• Progress in Superconductivity and Cryogenics
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• v.4 no.1
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• pp.145-150
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• 2002

The distillation column is one of large energy consumable units in the cryogenic air separation process and the accurate energy analysis of this unit is necessary for choice of energy saving process. In this work, the energy method was adopted for energy analysis of a cryogenic nitrogen distillation column. In order to designing the energy saving distillation column, the exergy distribution of feed air, exergy efficiency and exergy loss for process condition was investigated and the optimal process condition to minimize the exergy loss was found. The result from this work can be used as a guideline for the choice of the process design conditions and efficiency improvement of cryogenic distillation column.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.08a
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• pp.64-68
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• 2002

According to the increasing power demand for the future construction of many underground cables will be required. However, construction of new ducts for power cables will be more difficult. Therefore, research work for realizing the high temperature superconducting(HTS) cable has advanced, where the development of electrical insulating system at cryogenic temperature is one of the major researches. For an electrical insulation design of HTS cable, it is important to understand not only breakdown but also partial discharge and dielectric loss($tan{\delta}$) in liquid nitrogen/paper composite insulation system. In this paper, we investigated breakdown characteristics in liquid nitrogen/paper composite insulation system for the application to HTS cable. And, we studied the breakdown characteristics of the multi-layer and butt gap of the insulation papers in liquid nitrogen. Also, we measured dielectric loss($tan{\delta}$) of the mini-model Cable made of TERLAM IPP.

• The Korean Journal of Ecology
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• v.17 no.3
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• pp.311-318
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• 1994

We examined spatial and temporal patterns of root decomposition for three and half years, from October 1986 to April 1990, in semi-arid Chihuahuan Desert. Decomposition of roots occurred in a two-phased pattern: an early period of rapid mass loss followed by a period of slower loss. The rate of root decomposition had a high negative correlation with the initial lignin concentration in roots (r=-0.84, p<0.05). Annual mass loss rate of Baileya multiradiata, a herbaceous annual, was the highest with the value of 0.60, while that of Panicum obtusum. a perennial grass which was restricted to playa, was the lowest with 0.13. The mass loss rate of roots in the playa was the lowest among the vegetation zones along the transect. After 42 months elapsed, fluffgrass roots in playa lost 40% of the initial mass, while in other sites it lost on average 55% of the initial mass. In all roots except for desert marigold, there was an initial release of nitrogen early in decomposition followed by net nitrogen immobilization. Nitrogen concentration of the desert marigold roots showed linear increase from the beginning. Lignin concentration of perennial grass roots were higher than those of herbaceous annual and woody perennial root.

• Korean Journal of Environmental Agriculture
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• v.3 no.1
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• pp.57-62
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• 1984

Laboratory experiments of poultry manure incubated for three days at $35^{\circ}$ were conducted to learn some informations on the relief of nitrogen loss during processing. Results obtained are as follows: 1) Blending phosphoric acid, triplesuperphosphate or superphosphate to poultry manure could reduce the volatilization of ammonia and saved nitrogen in the manure by 80 to 90 percent, though nonblending saved the nitrogen only by 40 to 60 percent during three days incubation. 2) The additives must be blended thoroughly to the manure to obtain the least loss of nitrogen during the incubation. 3) The severe loss of nitrogen was occurred from the drying process of fermented manure of both treatment, that is $60{\sim}80$ percent loss at the blended treatment with phosphoric acid, triplesuperphosphate or superphosphate, and $70{\sim}90$ percent loss at non-blended. 4) Drying the fermented manure under the fixed temperature of about $65^{\circ}$ for three days saved more nitrogen than dried manure under the temperature gradually raised from the room temperature to about $45{\sim}65^{\circ}$ for three days.

• Korean Journal of Soil Science and Fertilizer
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• v.33 no.5
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• pp.347-355
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• 2000

To determine nitrogen balance (Input-Output) of Korea that was asked by Joint Working Party of the Committee for Agriculture and the Environment Policy Committee, OECD, nitrogen input and output were separately investigated as followings: nitrogen input included the amounts of chemical fertilizer consumption, cattle manure production, and biological nitrogen fixation in the national scale, and nitrogen output summed amounts withdrawn by crop and pasture harvesting, and crop residue removal, and lost by denitrification. In 1997, nitrogen balance of Korea was $158kg\;ha^{-1}$ and $211kg\;ha^{-1}$ on including and excluding denitrification loss, respectively. N balance excluded N loss by denitrification and N withdrawal by crop residues on nitrogen output was $250kg\;ha^{-1}$, which OECD asked to except two items from N balance determination because participants were not enough their data. Nitrogen balance was increased to 1.7~2.3 times in 1997 compared with 70 and $162kg\;ha^{-1}$ in 1985, which calculated on the condition of including denitrification and excluding denitrification and removal of crop residues in nitrogen output, respectively. This increase was caused mainly by increasing livestock manure production and chemical fertilizer consumption together with agricultural land area decrease. Nitrogen input was composed with 59% of chemical fertilizer. 42% of cattle manure and 5% of others in 1997, and output was with 73% of crop production, 23% of crop residue withdrawal and 4% of pasture production. Average nitrogen balance excluded N loss by denitrification and N withdrawals by crop residues in 1995~1997 calculated by OECD was $253kg\;ha^{-1}$, which was the second highest rank in OECD participants following $262kg\;ha^{-1}$ of Netherlands. Japanese N balance that has similar farming system with us was $135kg\;ha^{-1}$.

• Applied Biological Chemistry
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• v.43 no.2
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• pp.124-129
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• 2000

Nitrogen and P in surface runoff and eroded sediment from cropland areas can contaminate streams and lakes. Runoff losses of N and P were determined in a small field plot $(14.3{\times}24.8\;m)$ of peach orchard from March to November in 1999. Nitrogen and P were applied in the rate of 172 and 46 kg/ha using chemical fertilizer and mixed oil cake fertilizer. During the season, in 26 rainfall events, $421.5\;m^3/ha$ of runoff including 1,989 kg/ha of soil loss was collected. Concentrations of total-N, $NO_3-N$, $NH_4-N$, total-P and $PO_4-P$ in runoff samples were in the range of $4.7{\sim}171.0,\;0.1{\sim}188.0,\;0.13{\sim}3.36$, $0.58{\sim}4.99$ and $0.05{\sim}3.71\;mg/l$, respectively. Total loss of N was 16.39 kg/ha and 75% of the loss was $NO_3-N$. Total loss of P was 1.04 kg/ha, and $PO_4-P$ and sediment bound P accounted for 47 and 27% of the total loss, respectively. The losses of N and P were about 9.5 and 2.3% of the applied N and P in the plot, respectively. Although the loss of N or P would be relatively small in agricultural aspect, considering the high concentrations of N and P in runoff, loss of N and P from croplands should be controlled to reduce the eutrophication problem of stream waters.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.44 no.3
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• pp.230-235
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• 1999

To study the effects of an urease inhibitor, N-(n-butyl)-thiophosphoric triamide (NBPT), and a nitrification inhibitor, dicyandiamide (DCD), on nitrogen losses and nitrogen use efficiency, urea fertilizer with or without inhibitors and slowrelease fertilizer (synthetic thermoplastic resins coated urea) were applied to direct-seeded flooded rice fields in 1998. In the urea and the urea+DCD treatments, NH$_4$$^{+}$ -N concentrations reached 50 mg N L$^{-1}$ after application. Urea+NBPT and urea+ NBPT+DCD treatments maintained NH$_4$$^{+}$ -N concentrations below 10 mg N L$^{-1}$ in the floodwater, while the slow-release fertilizer application maintained the lowest concentration of NH$_4$$^{+}$ -N in floodwater. The ammonia losses of urea+NBPT and urea+NBPT+DCD treatments were lower than those of urea and urea+DCD treatments during the 30 days after fertilizer application. It was found that N loss due to ammonia volatilization was minimized in the treatments of NBPT with urea and the slow-release fertilizer. The volatile loss of urea+DCD treatment was not significantly different from that of urea surface application. It was found that NBPT delayed urea hydrolysis and then decreased losses due to ammonia volatilization. DCD, a nitrification inhibitor, had no significant effect on ammonia loss under flooded conditions. The slow-release fertilizer application reduced ammonia volatilization loss most effectively. As N0$_3$$^{[-10]}$ -N concentrations in the soil water indicated that leaching losses of N were negligible, DCD was not effective in inhibiting nitrification in the flooded soil. The amount of N in plants was especially low in the slow-release fertilizer treatment during the early growth stage for 15 days after fertilization. The amount of N in the rice plants, however, was higher in the slow-release fertilizer treatment than in other treatments at harvest. Grain yields in the treatments of slow-release fertilizer, urea+NBPT+ DCD and urea+NBPT were significantly higher than those in the treatments of urea and urea+DCD. NBPT treatment with urea and the slow-release fertilizer application were effective in both reducing nitrogen losses and increasing grain yield by improving N use efficiency in direct-seeded flooded rice field.field.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.40 no.2
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• pp.157-166
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• 1995

The fate and use efficiency of applied nitrogen were evaluated in a pot experiment with different fertilizers and water management practices during 30days after fertilizer application. N-P-K compound fertilizers, 13-10-1l(F-l) for upland Crop use and 15-10-10(F-3) for rice Crop use, and mixed fertilizer, 21-17-17(F-2) for basal dressing in rice were used. Fertilizers corresponding to 1.8g N were mixed thoroughly with the whole volume of sandy loam soil in a pot. The pots were flooded upto 3cm above soil surface for O(0dF), 10(10dF), 20(20dF), and 30(30dF) days after fertilizer application and all the treatments were flooded continuously from 30 days after fertilizer application. During the flooding period water percolation rate was adjusted to 2.5mm/day. Rice seedlings were transplanted 40 days after fertilizer application. The pH of infiltrated water increased with increasing duration of flooding. The pH of F-2 was higher than those of F-1 and F-3 between which there were no differences. The applied nitrogen remained 23% in F-1, 29% in F-2, and 29.1 % in F-3, and 45.0% in 0dF, 26.6% in 10dF, 24.8% in 20dF, and 20.3% in 30dF as inorganic nitrogen at 63 days after fertilizer application. Nitrogen losses by leaching amounted to 51.3%, 32.1% and 48.1% of applied nitrogen in F-1, F-2 and F-3, respectively. Nitrogen leaching losses increased with increasing duration of flood- ing, amounting to 25.7%, 29.8%, 32.7%, and 35.8% in 0dF, 10dF, 20dF and 30dF, respectively. Gaseous loss of applied nitrogen was greatest in F-2, followed by F-1 and F-3. Total loss of nitrogen due to gaseous volatilization and leaching was greatest in F -1, followed by F -2 and F-3, and were greater in the treatments with longer flooding after fertilizer application. Nitrogen recovery by rice shoot until 72 days after transplanting were 23.2%, 24.7% and 27.4% of applied nitrogen in F-1, F-2 and F-3, respectively and 34.1%, 25.5%, 21.1%, and 21.2% in 0dF, 10dF, 20dF and 30dF, respectively.

• The Korean Journal of Ceramics
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• v.4 no.4
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• pp.279-285
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• 1998

The $UO_2$ pellets are usually sintered under hydrogen gas atmosphere. Hydrogen gas may cause unexpected early failure of the refractory bricks in the sintering furnace. In this work, nitrogen was mixed with hydrogen to investigate the effect of nitrogen gas on a failure machanism of the refractory bricks and on the microstructure of the $UO_2$ pellet. The hydrogen-nitrogen mixed gas experiments show that the larger nitrogen the mixed gas contains, the less the refractory materials are reduced by hydrogen. The weight loss measurements at $1400^{\circ}C$ for fire clay and chamotte refractories containing high content of $SiO_2$ indicate that the weight loss rate for the mixed gas is about half of that for the hydrogen gas. Based on the thermochemical analyses, it is proposed that the weight loss is caused by hydrogen-induced reduction of free $SiO_2$ and/or $SiO_2$ bonded to $Al_2O_3$ in the fire clay and chamotte refractories. However, the retardation of the hydrogen-induced $SiO_2$ reduction rate under the mixed gas atmosphere may be due to the reduction of the surface reaction rate between hydrogen gas and refractory materials in proportion to volume fraction of nitrogen gas in the mixed gas. On the other hand, the mixed gas experiments show that the test data for $UO_2$ pellet still meet the related specification values, even if there exists a slight difference in the pellet microstructural parameters between the cases of the mixed gas and the hydrogen gas.

• Journal of Surface Science and Engineering
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• v.27 no.1
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• pp.36-44
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• 1994

The TiN films were deposited on the stainless substrates using arc vapor ion deposition process to in-vestigated the wear resistance. Pin-on-disc tests were performed to measure the volume wear loss of TiN films. The substrate bias voltages and nitrogen flow rates were selected as the deposition parameters of TiN films. It was found that the wear resistance of TiN films was enhanced with increasing bias voltages(0~-300 V) and nitrogen flow rates(220~380 SCCM). The volume wear loss TiN films were about 9.5~2.1$\times$$10^{-3}mm^3$ and 3.5~2.2$\times$$10^{-3}mm^3$ with bias voltages and nitrogen flow rates, respectively.