• Title/Summary/Keyword: non-halogen

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Evaluation of physical properties and non-flammability of Nylon6 using melamine-based halogen-free flame retardant. (멜라민계 난연제를 이용한 Nylons 의 난연성 및 물리적 특성 평가)

  • Kim Dong-Hak;Ryu Kwan-Suk
    • Proceedings of the KAIS Fall Conference
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    • 2004.11a
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    • pp.296-298
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    • 2004
  • 본 연구에서는 압출성형에서 Nylon6 를 기재로 멜라민계 난연제를 사용하여 난연성 및 물성평가를 비교, 분석하였다. 멜라민계 난연제를 선택한 이유는 탈할로겐화 추세에 일조를 하며 연기가 적고, 생분해를 하는 물질이기 때문에 큰 장점이 있다. 또한 새로운 제품 및 적용범위를 발굴하기가 상대적으로 용이하다는 장점이 있기 때문에 멜라민계 난연제를 선택하였다. 난연 Test는 UL-94 측정방법을 이용하였고 물성평가는 UTM 측정기기로 인장강도, 연신율, 굴곡강도, 굴곡탄성율 측정하였다. 또 충격강도 시험기로 충격강도를 측정하였고, 물성평가 경우에는 난연제로 인한 물성저하를 최소화 하기위해 Nano-clay 를 첨가하여 비교하였다. 연구결과는 난연 Test 경우 난연제의 함량이 $5wt\%$ 이상이면 V0급으로 나왔고 물성평가에서는 Nanoclay를 첨가한 실험이 물성저하를 대처할 수 있을 정도의 결과로 보여 진다.

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The Study of Infrared Thermography of a Mild Steel for Nondestructive Evaluation (적외선 카메라에 의한 연강의 비파괴 평가에 대한 연구)

  • Han, Jeong-Seb;Park, Jin-Hwan
    • Journal of Ocean Engineering and Technology
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    • v.22 no.2
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    • pp.72-77
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    • 2008
  • The application of infrared thermography for detecting defects under the surface of a material was studied. Defects in a specimen were made by back-drilled circular holes. To get alarge temperature difference at the surface, a halogen lamp was used for surface heating. We confirmed that the defect location had a good relationship with the maximum temperature difference. The sizes of the defects could be calculated by means of the FWHM. The value of the FWHM of a temperature difference decreased with time. Therefore in an extremely short time after the heating, the true defect size could be measured.

Noninvasive blood glucose monitoring system based on NIR spectroscopy with a contact pressure control device

  • Kang, Na-Roo;Baek, Ju-Hyun;Woo, Young-Ah;Kim, Hyo-Jin
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.67.3-68
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    • 2003
  • The purpose of this study is to improve repeatability of a non-invasive blood glucose measurement. The portable NIR system that was newly integrated by our lab includes a tungsten halogen lamp, a specialized reflectance fiber optic probe and a photo diode array type InGaAs detector, which was developed by a microchip technology based on the lithography. Reflectance NIR spectra of finger tip were recorded by using a fiber optic probe. The probe was fixed in the system and subjects put their finger on the probe head. (omitted)

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Fast Defect Detection of PCB using Ultrasound Thermography (초음파 서모그라피를 이용한 빠른 PCB 결함 검출)

  • Cho, Jai-Wan;Jung, Hyun-Kyu;Seo, Yong-Chil;Jung, Seung-Ho;Kim, Seung-Ho
    • Proceedings of the KIEE Conference
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    • 2005.10b
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    • pp.273-275
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    • 2005
  • Active thermography is being used since several years for remote non-destructive testing. It provides thermal images for remote detection and imaging of damages. Also, it is based on propagation and reflection of thermal waves which are launched from the surface into the inspected component by absorption of modulated radiation. For energy deposition, it use external heat sources (e.g., halogen lamp or convective heating) or internal heat generation (e.g., microwaves, eddy current, or elastic wave). Among the external heat sources, the ultrasound is generally used for energy deposition because of defect selective heating up. The heat source generating a thermal wave is provided by the defect itself due to the attenuation of amplitude modulated ultrasound. A defect causes locally enhanced losses and consequently selective heating up. Therefore amplitude modulation of the injected ultrasonic wave turns a defect into a thermal wave transmitter whose signal is detected at the surface by thermal infrared camera. This way ultrasound thermography(UT) allows for selective defect detection which enhances the probability of defect detection in the presence of complicated intact structures. In this paper the applicability of UT for fast defect detection is described. Examples are presented showing the detection of defects in PCB material. Measurements were performed on various kinds of typical defects in PCB materials (both Cu metal and non-metal epoxy). The obtained thermal image reveals area of defect in row of thick epoxy material and PCB.

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Study on the Smoke Density Characteristics of Flame Retardant Sol Manufactured by a Sol-gel Method (졸-겔법으로 제조된 방염제졸의 연기밀도 특성에 관한 연구)

  • Cho, Kyeong-Rae;Lee, Chun-Ha;Kim, Si-Kuk
    • Fire Science and Engineering
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    • v.31 no.3
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    • pp.11-18
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    • 2017
  • In this study, a non-halogen type organic-inorganic hybrid flame retardant sol, which can impart flame resistance to synthesize silicate of inorganic material and silane coupling agent of organic material by a sol-gel method, were newly manufactured. The addition of flame retardant will prevent loss of life in a fire because smoke from the flammability of interior finishing materials used as the construction materials poses a major danger. The smoke density measurement standard based on flame retardant performance standards, experiments were conducted according to the test equipment and procedures of ASTM E 662. The non-flaming mode experiment and the flaming mode experiment were conducted to confirm the performance of the manufactured flame retardant sol. As a result, the manufactured flame retardant sol improved the physical properties and heat resistance of existing flame retardants, and decreased the smoke production of the fire. Therefore, it may be possible to reduce the damage caused by smoke and expand the applications to various interior finishing materials.

Synthesis of Cyclotriphosphazene Derivatives for Flame Retardants (Cyclotriphosphazene을 이용한 난연제의 합성)

  • Kim, Hae Young;Shin, Young Jae;Ji, Young Jon;Shin, Jae Sup
    • Applied Chemistry for Engineering
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    • v.17 no.2
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    • pp.144-149
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    • 2006
  • Non-halogen flame retardants have been the focus of extensive research because of environmental problems. Hexakisp-henoxycyclotriphosphazene was synthesized in order to use as the flame retardant of ABS resin. And using bisphenol A, the polymers containing a cyclotriphosphazene structure were synthesized in order to also use as the flame retardant of ABS resin. All of the synthesized polymers themselves had the excellent flame retardancy. And as their molecular weight and crosslinking density were increased, the thermal stability was increased. But when the synthesized compounds were used as the flame retardant for ABS resin, the lower molecular weight compound in these compounds showed the better flame retardancy and the better physical properties of ABS resin.

Design and Fabrication of an NIR Grism Si Optical Area Sensor Spectrometer with In-band Reference Wavelength (대역 내 기준 파장을 갖는 근적외선 그리즘 실리콘 광 면 센서 분광기 설계 및 제작)

  • Song, Jae-Won
    • Journal of Sensor Science and Technology
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    • v.26 no.1
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    • pp.28-34
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    • 2017
  • An NIR grism Si optical area sensor spectrometer with in-band reference wavelength is designed and fabricated. It is composed of a transmission type diffraction grating (spatial density 300 line/mm), a rectangular N-BK7 prism (apex angle 30 degree), NIR filter(cutoff wavelength 720 nm), an imaging convex lens(focal length 50 mm F1.8) and an IR modified DSLR camera (Canon EOS40D) of Si optical area sensor ($3,888{\times}2,592$ pixels, pixel size $5.710{\mu}m$). "In-band reference wavelength function" is implemented using non-dispersive 0th diffraction order optical beam. The NIR grism spectrometer is tested in a laboratory using a halogen lamp and a Neon lamp. And the spectrometer is used in an astronomy field for obtaining the planet Jupiter NIR spectrum. In-band reference wavelength i.e. un-deviation wavelength is 846 nm, an wavelength resolution is 0.3027 nm/pixel, an wavelength resolving power is 2,794 and an wavelength range is 650~1,000 nm.

Preparation and Characterization of Polyurethane Flame Retardant Coatings Using Trichloro Lactone Modified Polyesters/IPDI-Isocyanurate (트리클로로 락톤 변성폴리에스테르/IPDI-Isocyanurate를 사용한 폴리우레탄 난연도료의 제조 및 특성)

  • Park, Hong-Soo;Jo, Hye-Jin;Shim, Il-Woo;Yang, In-Mo;Kim, Seung-Jin
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.3
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    • pp.252-263
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    • 2006
  • It is attempted to develop flame retardant polyurethane coatings, which have received significant attention in recent years. It is the purpose of this study to synthesize new reactive polyurethane coatings containing halogen. Lactone based modified polyester polyols, using trichlorobenzoic acid as chlorine moiety (TBAOs) were synthesized. These polyesters were cured with isophorone diisocyanate (IPDI)-isocyanurate at room temperature (TBAPUs). Physical properties of these flame retardant coatings were similar with those of non-flame retardant coatings. The flammability of coatings was strongly dependent on the chlorine contents. We found that the increasing chlorine contents showed better flame retarding properties and that, however, they also resulted in more smog generation during combustion. The detailed results of flammability test using various methods indicated $24{\sim}26%$ in LOI and $3.7{\sim}5.3\;cm$ char length in $45^{\circ}$ Meckel burner method.

Flame Retardants Containing Cyclophosphazene Ring for ABS (Cyclophosphazene 고리를 갖는 ABS용 난연제)

  • Shin, Young-Jae;Shin, Youn-Rok;Park, Soo-Jin;Shin, Jae-Sup
    • Polymer(Korea)
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    • v.31 no.4
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    • pp.273-277
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    • 2007
  • Cyclophosphazene derivatives were synthesized in order to use as a non-halogen flame retardant for ABS. Chlorocyclophosphazene was reacted with phenol, catechol, aniline, 1,2-diaminobenzene respectively, and each product was characterized by UL94 and LOI test for ABS resin. The physical properties of the sample containing these flame retardants were also characterized. The derivative synthesized from catechol showed best flame retardancy, and the derivative from phenol exhibited the flame retardancy in which the synergic effect was shown with novolac.

Feasibility Study on Detection of Crack in Bovine Incisor Using Active Thermography (보빈 치아 균열의 적외선 열화상 검사 가능성에 관한 실험적 연구)

  • Kim, Woo-Jae;Yang, Seung-Yong;Kim, No-Hyu
    • Journal of the Korean Society for Nondestructive Testing
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    • v.31 no.5
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    • pp.508-515
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    • 2011
  • Bovine incisor was investigated using active infrared thermography(IRT) to visualize crack on bovine teeth. An artificial crack was carefully created in bovine incisor sample by compression load of universal tensile machine. While applying a sinusoidal heat wave to the cracked bovine incisor through halogen lamp, consecutive digital infrared images was captured from the sample surface at a frequency synchronized with heat excitation. Phase information of thermal image was calculated by four-point correlation method and processed to produce the phase image of bovine incisor. This phase image showed clearly the crack on the incisor, which was hardly detected in traditional passive thermography.