• Title/Summary/Keyword: non-metal

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Synthesis and comparison of pure TiO2 and metal/non-metal doped TiO2 as a photocatalyst

  • Moon, Jiyeon;Lee, Kyusang;Kim, Seonmin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.370.1-370.1
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    • 2016
  • Volatile organic compounds (VOCs) are considered hazardous air pollutants and these are emitted from building materials and household products. VOCs can cause global warming as well as human sickness, and even cancer. Photocatalysis provides a way of converting VOCs into harmless materials. Various researches have shown that $TiO_2$ is the most efficient photocatalysts due to its excellent activity. In this study, metal/non-metal doped $TiO_2$ particles are synthesized for the enhancement of the photocatalytic properties of pure $TiO_2$. By metal/non-metal doping, band gap energies of prepared samples were analyzed by UV/Visible spectrophotometer. The physical and chemical properties of synthesized powder were characterized by field emission scanning electron microscope, by BET for measuring their specific surface area, and by XRD for phase identification and particle size determination. Degradation ability for p-xylene was evaluated through monitoring the concentration in a closed chamber. Relation between their properties and decomposition abilities for VOC were evaluated based on the experimental results.

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A study on the Bond Strength of Non-Precious Alloys Used for the Porcelain Fused to Metal Crown (도재 전장 금관용 비귀금속 합금의 결합강도에 관한 연구)

  • Kim, Cheol-Man;Lee, Jong-Hyuk;Cho, In-Ho
    • Journal of Dental Rehabilitation and Applied Science
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    • v.22 no.3
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    • pp.203-210
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    • 2006
  • Although porcelain fused to metal crowns made from non-precious metal have good mechanical properties, they also have disadvantages such as the poor biological acceptability and the low corrosional resistance. Titanium is used as the alternative metal for porcelain fused to metal crowns, in spite of difficulties in casting. For that reason non-precious alloy including titanium which is easy to cast is currently used. This study evaluated the bond strength between non-precious alloy including titanium and Ni-Cr alloy. $Tilite^{(R)}V$ as non-precious alloy including titanium, $Rexilium^{(R)}V$ as Ni-Cr alloy and $Omega900^{(R)}$ and $Vintage(Regular)^{(R)}$ as porcelain powders were used. The results were as follows. 1. In comparison with the kind of alloy, the bond strength of $Tilite^{(R)}V$ was lower than that of $Rexilium^{(R)}V$. There was no significant difference between two groups. 2. In comparison with the kind of porcelain powder, the bond strength of $Omega900^{(R)}$ was higher than that of $Vintage(Regular)^{(R)}$ in $Tilite^{(R)}V$. There was significant difference between two groups(p < 0.05).

AN EXPERIMENTAL STUDY ON THE FITNESS OF THE CERVICAL MARGIN IN THE CERAMO-METAL CROWN ACCORDING TO THE ALLOY TYPES AND THE CURVATURE OF LABIO-CERVICAL MARGIN (도재소부전장금관용 합금과 순측치경부 변연만곡도에 따른 변연적합도에 관한 연구)

  • Jeon Young-Chan;Kim Jung-Hwa
    • The Journal of Korean Academy of Prosthodontics
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    • v.29 no.3
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    • pp.181-196
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    • 1991
  • The Purpose of this study was to evaluate the marginal fit of ceramo-metal crown according to the different ceramo-metal alloy types and the curvature of labio-cervical margin. Degudent $G^{(R)}$ as precious and $Verabond^{(R)}$ as non-precious ceramo-metal alloy were used. The abutment was preparaed with two different curvature types : a normal curvature type and a pronounced curvature type. 20 crowns were farbricated using four different combinations and their marginal fits were measured at 3 consecutive stages (before degassing, after degassing, after glazing) using microscope under 200 magnification. The results were as follows: 1 . Marginal fitness before degassing. The groups of precious ceramo-metal exhibited better marginal fit than the groups of non-precious ceramo-metal with significant difference(P<0.05) . In the same ceramo-metal groups, the normal curvature group exhibited better marginal fit than the pronounced curvature group but without significant difference(P>0.05). 2. Marginal fitness after degassing. By degassing, the group of pronounced curvature and non-precious ceramo-metal was deformed the most, and the degree of margin fitness of each group was the same as before degassing. 3. Marginal fitness after glazing The group of normal curvature and precious ceramo-metal exhibited better marginal fit than the group of pronounced curvature and non-precious ceramo-metal with significant difference(P>0.05), and the degree of margin fitness of each group was the same as before degassing.

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Corrosion of the non-beryllium dental casting Ni-Cr alloys for the denture base framework metal and the porcelain-fused-to-metal crown (베릴륨 불포함 치과 주조용 니켈-크롬 합금 중 금속의치상용 합금과 금속소부도재관용 합금의 부식에 관한연구)

  • Kim, Hong-Sik;Song, Jae-Sang;Park, Soo-Chul
    • Journal of Technologic Dentistry
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    • v.34 no.4
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    • pp.337-344
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    • 2012
  • Purpose: This study examined the corrosion level by alloy type and pH, and used the corrosion levels as the dental health data. The study utilized one Ni-Cr alloy for the full and removable partial denture metal frameworks and two Ni-Cr alloys for porcelain-fused-to-metal crown, among the non-beryllium dental casting non-precious Ni-Cr alloys. Methods: The alloy specimens were manufactured in $10cm^2$ and stored in the corrosive solution(pH 2.2-4.4) in the electrical water bath($37^{\circ}C$) for seven days. Afterwards, the metal ions were quantitatively analyzed using the ICP. Results: Of the three metal alloys, Bellabond-Plus$^{(R)}$alloy and SOLIBOND N$^{(R)}$alloy, with 22% or higher chrome chemical contents, had higher corrosion resistance than Jdium-100$^{(R)}$alloy with 20% chrome chemical content. In all three alloys, the corrosion of Ni was highest, and metal ion corrosion was higher in the pH 2.2 corrosive solution. Conclusion: Although Ni-Cr alloy was not very corrosive, a Ni-allergic patient should not have Ni-Cr alloy prosthesis. The Ni-Cr alloy for porcelain-fused-to-metal crown should be designed for the dental porcelain to cover the whole crown.

On Feasibility Study of the Charged Particle Beam Pretreatment Process for Non-conducting Metal Coating (무전도 금속 증착을 위한 하전 입자빔 전처리 공정의 타당성 연구)

  • Na, Myung Hwan;Park, Young Sik;Shim, Ha-Mong;Chun, Young Ho
    • Journal of Korean Society for Quality Management
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    • v.42 no.2
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    • pp.179-187
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    • 2014
  • Purpose: Since several problems were found when present non-conducting metal coating process was applied to mass production, we study and develop to improve those problems. Methods: In this paper, a couple of analysis methods such as surface hardness, XPS spectrum analysis, morphology, and reflection ratio were used. Results: This paper suggest a new possibility of Non-conducting thin metal coating method that has quality of mass production phase without UV coating process. Conclusion: By the result of analysis, we can set optimized process conditions of the electro deposition coating using electron beam.

The Preparation of Non-aqueous Supercapacitors with Lithium Transition-Metal Oxide/Activated Carbon Composite Positive Electrodes

  • Kim, Kyoung-Ho;Kim, Min-Soo;Yeu, Tae-Whan
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3183-3189
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    • 2010
  • In order to increase the specific capacitance and energy density of supercapacitors, non-aqueous supercapacitors were prepared using lithium transition-metal oxides and activated carbons as active materials. The electrochemical properties were analyzed in terms of the content of lithium transition-metal oxides. The results of cyclic voltammetry and AC-impedance analyses showed that the pseudocapacitance may stem from the synergistic contributions of capacitive and faradic effects; the former is due to the electric double layer which is prepared in the interface of activated carbon and organic electrolyte, and the latter is due to the intercalation of lithium ($Li^+$) ions. The specific capacitance and energy density of a supercapacitor improved as the lithium transition-metal oxides content increased, showing 60% increase compared to those of supercapacitor using a pure activated carbon positive electrode.

Performance Determination of Novel Design Eddy Current Separator for Recycling of Non-Ferrous Metal Particles

  • Fenercioglu, Ahmet;Barutcu, Hamit
    • Journal of Magnetics
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    • v.21 no.4
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    • pp.635-643
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    • 2016
  • Improvements were made in the study for the design of the conventional Eddy Current Separator (ECS) used for separating small sized non-ferrous particles in the waste. These improvements include decreasing the air gap between the material and magnetic drum, making the drum position adjustable and placing the splitter closer to the drum. Thus, small particles were separated with high efficiency. The magnetic drum was removed from inside the ECS conveyor belt system as design change and was placed as a separate unit. Hence, the force generated on the test material increased by about 5.5 times while the air gap between the non-ferrous materials and drum decreased from 3 mm to 1 mm. The non-metal material in the waste is separated before the drum in the novel design. Whereas non-ferrous metal particles are separated by falling into the splitter as a result of the force generated as soon as the particles fall on the drum. Every material that passes through the drum can be recycled as a result of moving the splitter closer to the contact point of the drum. In addition, the drum can also be used for the efficient separation of large particles since its position can be adjusted according to the size of the waste material. The performance of the novel design ECS was verified via analytical approaches, finite element analysis (FEA) and experimental studies.

Design of Control System for All-Metal Domestic Induction Heating Considering Temperature and Quick-Response (워킹코일 온도 및 제어 속응성을 고려한 All-Metal Domestic Induction Heating 제어 시스템 설계)

  • Park, Sang-Min;Jang, Eun-Su;Joo, Dong-Myoung;Lee, Byoung-Kuk
    • The Transactions of the Korean Institute of Power Electronics
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    • v.23 no.3
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    • pp.199-207
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    • 2018
  • In this paper, an all-metal domestic induction heating (IH) system that can quickly identify ferromagnetic and non-ferromagnetic pots considering temperature changes in the working coil is designed. Load modeling is performed after analyzing the parameters of the pot material and the central misalignment of the working coil. To improve the performance and stability of the all-metal IH cooking heater, a power curve-fitting model is used to design a control system that quickly responds to load parameter fluctuations. In addition, a power control algorithm is established to compensate for the reference value by reflecting the increase in working coil temperature during heating of the non-ferromagnetic pot. The validity of the proposed control algorithm for the all-metal IH is verified by experiments using a 3.2 kW all-metal IH cooking heater.

폐금속광산 하류하천에서의 수변식물내 중금속의 축척에 관한 연구

  • 김주선;이재영;최상일
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.235-240
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    • 2004
  • This study is to study accumulation of the heavy metals by riparian vegetation throughout analysis of the heavy metal concentration in riparian vegetation, water, and sediment near mine drainage. According to analyzing concentration of the heavy metals in riparian vegetation, water, and sediment, the heavy metal was indicated at the leaf significantly. Compared with the concentration of sediment soil, the maximum concentration of the As, Cd, CN, Pb, Zn was higher 2.6, 2.6, 2.5, non-detect, and 1.5 times in leaf, Also those concentration have 9.6, 16.6, 2.5, 1.6, and 2.5 times in root. As the results, the author can know the sediment has a very relative to vegetation in mine drainage, because the increasing of concentration of heavy metal in sediment gives the more accumulative concentration of heavy metal in vegetation. Compared with the concentration of contaminated site and non-contaminated site. As, Cd, CN, Pb, Zn the maximum concentration in sediment soil was higher 5.7, 258.1, 10.9, 370.0, and 298.3 times respectively. In case of vegetation, the maximum concentration of the As, Cd, CN, Pb, Zn was higher 5.6, 62.3, 5.0, non-detect, and 30.6 times in leaf. Also those concentration have 8.5, 63.3, 2.6, 60.7, and 62.1 times in root. In this study, the author can surmise that there indicated a lot of adsorption with the heavy metal concentration in contaminated mine drainage.

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Evaluation of a metal level in non-precious metal alloys dental casting having beryllium by lactic acid Solution (베릴륨함유 치과 주조용 비귀금속 합금의 젖산용액에 의한 금속 노출수준 평가)

  • Park, Soo-Chul;Jang, Eun-Jin;Han, Sok-Yoon
    • Journal of Technologic Dentistry
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    • v.33 no.2
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    • pp.121-128
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    • 2011
  • Purpose: The purpose of this study is to investigate the level of each metal in non-precious metal alloys dental casting, still used even banned for use and trade by the law, for oral health. Methods: Two kinds of metal alloys were analyzed. One was Ticonium 100 for removable prosthesis and the other was Rexillium V for dental porcelain. Two samples of each metal alloy were made in 0.5g, 1.0g, and 1.5g. Total number of samples were 12. Two kinds of lactic acid Solution, pH7 and pH4.6, were injected into each samples. After injection, each samples had been for 21days ${\pm}$ 1 hour in the water tank of which temperature was $37^{\circ}C$. The level of metal was measured in each sample by inductively couplled plasma-atomic emission spectrometer. Results: In both metal alloys, metals, chrome, nickel, beryllium, and molybdenum, were founded. In Ticonium 1000, the highest level of nickel was 2.531ppm in 1.5g pH4.6 sample while the highest level of nickel was 4.062ppm in 1.5g pH4.6 sample of Rexillium V. In chemical composition of these methal alloys, chrome(14~17%) was much more than beryllium(1.95~1.99%) and molybdenum(5.0~9.0%) but berllium and molybdenum were founded more than chrome in samples. Therefore, chrome showed better anti-corrosion than other metal alloys. In both metal alloys, more metals were founded in higher pH level and more mass. Levels of chrome was significantly different in samples of both metal alloys in each pH level(p<0.05). Levels of nickels was significantly different in samples of both metal alloys in each pH level(p<0.05). Conclusion: For oral health, further studies are needed in nickel-chrome metal alloy and cobalt metal alloy of non-beryllium in addittion to beryllium metal alloy and also long-term studies needed in various period and other non-percious metal alloys for dental casting.