• 제목/요약/키워드: non-crystalline

검색결과 288건 처리시간 0.028초

Mg-Zn-Y 합금의 크리프 저항성에 미치는 칼슘의 영향 (Effect of calcium addition on creep properties in Mg-Zn-Y alloys)

  • 이윤희;임현규;김도형;김도향
    • 한국주조공학회지
    • /
    • 제27권5호
    • /
    • pp.198-202
    • /
    • 2007
  • In the present study, the high temperature mechanical properties and creep resistance of Mg-Zn-Y-Ca alloys has been investigated. The Mg-4Zn-0.8Y alloy consists of ${\alpha}$-Mg matrix and icosahedral quasicrystalline phase. Calcium addition into Mg-4n-0.8Y based alloy results in the formation of ${\tau}(Ca_{2}Mg_{6}Zn_{3})$ and $Mg_{2}Ca$ as the second solidification phases. Creep properties of the Mg-Zn-Y and Mg-Zn-Ca based alloys measured at applied stresses between 65 MPa and 85 MPa are significantly improved with adding calcium and yttrium, respectively. The improved creep resistance is due to the formation of thermally stable $Mg_{2}Ca$ phase.

나노 준결정상으로 강화된 Ti계 벌크 비정질기지 복합재의 제조 및 기계적 특성 고찰 (Fabrication and Mechanical Properties of Nanoquasicrystalline Phase Reinforced Ti-based Bulk Metallic Glass Matrix Composites)

  • 박진만;임가람;김태응;손성우;김도향
    • 한국주조공학회지
    • /
    • 제28권6호
    • /
    • pp.261-267
    • /
    • 2008
  • In-situ quasicrystalline icosahedral (I) phase reinforced Ti-based bulk metallic glass (BMG) matrix composites have been successfully fabricated by using two distinct thermal histories for BMG forming alloy. The BMG composite containing micron-scale Iphase has been introduced by controlling cooling rate during solidification, whereas nano-scale I-phase reinforced BMG composite has been produced by partial crystallization of BMG. For mechanical properties, micron-scale I-phase distributed BMG composite exhibited lower strength and plasticity compared to the monolithic BMG. On the other hand, nano-scale icosahedral phase embedded BMG composite showed enhanced strength and plasticity. These improved mechanical properties were attributed to the multiplication of shear bands and blocking of the shear band propagation in terms of isolation and homogeneous distribution of nanosize icosahdral phases in the glassy matrix, followed by stabilizing the mechanical and deformation instabilities.

액정성 고분자 블렌드의 편발광 (Polarized Light Emission of Liquid Crystalline Polymer Blends)

  • 김영철;조현남;김동영;홍재민;송남웅
    • 폴리머
    • /
    • 제24권2호
    • /
    • pp.211-219
    • /
    • 2000
  • 액정성을 가지는 플로렌계 발광고분자에 비버정성 플로렌계 발광고분자를 첨가한 블렌드를 제조하여 에너지전달 효과와 흡광 및 발광 이방성에 대하여 고찰하였다. 비액정성 고분자를 액정성 고분자에 0.5wt% 첨가하고 360nm로 여기한 결과, 420nm에서 관찰되었던 액정성 고분자의 발광피크는 거의 사라졌으며 대신 비액정성 고분자에 의한 480nm에서의 새로운 발광피크가 관찰되었다. 블렌드 시료의 480nm 발광은 비액정성 고분자가 2.0wt% 첨가되었을때 가장 강했으며, 발광강도는 블렌딩 이전의 각 고분자보다 13배 증자하였다. 블렌드내의 분자들을 마찰 폴리이미드 기판상에서 가열-냉각시켜 배향시키면 시료의 발광 이방성과 order parameter는 각각 2.0 및 0.25를 나타내었다. 시간 상관 단광자 계수법 (TCSPC)에 의해 고찰한 결과, 마찰 폴리이미드 기판상에서의 배향에 의해 두 발광고분자간의 에너지전달에 필요한 시간은 93 ps만큼 단축되며 에너지전달 효율은 9% 증가함을 알 수 있었다.

  • PDF

CCCC법에 의한 태양전지용 다결정 실리콘 잉고트의 제조 (Fabrication of poly-crystalline silicon ingot for solar cells by CCCC method)

  • 신제식;이동섭;이상목;문병문
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2005년도 춘계학술대회
    • /
    • pp.94-97
    • /
    • 2005
  • For the fabrication of poly-crystalline silicon ingot, CCCC (Cold Crucible Continuous Casting) method under a high frequency alternating magnetic field, was utilized in order to prevent crucible consumption and ingot contamination and to increase production rate. In order to effectively and continuously melt and cast silicon, which has a high radiation heat loss due to the high melting temperature and a low induction heating efficiency due to a low electric conductivity, Joule and pinch effects were optimized. Throughout the present investigation, poly-crystalline Si ingot was successfully produced at the casting speed of above 1.5 mm/min under a non-contact condition.

  • PDF

$CO_2$ 레이저 조사를 이용한 나노 입자의 크기, 형상과 결정상의 제어 (Control of Size, Morphology and Crystalline Phase of Nanoparticles Using $CO_2$ Laser Irradiation)

  • 이동근;최만수
    • 대한기계학회:학술대회논문집
    • /
    • 대한기계학회 2000년도 추계학술대회논문집B
    • /
    • pp.180-185
    • /
    • 2000
  • Nano crystalline or non-crystalline particles have been widely used in various industrial area, such as ceramics, catalysis, electronics, metallurgy and optic device. In all applications, synthesizing the particles as small as possible and controlling the crystalline phase according to its purpose are necessary for the enhancement of processing performance. In some cases, non-agglomerated particles may be necessary for solving the packing problems. This motivates our attempt of controlling size, morphology, phase of nano titania and silica particles. If one can enhance sintering rate of small aggregates independently of collision rate, one may expect that original aggregates can be changed into volume equivalent spheres and thereby the decrease of collision frequency due to the change leads to much smaller rate of growth of the particles. This is the basic idea of our control strategy.

  • PDF

Crystallization Behavior of Al-Ni-Y Amorphous Alloys

  • Na, Min Young;Kim, Kang Cheol;Kim, Won Tae;Kim, Do Hyang
    • Applied Microscopy
    • /
    • 제43권3호
    • /
    • pp.127-131
    • /
    • 2013
  • The crystallization behavior in the $Al_{87}Ni_3Y_{10}$ and $Al_{88}Ni_3Y_9$amorphous alloys has been investigated. As-quenched $Al_{87}Ni_3Y_{10}$ amorphous phase decomposes by simultaneous formation of Al and intermetallic phase at the first crystallization step, while as-quenched $Al_{88}Ni_3Y_9$ amorphous phase decomposes by forming Al nanocrystals in the amorphous matrix. The density of Al nanocrystals is extremely high and the size distribution is homogeneous. Such a microstructure can result from rapid explosion of the nucleation event in the amorphous matrix or growth of the preexisting nuclei embedded in the as-quenched amorphous matrix. The final equilibrium crystalline phases and their distribution at 873 K are exactly same in both $Al_{87}Ni_3Y_{10}$ and $Al_{88}Ni_3Y_9$ alloys.

긴장 및 무긴장 상태에서 열처리한 PP 필라멘트의 구조 및 역학적 성질에 관한 연구 (A Study On the Structure and Mechanical Properties of tensioned and non-tensioned annealed PP filaments)

  • 이은우
    • 한국산업융합학회 논문집
    • /
    • 제4권4호
    • /
    • pp.413-418
    • /
    • 2001
  • The change of crystalline structure and mechanical properties of drawn PP filaments which was treated by tensioned and non-tensioned annealing was investigated. Measurements were carried out with XRD for crystallite size, density gradient tube for crystallinity. and UTM for mechanical properties. Tensioend and non-tensioned annealing were carried out $80^{\circ}C$, $100^{\circ}C$, $120^{\circ}C$: for 10min., 30min., 60min, in oil bath. It was found that the crystallinity and crystallite size of (110) plane of samples were increased with increasing of annealed temperature and time. Also crystallinity and crystallite size of samples which was tensioned annealing were larger than those of non-tensioned annealed samples. Initial modulus and tensile strength of tensioned annealed samples were higher than non-tensioned annealed samples, But elongation of tensioned annealed samples was lower than non-tensioned annealed samples.

  • PDF