• Title/Summary/Keyword: non-ferrous metal

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Automated scrap-sorting research using a line-scan camera system (라인스캔 카메라 시스템을 이용(利用)한 스크랩 자동선별(自動選別) 연구(硏究))

  • Kim, Chan-Wook;Kim, Hang-Goo
    • Resources Recycling
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    • v.17 no.6
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    • pp.43-49
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    • 2008
  • In this study, a scrap sorting system using a color recognition method has been developed to automatically sort out specified materials from a mixture, and its application as been examined in the separation of Cu and other non-ferrous metal parts from a mixture of iron scraps. The system is composed of three parts; measuring, conveying and ejecting parts. The color of scrap surface is recognized by the measuring part consisting of a line-scan camera, light sources and a frame grabber. The recognition is program-controlled by a image processing algorithms, and thus only the scrap part of designated color is separated by the use of air nozzles. In addition, the light system is designed to meet a high speed of sorting process with a frequency-variable inverter and the air nozzled ejectors are to be operated by an I/O interface communication with a hardware controller. In the functional tests of the system, its efficiency in the recognition of Cu scraps from its mixture with Fe ones reaches to more than 90%, and that in the separation more than 80% at a conveying speed of 25 m/min. Therefore, it is expected that the system can be commercialized in the industry of shredder makers if a high efficiency ejecting system is realized.

Estimation of Quantitative Source Contribution of Ambient PM-10 Using the PMF Model (PMF모델을 이용한 대기 중 PM-10 오염원의 정량적 기여도 추정)

  • 황인조;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.6
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    • pp.719-731
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    • 2003
  • In order to maintain and manage ambient air quality, it is necessary to identify sources and to apportion its sources for ambient particulate matters. The receptor methods were one of the statistical methods to achieve reasonable air pollution strategies. Also, receptor methods, a field of chemometrics, is based on manifold applied statistics and is a statistical methodology that analyzes the physicochemical properties of gaseous and particulate pollutant on various atmospheric receptors, identifies the sources of air pollutants, and quantifies the apportionment of the sources to the receptors. The objective of this study was 1) after obtaining results from the PMF modeling, the existing sources of air at the study area were qualitatively identified and the contributions of each source were quantitatively estimated as well. 2) finally efficient air pollution management and control strategies of each source were suggested. The PMF model was intensively applied to estimate the quantitative contribution of air pollution sources based on the chemical information (128 samples and 25 chemical species). Through a case study of the PMF modeling for the PM-10 aerosols, the total of 11 factors were determined. The multiple linear regression analysis between the observed PM-10 mass concentration and the estimated G matrix had been performed following the FPEAK test. Finally the regression analysis provided quantitative source contributions (scaled G matrix) and source profiles (scaled F matrix). The results of the PMF modeling showed that the sources were apportioned by secondary aerosol related source 28.8 %, soil related source 16.8%, waste incineration source 11.5%, field burning source 11.0%, fossil fuel combustion source 10%, industry related source 8.3%, motor vehicle source 7.9%, oil/coal combustion source 4.4%, non-ferrous metal source 0.3%. and aged sea- salt source 0.2%, respectively.

Source Identification of Ambient PM-10 Using the PMF Model (PMF 모델을 이용한 대기 중 PM-10 오염원의 확인)

  • 황인조;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.6
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    • pp.701-717
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    • 2003
  • The objective of this study was to extensively estimate the air quality trends of the study area by surveying con-centration trends in months or seasons, after analyzing the mass concentration of PM-10 samples and the inorganic lements, ion, and total carbon in PM-10. Also, the study introduced to apply the PMF (Positive Matrix Factoriza-tion) model that is useful when absence of the source profile. Thus the model was thought to be suitable in Korea that often has few information about pollution sources. After obtaining results from the PMF modeling, the existing sources at the study area were qualitatively identified The PM-10 particles collected on quartz fiber filters by a PM-10 high-vol air sampler for 3 years (Mar. 1999∼Dec.2001) in Kyung Hee University. The 25 chemical species (Al, Mn, Ti, V, Cr, Fe, Ni, Cu, Zn, As, Se, Cd, Ba, Ce, Pb, Si, N $a^{#}$, N $H_4$$^{+}$, $K^{+}$, $Mg^{2+}$, $Ca^{2+}$, C $l^{[-10]}$ , N $O_3$$^{[-10]}$ , S $O_4$$^{2-}$, TC) were analyzed by ICP-AES, IC, and EA after executing proper pre - treatments of each sample filter. The PMF model was intensively applied to estimate the quantitative contribution of air pollution sources based on the chemical information (128 samples and 25 chemical species). Through a case study of the PMF modeling for the PM-10 aerosols. the total of 11 factors were determined. The multiple linear regression analysis between the observed PM-10 mass concentration and the estimated G matrix had been performed following the FPEAK test. Finally the regression analysis provided source profiles (scaled F matrix). So, 11 sources were qualitatively identified, such as secondary aerosol related source, soil related source, waste incineration source, field burning source, fossil fuel combustion source, industry related source, motor vehicle source, oil/coal combustion source, non-ferrous metal source, and aged sea- salt source, respectively.ively.y.

Microstructure and Mechanical Properties of β-SiAlON Ceramics Fabricated Using Self-Propagating High-Temperature Synthesized β-SiAlON Powder

  • Kim, Min-Sung;Go, Shin-Il;Kim, Jin-Myung;Park, Young-Jo;Kim, Ha-Neul;Ko, Jae-Woong;Yun, Jon-Do
    • Journal of the Korean Ceramic Society
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    • v.54 no.4
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    • pp.292-297
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    • 2017
  • ${\beta}-SiAlON$, based on its high fracture toughness, good strength and low abrasion resistance, has been adopted in several industrial fields such as bearings, turbine blades and non-ferrous metal refractories. In general, ${\beta}-SiAlON$ is fabricated by reactive sintering using expensive $Si_3N_4$ and AlN as starting materials. On the other hand, in this study, a cheaper ${\beta}-SiAlON$ starting powder synthesized by SHS was employed to improve price competitiveness compared to that of the reactive sintering process. ${\beta}-SiAlON$ ceramics with various content of the sintering additive $Y_2O_3$ up to 7 wt% were fabricated by conventional pressureless sintering at $1800^{\circ}C$ for 2 to 8 h under $N_2$ pressure of 0.1 MPa. The specimen with 3 wt% $Y_2O_3$ exhibited the best mechanical properties: hardness of 14 GPa, biaxial strength of 830 MPa, fracture toughness of $5MPa{\cdot}m^{1/2}$ and wear rate of about $3{\times}10^{-6}mm^3/N{\cdot}m$.

Electrochemical properties of dimensionally stable anodes materials for hydrometallurgy of Non-ferrous metal application (비철금속 제련용 DSA 재료의 전기화학적 특성)

  • Kim, Hyun-Sik;Lee, Hae-Yon;Huh, Jeoung-Sub;Kim, Bong-Seo;Lee, Dong-Yoon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.313-316
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    • 2002
  • 비철금속 습식 제련용 고효율 장수명의 양극을 개발하기 위해서 산소 과전압이 낮은 $MnO_{2}$를 촉매로 사용하여 반도체 산화물계의 산소선택성 전극을 제조하고 산화물 coating층의 미세구조와 전기화학적 특성을 분석하였다. PVDF : $MnO_{2}$의 함량비플 1 : 1 에서 1 : 40까지 정량적으로 변화시켰고, 용제의 점도에 지배적인 영향을 미치는 DMF의 함량을 각각의 고정된 PVDF : $MnO_{2}$의 함량비에서 변화시켜 용제를 제조하였으며 4% $HNO_{3}$ 용액에 세척된 Pb전극을 1.5 mm/sec 의 속도로 5회 dipping 하였다. PVDF : $MnO_{2}$ = 1 : 6인 경우 PVDF의 양이 증가하고 DMF의 양이 감소할수록 피막층이 두꺼워지고 PVDF : DMF = 4 : 96인 경우 pb 전극의 피막층이 얇기 때문에 박리현상이 일어났으며 이는 산화물 용제의 낮은 점도 때문인 것으로 판단된다. 또한 PVDF : DMF = 10 : 90의 경우는 5회 dipping 하여 약 $150{\mu}m$의 피막층을 형성하였다. PVDF : Mn02의 함량비가 1:1에서 1:6 까지는 DMF의 함량에 무관하게 전극 특성이 나타나지 않았지만 $MnO_{2}$의 양이 상대적으로 증가하면 cycle 이 증가하더라도 거의 일정한 전류 값을 갖고$MnO_2$와 PVDF의 비가 20:1 이상의 조성에서는 균일한 CV 특성을 나타냈다 이는 $MnO_{2}$가 효과적으로 촉매 작용을 한 것으로 판단되며 anodic polarization에 의한 산소 발생 과전압도 약 1.4V 정도로 감소되었다.

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Machine Vision Applications in Automated Scrap-separating Research (머신비젼 시스템을 이용(利用)한 스크랩 자동선별(自動選別) 연구(硏究))

  • Kim, Chan-Wook;Kim, Hang-Goo
    • Resources Recycling
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    • v.15 no.6 s.74
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    • pp.3-9
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    • 2006
  • In this study, a machine vision system using a color recognition method has been designed and developed to automatically sort out specified materials from a mixture, especially Cu and other non-ferrous metal scraps from a mixture of iron scraps. The system consists of a CCD camera, light sources, a frame grabber, conveying devices and an air-nozzle ejector, and is program-controlled by a image processing algorithms. The ejectors designed to be operated by an I/O interface communication with a hardware controller. In the functional tests of the system, its efficiency in the separation of Cu scraps from its mixture with Fe ones reaches to 90% or more at a conveying speed of 15m/min, and thus the system is proven to be excellent in terms of the separating efficiency. Therefore, it is expected that the system can be commercialized in the industry of shredder makers if an automated sorting system of high speed is realized.

Estimation of Mercury Emission from Major Sources in Annex D of Minamata Convention and Future Trend (국내 비의도적 주요 배출원의 지역별 수은 대기 배출량 산정 및 미래 활동도 변화와 최적가용기술 적용 시 배출량 추이)

  • Sung, Jin-Ho;Oh, Joo-Sung;Back, Seung-Ki;Jeong, Bup-Mook;Jang, Ha-Na;Seo, Yong-Chil;Kim, Seong-Heon
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.2
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    • pp.193-207
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    • 2016
  • This study discusses the present status of mercury emission and distribution from major anthropogenic sources in Korea and the future trend of mercury emission by activity changes and application of BATs. Atmospheric mercury emission from major anthropogenic sources based on Annex D of Minamata convention was estimated to around 4.89 tonne in 2012. Emission ratios of cement clinker production, coal-fired power plant, waste incineration and non-ferrous metal smelting were 68.68%, 24.75%, 6.29% and 0.28%, respectively. High mercury emission regions were characterized by the presence of cement clinker production facilities and coal-fired power plants. Prediction of future activities was carried out by linear regression of the previous year data. The (total) mercury emission was estimated to decrease up to 48% Under the scenario of BATs to be applied and the change of future activities. Emissions from coal-fired powerplants and cement clinkers were expected to decrease significantly.

The Effect of Grain Refinement on Fluidity of Al-4.8%CU-0.6%Mn Alloy (입자미세화가 Al-4.8%Cu-0.6%Mn 합금의 유동도에 미치는 영향)

  • Kwon, Young-Dong;Lee, Zin-Hyoung;Kim, Kyoung-Hyun
    • Journal of Korea Foundry Society
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    • v.22 no.3
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    • pp.109-113
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    • 2002
  • A good fluidity of high strength Al-alloys is required to cast thin wall castings needed to reduce the weight of cast parts. The fluidity, measured as the length to which the metal flows in a standard channel, is affected by many factors, such as the pouring temperature, solidification type of the alloy, the channel thickness, melt head, mold materials and temperature, coating etc. Therefore the experimentally measured fluidity scatters very much and makes it difficult to estimate the fluidity of a melt with a few measurements. The effect of Ti content and grain refinement on the fluidity of high strength aluminum alloy was investigated with a test casting with 8 thin flow channels to reduce the scattering of the fluidity results. The fluidity of Al-4.8%Cu-0.6%Mn Al-6.2%Zn-1.6%Mg-1.0%Cu and well-known commercial aluminum alloy, A356 was tested. Initial content of Ti was varied from 0 to 0.2wt% and Al-5Ti-B master alloy was added for grain refinement. The flow length varied linearly with superheat. By adding Ti and Al-5Ti-B, the fluidity increased. The grain size decreased by adding grain refiner at the same time. The fluidity depended on the degree of grain refinement. The fluidity of the alloy solidifying in mushy type is improved by grain refinement, because grain refinement increases the solid fraction at the time of flow stoppage.

Machine vision applications in automated scrap-separating research (머신비젼 시스템을 이용(利用)한 스크랩 자동선별(自動選別) 연구(硏究))

  • Kim, Chan-Wook;Lee, Seung-Hyun;Kim, Hang-gu
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2005.05a
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    • pp.57-61
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    • 2005
  • In this study, the machine vision system for inspection using color recognition method have been designed and developed to automatically sort out a specified material such as Cu scraps or other non-ferrous metal scraps mixed in Fe scraps. The system consists of a CCD camera, light sources, a frame grabber, conveying devices and an air nozzled ejector, and is program-controlled by a image processing algorithm. The ejector is designed to be operated by an I/O interface communication with a hardware controller. The sorting examination results show that the efficiency of separating Cu scraps from the Fe scraps mixed with Cu scraps is around 90 % at the conveying speed of 15 m/min. and the system is proven to be excellent in terms of its efficiency. Therefore, it is expected that the system can be commercialized in shredder firms, if the high-speed automated sorting system will be realized.

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Cyclic voltammetry characteristics of $MnO_2$ electrode mixed with PVDF in sulfuric acid solution (PVDF로 혼합된 $MnO_2$ 전극의 황산 수용액중의 cyclic voltammetry 특성)

  • Kim, Bong-Seo;Lee, Dong-Yoon;Lee, Hee-Woong;Kim, Hyun-Sik;Lee, Hae-Yon;Chung, Won-Sub
    • Proceedings of the KIEE Conference
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    • 2002.11a
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    • pp.82-84
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    • 2002
  • Dimensionally stable anode(DSA) can be used for the electrowinning of non-ferrous metal like as a Zn, and electrolysis of sea water. $MnO_2$ electrode satisfies the requirements of DSA, and has a good cycle life and a low overpotential for oxygen evolution. $MnO_2$ electrodes coated with DMF and PVDF based on Pb alloy produced at several compositions and dry temperatures. The viscosity of solvent used as a binder of $MnO_2$ powder increased with the increasing PVDF contents. When the ratio of PVDF to BMF with the 5 times dipping at the solution mixed with PVDF and DMF was 1/9, the coating thickness was $150{\mu}m$. When the ratio of PVDF to $MnO_2$ was lower than 1/6, the electrode didn't show any reaction irrespective of the concentrations of DMF. However, When the ratio of PVDF to $MnO_2$ was higher than 1/6, the electrode showed a constant current reactions and homogeneous cyclic voltammetry even though at a high cycle. The reason for the high current and homogeneous cyclic voltammetry is the good catalytic reactions of $MnO_2$ powder in electrode. The reactions of Pb electrode coated with $MnO_2$ and PVDF based on the pure Pb electrode.

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