• Title/Summary/Keyword: non-homogeneous

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Synthesis of New Bimetallic Chiral Salen Catalyst Bearing Co(BF4)2 Salt and Its Application in Asymmetric Ring Opening of Epoxide

  • Kim, Yong-Suk;Lee, Choong-Young;Kim, Geon-Joong
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2973-2979
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    • 2010
  • The newly synthesized homogeneous chiral Co(III) salen complexes were anchored non-covalently on the acidic sites of mesoporous Al-SBA-15. The Bronsted and Lewis acidic sites are attributed to the immobilization of fluorine functionalized chiral salen complexes on the supports. XRD, BET, TEM, FT-IR and ESCA (XPS) analyses were performed to characterize the property of support, and the structure of new homogeneous and heterogeneous chiral Co salen catalyst. The homogeneous and heterogeneous catalysts could be applied in asymmetric ring opening of epichlorohydrine (ECH) by water. They showed very high enantioselectivity and a good yield up to 99% in the catalytic synthesis of optically active products.

Non-Homogeneous Haze Synthesis for Hazy Image Depth Estimation Using Deep Learning (불균일 안개 영상 합성을 이용한 딥러닝 기반 안개 영상 깊이 추정)

  • Choi, Yeongcheol;Paik, Jeehyun;Ju, Gwangjin;Lee, Donggun;Hwang, Gyeongha;Lee, Seungyong
    • Journal of the Korea Computer Graphics Society
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    • v.28 no.3
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    • pp.45-54
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    • 2022
  • Image depth estimation is a technology that is the basis of various image analysis. As analysis methods using deep learning models emerge, studies using deep learning in image depth estimation are being actively conducted. Currently, most deep learning-based depth estimation models are being trained with clean and ideal images. However, due to the lack of data on adverse conditions such as haze or fog, the depth estimation may not work well in such an environment. It is hard to sufficiently secure an image in these environments, and in particular, obtaining non-homogeneous haze data is a very difficult problem. In order to solve this problem, in this study, we propose a method of synthesizing non-homogeneous haze images and a learning method for a monocular depth estimation deep learning model using this method. Considering that haze mainly occurs outdoors, datasets mainly containing outdoor images are constructed. Experiment results show that the model with the proposed method is good at estimating depth in both synthesized and real haze data.

ON FUNCTIONAL EQUATIONS OF THE FERMAT-WARING TYPE FOR NON-ARCHIMEDEAN VECTORIAL ENTIRE FUNCTIONS

  • An, Vu Hoai;Ninh, Le Quang
    • Bulletin of the Korean Mathematical Society
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    • v.53 no.4
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    • pp.1185-1196
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    • 2016
  • We show a class of homogeneous polynomials of Fermat-Waring type such that for a polynomial P of this class, if $P(f_1,{\ldots},f_{N+1})=P(g_1,{\ldots},g_{N+1})$, where $f_1,{\ldots},f_{N+1}$; $g_1,{\ldots},g_{N+1}$ are two families of linearly independent entire functions, then $f_i=cg_i$, $i=1,2,{\ldots},N+1$, where c is a root of unity. As a consequence, we prove that if X is a hypersurface defined by a homogeneous polynomial in this class, then X is a unique range set for linearly non-degenerate non-Archimedean holomorphic curves.

The Numerical multi-phase analysis of ventilating flow around vehicle (환기 공동을 이용한 수중운동체 주위의 초월 공동 다상유동장 해석)

  • Park, Wam-Gyu;Kim, Dong-Hyun;Jung, Chul-Min
    • 한국전산유체공학회:학술대회논문집
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    • 2011.05a
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    • pp.252-255
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    • 2011
  • Supercavitating torpedo uses the supercavitation technology that can reduce dramatically the skin friction drag. The present work focuses on the numerical analysis of the non-condensable cavitating flow around the supercavitating torpedo. The governing equations are the Navier-Stokes equations based on the homogeneous mixture model. The cavitation model uses a new cavitation model which was developed by Merkle(2006). The multiphase flow solver uses an implicit preconditioning scheme in curvilinear coordinates. The ventilated cavitation is implemented by non-condensable gas injection on backward of cavitator cone and the base of the torpedo. The comparison between the without and with ventilated cavitation numerical results, with ventilated cavitation using non-condensable gas injection is more efficient method.

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Nonlinear and linear thermo-elastic analyses of a functionally graded spherical shell using the Lagrange strain tensor

  • Arefi, Mohammad;Zenkour, Ashraf M.
    • Smart Structures and Systems
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    • v.19 no.1
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    • pp.33-38
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    • 2017
  • This research tries to present a nonlinear thermo-elastic solution for a functionally graded spherical shell subjected to mechanical and thermal loads. Geometric nonlinearity is considered using the Lagrange or finite strain tensor. Non-homogeneous material properties are considered based on a power function. Adomian's decomposition method is used for calculation of nonlinear results. Nonlinear results such as displacement can be evaluated for sphere in terms of different indexes of non-homogeneity. A comprehensive comparison between linear and nonlinear results and evaluation of the percentage of difference between them can be performed in this paper. The obtained results indicate that the improvement of the results due to usage of nonlinear analysis is depending on the non-homogeneous index.

Dynamical behavior of the orthotropic elastic material using an analytical solution

  • Balubaid, Mohammed;Abdo, H.;Ghandourah, E.;Mahmoud, S.R.
    • Geomechanics and Engineering
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    • v.25 no.4
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    • pp.331-339
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    • 2021
  • In this work, an analytical solution is provided for the dynamical response of an orthotropic non-homogeneous elastic material. The present study has engineering applications in the fields of geophysical physics, structural elements, plasma physics, and the corresponding measurement techniques of magneto-elasticity. The analytical performances for the elastodynamic equations has been solved regarding displacements. The influences of the rotation, the magnetic field, the non-homogeneity based radial displacement and the corresponding stresses in an orthotropic material are investigated. The variations of the stresses, the displacement, and the perturbation magnetic field have been illustrated. The comparisons is performed using the previous solutions in the magnetic field absence, the non-homogeneity and the rotation.

Improved Closure Approximation for Numerical Simulation of Fiber Orientation in Fiber-Reinforced Composite (단섬유 보강 복합재료에서의 섬유배향의 수치모사를 위한 개선된 근사모델)

  • D.H. Chung;T.H. Kwon
    • The Korean Journal of Rheology
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    • v.10 no.4
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    • pp.202-216
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    • 1998
  • Improved version of previous 'Orthotropic' closure approximation, termed 'ORW' has been numerically developed using new homogeneous flow data. Previous 'Orthotropic' closure approximation, i.e., ORF or ORL showed non-physical oscillation for interaction coefficient $C_1$<0.001 at simple shear flow. It also shows non-physcial oscillation and under-prediction compared with 'Distribution Function Calculation' at non-homogeneous flow of center-gated disk. These phenomena are mainly due to the flow data of 'Distribution Function Calculation' which were used for least-square optimization. ORW obtained by fitting flow data of low interaction coefficient does not show non-physical oscillation and results in reasonably good behaviors at non-homogeneous flows as well as homogeneous flows. Fitting function forms have not been found to improve overall behaviors. It has been found that considering all the eigenvalues of orientation tensor (including the third eigenvalues) might end up with a better closure approximation than just considering the first and second eigenvalues. It is, however, very important and yet difficult to select appropriate function forms of eigenvalues. Numerical simulation including coupling and in-plane velocity gradient effects were performed for injection mold filing process with a film-gated strip and a center-gated disk using ORW and various other closure approximations for comparisons. Although ORW is in excellent agreement with 'Distribution Function Calculation', the predicted results seem to have consistent error in comparison with experimental data. The diffusivity term with constant interaction coefficient might have to be further investigated in order to accurately describe orientation states.

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Collapse mechanism of tunnel roof considering joined influences of nonlinearity and non-associated flow rule

  • Yang, X.L.;Xu, J.S.;Li, Y.X.;Yan, R.M.
    • Geomechanics and Engineering
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    • v.10 no.1
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    • pp.21-35
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    • 2016
  • Employing non-associated flow rule and Power-Law failure criterion, the failure mechanisms of tunnel roof in homogeneous and layered soils are studied in present analysis. From the viewpoint of energy, limit analysis upper bound theorem and variation principle are introduced to study the influence of dilatancy on the collapse mechanism of rectangular tunnel considering effects of supporting force and seepage force. Through calculation, the collapsing curve expressions of rectangular tunnel which are excavated in homogeneous soil and layered soils respectively are derived. The accuracy of this work is verified by comparing with the existing research results. The collapsing surface shapes with different dilatancy coefficients are draw out and the influence of dilatancy coefficient on possible collapsing range is analyzed. The results show that, in homogeneous soil, the potential collapsing range decreases with the decrease of the dilatancy coefficient. In layered soils, the total height and the width on the layered position of possible collapsing block increase and the width of the falling block on tunnel roof decrease when only the upper soil's dilatancy coefficient decrease. When only the lower soil's dilatancy coefficient decrease or both layers' dilatancy coefficients decrease, the range of the potential collapsing block reduces.

An Analysis on the Identification Rate of Detection System Using Non-Homogeneous Discrete Absorbing Markov Chains (비 동질성 이산시간 흡수마코프체인을 활용한 탐지체계의 식별률 분석에 관한 연구)

  • Kim, Seong-Woo;Yoon, Bong-Kyoo
    • Journal of the Korean Operations Research and Management Science Society
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    • v.40 no.2
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    • pp.31-42
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    • 2015
  • The purpose of airborne radars is to detect and identify approaching targets as early as possible. If the targets are identified as enemies, detection systems must provide defense systems with information of the targets to counter. Though many previous studies based on the detection theory of the target have shown various ways to derive detection probability of each radar, optimal arrangement of radars for effective detection, and determination of the search pattern, they did not reflect the fact that most military radar sites run multiple radars in order to increase the accuracy of identifications by radars. In this paper, we propose a model to analyze the probability of identification generated by the multiple radars using non-homogeneous absorbing markov chains. Our results are expected to help the military commanders counter the enemy targets effectively by using radars in a way to maximize the identification rate of targets.

Separation of Text and Non-text in Document Layout Analysis using a Recursive Filter

  • Tran, Tuan-Anh;Na, In-Seop;Kim, Soo-Hyung
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.9 no.10
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    • pp.4072-4091
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    • 2015
  • A separation of text and non-text elements plays an important role in document layout analysis. A number of approaches have been proposed but the quality of separation result is still limited due to the complex of the document layout. In this paper, we present an efficient method for the classification of text and non-text components in document image. It is the combination of whitespace analysis with multi-layer homogeneous regions which called recursive filter. Firstly, the input binary document is analyzed by connected components analysis and whitespace extraction. Secondly, a heuristic filter is applied to identify non-text components. After that, using statistical method, we implement the recursive filter on multi-layer homogeneous regions to identify all text and non-text elements of the binary image. Finally, all regions will be reshaped and remove noise to get the text document and non-text document. Experimental results on the ICDAR2009 page segmentation competition dataset and other datasets prove the effectiveness and superiority of proposed method.