• Title/Summary/Keyword: non-cement

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Properties of non-cement mortars with small addition of alkali activator using fly ash and fused waste slag (석탄회 및 용융폐기물 슬래그에 소량의 알칼리 활성화제를 첨가한 무시멘트 모르타르의 특성)

  • Kim, Yootaek;Lee, Kyongwoo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.6
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    • pp.257-262
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    • 2015
  • Recently the world wide efforts reduce occurrence of $CO_2$; global warming main reason. The aim of this study is to improve recycling rate of the fly ash (FA) and fused waste slag (FWS) from the power plant and to carbonate under supercritical condition ($40^{\circ}C$, $80kgf/cm^2$ pressure, 60 min) for $CO_2$ fixation. Specimens of mortar with various mixing ratios of FA, FWS (from 100:0 to 20:80 in 5 steps of 20 % reduction each time), distilled water and 3 M NaOH alkali activators were prepared. As a result, the proportion of weight change ratio increases with CaO content, to 12 % after carbonation under the supercritical condition. There is difference of compressive strength between the carbonated and the alkali activator mortar specimens. The stabilization of $CO_2$ fixation through carbonation which could confirm the applicability of the eco-friendly materials without loss of compressive strength.

Effect of Timing of Light Curing on the Shear Bond Strength of Three Self-adhesive Resin Cements

  • Yoo, Yeon-Kwon;Kim, Sung-Hun;Ryu, Jae-Jun;Ryu, Jae-Jun
    • Journal of Korean Dental Science
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    • v.1 no.1
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    • pp.28-34
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    • 2008
  • Objectives. The objectives of this study were: 1) to compare the effect of varying timing of light curing on shear bond strength, and; 2) to compare the shear bond strength of three self-adhesive cements. Materials and methods. A total of 72 extracted non-carious teeth were divided into 24 for Unicem tests, 24 for Maxcem tests, and 24 for Biscem tests; they were assigned 3 * 2 subgroups of 12 teeth each. The specimens were prepared as follows: 1) The calculus and periodontal ligament were removed from the teeth; 2) The teeth were stored in normal saline; 3) The occlusal enamel of each tooth was removed using high-speed coarse diamond burs under water cooling, and; 4) Finally, the teeth were flattened by 600-grit silicone carbide paper disks. Resin blocks were adhered using either Unicem, Maxcem, or Biscem. Light curing timing was divided into two groups: U10, M10, and B10 were exposed to light after 10 seconds, and; U150, M150, and B150 on the other side were exposed to light after 150 seconds. Shear bond strength was measured by a Universal testing machine with cross head speed of 1mm/min. T-test and One way ANOVA were used for the statistical analysis of data. Results. The shear bond strength of U150 was not significantly higher than that of U10 (U150: 20.55.7Mpa, U10: 18.73.80Mpa). On the other hand, the shear bond strength of M150 was significantly higher than that of M10. The shear bond strength of B150 was also significantly higher than that of B10 (M150:14.45.7Mpa, M10: 9.94.2Mpa, B150: 24.38.3Mpa, B10: 17.27.3Mpa). When the light curing timing was 10sec after bonding, the shear bond strength of Unicem was highest; the shear bond strength of Biscem was highest when the light curing timing was 150sec after bonding (U10: 18.73.80Mpa, B150: 24.38.3Mpa). Significance. Since Unicem is less sensitive based on light curing timing, dentists seem to use it without considering the light curing timing. Maxcem showed the lowest bonding strength (especially M10). Thus, when using Maxcem, dentists need to delay the light curing after adhesion.

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Computer Simulation for the Thermal Analysis of the Energy Storage Board (에너지 축열보드 열해석을 위한 컴퓨터 수치해석)

  • 강용혁;엄태인;곽희열
    • Journal of Energy Engineering
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    • v.8 no.2
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    • pp.224-232
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    • 1999
  • Latent heat storage system using micro-encapsuled phase change material is effective method for floor heating of house and building. The temperature profile in capsule block and flow rate of hot water are important parameters for the development of heat storage system. In the present study, a mathematical model based on 3-D, non-steady state, Navier-Stokes equations, scalar conservation equations and turbulence model ($\kappa$-$\varepsilon$), is used to predict the temperature profiles in capsule and the velocity vectors in hot water pipe. The multi-block grids and fine grids embedding are used to join the circle in hot water pipe and square in capsule block. The phase change process of the capsule is quite complex not only because the size of phase change material is very small, but also because phase change material is mixed with the cement to form thermal storage block. In calculation, it's assumed that the phenomena of phase change is limited only the thermal properties of phase change material and the change of boundary is not happened in capsule. The purpose of this study is to calculate the temperature profiles in capsule block and velocity vectors in hot water pipe using the numerical calculation. Two kinds of thermal boundary condition were considered, the first (case 1) is the adiabatic condition for the both outside surfaces of the wall, the second (case 2) is the case in which one surface is natural convection with atmosphere and another surface is adaibatic. Calculation results are shown that the temperature profile in capsule block for case 1 is higher than that for case 2 due to less heat loss in adaibatic surface. Specially, in the domain of near Y=0, the difference of temperature is greater in case 1 than in case 2. The detailed experimental data of capsule block on the temperature profile and the thermal properties such as specific heat and coefficient of heat transfer with the various temperature are required to predict more exact phenomena of heat transfer.

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Effect of Fluorine-Silicate Hybrid Based Crack Reducing Agent on the Resistance for Shrinkage Crack and Gas Permeability of Concrete (불소-실리카 복합형 균열저감제가 콘크리트의 수축균열 저항성 및 투기성에 미치는 영향)

  • Lee, Man-Ik;Park, Jong-Hwa;Nam, Jae-Hyun;Kim, Do-Su;Kim, Jae-On
    • Journal of the Korea Concrete Institute
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    • v.18 no.5 s.95
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    • pp.631-637
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    • 2006
  • In this study, fundamental properties such as fresh and hardened performance of concrete mix(specification : 25-24-18) added fluorine-silicate hybrid based crack reducing agent(FS) were measured. Addition of FS ranged from 0.5% to 2.0% at intervals 0.5% based on cement weight. Adequate dosage(0.5%) of FS derived from basic properties measurements applied and compared resistance for shrinkage crack. The permeability of concrete in the absence(24-S-0.0) and presence(24-S-0.5) of evaluated at a mock-up sized concrete. Concrete added FS improved resistance for shrinkage crack and consequently crack number, length and area decreased to $50{\sim}74.4%$ compared non-added. As well, by the addition of FS, the resistance for permeability and penetration depth to concrete surface region increased 67% and 40%, respectively. Therefore it was confirmed that shrinkage crack resistance and permeability of concrete could be improved by the addition of FS.

FINITE ELEMENT ANALYSIS ON MAXILLARY MOLAR IMPLANT UNDER DIFFERENT C/R RATIO (상악 구치부 임플랜트 보철수복시 치관/치근비에 따른 응력 분포에 대한 유한 요소 분석)

  • Kim, Jin-Ho;Kim, Hyung-Seob;Choi, Dae-Gyun;Kwon, Kung-Rock
    • The Journal of Korean Academy of Prosthodontics
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    • v.44 no.5
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    • pp.561-573
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    • 2006
  • Statement of the problem: In cases of low bone level in maxilla followed by extraction due to severe periodontitis or enlarged maxillary sinus, crown-root ratio of implant prosthesis will increase. The prognosis of these cases is not good as expected. Purpose : The purpose is to compare stress distribution due to crown-root ratio and effect of splinting between two implants in maxillary molar area under different loads Material and methods: Using ITI($4.1{\times}10$ mm) implant. two finite element models were made(model S: two parallel implants, model A: one of two is 20 degree inclined). Each model was designed in different crown-root ratio(0.7:1, 1:1, 1.25:1) and set cement type gold crown to make it splinted or non-splinted clinical situations. After that, 300 N force was loaded to each model in four ways.(load 1 : middle of occlusal table, load 2 : middle of buccal cusp, load 3 : middle of lingual cusp, load 4 : horizontal load to middle of buccal cusp), and stress distribution was analyzed. Results: On all occasions, stress was concentrated on neck of implant near cortical bone. In the case of inclined implant, stress was increased compared with parallel implants. Under load 1, 2, 3, stress was not increased even when crown-root ratio increases, but under load 4, when crown-root ratio increases, stress also increased. And more stress was concentrated under load 1 than load 2, 3. When crown-root ratio was same, stress under load 1, 2, 3 decreased when splinting, but under load 4, stress did not really decrease. Conclusion: Under vertical load, stress distribution related to crown-root ratio did not change. But under horizontal load, stress increased as crown-root ratio increases. Under vertical load, splinting decreased stress but under horizontal load, effect of splinting was decreased as condition of implant changes for the worse such as increase of crown-root ratio, inclined implant.

FLEXURAL STRENGTH OF IMPLANT FIXED PROSTHESIS USING FIBER REINFORCED COMPOSITE (섬유성 강화 컴포지트를 사용한 임플랜트 고정성 보철물의 굴곡강도)

  • Kang, Kyung-Hee;Kwon, Kung-Rock;Lee, Sung-Bok;Choi, Dae-Gyun
    • The Journal of Korean Academy of Prosthodontics
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    • v.44 no.5
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    • pp.526-536
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    • 2006
  • Statement of problem : Use of fiber composite technology as well as development of nonmetal implant prosthesis solved many problems due to metal alloy substructure such as corrosion. toxicity, difficult casting, expensiveness and esthetic limit. After clinical and laboratory test, we could find out that fiber-reinforced composite prostheses have good mechanical properties and FRC can make metal-free implant prostheses successful. Purpose : The purpose of this study is to evaluate the flexural strength of implant fixed prosthesis using fiber reinforced composite. Material and methods : 2-implant fixture were placed in second premolar and second molar area in edentulous mandibular model, and their abutments were placed, and bridge prostheses using gold, PFG, Tescera, and Targis Vectris were fabricated. Tescera was made in 5 different designs with different supplements. Group I was composed by 3 bars with diameter 1.0mm and 5 meshes, 2 bars and 5 meshes for Group II, 1 bar and 5 meshes for Group III, and only 5 meshes were used for Group IV. And Group V is composed by only 3 bars. Resin (Tescera) facing was made to buccal part of pontic of gold bridge. All of gold and PFG bridges were made on one model, 5 Targis Vectris bridges were also made on one model, and 25 Tescera bridges were. made on 3 models. Each bridge was attached to the test model by temporary cement and shallow depression was formed near central fossa of the bridge pontic to let 5 mm metal ball not move. Flexual strength was marked in graph by INSTRON. Results : The results of the study are as follows. The initial crack strength was the highest on PFG. and in order of gold bridge Tescera I, Tescera II, Targis vectris, Tescera IV, Tescera III, and Tescera V. The maximum strength was the highest on gold bridge, and in order of PFG, Tescera I, Tescera IV Tescera II, Targis vectris, Tescera III, and Tescera V. Conculsions : The following conclusions were drawn from the results of this study. 1. Flextural strength of implant prosthesis using fiber reinforced composite was higher than average posterior occlusal force. 2. In initial crack strength, Tescera I was stronger than Tescera V, and weaker than PFG. 3. Kinds and number of auxillary components had an effect on maximum strength, and maximum strength was increased as number of auxillary components increased. 4 Maximum strength of Tescera I was higher than Targis vectris, and lower than PFG.

COMPARISON OF CANAL SHAPING METHODS WITH GTTM ROTARY FILE AND CONDENSATION METHODS (GT rotary file을 이용한 근관성형법과 충전방법의 비교)

  • Kang, Yu-Mi;Jin, Jeong-Hee;Yu, Mi-Kyung;Lee, Se-Joon;Lee, Kwang-Won
    • Restorative Dentistry and Endodontics
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    • v.27 no.5
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    • pp.521-529
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    • 2002
  • The purpose of this study was to compare the shaping time of two shaping methods and the leakage of three different obturation techniques. Ninty three canaled human molar teeth were used, which were randomly divided into two groups of forty teeth each and ten control teeth. After working length determination, the one group was prepared crown-down technique using rotary root canal instruments of GT rotary files .12/20, .10/20, .08/20 and .06/20 taper(Maillefer Instrument SA. Switzerland). The other group was instrumented with Gates Glidden burs(#1, #2, and #3) to coronal preparation and GT rotary files .08/20 and .06/30 taper to apical preparation. Shaping time was measured. After root canals were instrumented, they were divided to three subgroups and obturated as follows : Subgroup 1, obturated with single cone method Subgroup 2, obturated with lateral condensation : Subgroup 3, obturated with continuous wave technique. Three subgroups were obturated using non-standardized gutta-percha cone(Diadent, Korea, .06 or .08 taper) and AH-26(Dentsply DeTrey, Germany) as a root canal cement. Ten unobturated teeth served as positive and negative controls. After immersion in 2% methylene blue solution for 1 month, the teeth were washed during 24h. The teeth were demineralized in 10% nitric acid and dehydrated by immersion in 80, 90 and 100% ethyl alcohol. The teeth were finally cleared and stored in 100% methylsalicylate, and apical dye penetration was evaluated under stereomicroscope(Leica M420, LC, U.S.A)at $\times$8.75 magnification. Liner measurement of dye penetration was assessed with the use of digitalized image analysing system (analySIS, GmbH, Germany) The data were analysed statistically using independent T-test and Two-way ANOVA and Tukey test. The result were as follows 1. In canal prepared with GT$^{TM}$ rotary file, shaphing time taked more than the group of using Gates Glidden drill to coronal preparation without statistical significance (p>0.05) 2. The group of single cone obturation using canal preparation of GT$^{TM}$ rotary files showed significantly more apical leakage than those of lateral condensation and continuous wave technique regardless of shaping method (p<0.05). 3 The group of single cone obturation using canal preparation of GT$^{TM}$ rotary files and Gates Glidden drill showed significantly more apical leakage than those of continuous wave technique regardless of shaping method (p<0.05). 4. Regardless of shaping method, The group of continuous wave obturation showed less apical leakage than those of lateral condensation without statistical significance (p>0.05). 5. The group of single cone obturation using canal preparation of GT$^{TM}$ rotary files and Gates Glidden drill showed more apical leakage than the group of lateral condensation using same shaping method with-out statistical significance (p>0.05).

An Experimental Study on the Properties of Porous Concrete according to the Mix Factors and Compaction Load (배합조건 및 다짐하중에 따른 포러스 콘크리트의 특성에 관한 실험적 연구)

  • Lim, Seo-Hyung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.3
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    • pp.83-91
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    • 2015
  • Porous concrete consists of cement, water and coarse aggregate and has been used for the purpose of decreasing the earth environmental load such as air and water permeability, sound absorption, etc. However, the physical and mechanical properties of porous concrete changes due to compaction load during construction. For such a reason, the purpose of this study is to investigate the physical and mechanical properties of porous concrete according to the kinds of binder, the ratio of water to binder and target void ratio. In particular, this study has been carried out to investigate the influence of compaction load on the void ratio, strength and coefficient of permeability. Aggregate used in this study are by-products generated during production of crushed gravel with a maximum size of 13mm. The results of this study showed that the target void ratio, the coefficient of permeability and compressive strength of porous concrete had a close relationship with the void ratio, and it will be possible that the void ratio is suggested by the mix design of porous concrete. The compressive strength of porous concrete was the highest at the content of the expansive admixture of 5% and compared to non-mixture, 10% mixture of silica fume improved compressive strength about 32%. And in the result of the study to change the compaction load, the compressive strength increased from the load of 15kN, the void ratio decreased from the load of 0.8kN, the coefficient of permeability decreased from the load 35kN, respectively.

Research on Fire Safety of Mortar-Containing Waste Tire Powders and Flame Retardant (폐타이어 분말과 난연제가 혼입된 모르타르의 화재안전에 관한 연구)

  • Park, Jeong-Jin;Son, Ki-Sang
    • Fire Science and Engineering
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    • v.24 no.4
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    • pp.12-17
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    • 2010
  • The purpose of this study is to determine how effectively waste tire recycled material mixed with flame retardant work in combating fire. As discovered in the previous study, waste tire mixed with cement mortar has more insulation capacity. However, this mortar is weak against fire. Therefore flame retardant, with a specific proportional mix, will be added to increase its fire prevention capacity. Tests will be made in accordance with ISO 5657 procedures for measuring fire ignition time, flame and shape variation of test pieces at the Building Material Test Institute. The test piece will be set up with horizontal levels having a constant radiation heat of $1{\sim}5W/cm^2$. Temperature transfers and increases from the surface into the interior. Combustible gases result due to pyrolysis, and regular contact is maintained between the fire source and the center of the test piece for assessment purposes. Ignition has not been occurred without adding retardant meaning that there is almost no possibility of ignition of waste tire particle. This fact can be considered as fire load to appreciate a volume of combustion materials. Flame is not occurred due to heat-absorbing effect by adding non-organic series retardant into waste tire particle. Conclusions have been summarized as follows; 1) Combustion of building material can be decreased by adding retardant to waste tire-mixing mortar. But compressive strength and insulation capacity of the material should be measured later. 2) Firing prevention and ignition are main points of building fire. Reasonable fire engineering assessment of interior material should be made for establishing effective disaster prevention system.

Surface Properties of Color Concrete Using Acid Stained Agent (표면 착색용 산화제를 사용한 컬러 콘크리트의 표면 특성)

  • Kim, Jin-Man;Jeong, Ji-Yong;Park, Hyo-Jin
    • Journal of the Korea Concrete Institute
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    • v.23 no.3
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    • pp.265-272
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    • 2011
  • Even though concrete is the most important material for building structures, its intrinsic gray color degrades urban esthetics. In order to improve this problem, coloring methods of mixing pigment in concrete batch and painting the surface of concrete surface have been tried. However, applications of the coloring methods in construction field are difficult due to high cost and low durability. Recently, acid stain agent is emerging as a new coloring method for concrete. It is able to apply a remarkably thin colored layer on a concrete surface from chemical reaction between acid and alkaline solutions. This study has examined the changes and variations of the surface layer of mortar specimen from chemical reaction of acid stained agents. The colors were changed into natural irregular stains according to aging. After the staining, no shape change was found from visible inspections. Microstructure of the colored surface applied with acid stained agent was much rougher than that of original mortar. When the colored layer was compared to original surface, crystals of hydrate such as $Ca(OH)_2$ and C-S-H gel were observed. Surface hardness was same or slightly higher in the colored layer. The value of pH was reduced by approximately 10%, weight contents of elements such as Ca, Si, and Al were low. In the chemical composition of the colored layer, the non-cement based elements of Mn, Cr, and Cu increased. Also, Fe and alkali elements of K and Na increased.