• Composites Research
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• v.31 no.5
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• pp.267-275
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• 2018

A facile method for the preparation of nitrogen-doped microporous carbon via the pyrolysis of poly(vinylidene fluoride) (PVDF) using polypyrrole (PPy) as a selective nitrogen source was developed. A PVDF/PPy-800 sample (carbonized at $800^{\circ}C$) with a 1:0.5 ratio of PVDF and PPy exhibited the highest micropore volume. The activated microporous carbon materials obtained from PVDF/PPy-800 prepared at $800^{\circ}C$ with KOH possessed a large specific surface area and narrow pore-size distribution. They were characterized using $N_2$ adsorption at 77 K and argon (Ar) adsorption at 87 K, which allowed for the characterization of the narrow microporosity of the prepared materials due to the absence of interactions between Ar and the sample surface. In addition, the activated microporous carbon material with a KOH/carbon ratio of 2:1 was found to exhibit the largest specific surface area ($1296m^2g^{-1}$ in $N_2$ at 77 K) and microporosity, and a high specific capacitance ($122.8F\;g^{-1}$).

• Transactions of Materials Processing
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• v.20 no.4
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• pp.296-302
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• 2011

The objective of this paper is to determine the effect of process parameters on the behavior of a 18Cr-10Mn-$0.44N_2$ nitrogen steel sample deformed by hot rolling. Compression tests were carried out at high temperatures to determine the flow stresses needed for a finite element(FE) analysis. The strain rate, ranging from 0.1 to $1.0s^{-1}$, significantly affected the flow stress at temperatures higher than $1,000^{\circ}C$. Non-isothermal rolling simulations and laboratory rolling tests were performed with plate specimens 14.5mm thick, 135mm wide and 226mm long. A rolling reduction of 15% per pass leading to a cumulative rolling reduction of 60% was determined as optimal. The extension ratio of 176.5% in the length direction was about 30.4 times greater than the extension ratio of 5.8% in the width direction. Isotropic properties for tensile strength, microstructure and grain size were measured after mock-up hot rolling tests. The results from the mockup tests were found to be in good agreement with those of the simulations.

• Journal of Korean Society of Water and Wastewater
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• v.18 no.2
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• pp.121-127
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• 2004

It is necessary to supply external carbon source for enhancement of biological nitrogen removal from domestic wastewater with low influent C/N ratio. Sulfide was chosen as a cost effective electron donor and reaction stoichiometry for autotrophic denitrification was investigated by conducting bench-scale experiments in this study. Higher sulfur to nitrogen (S/N) ratio than the calculated value from theoretical reaction stoichiometry was required when the anoxic reactor was operated at open condition because dissolved oxygen introduced by surface aeration reacted with sulfide with ease. In addition, higher sulfate production and lower yield of microorganism could be observed under the same condition. It was possible to obtain reliable reaction stoichiometry for autotrophic denitrification by establishing pure anoxic condition. Linear relationship between bacterial growth and consumption of nitrate, sulfide, alkalinity, and sulfate production enabled to derive a relatively correct reaction stoichiometry for autotrophic denitrification when sulfide was used as an electron donor.

• Journal of The Korean Society of Agricultural Engineers
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• v.51 no.2
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• pp.51-57
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• 2009

The purpose of this study was to investigate characteristics of behavior of nutrients such as TN (Total nitrogen), TDN (Total dissolved nitrogen), TP (Total phosphorus) TDP (Total dissolved phosphorous) in runoff water from a nonpoint source dominated watershed ($6.67\;km^2$). Regular and intensive flow measurement and water sampling were taken during two years (February 2002 to January 2004) in the Ingyeong River, a tributary of the Han River. The mean concentrations of nutrients during rainy days were significantly (p < 0.05) higher than those during dry days. The mean TDN/TN ratio in rainy days (95%) is almost identical to that in dry days (96%), but mean TDP/TP ratio in rainy days (24%) significantly decreased compared with that in dry days (66%), suggesting that dominant form of TP is shifted from dissolved form to particulate form. Accordingly, the measures (.eg. filter strips, cover crops) to reduce soil erosion for fallow upland in the rainy season should be taken to control particulate phosphorous.

• Journal of the Korean Society of Combustion
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• v.9 no.1
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• pp.11-17
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• 2004

The purposes of this study are to analyze nitrogen oxides(NOx) formation mechanism and to reduce abnormal NOx emissions in gas turbines. Industrial gas turbines emissions have potential to negative affect to the atmosphere in many different ways such as photochemical smog, acid rain and global warming. In conventional gas turbine combustors, one of the main pollutants such as nitrogen oxide(NOx) species, are principally formed from combustion process of fuel with oxygen in the primary combustion zone, and their emission levels are highly depend on peak temperatures in the combustor. In order to examine the characteristics and the effect of NOx formation, we used gas turbine of which commercial operating in Korea. From the examination, it has been found that NOx emissions are relatively high at low load(output) and during combustion mode change. Also, the effect of Air/Fuel ratio was considered. As the Air/Fuel ratio was increased in Lean-Lean mode, the NOx emission was decreased. The results of this study indicated that NOx emission levels are highly depend on peak temperature and pressure of combustion process in the combustor.

• Journal of Animal Environmental Science
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• v.22 no.1
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• pp.35-44
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• 2016

This study was conducted to establish a database of high solid manure(HSM) in domestic. Theoretical methane potential and HSM characteristics was evaluated using breef and dairy manure (n=156). Total solids and Volatile solids of HSM increased depending on time flow, the results showed $20.4{\pm}3.2$ and $17.4{\pm}2.8%$. respectively. C/N ratio of breef HSM was higher than dairy HSM C/N ratio. In theoretical methane potential, the result of breef and dairy HSM was showed $505.2{\pm}25.3$ and $493.5{\pm}20.2$, respectively. Nitrogen content of total HSM increased depending on time flow, the result of breef and dairy nitrogen content was showed $1.9{\pm}0.3$ and $2.8{\pm}0.2$, respectively. Carbon content of total HSM showed approximately 10% reduction. The optimal time of bed replacement was indicated between 29 amd 31 days based on the optimal C/N ratio. Therefore, this study was considered that it has high utilization for livestock manure recycling and basis of relevant research.

• Journal of Ecology and Environment
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• v.35 no.4
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• pp.269-277
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• 2012

In order to investigate the effects of different maize-bean intercropping patterns, and of nitrogen fertilizers on morphological and yield related traits, a factorial study based on Randomized Complete Block Design (RCBD) was performed during the 2010 and 2011 growing seasons in a research filed of Shiraz University, Iran. The first factor of the study was seven different ratios of Maize-Bean intercropping system (Maize sole cropping, Bean sole cropping, and intercropping of maize/bean at the ratios of 1/3, 1/1, 2/3, 3/2 and 3/1) and the second factor was three nitrogen (N) fertilizer application levels (0, 100 and 200 kg N/ha). Results showed that with respect to increasing the levels of N fertilizer, the yield of bean sole cropping decreased but the yield of maize sole cropping increased. On the other hand, in intercropping systems with N fertilizer application, the yield of both crops increased. Results of total land equivalent ratio (LER) for both crops showed that the highest LER value under both 100 and 200 kg N/ha application was that of M1B1 (1 seed of maize after 1 seed of bean, consecutively, on a row with same distance). Under no N fertilizer application the highest LER value was that of M2B3 (2 seeds of maize after 3 seeds of bean, consecutively, on a row with same distance). Overall, it can be concluded that M1B1 is the best intercropping pattern in maize-bean intercropping systems and that the application of N fertilizer can be effective within practical settings of intercropping agriculture, resulting in higher yields.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.11
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• pp.1141-1145
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• 2005

A contactor coupled sequencing batch reactor composed of pre-anoxic contact zone and intermittently aerated zone was proposed and operated for nitrogen removal. Emphasis was placed on the fact that the contactor can be operated in a rapid reaction mode that results In biological uptake but incomplete metabolism of organic matter. Consequently, 61.2% of the sewage SCOD was adsorbed to activated sludge by 30-minute contact reaction. The specific uptake of organic matter was 22.3 mg SCOD/g MLVSS that enhanced the denitrification efficiency in the following denitrification stage. The removal efficiencies of the organic matter(SCOD) and the total nitrogen(T-N) were 86% and about 60% at the TCOD/TKN ratio as low as 6.0, respectively.

• Journal of Korean Tunnelling and Underground Space Association
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• v.18 no.2
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• pp.175-181
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• 2016

In this paper, the liquid air was selected as the refrigerant in artificial ground freezing to be used for rapid ground freezing and to reduce the risk of suffocation and the applicability of liquid air was verified. In order to evaluate the stability of the liquid air, the oxygen concentration of mixtures with liquid nitrogen and liquid oxygen was experimentally examined to meet the oxygen concentration criteria in the Occupational Safety and Health Act. In addition, the effects of the mixture ratio of liquid nitrogen and liquid oxygen, pressure and flow rate change in the storage vessel on the oxygen concentration in the liquid air were investigated. As a result, the ratio of liquid nitrogen and liquid oxygen 8: 2 was shown to meet the oxygen concentration standards. Pressure and flow rate change in the storage vessel did not have significant effects on the oxygen concentration in the liquid air.

• Journal of Korean Society of Water and Wastewater
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• v.25 no.3
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• pp.383-390
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• 2011

In this study, a process combined biofiltration with sulfur-utilizing autotrophic denitrification and membrane separation was proposed to examine the efficiency of nitrogen removal. As an experimental device, hollow-fiber module was installed in the center of reactor to generate the flux forward sulfur layer in the cylinder packed with granular sulfur. In addition, a simple module was installed in activated sludge aeration tank which inside and outside of sulfur-using denitrification module was covered with microfilter and the module was considered as an alternative of clarifier. The experiment for developing new MBR process was carried out for three years totally. As the results of first two-year experiment, successful nitrogen removal performance was revealed with lab-scale test and pliot scale plant using artificial wastewater and actual plating wastewater. In this year, pilot scale test using actual domestic wastewater was performed to prove field applicability. As the results, high-rate nitrogen removal performance was confirmed with about 0.19 kg ${NO_3}^--N/m^3$ day of rate. Also significant fouling and pressure increase were not found during the experiment. And, the production ratio of sulfate and the consumption ratio of alkalinity showed a slightly higher value about 311 mg ${SO_4}^{2-}/L$ and 369 mg $CaCO_3$/L, respectively. In conclusion, the developed MBR process can be utilized as an alternative for retrofiting existing wastewater plants as well as new construction of advanced sewage wastewater treatment plants, with cost-effective merit.