• Journal of the Korean Chemical Society
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• v.39 no.3
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• pp.191-197
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• 1995

The reactions of [${Mo(NO)_2Cl_2}_n$] with unidentate ligands in $CH_2Cl_2$ solvent afforded monomeric complexes [$Mo(NO)_2L_2Cl_2$]. $[Mo(NO)_2L_4](ClO_4)_2$ was obtained by reaction of unidentate with $[Mo(NO)_2L_2Cl_2]$ in aceton solvent. 4-Dimethylaminopyridine(dmap), pyridine(py), and isoquinoline(isoq) were used as coordinating ligands. These dinitrosylmolybdenum complexes are prepared and characterized by elemental analysis, $^1H$ NMR, infrared, and UV-Visible spectroscopy. The infrared spectra indicate that the NO groups occupy cis-positions of the octahedral.

• Bulletin of the Korean Chemical Society
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• v.35 no.4
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• pp.1117-1120
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• 2014

Ru/C-catalyzed hydrogenation of m-xylylene diamine into 1,3-cyclohexanebis(methylamine) was greatly accelerated by the presence of $LiNO_3$, $NaNO_2$, or $NaNO_3$. It was found that the effect of the nitrate salt was significantly affected by the size of cation. The promoting effect of the nitrate salt increased with the decrease of the cation size: $LiNO_3$ ~ $NaNO_2$ > $KNO_3$ > $CsNO_3$ >> [1-butyl-3-methylimidazolium]$NO_3$. XRD analysis of the recovered catalysts after the hydrogenation reactions showed that $LiNO_3$ and $NaNO_2$ were completely transformed into LiOH and NaOH, respectively, along with the evolution of $NH_3$, while $KNO_3$ and $CsNO_3$ remained unchanged.

• Proceedings of the Korean Society of Rheology Conference
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• 2003.05a
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• pp.33-36
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• 2003

No Abstract, See Full Text

• Proceedings of the Korean Society of Rheology Conference
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• 2003.05a
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• pp.73-76
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• 2003

No Abstract, See Full Text

• Proceedings of the Korean Society of Rheology Conference
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• 2003.05a
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• pp.127-130
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• 2003

No Abstract, See Full Text

• Proceedings of the Korean Society of Rheology Conference
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• 2003.05a
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• pp.139-142
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• 2003

No Abstract, See Full Text

• Proceedings of the Korean Society of Rheology Conference
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• 2002.11a
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• pp.51-54
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• 2002

No Abstract, See Full Text

• Proceedings of the Korean Society of Rheology Conference
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• 2002.11a
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• pp.23-26
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• 2002

No Abstract, See Full Text

• Proceedings of the Korean Society of Rheology Conference
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• 2003.05a
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• pp.77-80
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• 2003

No Abstract, See Full Text

• Proceedings of the Korean Society of Rheology Conference
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• 2001.09a
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• pp.154.2-154
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• 2001

(No abstract, see full-text)