• Title/Summary/Keyword: non-stoichiometric

Search Result 100, Processing Time 0.03 seconds

Numerical study on the reactive flow in Gas Generator (가스발생기 내부 유동 특성에 관한 수치 연구)

  • Yu Jungmin;Lee Changjin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • v.y2005m4
    • /
    • pp.198-202
    • /
    • 2005
  • Gas generator is the equipment to produce high enthalpy gas used to generate sufficient power to operate turbine and pump system for propellant feeding in liquid rocket engine. Since the limit in operating temperature is imposed due to turbine blade, the gas generator has to be operated at the temperature far below stoichiometric maintaining fuel rich combustion. In this research, fundamental study was performed to understand the non-equilibrium combustion process with in-house code and CFD-ACE as well.

  • PDF

The Blue and Red Luminescences from Ambient Air Aged Porous Silicon

  • Chang, S.S;Yoon, S.O;Choi, G.J;Kawakami, Y;Sakai, A
    • The Korean Journal of Ceramics
    • /
    • v.4 no.1
    • /
    • pp.28-32
    • /
    • 1998
  • This paper reports on photoluminescence (PL), luminescence decay curves, and compositional analysis of porous silicon(PS) which is aged under air ambient by Fourier transform infrared vibrational spectroscopy (FTIR) and by Auger electron spectroscopy (AES). Porous silicos which has been aged under air ambient yields two PL band structures, i.e. blue/violet PL and red PL. The evolution of a blue/violet band is pronounced, especially for thin PS film which is prepared in dilute HF solution. The blue/violet PL band has been observed initially to increrase rapidly with aging, then saturated with further atmospheric aging. The ambient air aged PS exhibits a fast decay time of sub-nanosecond at room temperature and shows appreciably faster decay time than that at 20K. Atmospheric aging of this thin blue/violet luminescing PS yield non-stoichiometric oxide judging from the vibrational spectra of Si-O and AES analysis.

  • PDF

Piezoelectric and Electrical properties of KNN ceramics as a function of the Variation of Nb (Nb 변화에 따른 KNN 세라믹스의 압전 및 전기적 특성)

  • Lee, Kba-Soo;Yoo, Ju-Hyun;Kim, In-Sung;Song, Jae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2010.06a
    • /
    • pp.302-302
    • /
    • 2010
  • The lead-free piezoelectric ceramics must have high piezoelectric properties and electrical properties for the applications of piezoelectric devices. Therefore, KNN ceramics were investigated as a function of the variation of Nb. The density was increased with the increase of Nb. The density was saturated above 0.8895 mol Nb. The maximum value of electromechanical coupling coefficient(kp) was obtained 0.428 at 0.8895mol Nb. This result can be attributed to the well sintered of specimens. Also, The maximum value of mechanical quality factor(Qm) showed 1554 at 0.8895mol Nb. Therefore, this composition can be used for application of piezoelectric device such as piezoelectric transformer and piezoelectric actuator.

  • PDF

Powder Sintering for Fabrication of Porous Ti Implants (다공성 티타늄 임플란트 제조를 위한 분말 소결)

  • Kim, Yung-Hoon;Lee, Sun-Kyoung
    • Journal of Technologic Dentistry
    • /
    • v.32 no.4
    • /
    • pp.337-340
    • /
    • 2010
  • Purpose: This study was performed to compare sintering conditions for fabrication of porous Ti implant. Methods: The porous Ti implant samples were fabricated by sintering of spherical Ti powders in vacuum and atmosphere conditions. Surface morphology, composition and phase were analyzed by FE-SEM, EDX and XRD. Results: Sintered Ti implant in the vacuum consisted of particles connected in three dimensions by clear necking without excessive oxide layers. However, sintered Ti implant in atmosphere was formed excessive oxide layers with non-stoichiometric compounds. Conclusion: The porous Ti implant can be sintered in vacuum condition preferably.

Dry-out conditions of free-breathing PEMFC with dry $H_2$ gas (자연급기 무가습 연료전지의 Dry-out조건)

  • Park, Sang-Kyun
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.30 no.2
    • /
    • pp.225-230
    • /
    • 2006
  • This study investigates drying condition when a small fan is added to a operating the free-breathing proton exchange membrane fuel cells (PEMFCs) with dry $H_2$ and Air. Polarization tests were conducted on PEMFCs at cell temperatures between 30 and $50^{\circ}C$ under dry operation. In the results, the cell performance strongly depended on the cell temperature and the cathode gas stoichiometric flow rates. The cell performance increases as cell temperature decreases from 50 to $30^{\circ}C$. In the domain where the stoichiometry of air is quite large, reduction of the concentration overpotential compensated the increased internal resistance due to drying. The maximum performance was obtained at the small air flow rate beyond which flooding occurs. This indicates that the fan should be operated in the stoichiometry domain with a well designed cell structure to avoid flooding.

A Study on the Combustion Characteristics and Radiation Efficiency of Metal Fiber Burners (메탈 화이버 버너에서의 연소 특성 및 복사 효율에 관한 실험적 연구)

  • Park, Ju-Won;Chung, Tae-Yong;Shin, Dong-Hoon
    • 한국연소학회:학술대회논문집
    • /
    • 2006.04a
    • /
    • pp.13-18
    • /
    • 2006
  • Radiant burners are applicable to drying, preheating and curing in materials manufacturing processes. High radiation efficiency is one of the most important performance criteria for these burners. The wide variation in reported radiation efficiencies are partly due to the differences in the measurement techniques. In the present work, water cooled radiant heat flux meter was used to measure radiant heat flux from a metal fiber mat burner. Non-contact type thermometer was also utilized to measure the surface temperature of the burner. Combustion gas was measured by gas analyzers. According to the thermal loads and stoichiometric ratios, radiant heat transfer ratio and combustion performance were discussed here in.

  • PDF

Numerical Investigation on Smoke Behavior in Rescue Station for Tunnel Fires (철도터널 화재 시 구난역 내의 연기거동에 대한 수치해석 연구)

  • Hong, Sa-Hoon;Ryou, Hong-Sun;Lee, Seong-Hyuk
    • Proceedings of the KSR Conference
    • /
    • 2008.06a
    • /
    • pp.1740-1746
    • /
    • 2008
  • The present study performed numerical investigation to analyze the smoke behavior in the rescue station by using the commercial CFD code (FLUENT Ver 6.3). The present study adopted a 10MW ultrafast mode for simulation, and it also used the MVHS(Modify Volumetric Heat Source) model modified from the original VHS(Volumetric Heat Source) model in order to treat the product generation and the oxygen consumption under the stoichiometric state. In addition, the present simulation includes the species conservation equation for the materialization of heat source and the estimation of smoke movement. From the results, the smoke flows are moving along the ceiling because of thermal buoyancy force and as time goes, the smoke gradually moves downward at the vicinity of the entrance. Moreover, without using ventilation, it is found that the smoke flows no longer spread across the cross-passages because the pressure in the non-accident tunnel is higher than that in the accident tunnel.

  • PDF

A Study on the Combustion Characteristics and Radiation Efficiency of Metal Fiber Burners (메탈 화이버 버너에서의 연소 특성 및 복사 효율에 관한 실험적 연구)

  • Park, Ju-Won;Chung, Tae-Yong;Shin, Dong-Hoon
    • Journal of the Korean Society of Combustion
    • /
    • v.11 no.1
    • /
    • pp.27-33
    • /
    • 2006
  • Radiant burners are applicable to drying, preheating and curing in materials manufacturing processes. Radiation efficiency is one of the important performance criteria for these burners. The wide variation in reported radiation efficiencies are partly due to the differences in the measurement techniques. In the present work, water cooled radiant heat flux meter was used to measure radiant heat flux from a metal fiber mat burner. Non-contact type thermometer was also utilized to measure the surface temperature of the burner. Combustion gas was measured by gas analyzers. According to the thermal loads and stoichiometric ratios, radiant heat transfer ratio and combustion performance were discussed here in.

  • PDF

XPS Studies of Oxygen Adsorption on Polycrystalline Nickel Surface

  • Lee, Soon-Bo;Boo, Jin-Hyo;Ahn, Woon-Sun
    • Bulletin of the Korean Chemical Society
    • /
    • v.8 no.5
    • /
    • pp.358-362
    • /
    • 1987
  • The interaction of oxygen with polycrystalline nickel surface has been studied by investigating the X-ray photoelectron spectra of O 1s, Ni $2p_{3/2}$, and their valence band electrons. By comparing the oxygen exposure of this work with the reported results of LEED, AES, and work function measurements, it is found that the atomic oxygen, adsorbed dissociatively in the initial stage of exposure, is responsible for a p(2 ${\times}$ 2) structure and a subsequent c(2 ${\times}$ 2) structure on the Ni(100) surface. This dissociatively adsorbed oxygen species forms surface NiO layer subsequently on further oxygen exposure. The NiO layer is more easily formed with the increasing temperature. Non-stoichiometric oxygen species is also found to accompany the NiO layer. It appears prior to the formation of bulk NiO at all of the temperatures of this work except at 523K.

Experimental Study on Flame-Vortex Interactions in Turbulent Hydrogen Non-premixed Flames with Coaxial Air (동축공기 수소확산 화염에서의 화염과 와류의 상호작용 실험연구)

  • Kim, Mun-Ki;Oh, Jeong-Suk;Choi, Young-Il;Yoon, Young-Bin
    • 한국연소학회:학술대회논문집
    • /
    • 2006.10a
    • /
    • pp.86-94
    • /
    • 2006
  • This paper investigates the effects of acoustic forcing on NOx emissions and mixing process in the near field region of turbulent hydrogen nonpremixed flames. The resonance frequency was selected to force the coaxial air jet acoustically, because the resonance frequency is effective to amplify the forcing amplitude and reduce NOx emissions. When the resonance frequency is acoustically excited, a streamwise vortex is formed in the mixing layer between the coaxial air jet and coflowing air. As the vortex develops downstream, it entrains both ambient air and combustion products into the coaxial air jet to mix well. In addition, the strong vortex pulls the flame surface toward the coaxial air jet, causing intense chemical reaction. Acoustic excitation also causes velocity fluctuations of coaxial air jet as well as fuel jet but, the maximum value of centerline fuel velocity fluctuation occurs at the different phases of $\Phi$=$180^{\circ}$ for nonreacting case and $\Phi$=$0^{\circ}$ for reacting case. Since acoustic excitation enhances the mixing rate of fuel and air, the line of the stoichiometric mixture fraction becomes narrow. Finally, acoustic forcing at the resonance frequency reduces the normalized flame length by 15 % and EINOx by 25 %, compared to the flame without acoustic excitation.

  • PDF