• Title/Summary/Keyword: nitrogen gas

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A Study on Process Design of Hot Oil Flushing System Using Oil-Nitrogen Gas Mixing Fluid (오일-질소가스 혼합유체를 이용한 고온 오일플러싱 시스템 공정설계에 관한 연구)

  • Lee, Yoon-Ho;Choi, Bu-Hong
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.5
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    • pp.541-548
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    • 2017
  • A theoretical study on gas-liquid two-phase flow flushing systemnitrogen gas to the oil used for existing flushing equipment was conducted on the basis of ISO code so as to improve performance of existing high-temperature oil flushing equipment used in ocean plant facility drying field. For study, we analyzed process simulation results mixed fluid mixing ratio, temperature, Reynolds number and liquid hold up affectcleaning performance after designing oil-nitrogen gas mixture flushing system process. As a result, as the volume flow rate of mixed fluid increases with the tube diameter the volume fraction of the gas phase constant, the liquid fraction difference value at the inlet and outlet of horizontal hydraulic piping increases. It was found that the phase distribution between oil and nitrogen gas bubbles varies depending on the position the pipe lengthdirection. This change in phase distribution is expected to have a significant impact on the clean performance of an oil-nitrogen gas mixture flushing system.

Optical properties of Si thin films grown by PLD (PLD로 제작한 Si 박막에서의 광학적 특성분석)

  • 배상혁;이상렬
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.532-534
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    • 2000
  • Si thin films on p-type (100) Si substrate have been fabricated by pulsed laser deposition technique using a Nd:YAG laser. The pressure of the environmental gas during deposition was varied from 1 to 3 Torr. After deposition, Si thin film has been annealed again at nitrogen ambient. Strong violet-indigo photoluminescence have been observed from Si thin film annealed in nitrogen ambient gas. As increasing environmental gas pressure, weak green and red emissions from annealed Si thin films also observed by photoluminescence.

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Influence of intermixed gas on stable townsend discharge (안정 Townsend 방전에 대한 혼입가스의 영향)

  • 하성철
    • 전기의세계
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    • v.30 no.5
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    • pp.306-312
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    • 1981
  • The Townsend discharge domain is generally observed with stable positive characteristics in N$_{2}$ gas discharge at low pressures differently in the others, which transfer immediately to glow dischage after self-sustaining discharge starts. In this paper, the presence of the stable Townsend discharge, applied voltage-discharge current characteristics and the effect of disgased electrode surface on stable townsend discharge are studied experimentaly in N$_{2}$ gas mixed with 0.05% of No in volume. As the result of this experiment, the stable Townssend discharge is observed only in pure nitrogen with the valve of pd.geq.8[torr.cm] (p=gas pressure, d=gap spacing), but not in gas mixtures. This is considered that No gas in gas mixtures disexcites effectively the metestble state of nitrogen.

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Preparation of Novel Sorbents for Gas-phase Mercury Removal

  • Lee, Si-Hyun;Rhim, Young-Jun;Park, Young-Ok
    • Carbon letters
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    • v.3 no.4
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    • pp.187-191
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    • 2002
  • In the present research, we prepared the activated carbon (AC) sorbents to remove gas-phase mercury. The mercury adsorption of virgin AC, chemically treated AC and fly ash was performed. Sulfur impregnated and sulfuric acid impregnated ACs were used as the chemically treated ACs. A simulated flue gas was made of SOx, NOx and mercury vapor in nitrogen balance. A reduced mercury adsorption capacity was obtained with the simulated gas as compared with that containing only mercury vapor in nitrogen. With the simulated gas, the sulfuric acid treated AC showed the highest performance, but it might have the problem of corrosion due to the emission of sulfuric acid. It was also found that the high sulfur impregnated AC also released a portion of sulfur at $140^{\circ}C$. Thus, it was concluded that the low sulfur impregnated AC was suitable for the treatment of flue gas in terms of stability and efficiency.

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Experimental Study on the Flame Behavior and the NOx Emission Characteristics of Low Calorific Value Gas Fuel (저 발열량 가스 연료의 화염거동 및 NOx 발생 특성에 관한 실험적 연구)

  • Kim, Yong-Chul;Lee, Chan
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.05a
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    • pp.89-93
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    • 1999
  • Experimental studies are conducted to investigate the flame stability and the thermal/fuel NOx formation characteristics of the low calorific value(LCV) gas fuel. Synthetic LCV fuel gas is produced through mixing carbon monoxide, hydrogen, nitrogen and ammonia on the basis that the thermal input of the syngas fuel into a burner is identical to that of natural gas, and then the syngas mixture is fed to and burnt with air on flat flame burner. Flame behaviors are observed to identify flame instability due to blow-off or flash-back when burning the LCV fuel gas at various equivalence ratio conditions. Measurements of NOx in combustion gas are made for comparing thermal and fuel NOx emissions from the LCV syngas combustion with those of the natural gas one, and for analyzing ammonia to NOx conversion mechanism. In addition, the nitrogen dilution of the LCV syngas is preliminarily attempted as a NOx reduction technique.

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Simultaneous Determination of Haloperidol and Its Metabolite, Reduced Haloperidol, in Plasma by Gas Chromatography Using Nitrogen Phosphorous Selective Detection (Gas Chromatography-Nitrogen Phosphorous Selective Detection을 이용한 혈장중 Haloperidol 및 대사체인 Reduced Haloperidol의 동시정량)

  • Park, Kyoung-Ho;Lee, Min-Hwa;Shim, Chang-Koo;Lee, Myung-Gull;Park, Jong-Sei
    • Journal of Pharmaceutical Investigation
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    • v.22 no.3
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    • pp.197-204
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    • 1992
  • A gas chromatographic method using nitrogen phosphorous selective detection was developed for simultaneous determination of haloperidol and its metabolite, reduced haloperidol, in human plasma. Combelen was used as internal standard, The method involved extraction and trimethylsilylation followed by the injection of $2-4\;{\mu}l$ of benzene layer, which was used to dissolve the trimethylsilylated derivatives of haloperidol and reduced haloperidol, onto SE-54 column [5% phenyl methyl silica fused capillary column, $16m{\times}0.22\;mm$ $(I.D.){\times}0.33\;{\mu}m$ (coated thickness)]. The temperature of column oven was programmed from $200^{\circ}C\;to\;300^{\circ}C$ at the increase rate of $10^{\circ}C/min and also the temperatures of injector and detector were set at $300^{\circ}C$. Helium was used as carrier gas and its flow rate was maintained at 30 ml/min. The detection was conducted with nitrogen phosphorous selective detector. The retention times for combelen, reduced haloperidol and haloperidol were found to be 9.14, 9.75 and 9.99 min, respectively. The detection limits for haloperidol and reduced haloperidol in human plasma were both 0.2 ng/ml. The coefficients of variation of the intra-assay were generally low (below 9.8%). The mean absolute recoveries of added haloperidol and reduced haloperidol from plasma were 72% and 84%, respectively. No interferences from endogenous substances were found.

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Simultaneous Analysis of Stimulants and Narcotic Analgesics by Capillary Column Gas Chromatography with Nitrogen Phosphorus Detector (Capillary Column Gas Chromatography/Nitrogen Phosphorus Detector를 이용한 흥분제 및 마약성 진통제의 동시분석에 관한 연구)

  • Lho, Dong-Seok;Shin, Ho-Sang;Kang, Bo-Kyung;Paek, Heang-Kee;Kim, Seung-Ki;Lee, Jeong-Ae;Kim, Young-Lim;Park, Jong-Sei
    • Journal of the Korean Chemical Society
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    • v.35 no.6
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    • pp.659-666
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    • 1991
  • A systematic analysis of 18 stimulants and narcotic analgesics containing nitrogen atom (s) in human urine by gas chromatography with nitrogen phosphorus detector (GC-NPD), is described. The urinary extract with diethyl ether at pH 8.5 showed good recoveries of the drugs and less interference peaks on GC chromatogram. Retention data were standardized by the calculation of relative retention times using diphenylamine as the internal standard. The relative standard deviations of retention times were less than 0.1% for the within-run analyses. The response factor (RRF) of a drug relative to the internal standard was calculated. RRF decreased with increasing number of nitrogen atoms. This technique can be adapted to various analytical toxicology problems.

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Influence of Ambient Gas Composition on the Microstructure of Plasma Nitrocarburised SCM435 steel (플라즈마 질탄화처리된 SCM435강의 미세조직에 미치는 가스 조성의 영향)

  • Lee, In-Seop
    • Korean Journal of Materials Research
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    • v.12 no.6
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    • pp.427-430
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    • 2002
  • Plasma nitrocarburizing treatment was performed for SCM 435 steel by using a plasma ion nitriding system. The effects of the variation of nitrogen and methan contents upon the hardened layer was investigated. Both the thickness of the compound layer and the amount of $\varepsilon$ phase in the compound layer increased with increasing nitrogen content. However, the thickness of the compound layer decreased due to unstable plasma for an atmosphere containing 90% $N_2$ gas content in the gas mixture. The amount of $\varepsilon$phase in the compound layer increased with increasing $CH_4$ gas content. For $CH_4$ gas content more than 2% in the gas mixture, the thickness of the compound layer decreased due to the formation of $\theta$ phase.

Gas sensing characteristics of carbon nanotube gas sensor using a diaphragm structure (다이아프램 구조를 이용한 탄소나노튜브 가스 센서의 가스 감응 특성)

  • Cho, Woo-Sung;Moon, Seung-Il;Kim, Young-Cho;Park, Jung-Ho;Ju, Byeong-Kwon
    • Journal of Sensor Science and Technology
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    • v.15 no.1
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    • pp.13-19
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    • 2006
  • The micro-gas sensor based on carbon nanotubes (CNTs) was fabricated and its gas sensing characteristics on nitrogen dioxide ($NO_{2}$) have been investigated. The sensor consists of a heater, an insulating layer, a pair of contact electrodes, and CNT-sensing film on a micromachined diaphragm. The heater plays a role in the temperature change to modify sensor operation. Gas sensor responses of CNT-film to $NO_{2}$ at room temperature are reported. The sensor exhibits a reversible response with a time constant of a few minutes at thermal treatment temperature of $130^{\circ}C$.

The effect of shielding gases on the characteristics of super duplex weld metal (슈퍼 듀플렉스 용접부에 미치는 보호가스의 영향)

  • Hong, In-Pyo;Lee, Cheol-Hwan;Kim, Yu-Gi;Kim, Dae-Sun
    • Proceedings of the KWS Conference
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    • 2005.06a
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    • pp.209-211
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    • 2005
  • Super duplex stainless steels have been used for offshore oil and gas piping systems which are subject to corrosion atmosphere, because they have excellent resistance to Stress Corrosion Cracking (SCC) and Pitting corrosion and high strength/weight ratio. Normally, the welding for duplex stainless steels has been peformed using GTAW with Ar shielding gas. However, in case of using Ar as shielding gas, the corrosion resistance at root weld metal will be deteriorated due to loss of nitrogen from weld deposit during welding. It is wellknown that the corrosion resistance of super duplex stainless can be restored by addition of nitrogen as shielding gas. In this study, we made super duplex welding with using several kinds of shielding and purging gases and investigated the relationship between shielding gas and corrosion resistance. Consequently, it was shown that corrosion resistance of weld deposit can be restored by addition of $N_{2}$ as shielding gas.

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