• Journal of Electrochemical Science and Technology
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• v.7 no.4
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• pp.306-315
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• 2016

Amorphous vanadium titanates (aVTOs) are examined for use as a negative electrode in lithium-ion batteries. These amorphous mixed oxides are synthesized in nanosized particles (<100 nm) and flocculated to form secondary particles. The $V^{5+}$ ions in aVTO are found to occupy tetrahedral sites, whereas the $Ti^{4+}$ ions show fivefold coordination. Both are uniformly dispersed at the atomic scale in the amorphous oxide matrix, which has abundant structural defects. The first reversible capacity of an aVTO electrode ($295mAhg^{-1}$) is larger than that observed for a physically mixed electrode (1:2 $aV_2O_5$ | $aTiO_2$, $245mAhg^{-1}$). The discrepancy seems to be due to the unique four-coordinated $V^{5+}$ ions in aVTO, which either are more electron-accepting or generate more structural defects that serve as $Li^+$ storage sites. Coin-type Li/aVTO cells show a large irreversible capacity in the first cycle. When they are prepared under nitrogen (aVTO-N), the population of surface hydroxyl groups is greatly reduced. These groups irreversibly produce highly resistive inorganic compounds (LiOH and $Li_2O$), leading to increased irreversible capacity and electrode resistance. As a result, the material prepared under nitrogen shows higher Coulombic efficiency and rate capability.

• Korean Journal of Soil Science and Fertilizer
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• v.39 no.2
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• pp.102-108
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• 2006

It is very important to improve fertilizer use efficiency for the saving of fertilizers and for environmental purposes as well. However, there was no effective ways for the fertilization in the mid of growth under the plastic film mulching cultivation so far. For this, a Band Spotty Fertilization (BSF) machine was developed recently. So, we tried to establish a low input fertilization technique using this BSF machine in the vinyl mulching cultivation of onion (Allium cepa L.). Fertilization efficiency, soil properties, and crop yield were examined and compared among treatments from 2000 to 2001. The content of exchangeable K in soils were higher after fertilization but that of available $P_2O_5$ was lower than before the experiment in all plots. The content of nitrate-N was highest at the early growth stage, and higher in BSF plots than that of conventional fertilization (CF). BSF plot showed higher growth rate, and uptake amount of nitrogen of onion by 59-69% than that of CF. N use efficiency in BSF was higher in the order of two time-split application, one time-split application, and three time application. K use efficiency was high 13-17% BSF plots than that in CF($63kg\;ha^{-1}$) plots. The amount of residual N in soils was high by 8-14% in BSF plots compared to that in CF plots, and the loss of N was lowered 26-34% by BSF. Also, the amount of residual K in soils was high by 13-18% and the loss of K was low by 29-31% in BSF plots compared to that in CF plots. The yield of onions increased by 7-13% by BSF due to increased diameter and weight of bulbs. As the results, N fertilization efficiency increased by 22-42% by BSF.

• Korean Journal of Soil Science and Fertilizer
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• v.43 no.6
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• pp.981-986
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• 2010

This study was carried out to investigate the effects of fertilizer and organic resource annual dressing for 30 years of Jeonbug series (silt loam) on soil properties and rice N uptake in paddy field soil. In the study field, treatments including control (NPK), NPK+rice straw, NPK+rice straw compost and nitrogen fertilization levels at 0, 100, 150, 200, 250 kg $ha^{-1}$ have been imposed for 30 years. Soil hardness and bulk density decreased from 15.7 mm and 1.381 Mg $m^{-3}$ in the control to 12.5 mm and 1.244 Mg $m^{-3}$ in NPK+rice straw compost treatment, respectively, indicating improvement of soil physical conditions such as porosity. Co-application of straw compost with NPK also result in a better chemical properties than NPK alone as it increased available phosphate (from 96 to 133 mg $kg^{-1}$), available silicate (from 81 to 116 mg $kg^{-1}$), and cation exchange capacity (from 9.8 to 11.4 $cmol_c\;kg^{-1}$). Soil organic matter concentration of top soil (0 to 7.5 cm in depth) was higher in NPK+rice straw and NPK+rice straw compost than in control. Fertilizer N uptake amount was much higher in NPK+rice straw (nitrogen fertilization level; 250 kg $ha^{-1}$) and NPK+rice straw compost (nitrogen fertilization levels; 200, 250 kg $ha^{-1}$) plots compared to the control (nitrogen fertilization level; 100 kg $ha^{-1}$) plot. Nitrogen use efficiency was showed significantly high in the NPK+rice straw compost (nitrogen fertilization levels; 100, 150 kg $ha^{-1}$) plot compared to the control (nitrogen fertilization level; 100 kg $ha^{-1}$) plot. Therefore, it was suggested that application of organic inputs is helpful in improving soil fertility and physical conditions and thus in N uptake.

• Korean Journal of Soil Science and Fertilizer
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• v.38 no.3
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• pp.157-163
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• 2005

The increasing of greenhouse gases may change agricultural environment. The agronomic productivity will depend upon change of temperature, precipitation, solar radiation and fertilization. Particularly, nitrogen fertilization considerably influences rice productivity and agricultural environments. This experiment was conducted to study transformation of nitrogen and to determine the primary yield components responsible for yield differences in paddy soil. $NH_4-N$ concentration of NPK plot in surface water of paddy soil was $2.07mg\;L^{-1}$ at 5 days after transplanting, and then was decreased sharply due to rice absorption and loss to environment. $NO_3-N$ concentration of NPK plot in surface water was $3.97mg\;L^{-1}$ at 10 days after transplanting. $NO_3-N$ concentration range of CRF plot in surface water was $3-5mg\;L^{-1}$ at 30th after transplanting. The accumulation of $NH_3$ volatilization in NPK plot was $22.39kg\;ha^{-1}$, which accounted for 20% of N fertilizer applied but using of CRF fertilizer can reduce $NH_3$ volatilization by 67% in paddy soil. Use efficiency of N fertilizer was not different between CRF70% and CRF100% plot. Rate of N use efficiency were 27.4%, 51.2%, 49.0% in paddy field NPK, CRF70% and CRF100% plots respectively. The yield of CRF70% showed the best effect with 9.3% increase production ratio, compare with NPK plot.

• Korean Journal of Soil Science and Fertilizer
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• v.7 no.4
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• pp.215-220
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• 1974

The relation between yield or total dry matter yield and nitrogen, phosphorus, potassium or silica uptake was investigated according to simple or multiple correlation coefficients, and multiple regression equations. 1. Simple correlation coefficient was always higher with total dry matter yield than with grain yield and highest with N in no nitrogen (0-6-8) or no fertilizer (0-0-0) plot, with P in no phosphorus plot (10-0-8) but lowest with K in no potassium plot (10-6-0). 2. Multiple correlation coefficient was always higher than simple correlation and the same is true with including Si as one more variation. There was clear trend that multiple correlation coefficient was highest in no fertilizer plot and lowest in no potassium plot. 3. Simple correlation coefficient with P was higher in the warm year in which P uptake and fertilizer-P use efficiency were higher while it with K was higher in the cool year in which K uptake and fertilizer-K use efficiency were higher. Nitrogen and silicate followed potassiuum. But partial regression coefficients of N. P. K and Si with yield were mostly significant only in the warm year. 4. Partial regression coefficient of K was negative in many cases with yield but significant positive value with total dry matter yield. 5. Partial regression coefficients of N. P and K were decreased when Si was included and the decrease was great in P. 6. With the increase of nitrogen fertilizer level partial regression coefficient was increased in N but decreased in P, and no consistency in K or Si. 7. According to single or multiple correlation coefficients and partial regression coefficients the contribution of nutrient to grain yield appears to be in the order of N > Si > P > K and to total dry matter yield in the order of N > K > Si > P, indicating that N is the main factor and others are closely related to each other throughout to N. The superiority of N was also proved by frequency pattern of relative yield.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.6
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• pp.1107-1111
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• 2011

Organic fertilizers application has become a popular alternatives to reduce the dependence on chemical fertilizer in Korean farming systems. In this study, we evaluated the nitrogen (N) use efficiency and growth performance of Chinese cabbage grown by black vinyl mulching after application of organic and chemical fertilizers compared with no-mulching. The treatments included chemical fertilizer alone as control (NPK, N-$P_2O_5-K_2O$ : $320-78-198kg\;ha^{-1}$), organic fertilizer alone (OF100), 70% organic fertilizer and 30% chemical fertilizer (OF70+N30), and 30% organic fertilizer and 70% chemical fertilizer (OF30+N70), which were all applied in the no-mulching plots and in plots with black vinyl mulching. Daily means soil temperature was $2^{\circ}C$ higher in the black vinyl mulched treatments throughout the 54 days compared with no-mulched treatments. OF100 with black vinyl mulching gave highest soil inorganic N content. Also, Chines cabbage yield increased 46% by black vinyl mulched compared with no-mulching in OF100 treatment. Without mulching, N use efficiency was, 44, 26, 29, and 27% in NPK, OF100, OF70+N30, and OF30+N70, respectively. However, black vinyl mulching much more effectively increased N use efficiencies by 56, 55, 51, and 39% in the same treatments in the order as mentioned above. Conclusively, combined organic and chemical fertilizers application with black vinyl mulching could be good practical technique to reduce a amount of used nitrogen because of its greater ability to enhance N use efficiency.

• Journal of the Korea Organic Resources Recycling Association
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• v.23 no.3
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• pp.33-41
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• 2015

An alternative was investigated to maximize the treatment efficiency of wastewater treatment plant without large scale expansion. 79% of detention time was required for enough nitrogen control. As aeration time was extended, nitrification was processed, but opposite trend was seen in phosphorus. High concentration of $NO_3-N$ interrupted PAOs activity not to absorb phosphorus. An alternative was devised for selective use of anaerobic or anoxic zone. Trisection was suggested for alternative use of center room. The result was relatively successful. The concentration of phosphorus was reduced with reduction of nitrogen. Extended anaerobic condition seemed to stimulate denitrification. Valve connection of internal return from aeration tank will make it possible to use middle room alternatively. This method will be a good alternative for seasonal variation of water temperature.

• Journal of Korean Society on Water Environment
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• v.25 no.6
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• pp.832-839
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• 2009

Since construction of the estuarine barrage at the mouth of the Nakdong River, eutrophication and increased abundance of phytoplankton have occurred mainly due to the increased retention time in the reach. However, during the spring, there is a decrease in chlorophyll-a, as a result of an increase in zooplankton number, which preys upon phytoplankton and affects the value of chlorophyll-a. In order to emphasize the importance of zooplankton data in water quality simulation, zooplankton community data were used to simulate water quality and eutrophication at Mulgeum located in 27 km upstream from the barrage. WASP 7.2 was used as the water quality model for the river, using a monthly data set from 2003 to 2005 for model calibration and verification. The results showed that chlorophyll-a, DO, and total nitrogen in the river were simulated well during the verification period. The results of water quality simulation using zooplankton community data in the model were better than those with phytoplankton death rate, in terms of the absolute value of percent bias, root mean square error, and Nash-Sutcliffe efficiency. Those results indicate the use of zooplankton data provides more accurate simulation results for chlorophyll-a and eutrophication.

• Journal of The Korean Society of Agricultural Engineers
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• v.49 no.1
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• pp.89-97
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• 2007

Simple regression models for pollutants load estimation of paddy developed by the Ministry of Environment in 1995 were tested with the data (T-N, T-P, $COD_{Mn}$, and SS) collected from Yeongsan and Seomjin river watersheds, and improvement measures were suggested. Overall, the simulated values showed a great difference from the measured values except for T-P according to the statistical analyses (RMSE, root mean square error; RMAE, root mean absolute error; RB, relative bias; EI, efficiency index). Such difference was assumed due to the fact that the models use only hydrologic factors (quantity factor) associated with precipitation and run-off as input parameters, but do not consider other factors which are likely to affect pollutant concentration (quality factor) including days after fertilization. In addition, in terms of accessibility of the models, some parameters in the models such as run-off depth and run-off amount which can not be obtained from the weather database but should be collected by on-site measurements need to be replaced with other variables.

• Journal of Korean Society of Water and Wastewater
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• v.38 no.2
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• pp.95-107
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• 2024

This study proposes the use of a cobalt-based Prussian blue analogue (Co-PBA; potassium cobalt hexacyanoferrate), as an adsorbent for the cost-effective recovery of aqueous ammonium ions. The characterization of Co-PBA involved various techniques, including Fourier-transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, nitrogen adsorption-desorption analysis, and zeta potential. The prepared Co-PBA reached an adsorption equilibrium for ammonium ions within approximately 480 min, which involved both surface adsorption and subsequent diffusion into the interior. The isotherm experiment revealed a maximum adsorption capacity of 37.29 mg/g, with the Langmuir model indicating a predominance of chemical monolayer adsorption. Furthermore, the material consistently demonstrated adsorption efficiency across a range of pH conditions. Notably, adsorption was observed even when competing cations were present. Co-PBA emerges as a readily synthesized adsorbent, underscoring its efficacy in ammonium removal and selectivity toward ammonium.