complex least-square fit of the spectrum to thermal impedance model. Obtained data is used to simulate a response of the battery to internal heating during discharge. It is found that temperature inside the battery is by one-third larger that on its surface. This observation has to be considered to prevent damage by overheating.

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Solid State Cesium Ion Beam Sputter Deposition

  • Baik, Hong-Koo
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06a
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    • pp.5-18
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    • 1996
  • The solid state cesium ion source os alumino-silicate based zeolite which contains cerium. The material is an ionic conductor. Cesiums are stably stored in the material and one can extract the cesiums by applying electric field across the electrolyte. Cesium ion bombardment has the unique property of producing high negative ion yield. This ion source is used as the primary source for the production of a negative ion without any gas discharge or the need for a carrier gas. The deposition of materials as an ionic species in the energy range of 1.0 to 300eV is recently recognized as a very promising new thin film technique. This energetic non-thermal equilibrium deposition process produces films by “Kinetic Bonding / Energetic Condensation" mechansim not governed by the common place thermo-mechanical reaction. Under these highly non-equilibrium conditions meta-stable materials are realized and the negative ion is considered to be an optimum paeticle or tool for the purpose. This process differs fundamentally from the conventional ion beam assisted deposition (IBAD) technique such that the ion beam energy transfer to the deposition process is directly coupled the process. Since cesium ion beam sputter deposition process is forming materials with high kinetic energy of metal ion beams, the process provider following unique advantages:(1) to synthesize non thermal-equilibrium materials, (2) to form materials at lower processing temperature than used for conventional chemical of physical vapor deposition, (3) to deposit very uniform, dense, and good adhesive films (4) to make higher doposition rate, (5) to control the ion flux and ion energy independently. Solid state cesium ion beam sputter deposition system has been developed. This source is capable of producing variety of metal ion beams such as C, Si, W, Ta, Mo, Al, Au, Ag, Cr etc. Using this deposition system, several researches have been performed. (1) To produce superior quality amorphous diamond films (2) to produce carbon nitirde hard coatings(Carbon nitride is a new material whose hardness is comparable to the diamond and also has a very high thermal stability.) (3) to produce cesiated amorphous diamond thin film coated Si surface exhibiting negative electron affinity characteristics. In this presentation, the principles of solid state cesium ion beam sputter deposition and several applications of negative metal ion source will be introduced.

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Micro Hole Machining for Ceramics ($Al_2O_3$) Using Ultrasonic Vibration (초음파 진동을 이용한 세라믹 소재의 마이크로 홀 가공)

  • 박성준;이봉구;최헌종
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.13 no.2
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    • pp.104-111
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    • 2004
  • Ultrasonic machining is a non-thermal, non-chemical, md non-electorial material removal process, and thus results in minimum modifications in mechanical properties of the brittle material during the process. Also, ultrasonic machining is a non-contact process that utilize ultrasonic vibration to impact a brittle material. In this research characteristics of micro-hole machining for brittle materials by ultrasonic machining(USM) process have been investigated. And the effect of ultrasonic vibration on the machining conditions is analyzed when machining fir non-conductive brittle materials using tungsten carbide tools with a view to improve form and machining accuracy.

Melting of ice on the heating plate with split fins (분할된 핀붙이 전열면상에서의 얼음의 용융)

  • 홍희기;김무근
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.1
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    • pp.67-74
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    • 2000
  • One of the important application of a contact melting process is a latent thermal energy storage owing to its high heat flux. In some previous works, the split fins have been employed in order to enhance the melting speed. In the present work, the close contact melting was experimentally investigated using an ice as specimen for both split and non-split fins. It was shown that the contact melting by split fins increases the melting rate compared to that of non-split ones.

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Characteristics of $CH_4$ Decomposition by Plasma (플라즈마 이용 메탄 분해 특성)

  • Kim, Kwan-Tae;Lee, Dae-Hoon;Cha, Min-Suk;Ryu, Jeong-In;Song, Young-Hoon
    • Journal of the Korean Society of Combustion
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    • v.10 no.4
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    • pp.24-32
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    • 2005
  • Various types of plasma source applied in $CH_4$ decomposition process are compared. DBD by pulse and AC power, spark by pulse and AC power, rotating arc and hollow cathode plasma are chosen to be compared. The results show that $CH_4$ conversion per given unit power is relatively high in hollow cathode plasma and rotating arc that induces rather high temperature condition and that is why both thermal dehydration and plasma induced decomposition contribute for the overall process. In case of DBD wherein high temperature electron and low temperature gas molecule coexist, the process shows low conversion rate, for in rather low temperature condition the contribution of thermal dehydration is lowered. Selectivity of $C_2H_6$ and $C_2H_2$ is shown to be a good parameter of the relative contribution of plasma chemistry in the overall process. From the results we concluded that required condition of plasma source for a cost effective and high yield $CH_4$ decomposition is to have characteristics of both thermal plasma and non thermal plasma in which temperature is high above a certain threshold state for thermal dehydration and electron induced collision is maximized in the same breath.

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Temperature Field and Thermal Stress Simulation of Solid Brake Disc Based on Three-dimensional Model (3차원 브레이크 디스크 모델의 온도 분포와 열응력 시뮬레이션에 관한 연구)

  • Hwang, Pyung;Seo, Hee-Chang;Wu, Xuan
    • Tribology and Lubricants
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    • v.26 no.1
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    • pp.31-36
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    • 2010
  • The brake system is an important part of the automobile safety system. The disc brake system is divided into two parts: a rotating axi-symmetrical disc, and the stationary pads. The frictional heat, which is generated on the interface of the disc and pads, can cause high temperatures during the braking process. The frictional heat source (the pads) is moving on the disc and the location is time-dependent. Our study applies a moving heat source, which is defined by the time and space variable on the frictional surface, in order to simulate the frictional heat behavior accurately during the braking process. The object of the present work is the determination of the temperature distribution and thermal stress in the solid disc by non-axisymmetric 3D modeling for repeated braking.

Characteristics of Toluene Destruction by Non-thermal Plasma in Packed with Catalyst Reactor (촉매가 충진된 플라즈마 반응기에서의 Toluene 제거특성)

  • 한소영;송영훈;차민석;김석준;최경일;신동준
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.1
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    • pp.51-58
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    • 2002
  • Destruction process of toluene using a wire-cylindrical BBD (Dielectric Barrier Discharge) reactor packed with catalysts was investigated to characterize the synergetic effects of non-thermal plasma and catalyst process. The catalysts used in the present study were ${\gamma}$-Al$_2$BO$_3$ and Pt/${\gamma}$-Al$_2$O$_3$. Under the numerous test conditions, specific energy density (SED (J/L)) and the conversion of toluene, defined as (1 -[C$_{f}$]/[C$_{i}$]), were measured. The test results showed that toluene decomposition efficiency followed the pseudo-first order in the case of plasma only process. The pseudo-first order process, however, was modified to pseudo-zeroth order reaction in the case of catalyst-assisted plasma process. This modification of the reaction order was verified based on a simple kinetic model proposed in the present study. Owing to the modification of reaction order, which resulted from the catalytic process, the specific energy to achieve the high removal efficiencies, i.e. 80~90%, was reduced significantly.y.y.

Reliability Evaluation of Aircraft Brake Disk using the Non-contact Air-coupled Ultrasonic Transducer Method (비접촉 초음파 탐상 기법을 이용한 항공기 브레이크 디스크의 신뢰성 평가)

  • Kwak, Nam-Su;Kim, Jae-Yeol;Gao, Jia-Chen;Park, Dae-Kwang
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.15 no.3
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    • pp.36-43
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    • 2016
  • Carbon fiber-reinforced silicon carbide (Cf-SiC) and SiC / SiC composites have high thermal conductivity, and excellent corrosion and wear resistance, a low coefficient for thermal expansion and are lightweight. This is why they are commonly used in parts of the aerospace industry to develop an aircraft thrust deflector, jet vane, combustion chamber, elevens, body flap, and a shingle. So, understanding how this state-of-the-art Cf-SiC affects both internal and external crack detection and determining issues during the manufacturing process of composite materials, should be evaluated according to valuation techniques in the external environment. In this paper, we apply a non-contact air ultrasonic technique of non-destructive testing techniques to perform a study on internal defect detection identification and assessment of carbon-fiber reinforced silicon carbide composites to perform basic research and applied research.

Characteristics of Low Temperature De-NOx Process with Non-thermal Plasma and NH3 Selective Catalytic Reduction (I) (저온 플라즈마 및 암모니아 선택적 환원공정을 활용한 저온 탈질공정의 특성(I))

  • Lee, Jae-Ok;Song, Young-Hoon
    • Applied Chemistry for Engineering
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    • v.17 no.4
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    • pp.409-413
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    • 2006
  • An experimental study on a combined $De-NO_x$ process of non-thermal plasma and $NH_{3}$ SCR, which can be operated under low temperature conditions, i.e. $150{\sim}200^{\circ}C$, has been conducted. The test results confirmed feasibility of fast SCR reaction, which shows faster reactivity compared with typical SCR reaction under the low temperature conditions. The test showed that pre-oxidation step to convert NO to $NO_2$ is necessary for the fast SCR reaction, and the appropriate ratio of $NO_{2}/NO_{x}$ ranges from 0.3 to 0.5. Ammonium salts produced under low temperature conditions, effects of hydrocarbons on the combined process, the operation power of the process are discussed in the present study.