• 대한치과기공학회지
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• 제9권1호
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• pp.39-49
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• 1987

This study done to evaluate some surface treatment methods in metal coping which can increase the bond strength between porcelain and metal. Therefore this experiment was performed according to the Mc Lean's Theory of bond strength between porcelain and strength between porcelain and metal. In the experiment the author measured respective thermal expansion coefficents in three types of metal(Tallasium, Vera Bond and Rexillium) and Vita Porcelain to get the differences in the coefficents between porcelain and metals. And using insteron testing machine, the author also performed Planar interface shear bond tests on the 45 specimens(15 specimens in oxide surface, rough surface and fine surface treatment methods respectively) to measure bond strength between metal and porcelain. The results Were as follows, 1. The differences in thermal expansion coefficients between three types of metal and Vita procelain: Talladium - $1.2\;10^{-6/0}\;C$, Vera Bond - $1.6\;10^{-6/0}\;C$, Rexillium - $1.9\;10^{-6/0}\;C$. 2. The bond strength in oxide surface on the Shear bond test was the lowest among the treatment methods. 3. There was no significant differences in treatment methods of rough surface of fine surface. 4. In the oxide surface treatment method, there were significant differences(P<0.05)between Vera bond and Rexillium, and between Talladium and Rexillium. 5. In the fine surface treatment, there was a significant difference(P<0.05)between Talladium and Rexillium.

• 대한치과기공학회지
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• 제31권4호
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• pp.15-23
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• 2009

The aim of this study was to evaluate the bond strength of using a Au bonding agent applied on cp-Ti and nonprecious metal-gold-ceramic system. Metallic frameworks(diameter: 5mm, height: 20mm)(N=56, n=7per group) cast in Ni-Cr alloy, Co-Cr alloy and cp-Ti were obtained using acrylic templates and airborne particle abraded with $110{\mu}m$ aluminum oxide. Au bonding agent was applied on wash opaque firing as intermediate layer. SEM and SEM/EDS line profile were performed on the cutting the cross-section of the metal substrate-porcelain with intermediate Au coating. Groups were tested using shear bond strength(SBS) testing at 0.5mm/min. The mean SBS values for the ceramic-Au layer-metal combination were significantly higher than those ceramic-metal combination. While ceramic-Au layer-cp-Ti combinations failed to increase bond strength instead of using a titanium bonding porcelain. The appication of using Au intermediate layer significantly improve the bond strength combination with metal-ceramic system.

• Bulletin of the Korean Chemical Society
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• 제26권3호
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• pp.393-398
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• 2005

The stability constants for the diaza-18-crown-6 ethers 2-6 and alkali metal cations ($Na^+,\;K^+,\;Rb^+\;and\;Cs^+$) were determined using potentiometry in 95% methanol. For each metal ion the stability constants of the partiallyfluorinated ligands 3-6 were larger than that of the non-fluorinated ligand 2, which might reflect an interaction between fluorine atoms and alkali metal cations. The stability constant of the ligand 4 was larger than that of the ligand 5 for each metal cation tested. This finding was also supported by the results of cation-induced chemical shifts in $^1H-,\;^{19}F$-NMR and extraction experiment. The potentiometry and NMR results as well as the X-ray crystal structures revealed that the position and number of fluorine atoms in the benzyl side arms was crucial for the enhanced interaction between a ligand and an alkali metal.

• 소성∙가공
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• 제20권5호
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• pp.377-386
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• 2011

During stamping processes, the air trapped between sheet metal and the die cavity can be highly compressed and ultimately reduce the shape accuracy of formed panels. To prevent this problem, vent holes and passages are sometimes drilled into the based on expert experience and know-how. CAE can be also used for analyzing the air behavior in die cavity during stamping process, incorporating both elasto-plastic behavior of sheet metal and the fluid dynamic behavior of air. This study presents sheet metal forming simulation combined simultaneously with simulation of air behavior in the die cavity. There are three approaches in modeling of air behavior. One is a simple assumption of the bulk modulus having a constant pressure depending on volume change. The next is the use of the ideal gas law having uniform pressure and temperature in air domain. The third is FPM (Finite point method) having non-uniform pressure in air domain. This approach enables direct coupling of mechanical behavior of solid sheet metal and the fluid behavior of air in sheet metal forming simulation, and its result provides the first-hand idea for the location, size and number of the vent holes. In this study, commercial software, PAM-$STAMP^{TM}$ and PAM-$SAFE^{TM}$, were used.

• 한국안전학회지
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• 제18권4호
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• pp.92-97
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• 2003

The purpose of this study is heavy metal absorption of recycled PET(poly ethylene terephatalate) NWF(non woven faric). The results of test are summarized as follows; Heavy metal abworption rates in Ni ions were higher then Zn and Cu ions, whereas heavy metal absorption rates by sulfonation times were not different. The heavy metal absorption times have a higher tendency from 60 min to 120 min. There were significant negative correlations among the amount used CSA(Chloro Sulfuric Acid) and the amount of absorption Zn(r = -0.33784, p < 0.05), Cu(r = -0.61177, p < 0.01) ions, whereas correlations between heavy metal absorption rates and sulfonation times were not significant. There were significant positive correlations among the amount of absorption Zn ions and the amount of absorption Ni(r = 96475, p < 0.014), Cu(r = 0.51614, p < 0.01) ions, likewise the positive correlations between the amount of absorption N ions and the amount of absorption Cu(r = 0.54766) ions were significant(p < 0.01).

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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• pp.865-868
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• 2008

본 연구에서는 최근 사용이 증대되고 있는 고성능 콘크리트의 폭렬현상을 방지하기 위해 일련의 연구 중 메탈라스 횡구속을 병행한 비탈형 거푸집을 사용한 고성능 콘크리트 RC기둥부재의 내화특성을 검토하였는데, 그 결과를 요약하면 다음과 같다. 유동성 및 공기량은 모두 목표 범위를 만족하였고, 압축강도는 재령 28일에서 80 MPa이상으로 고강도범위를 나타내었다. 폭렬 특성으로는 섬유를 혼입하지 않은 플레인의 경우는 심한 폭렬이 발생하였고, 나일론(이하 NY)+폴리프로필렌(이하 PP) 섬유를 0.05%를 혼입한 경우에는 표면부에만 부분적인 박리폭렬이 발생하였다. 비탈형 거푸집 변화에 따라서는 비탈형 25-20, 비탈형 50-20의 경우에는 모두 마 감재부분에 폭렬이 발생하였는데, 비탈형 50-20의 경우가 비탈형 25-20보다 양호한 폭렬방지 성능을 나타내었다. 비탈형 50-40의 경우는 폭렬이 방지되었는데 질량감소율은 10%이하로 나타났고, 온도이력은 모재표면부 최고온도가 $376.1^{\circ}C$로 가장 우수한 내화 성능을 나타내었다.

• 자원리싸이클링
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• 제28권3호
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• pp.68-76
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• 2019

비철금속의 국내 수요 공급과 스크랩들의 리싸이클링 현황을 파악하는 것은 자원재활용 관련업계와 연구자들에게 매우 필요한 일이다. 국내에서는 10여 년 전부터 한국자원리싸이클링학회지를 통하여 3~5년 주기로 주요 비철금속의 수급과 스크랩 리싸이클링 현황을 조사, 발표하고 있는데, 전체 비철금속에 대해서 조사하기에는 분량이 너무 방대하여 사용량이 많은 범용 비철금속과 그 스크랩들에 국한하여 발표하고 있다. 본 조사연구에서는 기존 조사대상인 동, 알루미늄, 아연, 연, 니켈, 마그네슘 6종에 주석을 추가하여 총 7종의 비철금속에 대하여 관세청 수출입 통계와 한국비철금속협회 자료 및 비철산업 관련 정보지들을 통해서 최근 5년 (2014 ~ 2018년) 간의 국내 수급 현황을 조사하였고 이를 토대로 그 스크랩들의 재활용율을 추정하였다.

• 대한치과보철학회지
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• 제29권2호
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• pp.245-265
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• 1991

The purpose of this study was to observe the changes of the elemental transmission and bond strength between the metal and porcelain according to various kinds of ion beam mixing method. ion beam mixing of $meta1/SiO_2$ (silica), $meta1/Al_2O_3$(alumina) interfaces causes reactions when the $Ar^+$ was implanted into bilayer thin films using a 100KeV accelerator which was designed and constructed for this study. A vacuum evaporator used in the $10^{-5}-10^{-6}$ Torr vacuum states for the evaporation. For this study, three kinds of porcelain metal selected, -precious, semiprecious, and non-precious. Silica and alumina were deposited to the metal by the vacuum evaporator, separately. One group was treated by two kinds of dose of the ion beam mixing $(1\times10^{16}ions/cm^2,\;5\times10^{15}ions/cm^2)$, and the other group was not mixed, and analyzed the effects of ion beam mixing. The analyses of bond strength, elemental transmissions were performed by the electron spectroscopy of chemical analysis (ESCA), light and scanning electron microscope, scratch test, and micro Vickers hardness tests. The finding led to the following conclusions. 1. In the scanning electron and light microscopic views, ion beam mixed specimens showed the ion beam mixed indentation. 2. In the micro Vickers hardness and scratch tests, ion beam mixed specimens showed higher strength than that of non mixed specimens, however, nonprecious metal showed a little change in the bond strength between mixed and non mixed specimens. 3. In the scratch test, ion beam mixed specimens showed higher shear strength than that of non treated specimens at the precious and semiprecious groups. 4. In the ESCA analysis, Au-O and Au-Si compounds were formed and transmission of the Au peak was found ion beam mixed $SiO_2/Au$ specimen, simultaneously, in the higher and lower bonded areas, and ion beam mixed $SiO_2/Ni-Cr$ specimen, oxygen, that was transmitted from $SiO_2\;to\;SiO_2/Ni-Cr$ interface combined with 12% of Ni at the interface.

• Fibers and Polymers
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• 제3권4호
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• pp.147-152
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• 2002

Copper (II) salts are used as metallizing agents in the synthesis of new non-genotoxic direct dyes for cotton. Specifically, cotton fabric is dyed with non-genotoxic disazo direct dyes and then treated with copper salts. The complexes are characterized by neutron activation analysis, absorption spectrometry and standard Salmonella mammalian mutagenicity assay, and the after-treated fabrics are evaluated for lightfastness and washfastness. Direct dyes possessing ortho-propoxy and ortho'-hydroxy substituted systems formed the corresponding nonmutagenic 1:2 dye:metal complex and undergo significant improvement in lightfastness following metallization.

• 대한치과기공학회지
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• 제35권1호
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• pp.43-48
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• 2013

Purpose: This study aimed to investigate the shear bond strength for non-precious alloy castings without beryllium, which has been used repeatedly for economical reason. Methods: The Schmitz-Schulmeyer test method was used to evaluate the shear bond strength between the non-beryllium Ni-Cr alloy Vera Bond 2V(AlbaDent, Inc. USA) and the Ceramco 3(Dentstply, York, PA, USA) porcelain powder. The maximum loading and shear bond strength were measured. The average shear strength(MPa) was analyzed with the one-way ANOVA and the Tukey's test( =.05). The fracture specimens were examined using Microscope to determine the failure pattern. Results: The mean shear bond strengths(SD) in MPa were group A(100% new metal) control 28.72(3.31); group B(50% new + 50% reused) 27.28(1.13); group C(all reused) 26.61(5.47). Microscope examination showed that group A and B specimens presented mixed failure, and group C specimens showed adhesive failure. Conclusion: In conclusion, forward this non-precious alloy dose not contain beryllium for how should use a more systematic study and for future advanced research is performed giving effect to be considered desirable.