• Title/Summary/Keyword: nitrogen ratio

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Runoff Characteristics of Non-point Pollutant Sources in an Agricultural Area Watershed (농촌지역 비점오염물질의 유출 특성)

  • Ryu, Kwang-Hyun;Lee, Geon-Jik;Seong, Jin-Uk;Kim, Dong-Sup;Park, Jae-Chul
    • Korean Journal of Ecology and Environment
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    • v.44 no.2
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    • pp.178-186
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    • 2011
  • This study was conducted to investigate runoff characteristics of non-point pollutant sources in an agricultural area watershed in Boeun area, Chungbuk Province. The monitoring site represented 1.56 $km^2$, about 44.4% of which was covered with paddy fields. The monitoring was conducted for six events in a period of 5 month. Event Mean Concentration (EMC) and Site Mean Concentration (SMC) of suspended solids (SS), biochemical oxygen demand (BOD), chemical oxygen demand (COD), total nitrogen (T-N) and total phosphorus (T-P) were calculated using the results of the water quality parameters. A comparison between arithmetic mean concentration and EMC revealed that nearly all EMCs were higher than the corresponding arithmetic mean concentrations. First-flushing effects were exhibited for SS, BOD, and T-P, with relatively high concentrations in early-stage storm events.

Distribution Characteristics of Organic Matters and Heavy Metals in Surface Sediments of Samcheok Port (삼척항 표층퇴적물 내 유기물 및 중금속 분포 특성)

  • Shin, Woo-Seok;Kim, Young-Kee
    • Applied Chemistry for Engineering
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    • v.31 no.5
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    • pp.481-486
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    • 2020
  • To evaluate geochemical characteristics of surface sediments in Samcheok Port, the distribution characteristics of particle sizes, organic matters and heavy metals were investigated. The sediments showed a mixed property of sand, silt, and clay, however fine-grains dominated at the inner port and coarse-grains dominated at the outer port. The organic (COD, TOC, and IL) contamination of the sediment at the inner port were higher than that of the outer port, and the concentrations of total nitrogen and total phosphorus at the inner port was higher than those of the outer port. Also, heavy metals contamination of surface sediments at the inner port was higher than those of the outer port (except for As). From the results of high organic matter concentrations and C/N ratio at the inner port, it is considered that the contamination of organic matters was mainly derived from the land. The correlation analysis among the particle size, chemical composition, and heavy metals resulted in high correlation between silt-clay and heavy metals, and between organic matters and heavy metals. The sequential extraction results of heavy metals showed the sum of exchangeable, carbonate, and oxide fractions of Ni, Zn, Cu, Pb, Cd, and As were 14.8, 49.8, 39.1, 32.2, 51.8 and 26.6%, respectively.

Processing of Pen Shell By-product Hydrolysate Using Response Surface Methodology (반응표면분석법에 의한 키조개 부산물 단백질 가수분해물의 제조조건)

  • Cha, Yong-Jun;Kim, Eun-Jeong;Baek, Hyung-Hee
    • Korean Journal of Food Science and Technology
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    • v.27 no.6
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    • pp.958-963
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    • 1995
  • The hydrolysis of pen shell by-product by the APL $440^{TM}$, selected as the suitable alkaline protease on the basis of cost per unit enzyme activity, was optimized using response surface methodology(RSM). A model equation obtained from the results of RSM could be used for the prediction of degree of hydrolysis(DH) as follows: $%DH=51.126+2.419\;pH+2.415T-2.426S-2.846pH^2-4.211T^2-3.014t^2+2.419S^2$. From the ridge analysis, the conditions favoring the highest degree of hydrolysis were pH 10.2, $61.4^{\circ}C$, 2.58 hrs reaction time, 30.9% substrate concentration, and 0.32% enzyme/substrate ratio. The effect of autolysis affecting degree of hydrolysis in pen shell by-product was negligible. Hydrolysate produced under the optimal condition increased 3.5 times and 7.7 times in amino nitrogen and salinity, respectively, comparing with raw pen shell by-product.

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Studies on the Nutritional Components of Purple Sweet Potato(Ipomoea batatas) (자색(紫色) 고구마의 영양성분에 관한 연구)

  • Kim, Sun-Young;Ryu, Chung-Hee
    • Korean Journal of Food Science and Technology
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    • v.27 no.5
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    • pp.819-825
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    • 1995
  • Two sweet potato CV.(Ipomoea batatas) were examined, i.e. purple flesh sweet potato(PSP) and light yellow flesh sweet potato(LYSP) which varied in degree of sweetness. On a fresh weight basis, nitrogen free extract in cultivars ranged from $25.73{\sim}26.24%$ and PSP contained more crude fat than LYSP. Total amino acids of PSP and LYSP were 5676.57mg% and 4550.86mg%, respectively. Aspartic acid, serine, alanine and valine were the major components in sweet potatoes. Sulfur-containing amino acids are the first limiting amino acid in PSP. The major fatty acids in PSP and LYSP analyzed by GC were palmitic acid, linoleic acid. The content of the saturated fatty acid was less than that of the unsaturated fatty acid. Carbohydrate contents were $75.43{\sim}79.10%$ and neutral sugars contents were $67.22{\sim}64.85%$(dry wt). Two sweet potato CV. contained the most glucose of all neutral sugars. PSP contained 11.88% for uronic acid, 59.42% for starch. Free sugars of PSP(0.82%) was much less than that of LYSP(2.53%). The contents of thiamin, riboflavin and niacin were similar, and the ascorbic acid contents in PSP and LYSP were 63.4mg% and 48.7mg%(dry wt), respectively. Comparing the mineral content in PSP, K was the greatest element in concentration followed by mg, Ca, Na. The total dietary fiber(TDF) value was 13.43% in PSP, 9.79% in LYSP respectively. The ratio of soluble dietary fiber(SDF) content and insoluble dietary fiber(IDF) content to TDF content for PSP were 57.6%, 42.4%, respectively.

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Characteristics of Kanjang Made with Barley Bran (보리등겨로 제조한 간장의 품질특성)

  • Lee, Eun-Jeong;Son, Dong-Hwa;Choi, Ung-Kyu;Lee, Suk-Il;Im, Moo-Hyeog;Kim, Dae-Gon;Kwon, O-Jun;Chung, Yung-Gun
    • Korean Journal of Food Science and Technology
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    • v.34 no.2
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    • pp.200-206
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    • 2002
  • This study was conducted to identify characteristics of kanjang made with barley bran. Characteristics of kanjang made with barley bran were compared to those of kanjang made with soybean. Total nitrogen was maintained more than 0.7% at 90 days after fermentation. In case of free sugars, the contents of arabinose, xylose, fructose, glucose and maltose were more abundant in kanjang made with barley bran than kanjang made with soybean. The contents of propionic acid and butyric acid were rich among volatile organic acids. Nonvolatile organic acid of lactic acid which was known as abundant component in kanjang was not detected in kanjang made with barley bran. In case of free amino acid, glutamic acid was the most abundant in kanjang made with barley bran, followed by proline and phenylalanine. The ratio of glutamic acid content to total amino acid content was $24.8{\sim}28.0%$. Essential amino acid was $26.7{\sim}29.9%$. Total contents of amino acids were $0.7{\sim}1.4%$. Result of sensory evaluation showed that taste of kanjang made with barley bran was good for fermented after 45 days.

A Study on Establishment of the Fermentation Process for Traditional Andong Sickhae (전통 안동식혜의 제조공정 확립에 관한 연구)

  • Choi, Cheong;Seog, Ho-Moon;Cho, Young-Je;Lim, Seong-Il;Lee, Woo-Je
    • Korean Journal of Food Science and Technology
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    • v.22 no.7
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    • pp.724-731
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    • 1990
  • The fermentation process of Andong Sickhae including optimal composition of the product was investigated. Through sensory evaluation and ingredient analysis of ten samples prepared in the laboratory and the samples collected from Andong region, we found that the ratio of ingredient of the product by weigh are as follow : [glutinous rice(80) : malt(50) : radish(100) : water(500) : ginger(8) : red pepper(4)]. The level of nitrogen compound turned out to be low while that of soluble protein and salt soluble protein was high. The content of total sugar and reducing sugar was found to be considerable high and among the free sugar, maltose was the highest(80%), followed by glucose and maltotriose. Activities of acid protease and saccharogenic amylase were 1.55 unit per milliliter and $12.5D^{40}_{30}^{\circ}$ respectively. Results of sensory evaluation showed that the good Andong Sickhae turned out to have well harmonized taste of flavor, sweetness and sourness while the color looked slightly red.

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The Taste Compounds in Boiled-Dried Anchovy (시판 마른 멸치의 정미성분)

  • LEE Eung-Ho;KIM Se-Kwon;JEON Joong-Kyun;CHA Yong-Jun;CHUNG Sook-Hyun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.14 no.4
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    • pp.194-200
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    • 1981
  • Boiled-dried anchovy is one of nation-widely consumed dried fish foods in Korea. In this study, the taste compounds including nucleotides and their related compounds, free amino acids, trimethylamine oxide and total creatinine were analyzed, and their roles in tasting activity were investigated. IMP content in large size, middle size, small size and least size boiled-dried anchovy was $22.7{\mu}mole/g,\;18.6{\mu}mole/g,\;20.3{\mu}mole/g\;and\;4.0{\mu}mole/g$, respectively, and the ratio of IMP to the total nucleotides and their related compounds in each sample was $55.0\%,\;51.0\%,\;69.1\%\;and\;47.0\%$, respectively. In the free amino acid composition of the four size groups of boiled-dried anchovy, abundant amino acids were histidine, lysine, alanine and proline, and the sum of these amino acids occupied $69.0\%,\;67.7\%$. $66.8\%\;and\;45.9\%$ of the total free amino acid in each sample, respectively. Among these. histidine was the most dominant in all samples amounting to 589.0 mg/100g in lage size, 373.9 mg/100g in middle size, 437.8 mg/100g in small sire and 101.0 mg/100g in least size, while aspartic acid and methionine were poor in content. Among the organic bases, total creatinine was abundant, and its nitrogen content ranged from $21\%\;to\;39\%$ of the total extractive nitogen. From the results of omission test, the taste-active compounds of the boiled-dried anchovy are assumed to be IMP and free amino acids.

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A Comparative Study on the Use of Seawater and Sea Salt in Nutrient Elimination (영양염제거에서 해수 및 해수염에 관한 비교연구)

  • Cainglet, Annaliza Pabrua;Kim, Woo-Hang
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.22 no.7
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    • pp.829-835
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    • 2016
  • An excess in the nutrients such as nitrogen and phosphate leads to a phenomenon called eutrophication. In order to avoid this, numerous methods have been used to remove excess nutrients in the water. In this study, the use of a chemical method was assessed through the formation of magnesium ammonium phosphate. The difference in the removal efficiency of seawater and sea salt solution as primary sources of $Mg^{2+}$ ions and $Ca^{2+}$ ions for the formation of magnesium ammonium phosphate (MAP) and hydroxyapatite (HAP) respectively, were observed, taking into account the changes in pH and concentration. The results showed that seawater removed about 90 % phosphate and less than 50 % ammonia in sewage water condition, whereas the sea salt solution removed almost 90 % phosphate and 70 % ammonia in solution at pH 9 and 10 mM concentration of sea salt which further increases as the optimum ${Mg/PO_4}^{3-}$, ${NH_4}^+$ ratio reaches 2. The difference in the removal efficiency of seawater and sea salt was due to the fact that the set-ups were prepared in different conditions. This study suggests that both seawater and sea salt can be used to remove nutrients from the water. The relatively higher removal of phosphate can be explained by the formation of HAP from free $Ca^{2+}$ ions initially present in seawater and sea salt solution.

Fermentation and Quality Characteristics of Cheonggukjang with Chinese Cabbage (배추 첨가 청국장의 제조 및 품질특성)

  • Kim, Jin Hak;Park, La Young;Lee, Shin Ho
    • Food Science and Preservation
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    • v.19 no.5
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    • pp.659-664
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    • 2012
  • The fermentation and quality characteristics of Cheonggukjang with Chinese cabbage, which is produced as a by-product in the kimchi industry, were investigated. Cheonggukjang was prepared with cooked soybean without Chinese cabbage (control), with 10% Chinese cabbage (A10), and with 20% Chinese cabbage (A20), respectively. The A10 and A20 pH values did not show a significant difference compared with the control during fermentation for 72 h. The total aerobes of the Cheonggukjangs reached 8.65 (control), 8.73 (A10), and 9.11 (A20) log CFU/mL after fermentation for 72 h at $37^{\circ}C$, respectively. The numbers of lactic acid bacteria were found to be 5.62 (A10) and 5.87 (A20) log CFU/mL during fermentation for 72 h at $37^{\circ}C$, but lactic acid bacteria were not detected in the control. The amino nitrogen and viscous substance contents of A10 and A20 were lower than those of the control. The total polyphenol contents and DPPH radical scavenging abilities of the tested Cheonggukjang were increased by fermentation. The increasing ratio of polyphenol and the DPPH radical scavenging ability of A10 were higher than those of the control and of A20. The sensory quality of A10 was higher than that of the control and of A20 in taste, color, and overall acceptability.

The Reactivity and Regiochemical Effect of Nitrosonium Species in the Nitrosation of N-Methyl-N'-Substituted Phenylureas (N-메틸-N'-치환페닐우레아화합물들의 니트로소화 반응에 있어서 니트로소화 화학종의 반응성 및 위치화학적 영향)

  • Jack C. Kim;In-Seop Cho;Soon-Kyu Choi
    • Journal of the Korean Chemical Society
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    • v.35 no.3
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    • pp.240-248
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    • 1991
  • The regioselectivity in the nitrosation of seven N-methyl-N'-substituted phenylureas ($CH_3NHCONHC_6H_4-G$; G = H, p-CH$_3$, m-CH$_3$, m-CH$_3$O, p-F, m-F, m-Br) was examined using NaNO$_2$ and 4 different acids (diluted HCl, HCOOH, CH$_3$COOH, CF$_3$COOH). In all cases, the two regioisomeric products, N-nitroso-N-methyl-N'-substituted phenylureas (A) and N'-nitroso-N-methyl-N'-substituted phenylureas (B) were observed to be formed as major products and product ratios were determined by the integration of their methyl peaks in $^1$H-NMR. Electron donating substitutent(G) on phenyl of the ureas generally led to increase the ratio of B to A. The data have revealed that the relative sensitivity of the nitrosonium species (HONO, HCOONO, CH$_3$COONO, CF$_3$COONO) toward the change of electron density on nitrogen with phenyl substitutents are 1.00 : 0.93 : 0.78 : > ∼ 0.7.

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