• Title/Summary/Keyword: non-metal

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Comparison of Heavy Metal Level in Blood Between Industrial Workers and General People

  • Lee Mi-Hwa
    • Biomedical Science Letters
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    • v.10 no.4
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    • pp.453-457
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    • 2004
  • The welders and car painters are frequently exposed to heavy metals such as lead, zinc, cadmium and chromium, and those are a major source of heavy metal poisoning. This study was carried out to investigate the relationship of the heavy metal level in blood by age, working duration, and smoking status among 105 industrial workers and 88 general people in Gyeongnam province from October 2003 to October 2004. The heavy metal level in blood was analyzed by atomic absorption spectrophotometer. Mean blood lead level in exposed group and control group was 8.40±4.67μl/dl, 1.82±1.35μl/dl, respectively. Mean blood zinc level in exposed group and control group was 9.43±5.38 ㎍/ml, 2.89±1.79㎍/ml, respectively. Mean blood cadmium level in Exposed group and control group was 1.53±1.05μl/dl, 0.60±0.49 μl/dl, respectively. Mean blood chromium level in exposed group and control group was 0.89±0.76μl/dl, 0.68±0.63μl/dl, respectively. Lead, zinc, cadmium and chromium level in blood of exposed group was significantly higher than that of control group. In the comparison of smoking status, lead, zinc and cadmium level of smoker's was significantly higher than that of non-smoker's. Comparison of heavy metal level by age, lead, zinc, cadmium level in 40's, 50's (exposed group) in blood significantly higher than that of 20's, 30's. In exposed group, working duration has no significant difference. In conclusion, smoking was the most hazardous factor to elevate in blood heavy metal levels.

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Heavy Metal Levels in the Outdoor Workers Exposed in Yellow Sand (황사에 노출된 옥외 근로자의 혈중 중금속 농도)

  • Lee, Mi-Hwa
    • Korean Journal of Clinical Laboratory Science
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    • v.41 no.3
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    • pp.105-110
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    • 2009
  • Yellow sand (or Asian dust) occurs mainly in spring in East Asia. Yellow sand from China and its surrounding regions transports air pollutants, such as aerosols, ozone, and heavy metals. The outdoor workers are frequently exposed to heavy metals during yellow sand phenomenon. This study was carried out to investigate the heavy metal levels in blood among 75 outdoor workers (exposed group) and 86 indoor workers (controled group) in Gyeonggi province from March 2008 to May 2009. Heavy metal levels in blood were analyzed by atomic absorption spectrophotometer. Mean blood lead levels in exposed group and controled group were $5.19{\pm}1.64{\mu}g/dL$, $4.24{\pm}1.34{\mu}g/dL$, respectively. Mean blood cadmium levels in exposed group and controled group were $1.28{\pm}0.89{\mu}g/dL$, $0.90{\pm}0.59{\mu}g/dL$, respectively. Lead and Cadmium levels in blood of exposed group were significantly higher than those of controled group. In the comparison of smoking status, lead and cadmium levels of smokers were significantly higher than those of non-smokers. In conclusion, the heavy metal levels of outdoor workers were significantly higher than those of indoor workers. And smoking was hazardous factor to elevate heavy metal levels in blood.

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Optical Properties of Metal Halide Perovskite Nanocrystals with Addition of Metal Bromide (금속 브롬화물의 첨가에 따른 금속 할라이드 페로브스카이트 나노결정의 광학적 특성 변화)

  • Yun, Seokjin;Choi, Jihoon
    • Journal of Surface Science and Engineering
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    • v.52 no.6
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    • pp.334-341
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    • 2019
  • Organometal halide perovskite materials have attracted much attention in the photovoltaic and light emitting devices due to the compositional flexibility with AMX3 formula (A is an organic amine cation; M is a metal ion; X is a halogen atom). The addition of homovalent or heterovalent metal cations to the bulk organohalide perovskites has been performed to modify their energy band structure and the relevant optoelectronic properties by ligand-assisted ball milling. Here, we report CH3NH3Pb1-xMxBr3 nanocrystals substituted by metallic cations (M is Sn2+, In3+, Bi3+; x = 0, 0.01, 0.02, 0.05, 0.1, 0.2). Photoluminescence and quantum yield was significantly reduced with increasing metallic cations content. These quenching effect could be resulted from the metal cations that behave as a non-radiative recombination center.

Comparison of Heavy Metal Contents in Eyeliner Products -Focused on Domestic and Foreign Cosmetic Brands-

  • Lee, Kee-Young;Kim, Jeong-hee
    • Journal of Fashion Business
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    • v.19 no.3
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    • pp.113-120
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    • 2015
  • Heavy metal ingredients of eyeliner product could cause side effect ranging from simple irritation, keratitis, corneal epithelium inflammation, eyelid dermatitis and dry eye symptoms have been reported. This study was conducted in order to prepare fundamental data for acceptable quality level heavy metal ingredients in the domestic and foreign cosmetic brand eyeliner products and to assess theirs the heavy metal concentrations. We measured the concentration of 5 heavy metals in 10 eyeliner products using ICP/MS-LC. According to the results, the average metal concentrations were as follows.; In case of domestic eyeliner products, 289.4 ppm for aluminium(Al), 304 ppm for manganese(Mn), 44 ppm for nickel(Ni), 0.58 ppm for arsenic(As) and 0.35 ppm for lead(Pb). In case of Foreign eyeliner products, 11337.8 ppm for aluminium(Al), 1678.8 ppm for manganese(Mn), 74.2 ppm for nickel(Ni), 1 ppm for arsenic(As) and 0.8 ppm for lead(Pb). Foreign products contained higher amounts of the two elements(Pb, As) compared to domestic ones. Also, greater concentrations of arsenic(As) were detected from waterproof products than non-waterproof ones. In conclusion, for safety reasons we suggested the amounts of heavy metals from the domestic and foreign eyeliner products. This finding will be helpful to provide the fundamental data which is standard of toxicological heavy metals acceptable on eyeliner products.

Effects of Fineness of Chitosan Fiber on the Adsorption Characteristics of Metal Ion (금속이온흡착 특성에 미치는 키토산 섬유 굵기의 영향)

  • 최해욱;정영진;이명환;이순장;박수영;이신희
    • Textile Coloration and Finishing
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    • v.15 no.3
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    • pp.146-153
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    • 2003
  • This article describes the metal ions adsorption of chitosan fibers. The chitosan fibers were manufactured by wet spinning using 2% acetic acid as solvent, 10% aqueous sodium hydroxide as non solvent, and 4%chitosan solution as a solvent. The adsorption characteristics of chitosan fibers towards 100ppm solutions of various metal ions such as Cu(II), Cd(II), Cr(III), Hg(II) were examined at different pH value by ICP-Atomic Emission Spectrometer. The adhesiveness of metallic ions to the chitosan fiber were increased with the increase of pH and the decrease of denier. On the other hand, from pH4, chitosan fiber that is immersed in metal ion aqueous solution of Cu(II) and Cd(II) became homogeneous solution because is dissolved. The adhesiveness of metallic ions to chitosan fiber were found to increased in a sequence of Hg(II)> Cr(III)> Cu(II)> Cd(II). The antimicrobial characteristics of the chitosan fiber by adhered metal ions, virgin chitosan fiber, and cotton fiber were evaluated. The antimicrobial activity of the fibers were increased with the decrease of denier.

A Study of the Metal Recovery from the Aluminium Scrap (Al 스크랩으로부터 금속회수에 관한 연구)

  • 김준수;임병모;윤의박
    • Resources Recycling
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    • v.4 no.1
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    • pp.25-30
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    • 1995
  • In the preparatIon of reclaimed aluminium lllgot from alumimum scrap, the aluminium recovery was studied a as a function of the preliminary treatment of samples, addition of flux and melting atmosphere. AI dross is produced by an oxidation reaction at the surface of liquid metal. The recovery of AI metal increases u up to maximum 95% by adding salt up to 7%, The recovery of AI metal in the compacted chip bale without oil removal mcrease about 14% compared io non-compacted chip. In the case of the AI seed melting process, the recovery of Al metal of the crushed and compacted chip hale is 97%, In meltmg of alumimum scrap under the atmosphere of carbon and nitrogen gas, the recovery of AI metal increase, but it is decreased when the mixture of salt and carbon powder is added excessively.

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Analyzing the Impact of Price Fluctuation of Nonferrous Metal Materials on Sectoral Construction Cost (비철금속자재 가격의 변동이 업종별 건설공사비에 미치는 영향 분석)

  • Sang, Jun;Lee, Suk-Won;Kim, Ju-Hyung;Kim, Jae-Jun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.11a
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    • pp.149-151
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    • 2012
  • Changes in the price of materials in construction projects is one of the important variables. Therefore, measures are necessary to respond to the demand and supply of materials and price instability. In previous studies, mainly of ready-mix concrete and steel beam analysis was carried out. However, a study of non-ferrous material prices are still insufficient. So, in this study, the researcher identified the causal relationship between the construction cost and non-ferrous materials prices. Construction Cost Index was selected as a proxy variable of construction cost.

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A study on the defects of die casting mold for air-motor housings and on problem-solving measures (에어모터 하우징 양산용 다이캐스팅 금형의 불량과 대책에 관한 연구)

  • Kim, Sei-hwan;Choi, Kye-kwang
    • Design & Manufacturing
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    • v.6 no.1
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    • pp.18-23
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    • 2012
  • HI-WORTH T-32, a non-powered plasma cutter, is a portable cutter that utilizes compressor-plasma inverter. With a special air-pressure piston, the cutter is semiautomatic. When they were produced by die casting dies, the bodies or housings of the cutter have defects about 100 percent of defect rate due to blisters and thermal deformation. Therefore, they are produced by mechanical machining, which leads to a hike in material and machining costs and to the loss of productivity. And companies are left with insignificant profit margins. Besides mechanical machining, this study proposes to modify defective mold and cut down defective rate and boost productivity.

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Three Dimensional Finite Element Analysis of Particle Reinforced Metal Matirx Composites Considering the Thermal Residual Stress and the Non-uniform Distribution of Reinforcements (금속복합재료의 열잔류 응력과 강화재의 불규칙 분산 상태를 고려한 3차원 유한 요소 해석)

  • 강충길;오진건
    • Journal of the Korean Society for Precision Engineering
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    • v.17 no.6
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    • pp.199-209
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    • 2000
  • Particles reinforced MMCs have higher specific modulus, higher specific strength, better properties at elevated temperatures and better wear resistance than monolithic metals. But the coefficient of thermal expansion(CTE) of Al6061 is 5 times larger than that of SiCp. The discrepancy of CTE makes some residual stresses inside of MMCs. This work investigates Si$C_p$/Al6061 composites at high temperatures in the microscopic view by three-dimensional elasto-plastic finite element analyses and compares the analytical results with the experimental ones. The theoretical model is not able to consider the nonuniform shape of particle. So the shape of particle is assumed to be perfect global shape. And also particle distribution is not homogeneous in experimental specimen. It is assumed to be homogeneous in simulation model. The type of particle distribution is face-centered cubic array(FCC array). Furthermore, non-homogeneous distribution is modeled by combination of several volume fractions.

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Non-Pt transition metal electrode catalyst for Oxygen Reuction Reaction of Polymer Electrolyte Membrane Fuel Cell (고분자 전해질 연료전지의 산소환원반응을 위한 비백금계 전이금속 전극 촉매)

  • Kim, Jy-Yeon;Lee, Sang-Beom;Park, Kyung-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.383-385
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    • 2009
  • 비백금계 코발트 전이금속 촉매를 탄소지지체에 담지한 뒤, 암모니아 분위기에서 $500^{\circ}C$에서 3시간 동안 열처리하는 과정을 통해 코발트 질화물 촉매를 제조했다. 제조된 촉매들의 구조와 형태를 각각 XRD, HE-TEM등을 통해 분석하였고, 전위 측정기를 이용한 CV, LSV 결과로부터 촉매의 전기화학적 산소 환원특성을 분석하여, 기존의 연료전지 양극 촉매로 사용되는 고가의 백금촉매를 대체하기 위한 비백금계로서의 가능성을 확인하였다.

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