• 한국화재소방학회논문지
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• 제14권2호
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• pp.33-38
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• 2000

전자산업의 공정에서 PCB기판납땜은 괼수적이며 이에 사용하는 Flux내 용제인 IPA(Iso--propyl alcohol)와 메탄올은 인화성과 폭발성이 강한 물질로 화재위험성이 대단히 높다. 또한 메탄올은 유독성물질로 지정되어 있으며, 환경법상 VOC(Volatile Organic Compound : 휘발성유기화합물)규제물질로 지정되어 있어 대체물질 개발이 절실히 요구된다. 이에 기존 Flux특성을 가지고 있으면서 화재위험성은 없고, 휘발성유기화합물 규제물질에는 해당되지 않는 디클로로프로판(Dichloropropane, DCP)를 주성분으로 하여 Flux 특성에 맞는 안정제 및 첨가제를 적정 조성비로 조합하여 용제를 개발하였다. 그 결과 200ppm의 작업환경허용농도를 470 ppm으로 완화시킬 수 있었으며 납땜불량율은 0.083%에서 0%로, 퍼짐성은 85%에서 87%로, 전연저항은 1.0$\times$$10^{12}$$\Omega$에서 6.9$\times$$10^{12}$/$\Omega$으로 기존 Flux보다 우수하였다. 그러므로 Flux의 안정성은 물론 환경안전측면과 품질, 생산성도 향상이 가능함을 확인하였고, 품질 특성시험 및 제품 신뢰성 시험 결과 만족할 만한 곁과를 얻었다.

• 한국추진공학회지
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• 제21권5호
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• pp.10-18
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• 2017

알루미늄 입자들이 함유된 고폭약의 비정상 데토네이션 전파속도에 대하여 수치 해석을 수행하였다. 알루미늄 입자의 점화와 연소는 고폭약에 비해 상대적으로 긴 시간이 요구되기 때문에, 알루미늄 입자연소에 의한 에너지 발산은 고폭약의 데토네이션 후방에서 이루어진다. 이러한 비정상 데토네이션에 대한 수치해석은 기체상과 균일하게 분포된 고체 입자와의 질량, 운동량, 에너지 교환을 다루는 이종매질 이론을 이용한다. 알루미늄 입자가 함유된 고폭약의 데토네이션 전파에 대한 수치 해석은 폭약 HMX에 대하여 수행되었으며, 5~25%의 알루미늄 함량과 0.5, 7, $15{\mu}m$의 알루미늄 입자크기에 대한 수치 해석 결과와 실험 결과를 비교하여 검증하였다.

• 대한안전경영과학회지
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• 제16권2호
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• pp.43-52
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• 2014

In weapon systems development, live fire tests have been frequently adopted to evaluate the performance of the systems under development. Therefore, it is necessary to ensure safety in the test ranges where the live fire tests can cause serious hazards. During the tests, a special care must be taken to protect the test and evaluation (T&E) personnel and also test assets from potential danger and hazards. Thus, the development and management of the range safety process is quite important in the tests of guided missiles and artillery considering the explosive power of the destruction. Note also that with a newly evolving era of weapon systems such as laser, EMP and non-lethal weapons, the test procedure for such systems is very complex. Therefore, keeping the safety level in the test ranges is getting more difficult due to the increased unpredictability for unknown hazards. The objective of this paper is to study on how to enhance the safety in the test ranges. To do so, an approach is proposed based on model-based systems engineering (MBSE). Specifically, a functional architecture is derived utilizing the MBSE method for the design of the range safety process under the condition that the derived architecture must satisfy both the complex test situation and the safety requirements. The architecture developed in the paper has also been investigated by simulation using a computer-aided systems engineering tool. The systematic application of this study in weapon live tests is expected to reduce unexpected hazards and test design time. Our approach is intended to be a trial to get closer to the recent theme in T&E community, "Testing at the speed of stakeholder's need and rapid requirement for rapid acquisition."

• 한국수소및신에너지학회논문집
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• 제34권6호
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• pp.734-740
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• 2023

Hydrogen emphasis on safety management due to its high potential for accidents from wide explosive limits and low ignition energy. To prevent accidents, appropriate explosion-proof electrical equipment with installed to safe management of ignition sources. However, designing all facilities with explosion-proof structures can significantly increase costs and impose limitations. In this study, we optimize the barrier to effectively control the initial momentum in case of hydrogen release and form the control room as a non-hazardous area. We employed response surface method (RSM), the barrier distance, width and height of the barrier were set as variables. The Box-Behnken design method the selection of 15 cases, and FLACS assessed the presence of hazardous area. Analysis of variance (ANOVA) analysis resulting in an optimized barrier area. Through this methodology, the workplace can optimize the barrier according to the actual workplace conditions and classify reasonable hazardous area, which is believed to secure safety in hydrogen facilities and minimize economic burden.

• 한국융합학회논문지
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• 제12권7호
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• pp.45-51
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• 2021

급속한 비대면 환경과 모바일 우선 전략에 따라 해마다 많은 정형/비정형 데이터의 폭발적인 증가와 생성은 모든 분야에서 빅데이터를 활용한 새로운 의사 결정과 서비스를 요구하고 있다. 그러나 매년 급속히 증가하는 빅데이터를 활용하여 실무 환경에서 적용 가능한 표준 플랫폼으로 빅데이터를 수집하여 적재한 후, 정재한 빅데이터를 관계형 데이터베이스에 저장하고 처리하는 하둡 에코시스템 활용의 참조 사례들은 거의 없었다. 따라서 본 연구에서는 스프링 프레임워크 환경에서 3대의 가상 머신 서버를 통하여 하둡 2.0을 기반으로 쇼셜 네트워크 서비스에서 키워드로 검색한 비정형 데이터를 수집한 후, 수집된 비정형 데이터를 하둡 분산 파일 시스템과 HBase에 적재하고, 적재된 비정형 데이터를 기반으로 형태소 분석기를 이용하여 정형화된 빅데이터를 관계형 데이터베이스에 저장할 수 있게 설계하고 구현하였다. 향후에는 데이터 심화 분석을 위한 하이브나 머하웃을 이용하여 머신 러닝을 이용한 클러스터링과 분류 및 분석 작업 연구가 지속되어야 할 것이다.

• 한국재료학회지
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• 제22권5호
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• pp.253-258
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• 2012

Activated magnetite ($Fe_3O_{4-{\delta}}$) was applied to reducing $CO_2$ gas emissions to avoid greenhouse effects. Wet and dry methods were developed as a $CO_2$ removal process. One of the typical dry methods is $CO_2$ decomposition using activated magnetite ($Fe_3O_{4-{\delta}}$). Generally, $Fe_3O_{4-{\delta}}$ is manufactured by reduction of $Fe_3O_4$ by $H_2$ gas. This process has an explosion risk. Therefore, a non-explosive process to make $Fe_3O_{4-{\delta}}$ was studied using $FeC_2O_4{\cdot}2H_2O$ and $N_2$. $FeSO_4{\cdot}7H_2O$ and $(NH_4)_2C_2O_4{\cdot}H_2O$ were used as starting materials. So, ${\alpha}-FeC_2O_4{\cdot}2H_2O$ was synthesized by precipitation method. During the calcination process, $FeC_2O_4{\cdot}2H_2O$ was decomposed to $Fe_3O_4$, CO, and $CO_2$. The specific surface area of the activated magnetite varied with the calcination temperature from 15.43 $m^2/g$ to 9.32 $m^2/g$. The densities of $FeC_2O_4{\cdot}2H_2O$ and $Fe_3O_4$ were 2.28 g/$cm^3$ and 5.2 g/$cm^3$, respectively. Also, the $Fe_3O_4$ was reduced to $Fe_3O_{4-{\delta}}$ by CO. From the TGA results in air of the specimen that was calcined at $450^{\circ}C$ for three hours in $N_2$ atmosphere, the ${\delta}$-value of $Fe_3O_{4-{\delta}}$ was estimated. The ${\delta}$-value of $Fe_3O_{4-{\delta}}$ was 0.3170 when the sample was heat treated at $400^{\circ}C$ for 3 hours and 0.6583 when the sample was heat treated at $450^{\circ}C$ for 3 hours. $Fe_3O_{4-{\delta}}$ was oxidized to $Fe_3O_4$ when $Fe_3O_{4-{\delta}}$ was reacted with $CO_2$ because $CO_2$ is decomposed to C and $O_2$.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2012년도 춘계학술발표대회
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• pp.65-65
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• 2012

Copper zinc tin sulfide ($Cu_2ZnSnS_4$, CZTS) is a very promising material as a low cost absorber alternative to other chalcopyrite-type semiconductors based on Ga or In because of the abundant and economical elements. In addition, CZTS has a band-gap energy of 1.4~1.5eV and large absorption coefficient over ${\sim}10^4cm^{-1}$, which is similar to those of $Cu(In,Ga)Se_2$(CIGS) regarded as one of the most successful absorber materials for high efficient solar cell. Most previous works on the fabrication of CZTS thin films were based on the vacuum deposition such as thermal evaporation and RF magnetron sputtering. Although the vacuum deposition has been widely adopted, it is quite expensive and complicated. In this regard, the solution processes such as sol-gel method, nanocrystal dispersion and hybrid slurry method have been developed for easy and cost-effective fabrication of CZTS film. Among these methods, the hybrid slurry method is favorable to make high crystalline and dense absorber layer. However, this method has the demerit using the toxic and explosive hydrazine solvent, which has severe limitation for common use. With these considerations, it is highly desirable to develop a robust, easily scalable and relatively safe solution-based process for the fabrication of a high quality CZTS absorber layer. Here, we demonstrate the fabrication of a high quality CZTS absorber layer with a thickness of 1.5~2.0 ${\mu}m$ and micrometer-scaled grains using two different non-vacuum approaches. The first solution-processing approach includes air-stable non-toxic solvent-based inks in which the commercially available precursor nanoparticles are dispersed in ethanol. Our readily achievable air-stable precursor ink, without the involvement of complex particle synthesis, high toxic solvents, or organic additives, facilitates a convenient method to fabricate a high quality CZTS absorber layer with uniform surface composition and across the film depth when annealed at $530^{\circ}C$. The conversion efficiency and fill factor for the non-toxic ink based solar cells are 5.14% and 52.8%, respectively. The other method is based on the nanocrystal dispersions that are a key ingredient in the deposition of thermally annealed absorber layers. We report a facile synthetic method to produce phase-pure CZTS nanocrystals capped with less toxic and more easily removable ligands. The resulting CZTS nanoparticle dispersion enables us to fabricate uniform, crack-free absorber layer onto Mo-coated soda-lime glass at $500^{\circ}C$, which exhibits a robust and reproducible photovoltaic response. Our simple and less-toxic approach for the fabrication of CZTS layer, reported here, will be the first step in realizing the low-cost solution-processed CZTS solar cell with high efficiency.

• 한국재료학회지
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• 제22권11호
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• pp.620-625
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• 2012

A general synthetic method to make $Fe_3O_{4-{\delta}}$ (activated magnetite) is the reduction of $Fe_3O_4$ by $H_2$ atmosphere. However, this process has an explosion risk. Therefore, we studied the process of synthesis of $Fe_3O_{4-{\delta}}$ depending on heat-treatment conditions using $FeC_2O_4{\cdot}2H_2O$ in Ar atmosphere. The thermal decomposition characteristics of $FeC_2O_4{\cdot}2H_2O$ and the ${\delta}$-value of $Fe_3O_{4-{\delta}}$ were analyzed with TG/DTA in Ar atmosphere. ${\beta}-FeC_2O_4{\cdot}2H_2O$ was synthesized by precipitation method using $FeSO_4{\cdot}7H_2O$ and $(NH_4)_2C_2O_4{\cdot}H_2O$. The concentration of the solution was 0.1 M and the equivalent ratio was 1.0. ${\beta}-FeC_2O_4{\cdot}2H_2O$ was decomposed to $H_2O$ and $FeC_2O$4 from $150^{\circ}C$ to $200^{\circ}C$. $FeC_2O4$ was decomposed to CO, $CO_2$, and $Fe_3O_4$ from $200^{\circ}C$ to $250^{\circ}C$. Single phase $Fe_3O_4$ was formed by the decomposition of ${\beta}-FeC_2O_4{\cdot}2H_2O$ in Ar atmosphere. However, $Fe_3C$, Fe and $Fe_4N$ were formed as minor phases when ${\beta}-FeC_2O_4{\cdot}2H_2O$ was decomposed in $N_2$ atmosphere. Then, $Fe_3O_4$ was reduced to $Fe_3O_{4-{\delta}}$ by decomposion of CO. The reduction of $Fe_3O_4$ to $Fe_3O_{4-{\delta}}$ progressed from $320^{\circ}C$ to $400^{\circ}C$; the reaction was exothermic. The degree of exothermal reaction was varied with heat treatment temperature, heating rate, Ar flow rate, and holding time. The ${\delta}$-value of $Fe_3O_{4-{\delta}}$ was greatly influenced by the heat treatment temperature and the heating rate. However, Ar flow rate and holding time had a minor effect on ${\delta}$-value.

• 항공우주시스템공학회지
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• 제15권5호
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• pp.81-88
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• 2021

일반적으로 큐브위성용 전개형 태양전지판을 수납 및 전개시키기 위해 사용되는 구속분리장치는 비폭발식 나일론선 절단방식이 적용된다. 그러나 상기 방식은 태양전지판 수납 상태에서 큐브위성의 배터리 충전, PCB 및 탑재체의 전기적 점검 및 시험 등을 위한 접근 포트 연결 시 분리장치의 구속해제 및 재채결 작업이 반복적으로 요구된다. 따라서, 기존의 구속분리장치는 위성체 내부 접근을 위해서는 작업자의 번거로움 및 일관된 나일론선 체결작업 공정 유지의 어려움이 존재한다. 본 연구에서는 나일론 선 절단 없이 구속 핀 분리만으로 자유롭게 태양전지판 전개 및 수납이 가능한 Pin-puller형 태양전지판 구속분리장치를 제안하였으며, 기능 및 성능검증을 위한 분리장치의 전개시험 및 최대 분리하중 측정 시험을 통해 분리장치 설계의 유효성을 입증하였다.

• 분석과학
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• 제22권5호
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• pp.386-394
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• 2009

폼알데히드는 피혁 제조나 사진 건판, 폭약 등을 만들 때 이용되며, 정수장에서 오존 처리시 생성되는 소독 부산물이기도 하다. 노출시 안구 가려움증, 간지러움, 콧물, 코막힘, 두통 등의 증상이 나타나며 목이 건조해지거나 염증이 유발된다. 폼알데히드는 US. EPA에서 호흡으로 흡입할 경우 발암등급 B1으로 분류하는 발암성 물질이다. 본 연구에서는 폼알데히드의 분석을 위해 2,4-dinitrophenylhydrazine (DNPH) 유도체를 만든 후, 고체상 카트리지를 사용하여 추출하였고 High Performance Liquid Chromatography/Diode Array Detector (HPLC/DAD) 로 분석하였다. 검출 한계는 $3{\mu}g/L$이고, 72.3~109.1% (상대표준편차 2.9~11.5%)의 회수율을 보였다. 1998년도부터 2007년도까지 4대강 수계를 중심으로 채수하여 분석한 결과, 정수에서 검출 빈도 48.8% (630/1291), $5.15{\sim}101.9{\mu}g/L$의 농도로 검출되었다. 먹는물 음용시 비발암성을 고려한 95 percentile 전국 평균 위험지수는 $4.37{\times}10^{-3}$로, 이는 1 이하였으므로 안전한 수준으로 판단하였다.