• Title/Summary/Keyword: nitrogen oxide(NOx)

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An Study on Estimating Cargo Handling Equipment Emission in the Port of Incheon (인천항 하역장비 대기오염물질 배출량 산정 연구)

  • Zhao, Ting-Ting;Pham, Thai-Hoang;Lee, Hyang-Sook
    • Journal of Korea Port Economic Association
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    • v.36 no.3
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    • pp.21-38
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    • 2020
  • Currently, in-port emissions are a serious problem in port cities. However, emissions, especially non-greenhouse gases, from the operation of cargo handling equipment (CHE) have received significant attention from scientific circles. This study estimates the amount of emissions from on-land port diesel-powered CHE in the Port of Incheon. With real-time activity data provided by handling equipment operating companies, this research applies an activity-based approach to capture an up-to-date and reliable diesel-powered CHE emissions inventory during 2017. As a result, 105.6 tons of carbon monoxide (CO), 243.2 tons of nitrogen oxide (NOx), 0.005 tons of sulfur oxide (Sox), 22.8 tons of particulate matter (PM), 26.0 tons of volatile organic compounds (VOCs), and 0.2 tons of ammonia (NH3) were released from the landside CHE operation. CO and NOx emissions are the two primary air pollutants from the CHE operation in the Port of Incheon, contributing 87.71% of the total amount of emissions. Cranes, forklifts, tractors, and loaders are the four major sources of pollution in the Port of Incheon, contributing 84.79% of the total in-port CHE emissions. Backward diesel-powered machines equipped in these CHE are identified as a key cause of pollution. Therefore, this estimation emphasizes the significant contribution of diesel CHE to port air pollution and suggests the following green policies should be applied: (1) replacement of old diesel powered CHE by new liquefied natural gas and electric equipment; (2) the use of NOx reduction after-treatment technologies, such as selective catalytic reduction in local ports. In addition, a systematic official national emission inventory preparation method and consecutive annual in-port CHE emission inventories are recommended to compare and evaluate the effectiveness of green policies conducted in the future.

Effect of EGR on power and exhaust emissions in diesel engine (디젤엔진의 출력 및 배기가스에 미치는 EGR의 영향)

  • Song, Kyu-keun
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.9
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    • pp.870-875
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    • 2015
  • Diesel engines are widely used due to superior power and fuel consumption, however there are many challenges in exhaust gas management. Exhaust gas recirculation (EGR) is the most effective technique for reducing mono-nitrogen oxide (NOx) emissions in a diesel engine, in comparison with other catalytic technologies. In addition, the technology has a number of advantages in terms of economic efficiency and implementation. In this study, the effects on the power and exhaust characteristics of diesel engines equipped with EGR systems were investigated. It was found that as the EGR rate increased, horsepower expressed as IHP and BHP decreased. The net effect of the application of EGR was measured at various engine speeds. EGR technology caused decreases in BHP of around 9% during low engine speed and 3.5% during high engine speed. Additionally, NOx emissions reduced as the EGR rate increased, and increased as engine speed increased. However, smoke emissions increased as the EGR rate increased, and decreased as engine speed increased. The optimum operating conditions and ERG rate to simultaneously achieve minimum NOx and smoke emissions were investigate. It was found that as the EGR rate increased, optimal operating speed for minimal NOx and smoke also increased. Keywords: Diesel engine, Exhaust gas recirculation, Power perfomance, Emission characteristics, NOx, Smoke

A Reaction Kinetic for Selective Catalytic Reduction of NOx with NH3 over Manganese Oxide (NMO, MnO2, Mn2O3) at Low Temperature (망간산화물(NMO, MnO2, Mn2O3)을 이용한 저온에서의 NH3-SCR의 반응속도 연구)

  • Kim, Min Su;Hong, Sung Chang
    • Clean Technology
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    • v.24 no.4
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    • pp.307-314
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    • 2018
  • In this study, NMO (Natural Manganese Ore), $MnO_2$, and $Mn_2O_3$ catalysts were used in the selective catalytic reduction process to remove nitrogen oxides (NOx) using $NH_3$ as a reducing agent at low temperatures in the presence of oxygen. In the case of the NMO (Natural Manganese Ore), it was confirmed that the conversion of nitrogen oxides in the stability test did not change even after 100 hours at 423 K. The Kinetics experiments were carried out within the range where heat and mass transfer were not factors. From a steady-state Kinetics study, it was found that the low-temperature SCR reaction was zero order with the respect to $NH_3$ and 0.41 ~ 0.57 order with the respect to NO and 0.13 ~ 0.26 order with the respect to $O_2$. As temperature increases, the reaction order decreases as a result of $NH_3$ and oxygen concentration. It was confirmed that the reaction between the $NH_3$ dissociated and adsorbedon the catalyst surface and the gaseous nitrogen monoxide (E-R model) and the reaction with the adsorbed nitrogen monoxide (L-H model) occur.

Fundamental Study on Applying an Integral TiO2 Solution to Asphalt Pavement (1액형 광촉매를 아스팔트 포장에 적용하기 위한 기초연구)

  • Park, Jaeyoung;Kim, Young;Kim, Hyeok-Jung;Hwang, Yong-Kyung;Lee, Jaejun
    • International Journal of Highway Engineering
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    • v.19 no.1
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    • pp.53-62
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    • 2017
  • PURPOSES : This research was a fundamental study on the application of an integral $TiO_2$ solution to asphalt concrete pavement. The integral $TiO_2$ solution was produced in pilot production equipment; application of the integral $TiO_2$ solution to asphalt pavement was conducted to examine the pollution-reducing capability of photocatalytic compounds such as $TiO_2$. The photocatalytic $TiO_2$ reacted with air pollutants, converting them into small amounts of relatively benign molecules. METHODS : In this study, laboratory experiments were conducted using five various testing methods. Tensile strength ratio (TSR) and British pendulum test (BPT) were conducted in order to evaluate the properties of asphalt pavement subsequent to the integral $TiO_2$ solution coating. In addition, methylene blue testing, a measurement of nitrate on the coated pavement, and nitrogen oxide (NOx) reduction testing were conducted in order to evaluate photocatalytic reaction. Lastly, a UV-A lamp was used as a light source for photocatalytic reactions. RESULTS : Test results indicated no change in the properties of asphalt pavement following the integral $TiO_2$ solution coating. In order to evaluate the performance of asphalt pavement as a function of $TiO_2$, the moisture susceptibility and skid resistance were investigated. The moisture susceptibility and skid resistance satisfied there quirements related to pavement quality and safety specification. Furthermore, the effects of reduction of air pollution were significantly improved as determined via the methylene blue test and NOx reduction test. The $TiO_2$-paved asphalt specimen exhibited approximately 43% reduction of NOx. CONCLUSIONS : This study has suggested that applying $TiO_2$ rarely impacts asphalt pavement performance measures such as moisture susceptibility and skid resistance, and that its application may be a better means of reducing air pollution. Further studies, such as proper $TiO_2$ dosage rates and compatibility with various pavement types, are required to broaden and generalize its application.

Study on NOx Reduction with Multi-Perforated Tube Geometry in Integrated Urea-SCR Muffler (촉매삽입형 Urea-SCR 머플러 다공튜브 형상변화에 따른 NOx 저감 특성에 관한 연구)

  • Moon, Namsoo;Lee, Sangkyoo;Ko, Sangchul;Lee, Jeekeun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.12
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    • pp.1017-1026
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    • 2014
  • A multi-perforated tube is generally installed between the muffler inlet and in front of selective catalytic reduction (SCR) catalysts in the integrated urea-SCR muffler system in order to disperse the urea-water solution spray uniformly and to make better use of the SCR catalyst, which would result in an increase nitrogen oxide ($NO_x$) reduction efficiency and a decrease in the ammonia slip. The effects of the multi-perforated tube orifice area ratios on the internal flow characteristics were investigated analytically by using a general-purpose commercial software package. From the results, it was clarified that the multi-perforated tube geometry sensitively affected the generation of the bulk swirling motion inside the plenum chamber set in front of the SCR catalyst and to the uniformity index of the velocity distribution produced at the inlet of the catalyst. To verify the analytical results, engine tests were carried out in the ESC and ETC modes. Results of these tests indicated that the larger flow model in the longitudinal direction showed the highest NOx reduction efficiency, which was a good agreement with the analytical results.

Emissions of Marine Heavy Fuel Oil in the Spray Flame

  • An, Suk-Heon
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.7
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    • pp.1030-1035
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    • 2008
  • Recently, the International Maritime Organization makes an effort for an effective solution against the emissions from shipping in the international maritime industry. The objective of the study was to quantify the exhaust emissions of marine heavy fuel oil in the combustion process of the spray flame. An experiment was performed to measure CO, $CO_2$, NOx, $SO_2$, ${N_2}O$, DS, SOF and the other components with the flame temperature. The sampling probe was directly set up in the flame fields at each position of 103, 324, 545, 766 and 987mm vertically apart from the fuel-injected nozzle in the burner furnace. From the results of the study, it was estimated that approximately 270ppm of oxides of nitrogen (NOx), $1000{\sim}1400ppm$ of sulfur dioxide ($SO_2$), 8ppm of nitrous oxide (${N_2}O$), $2.0{\sim}2.5g/m^3$ of particulate matter (PM) divided with dry soot (DS) and soluble organic fraction (SOF) and $60{\sim}80mg/m^3$ of sulfuric acid. With respect to further development of this work, the emission quantification could also be applied to assessing emission reduction from the international shipping.

Hybrid artificial bee colony-grey wolf algorithm for multi-objective engine optimization of converted plug-in hybrid electric vehicle

  • Gujarathi, Pritam K.;Shah, Varsha A.;Lokhande, Makarand M.
    • Advances in Energy Research
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    • v.7 no.1
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    • pp.35-52
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    • 2020
  • The paper proposes a hybrid approach of artificial bee colony (ABC) and grey wolf optimizer (GWO) algorithm for multi-objective and multidimensional engine optimization of a converted plug-in hybrid electric vehicle. The proposed strategy is used to optimize all emissions along with brake specific fuel consumption (FC) for converted parallel operated diesel plug-in hybrid electric vehicle (PHEV). All emissions particulate matter (PM), nitrogen oxide (NOx), carbon monoxide (CO) and hydrocarbon (HC) are considered as optimization parameters with weighted factors. 70 hp engine data of NOx, PM, HC, CO and FC obtained from Oak Ridge National Laboratory is used for the study. The algorithm is initialized with feasible solutions followed by the employee bee phase of artificial bee colony algorithm to provide exploitation. Onlooker and scout bee phase is replaced by GWO algorithm to provide exploration. MATLAB program is used for simulation. Hybrid ABC-GWO algorithm developed is tested extensively for various values of speeds and torque. The optimization performance and its environmental impact are discussed in detail. The optimization results obtained are verified by real data engine maps. It is also compared with modified ABC and GWO algorithm for checking the effectiveness of proposed algorithm. Hybrid ABC-GWO offers combine benefits of ABC and GWO by reducing computational load and complexity with less computation time providing a balance of exploitation and exploration and passes repeatability towards use for real-time optimization.

An Experimental and Numerical Study on the Oxy-MILD Combustion at Pilot Scale Heating Capacity (Pilot급 산소 MILD 연소에 관한 실험 및 수치해석적 연구)

  • Cha, Chun-Loon;Lee, Ho-Yeon;Hwang, Sang-Soon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.28 no.7
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    • pp.275-282
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    • 2016
  • MILD (Moderate and Intense Low-oxygen Dilution) combustion using oxygen as an oxidizer is considered as one of the most promising combustion technologies for high energy efficiency and for reducing nitrogen oxide and carbon dioxide emissions. In order to investigate the effects of nozzle angle and oxygen velocity conditions on the formation of oxygen-MILD combustion, numerical and experimental approaches were performed in this study. The numerical results showed that the recirculation ratio ($K_V$), which is an important parameter for performing MILD combustion, was increased in the main reaction zone when the nozzle angle was changed from 0 degrees to 15 degrees. Also, it was observed that a low and uniform temperature distribution was achieved at an oxygen velocity of 400 m/s. The perfectly invisible oxy-MILD flame was observed experimentally under the condition of a nozzle angle of $10^{\circ}$ and an oxygen velocity of 400 m/s. Moreover, the NOx emission limit was satisfied with NOx regulation of less than 80 ppm.

A Study for Development of a Marine Diesel Engine from a 500Ps Commercial Vehicle Diesel Engine (500Ps급 상용차량 디젤엔진을 이용한 선박용 디젤엔진 개발 연구)

  • Sim, Han-Sub
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.12 no.6
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    • pp.125-131
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    • 2013
  • This study was carried out to develop a diesel engine for marine propulsion. This marine diesel engine was developed based on a 500Ps vehicle diesel engine. Many main parts, such as the intercooler, radiator, and engine controller were designed for the marine diesel engine. The intercooler was designed to be of sea water cooling type; inlet air is cooled by sea water. Engine coolant is cooled by sea water in the radiator too. The water cooling heat exchanger has high cooling performance. In the cooling system, consists of the intercooler and the radiator, the sea water passes through the intercooler and then the radiator, in sequence. This process is very effective compared to the reverse method in which sea water passes through the radiator and then the intercooler, in sequence. The control performance of the engine controller and the fuel injection rate were improved using an engine speed controller. This system was tested on an engine dynamometer and an exhaust gas analyzer using the marine diesel engine test method. Test results show that the 500Ps marine diesel engine satisfied the IMO NOx regulations; Tier II.

Effect of EGR and Supercharging on the Diesel HCCI Combustion (디젤 예혼합 압축착화 엔진에서 배기가스 재순환과 과급의 영향)

  • Park, Se-Ik;Kook, Sang-Hoon;Bae, Choong-Sik;Kim, Jang-Heon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.5
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    • pp.58-64
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    • 2006
  • Homogeneous charge compression ignition(HCCI) combustion is an advanced technique for reducing the hazardous nitrogen oxide(NOx) and particulate matter(PM) in a diesel engine. NOx could be reduced by achieving lean homogeneous mixture resulting in combustion temperature. PM could be also reduced by eliminating fuel-rich zones which exist in conventional diesel combustion. However previous researches have reported that power-output of HCCI engine is limited by the high intensive knock and misfiring. In an attempt to extend the upper load limit for HCCI operation, supercharging in combination with Exhaust Gas Recirculation(EGR) has been applied: supercharging to increase the power density and EGR to control the combustion phase. The test was performed in a single cylinder engine operated at 1200 rpm. Boost pressures of 1.1 and 1.2 bar were applied. High EGR rates up to 45% were supplied. Most of fuel was injected at early timing to make homogeneous mixture. Small amount of fuel injection was followed near TDC to assist ignition. Results showed increasing boost pressure resulted in much higher power-output. Optimal EGR rate influenced by longer ignition delay and charge dilution simultaneously was observed.