• 한국표면공학회지
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• 제29권5호
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• pp.498-504
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• 1996

The synthesis of carbon nitride thin films with high nitrgen concentration was accomplished by reactive supttering at relatively high working pressure. In conventional reactive sputter-deposition of carbon nitride films, working pressure was 0.3-5Pa and the ratio of nitrogen to carbon(N/C ratio) in the films was less than 0.5. In this study, amorphous carbon nitride films with the N/C ratio $\tickapprox$ 1.0 were prepared on Si(100). substrates at higher pressure, 20-60 Pa. Structural analyses with Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy revealed that the films prepared consisted of triazine-like plain network.

• 환경생물
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• 제31권4호
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• pp.383-392
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• 2013

본 연구는 식물성 플랑크톤의 1차 생산력에 대한 N:P ratio의 영향을 분석하기 위해 "영양염 첨가실험(NEBs)"을 실시하였다. 영양염 첨가실험(NEBs)에 의한 N:P Ratio의 영향은 대청호에서 측정된 수질데이터와 비교분석하였다. 단기 영양염 첨가실험 결과, 인 (P)을 첨가한 처리군들 (N:P Ratio=5, 15, 20, 30)에서의 1차 생산력의 반응이 대조군 (Control)과 인(P)을 첨가한 처리군 (N:P Ratio=80, $T_V$), 질소(N)를 첨가한 처리군(N:P Ratio=150, $T_{VI}$)에서보다 높았다. 또한 질소 (N)를 처리한 처리군에서는 대조군과 모든 처리군에서보다 1차 생산력의 반응이 유의하게 작았다. 영양염 첨가실험의 결과, 식물성 플랑크톤의 성장에 인이 제한영양염으로 작용하고 있었으며, 질소첨가 (Spiking N)는 식물성 플랑크톤의 성장을 억제한 것으로 사료된다. 대청호의 영양염 변이 분석 결과, 최소 N:P Ratio에서 엽록소-a의 최대농도가 나타났고, N:P Ratio는 식물성 플랑크톤의 성장에 대한 핵심 조절자로 사료되었다. 본 연구결과를 종합해 볼 때, N:P Ratio가 식물성 플랑크톤의 성장을 조절하는 핵심 인자로 작용 할 것으로 사료된다.

• Asian-Australasian Journal of Animal Sciences
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• 제30권6호
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• pp.797-803
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• 2017

Objective: Effects of nitrogen supplementation associated with different levels of starch on voluntary intake, digestibility, and rumen and metabolic characteristics of cattle fed low-quality tropical forage (Brachiaria decumbens hay, 7.4% crude protein, CP) were evaluated using ruminal and abomasal cannulated steers. Methods: Five European${\times}$Zebu young bulls (186 kg body weight, BW) were distributed according to a $5{\times}5$ Latin square. The following treatments were evaluated: control, supplementation with 300 g CP/d (0:1), supplementation with 300 g starch/d and 300 g CP/d (1:1), supplementation with 600 g starch/d and 300 g CP/d (2:1), and supplementation with 900 g starch/d and 300 g CP/d (3:1). A mixture of nitrogenous compounds provided 1/3 from true protein (casein) and 2/3 from non-protein nitrogen (mixture of urea and ammonium sulphate, 9:1) was used as the nitrogen supplement. In order to supply energy a unique source of corn starch was used. Results: Supplements increased (p<0.05) dry matter intake, but did not affect (p>0.05) forage intake. There was a cubic effect (p<0.05) of starch on voluntary intake. This was attributed to the highest forage intake (g/kg BW) when using the 2:1 starch:CP ratio. Supplements increased (p<0.05) organic matter (OM) digestibility, but did not affect (p>0.05) neutral detergent fibre corrected for ash and protein (NDFap) digestibility. There was a positive linear effect (p<0.05) of the amount of starch supplemented on OM digestibility. Total NDFap digestibility was not affected (p>0.05) by the amount of supplemental starch. Ruminal ammonia nitrogen concentrations were higher (p<0.05) in supplemented animals, however, a negative linear effect (p<0.05) of amount of starch was observed. Supplements increased (p<0.05) the nitrogen balance (NB) and efficiency of nitrogen utilization. These effects were attributed to increased body anabolism, supported by higher (p<0.05) serum concentration of insulin-like growth factor 1. Increasing the amount of starch tended (p<0.06) to linearly increase the NB. In spite of this, there was a highest NB value for the 2:1 starch:CP ratio amongst the treatments with supplementation. Conclusion: Nitrogen supplementation in cattle fed low-quality tropical forage increases nitrogen retention in the animal's body. An additional supply of starch increases nitrogen retention by increasing energy availability for both rumen and animal metabolism.

• 한국작물학회지
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• 제35권6호
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• pp.497-503
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• 1990

질소와 가리 시용량이 버어리종 잎담배(1988년; Burley 21, 1989년 ; Burley 21과 KB 101)의 생육, 수량 및 품질에 미치는 영향을 알아보기 위하여 질소 3수준(1988년 ; 17.5, 22.75, 28.0kg/10a, 1989년 ; 12.5, 17.5, 22.5kg/10a), 가리 3수준(1988년 ; 17.5, 35.0, 52.5kg/10a, 1989년 ; 25.0, 35.0, 45.0kg/10a)을 두어 포장에서 시험한 바, 그 결과를 요약하면 다음과 같다. 1. 적심기 생육에 미치는 질소 시용량의 영향은 년차간 변이가 큰 것으로 나타났으며 가리시용량은 적심기 생육에 별다른 영향을 미치지 않았다. 2. 질소나 가리 시용량이 생육기간중의 엽중 질소함량에는 비교적 큰 영향을 미쳤으나 가리함량에 미치는 영향은 비교적 작았다. 3. Burley 21에 비하여 KB 101이 다수성이었으며, 질소감비상태에서의 생산성도 높았다. 4. 질소를 22.75kg/10a까지 시용할 때는 수량과 품질이 높아졌으나, 그 이상 시용할때는 수량은 증가되지 않고 품질은 낮아졌다. 5. 가리시용량이나 가리/질소 시용비에 따른 수량, 품질 차이는 크지 않았으나, 가리/질소 시용비가 작을 때는 품질이 다소 낮아졌다 6. 질소시용량이 22.75kg/10a을 초과할 때, 잎담배 수량 및 품질면에서 유리한 점은 없었으며, 가리시용량은 35.0kg/10a이면 충분하며 그 이하로의 감비도 여지가 있을 것으로 생각된다.

• 한국초지조사료학회지
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• 제16권3호
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• pp.199-207
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• 1996

This experiment was canied out to determine the effects of seeding method and seeding ratio in mixed cropping of forage rye and red clover on dry matter yield, nutritional yield and chemical characteristics of soil. The main treatment was two seeding methods(drilling and broadcasting) and the sub treatment was six seeding ratios between rye and red clover(T1; 150kg : 0 kg/ha, T2; 120 : 3, T3; 90 : 6, T4; 60 : 9, T5; 30 : 12, T6; 0 : 15). The experiment was performed at the College of Natural Science of Kon-Kuk University in Chungju in 1992. The results were summarized as follows; 1. Protein content was increased by increasing the seeding ratio of red clover, but content of NDF and ADF were decreased. 2. The seeding method did not affects significantly the dry matter yield, but broadcasting showed higher dry matter yield than drilling in the same seeding ratio. Especially, T3 of broadcasting was the highest yield of 13, 172 kg/ha The T3 of broadcasting and T4 of drilling showed hlghly crude protein yield of 1, 268 kgha and 1, 252 kg/ha, respectively. 3. Comparing the each seeding ratio of two seeding method, total nitrogen yield of shoot and root of drilling were higher than broadcasting. Especially, T2 and T4 of drilling were the highest in total nitrogen yield. 4. There were more increase in organic matter and nitrogen contents but decrease in K, Ca of soil by increasing the seeding ratio of red clover than soil before experiment. In the seeding methods, broadcasting was an effect of soil improvement.

• 약학회지
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• 제4권1호
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• pp.14-16
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• 1959

In order to confirm the biochemical process of the fermentation from soybean to maiju and of the fermentation from maiju to kanjang and dainjang, the introgen distributions of soybean, maiju, kanjang, and dainjang are studied on protein nitrogen, peptide nitrogen, amino nitrogen and volatile nitrogen. And the contents of amino nitrogen, peptide nitrogen, and true protein nitrogen to the total nitroge of soybean, maiju, kanjang, and dainjang are shown in table 1 and the ratios are shown in table 2 and the figure. According to the results indicated in the tables and figure, the following conclusions are summerized. 1. The main biochemical process at the fermentation from soybean to maiju would be the degradation from protein in soybean to peptide compounds in maiju. 2. The main biochemical process at the fermentation from maiju to kanjang and dainjand would be the degradation from peptide compounds in maiju to amino nitrogen compounds in kanjang and dainjang. 3. However bacause the protein nitrogen indicated as the ratio of protein nitrogen to total nitrogen is contained still higher content in dainjang. It is assumed that there might be two kinds of proteins in soybean one is the protein which could be converted to peptides at the maiju fermentation and to amino nitrogen compounds lastly at the kanjang fermentation. The other is the protein which would not be effected at these fermentation at all remaining as the protein nitrogen in dainjang. One of the finished products. 4. It can be indicated that the process from maiju to kanjang and dainjang would be due to the fermentation as indicated by HAW and CHOI.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.163.2-163.2
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• 2010

We developed a simple method to synthesis a nitrogen doped graphene, nitrogen plasma treated graphene (NPG) sheets thought nitrogen plasma etching of graphene oxide (GO). X-ray photo electron spectroscopy (XPS) study of NPG sheets treated at various plasma conditions reveal that N-doping is classified to 3 kinds of binding configurations. The nitrogen doping concentration is at least 1.5 at % and up to 3 at% with changing of ratio of nitrogen configuration in NPG. Our group demonstrate ultracapacitor with high capacity and extremely durable using a NPG sheets that are comparable to pristine graphene supercapacitor, and pseudocapacitor using polymer and metal oxide with redox reaction, capacitance that are three-times higher, and a cycle life that are extremely stable. We also realized flexible capacitor by using the paper electrode that are coated by NPG sheets. NPG paper capacitor presented almost same performance compare with NPG on a metal substrate, and durability is much more enhanced than that. To additionally explain that how different kind of atoms in graphene layers can act as the ion absorption sites, we simulated the binding energy between nitrogen in graphene layer and ions in electrolyte. Increasing the energy density and long cycle life of ultracapacitor will enable them to compete with batteries and conventional capacitors in number of applications.

• 한국환경보건학회지
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• 제16권2호
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• pp.31-39
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• 1990

An analytical method for particulate carbon and other elements by using elemental analyzer was investigated. Carbon, hydrogen, and nitrogen was determined as CO$_{2}$, H$_{2}$, and N$_{2}$, respectively. Organic was determined after scparation from elemental carbon(Cae) by volatilization and thermal decomposition in a heated helium flow. With organic materials examined in this reprot, more than 90% of carbon was detected as above 600$^{\circ}$C. But it is considered that a few percents of some compounds were charred above 550$^{\circ}$C. A small amount of Cae was oxidized in the inert atmosphere above 850$^{\circ}$C, but the reason was not explained clearly. Based on the thermal chracteristics of Cao it was found that the optimum temperature of heating in the helium flow of an elemental analyzer for Cao analysis is 630$^{\circ}$C. Carbon in a sample after removing Cao was assumed as Cae and the gramatom ratio of hydrogen to carbon in the sample was 0.4 and less. Rescovery of nitrogen derived from some ammonium salts and nitrates was 100% by two-step measurement with elemental analyzer. By the analytical method investigated in this report, carbon and other elements in suspended particulates(S.P) collected at an urban area in Seoul were measured. There was a good correlation between total nitrogen in SP measured by elemental analyzer and nitrogen estimated form ammonium ions and nitrate ions in SP. The nitrogen from these ions accounts for 80% of the total nitrogen. It is further suggested that the residue(20%) of the total nitrogen is attributed to the other nitrogeneous compounds.

• 한국유기농업학회지
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• 제25권4호
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• pp.805-819
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• 2017

The study was carried out to develop a mathematical model for evaluating the effect of organic fertilizers in organic rice production systems. A function to simulate the nitrogen mineralization process in the paddy soil has been developed and integrated into ORYZA2000 crop growth model. Inorganic nitrogen in the soil was estimated by single exponential models, given temperature and C:N ratio of organic amendments. Data collected from the two-year field experiment were used to evaluate the performance of the model. The revised version of ORYZA2000 provided reasonable estimates of key variables for nitrogen dynamics and crop growth in the organic rice production systems. Coefficient of determination between the measured value and simulated value were 0.6613, 0.8938, and 0.8092, respectively for soil inorganic nitrogen, total dry matter production, and rice yield. This means that the model could be used to quantify nitrogen supplying capacity of organic fertilizers relative to chemical fertilizer. Nitrogen dynamics and rice growth simulated by the model would be useful information to make decision for organic fertilization in organic rice production systems.

• 한국진공학회지
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• 제8권2호
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• pp.165-171
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• 1999

Diamond-like carbon(DLC) films were synthesized using the rf-plasma CVD technique with the addition of small amounts of nitrogen and oxygen to a gas mixture of $CH_4$ and $H_2$. The gas flow ratio of $CH_4$ to $H_2$ was 2.4:1, and 3% , 13.6% of nitrogen were added to the gas mixture of $CH_4$ and $H_2$ for the deposition of DLC films. The film stress tended to decrease as the nitrogen concentration increased from 3% to 13.6%, probably due to the decrease of the number of the interlink between carbon atoms. The residual stress tended to slightly decrease when 3% of oxygen was added. Scratch tests were performed to investigate the adhesion between the DLC films and the Ti intelayer after pretreating the TiN surface with direct hydrogen plasma. The adhesion was enhanced by adding nitrogen and oxygen to the $CH_4$ and $H_2$ gas mixture. The adhesion for the 3% nitrogen addition was better than that for the 13.6% nitrogen addition. The Vicker's hardness of the DLC films was measured to be 1100Hv.