• Title/Summary/Keyword: nitrogen depletion

검색결과 53건 처리시간 0.024초

분위기 변화에 따른 반도성 $BaTiO_3$ 전기적 특성 연구 (Studies on the Electrical Properties of Semiconducting $BaTiO_3$ by Changing Sintering Atmosphere)

  • 최기영;한응학;박순자
    • 한국세라믹학회지
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    • 제28권3호
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    • pp.179-188
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    • 1991
  • The semiconducting BaTiO3 ceramics used in this study were sintered in the reducing atomosphere(hydrogen gas) and neutral atmosphere(nitrogen gas), then were heat-treated in air to vary defect concentrations. In this experiment, the correlations between the composition analysis and electrical characteristics of these samples were investigated. When the BaTiO3 ceramics were sintered in N2 atmosphere, it was observed that the Ba contents near the interface were lower than that of the grain center, and these samples showed superior PTCR effects. From analysis of the resistivities of grains and grain boundaries by CIRM(Complex Impedance Resonance Method), it was confirmed that the PTCR effects were caused by the resistivity of grain boundaries. And from measurement of the capacitance at each temperature, the samples sintered in N2 atmosphere show the increase of room temperature resistance and the decrease of capacitance as a result of the increase of the charge depletion layers. This phenomenon agrees well with the cation deficiencies in the analytical results.

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n형 GaN의 doping 농도에 따르는 건식 식각 손상 (Doping-level dependent dry-etch damage of in n-type GaN)

  • 이지면
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.1
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    • pp.417-420
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    • 2004
  • The electrical effects of dry-etch on n-type GaN by an inductively coupled $Cl_2/CH_4/H_2/Ar$ plasma were investigated as a function of ion energy, by means of ohmic and Schottky metallization method. The specific contact resistivity(${\rho}_c$) of ohmic contact was decreased, while the leakage current in Schottky diode was increased with increasing ion energy due to the preferential sputtering of nitrogen. At a higher rf power, an additional effect of damage was found on the etched sample, which was sensitive to the dopant concentration in terms of the ${\rho}_c$ of ohmic contact. This was attributed to the effects such as the formation of deep acceptor as well as the electron-enriched surface layer within the depletion layer. Furthermore, thermal annealing process enhanced the ohmic and Schottky property of heavily damaged surface.

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기후변화를 고려한 미래 융설이 수문-수질에 미치는 영향 평가 (Assessment of climate change impact on Hydrology and water quality by snowmelt)

  • 김샛별;하림;유영석;이재응;김성준
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2012년도 학술발표회
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    • pp.126-126
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    • 2012
  • 기후변화는 전 세계적으로 다양한 영향을 미치고 있으며 특히, 홍수나 대설로 인한 수문변화에 영향을 준다. 본 연구는 준분포형 연속 모형인 SWAT (Soil and Water Assessment Tool)모형을 이용하여 우리나라 3대 대설지역에 속하는 다목적댐인 충주댐유역(6642.0 m)의 기후변화에 따른 융설이 수문과 수질에 미치는 영향을 분석하고자 한다. 먼저, 융설 모형의 매개변수인 적설분포면적감소곡선 (Snow Cover Depletion Curve; SCDC)을 구축하기 위하여 10년(2000-2010)동안의 Terra MODIS (MODerate resolution Imaging Spectroradiometer) 위성영상자료와 6개 기상관측소(충주, 제천, 원주, 영월, 대관령, 태백)의 최심적설자료를 이용하여 연도별 SCDC을 구축하였다. 구축 결과, 눈이 50% 피복 일 때 snow volume은 연 평균 0.47로 분석되었다. 이를 SWAT 모형에 적용하여 수문과 수질에 대한 적용성 평가를 실시한 결과, 유출의 경우 NSE는 융설기간 동안 평균 0.8, 전체기간은 평균 0.6으로 나타났으며 수질(Sediment, T-N, T-P)의 경우 각각 평균 0.72, 0.70, 0.85을 나타내었다. 미래 기후자료는 IPCC(Intergovernmental Panel on Climate Change)에서 제공하는 SRES(Special Report on Emission Scenarios) A1B, B1 기후변화시나리오의 HadCM3 모델의 결과 값을 이용하였으며 기간은 과거 30년 기후자료(1981-2010, baseline)를 바탕으로 2040s(2020-2059), 2080s(2060-2099)의 두 기간으로 나누어 각각 분석하였으며 기후변화 결과 값의 불확실성을 줄이고자 과거 자료와 GCM의 1981년에서 2000년까지의 값을 비교하여 온도와 강수량의 보정을 실시한 후 LARS-WG를 이용하여 온도와 강수량 자료를 구축하였다. SWAT 모형을 적용한 결과, 평균 1.92 증가한 것으로 나타났으며 유출은 융설기간(Nov-Apr)이 비융설기간(May-Oct)보다 10% 더 증가하였다. 본 연구에서는 SWAT 모형을 통한 유출 및 환경부하량 전망을 목표로 하여 미래 기후변화를 고려한 융설이 다목적댐에서의 유출과 수질 (Sediment, Total Nitrogen, Total Phosphorus)에 미치는 영향을 평가해 보고자 한다.

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알킬렌디아미노알킬-비스-포스폰산과 비스-디메틸아미노메틸 포스핀산으로 처리된 중질섬유판의 연소가스 발생 (Combustion Gas-emission of Medium Density Fibreboard (MDF) Treated with Alkylenediaminialkyl-bis-phosphonic Acids and Bis-(dimethylaminomethyl) Phosphinic Acid)

  • 박명호;정영진
    • 공업화학
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    • 제28권1호
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    • pp.112-117
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    • 2017
  • 이 연구에서는 피페라지노메틸-비스-포스폰산(PIPEABP), 메틸피페라지노메틸-비스-포스폰산(MPIPEABP), N,N-디메틸렌디아미노메틸-비스-포스폰산(MDEDAP) 그리고 비스-디메틸아미노메틸 포스핀산(DMDAP)의 화학 첨가제로 처리된 중질섬유판(MDF)의 연소가스 발생을 시험하였다. 15 wt%의 인-질소산류 첨가제 수용액으로 중질섬유판에 붓으로 3회 칠하여 실온에서 건조시킨 후, 콘칼로리미터(Conecalorimeter, ISO 5660-1, 2)를 이용하여 연소가스의 발생을 시험하였다. 그 결과, 인-질소산류 첨가제로 처리한 시험편의 최대연기발생률($SPR_{peak}$)은 무처리 시험편에 비교하여 18.5~41.5%로 낮게 나타내었다. 그러나 인-질소산류 첨가제로 처리한 시험편에 대한 최대일산화탄소 생성($CO_{peak}$), (6.7~24.2)%은 공시험편보다 높게 나타났다. 또한 최대이산화탄소 발생($CO_{2peak}$), (4.2~24.4)%은 공시험편보다 낮게 나타났다. 반면에 $O_2$의 최대결핍률은 사람에게 치명적일 수 있는 수준인 15%보다 훨씬 높으므로 그로 인한 위험성은 피할 수 있었다. 결론적으로 MDF에 인-질소산류로 처리한 시험편은 부분적으로 연소성이 억제되었다. 그러나 일산화탄소의 감소에는 부정적인 영향을 미쳤다.

열량제한(熱量制限) 및 무단백식이(無蛋白食餌)가 흰쥐의 체내대사(體內代謝)에 미치는 영향(影響) (Effects of Protein Depletion and Protein Calorie Restriction on Metabolic and Enzymatic Activities in Adult Rats)

  • 김경자;김숙희
    • Journal of Nutrition and Health
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    • 제6권3호
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    • pp.1-8
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    • 1973
  • Metabolic responses to the protein-free, high-carbohydrate diet and subsequent food restriction on the same diet at the level of 50% and 75% has been studied on the adult albino rats. The energy source was either corn starch or sugar. In experiment I, adult male rats weighing $509{\pm}8g$ were divided into two groups 10 rats each. Rats fed on the stock diet served as a control. Rats of restriction group received a protein free diet until they reduced their weight down to 400g and continue on a protein-calorie restriction diet until they reduced their weight down to 300g. In experiment II, 28 adult male rats and the same numbers of female rats weighing $329{\pm}5g$ and $223{\pm}4g$ respectively were divided into four groups, 7 males and females in each. Rats fed on a stock diet were sacrificed at the point when others started a protein free diet. These were served as the control. The protein free group received a protein free diet ad libitum for 4 weeks. The 50% restriction group and 75% restriction group were fed on a protein free diet coupled with food restriction at levels of 50% and 75% respectively for 3 weeks. In the result of this study: 1. The rate of body weight changes was similar between the males and the females. Feeding protein free diet ad lib. initiated a rapid weight lost of approximately 25% and protein free diet coupled with food restriction showed 37-43% reduction of their initial weight. 2. There was no significant differences in the value of the N concentration in liver, spleen, brain and muscle between controls and experimental groups. 3. Rats fed on protein free diet showed 1/10 value of the control in the nitrogen excretion in urine. However female showed less N excretion than male. 4. Observing blood picture, the effects of protein depletion and calorie restriction were not appeared any remarkable changes. 5. There was no sign of fatty liver which might result from protein depletion and calorie restriction. 6. Following semi-starvation, FAO and HMP-DH total enzyme activity was reduced, but activity per unit weight was relatively stable.

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기후변화와 동해안에서의 명태 자원의 고갈 (Climate Change and Depletion of Walleye Pollock Resources in the East Sea)

  • Kim, Jong-Gyu;Kim, Joong-Soon
    • 한국환경보건학회지
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    • 제44권3호
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    • pp.259-266
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    • 2018
  • Objectives: Considered the "national fish" in Korea, the walleye pollock (Gadus chalcogrammus) has disappeared in the East Sea (Sea of Japan), a main habitat and fishing ground for the species. The reason for the disappearance is still a matter of controversy. This study was performed to investigate the long-term relationship between the walleye pollock catch and various meteorological and oceanographic factors in these waters. Methods: Fishery data on walleye pollock and data on meteorological and marine environmental factors over the 30 years (1981-2010) were obtained from the official national database. Time series analysis and correlation and regression analyses were performed to study the relationships. Results: Both air temperature and sea surface temperature in the East Sea rose over these 30 years, and the latter became more prominent. Salinity and dissolved oxygen showed a tendency to decrease while concentrations of nutrients such as nitrite nitrogen and nitrate nitrogen showed an increasing tendency. Sea surface temperature, air temperature, atmospheric pressure, and wind grade were negatively correlated with the catch size of walleye pollock (p<0.05), but salinity was positively correlated (p<0.001). Conclusion: The results of this study indicate that climate change, especially ocean warming, affected the habitat of walleye pollock. The results also indicate that lower sea surface and air temperatures, milder wind grade, and higher salinity were preferred for the survival of the fish species. It is necessary to pay attention to changes of the ocean ecosystem in terms of environmental pollution as well as seawater temperature.

CHARACTERISTICS OF A WATER-PURIFICATION SYSTEM USING IMMOBILIZED PHOTOSYNTHETIC BACTERIA BEADS

  • Kim, Joong-Kyun;Park, Kyoung-Joo;Cho, Kyoung-Sook;Nam, Soo-Wan;Kim, Yong-Ha
    • Environmental Engineering Research
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    • 제10권5호
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    • pp.227-238
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    • 2005
  • The characteristics of nitrogen removal by the free cell and the immobilized cell of R. capsulatus were investigated. Denitrification by R. capsulatus cells resulted in reduction of ORP with the rapid depletion of DO and the increase of pH. Without accumulation of nitrite, the removal efficiencies of ${NO_3}^-$-N for the free cell and the immobilized cell were 99.1 and 99.3%, respectively. During the three-month experiment of goldfish breeding equipped with a water-purification biofilter, the average values of pH and total cell numbers present in an aquarium were not significantly different between water-purification system and the control. The average concentrations of ${NH_4}^+$-N and ${PO_4}^{2-}$-P in water-purification system were relatively low, compared to that in the control. Goldfish died at $11^{th}$, $16^{th}$, $43^{rd}$, and $67^{th}$ days in the control, while goldfish died at $10^{th}$, $20^{th}$, and $39^{th}$ days in the water-purification system. On the days of goldfish's death, the total concentrations of nitrogenous compounds except for ${NO_2}^--N$ were higher than those on the other days of the experiment, especially with the concentrations of ${NH_4}^+$-N ranging from 7.4 to 13.5 mg/L. The water-purification system also showed the less turbidity of water with more active movement of goldfish than the control. PVA gel beads showed almost the full denitrifying ability even after the long-term experiment. As a result, the water-purification system was effective to remove nitrogenous compounds with better survival of goldfish.

Biosurfactant 생산균주 Pseudomonas aeruginosa F722의 배양특성 (Cultural Characteristics of a Biosurfactant-Producing Microorganism Pseudomonas aeruginosa F722)

  • 정선용;오경택;강창민
    • 한국미생물·생명공학회지
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    • 제31권2호
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    • pp.171-176
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    • 2003
  • 생물계면활성제 생성균주, Pseudomonas aeruginosa F722를 이용하여 다양한 배양조건과 배지조성에서 생물계면활성제 생산성을 검토하였다. 질소원과 탄소원을 검토하기 전에는 P. aeruginosa F722의 생물계면활성제 생산량은 0.78 g/l이었다. 하지만, 질소원과 탄소원을 검토한 후에는 생물계면활성제 생산량이 2배 증가한 1.66g/l이었다. 무기질소원으로 $_NH4$Cl 또는 $NaNO_2$를 첨가하였을 때 생물계면활성제 활성에 효과적이었으며 유기질소원으로는 yeast extract 또는 tryptone을 첨가하였을 때 생물계면활성제 활성이 높았다. 이중 무기 질소원으로 0.05% $NH_4$Cl , 유기 질소원으로 0.1% yeast extract를 질소원으로 첨가하였을 때 가장 최적이었다. 탄소원으로 소수성 기질(n-alkane) 또는 친수성 기질(glucose, glycol)을 첨가하여 생물계면활성제 생산량을 조사하였는데 소수성 기질보다는 친수성 기질인 3.0% glucose를 첨가하였을 때 생물계면활성제 생산량이 높았다. 이때의 탄소원/질소원 비율은 17~20이었다. P. aeruginosa F722는 배양조건 3.0% glucose, 0.05% $NH_4$Cl, 0.1% yeast extract, $35^{\circ}C$, pH 7.0, C/N ratio 20, 5 days에서 생물계면활성제 생산량은 1.66g/l이였다. 질소원이 결핍 후 탄소원을 첨가하여 배양하였을 때가 질소원과 탄소원을 함께 첨가하여 배양했을 때보다 생물계면활성제 생산속도 및 균체 생장속도가 높았다. 최적 배양조건하에서 얻어진 배양액의 표면장력은 30mN/m이었다.

Proteases and Protease Inhibitors Produced in Streptomycetes and Their Roles in Morphological Differentiation

  • KIM DAE WI;KANG SUNG GYUN;KIM IN SEOP;LEE BYONG KYU;RHO YONG TAIK;LEE KYE JOON
    • Journal of Microbiology and Biotechnology
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    • 제16권1호
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    • pp.5-14
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    • 2006
  • Streptomycetes are Gram-positive microorganisms producing secondary metabolites through unique physiological differentiation [4]. The microbes show unusual morphological differentiation to form substrate mycelia, aerial mycelia, and arthrospores on solid medium [19]. Substrate mycelium growth is sustaining with sufficient nutrients in the culture medium. The concentration of a specific individual substrate in the culture environment is the most important extracellular factor allowing vegetative mycelia growth, where extracellular hydrolytic enzymes participate in the utilization of waterinsoluble substrates. However, with starvation of nutrients in the culture medium, the vegetative mycelia differentiate to aerial mycelia and spores. It has been considered that shiftdown of essential nutrients for mycelia growth is the most important factor triggering morphological and physiological differentiation in Streptomyces spp. Since proteineous macromolecule compounds are the major cellular components, these are faced to endogenously metabolize following a severe depletion of nitrogen source in culture nutrients (Fig. 1). Various proteases were identified of which production was specifically related with the phase of mycelium growth and also morphological differentiation. The involvement of proteases and protease inhibitor is reviewed as a factor explaining the mycelium differentiation in Streptomyces spp.

Differential Effect of Harmalol and Deprenyl on Dopamine-Induced Mitochondrial Membrane Permeability Change in PC12 Cells

  • Lee, Chung-Soo
    • Biomolecules & Therapeutics
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    • 제12권1호
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    • pp.9-18
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    • 2004
  • Opening of the mitochondrial permeability transition pore has been recognized to be involved in cell death. The present study investigated the effect of ${\beta}$-carbolines (harmaline and harmalol) and deprenyl on the dopamine-induced change in the mitochondrial membrane permeability and cell death in differentiated PC12 cells. Cell death due to 250 4{\mu}$M dopamine was inhibited by caspase inhibitors (z-IETD.fmk, z-LEHD.fmk and z-DQMD.fmk) and antioxidants (N-acetylcysteine, ascorbate, superoxide dismutase, catalase and carboxy-PTIO). ${\beta}$-Carbolines prevented the dopamine-induced cell death in PCl2 cells, while deprenyl did not inhibit cell death. ${\beta}$-Carbolines decreased the condensation and fragmentation of nuclei caused by dopamine in PC12 cells. ${\beta}$-Carbolines inhibited the decrease in mitochondrial transmembrane potential, cytochrome c release, formation of reactive oxygen species and depletion of GSH caused by dopamine in PC12 cells, whereas deprenyl did not decrease dopamine-induced mitochondrial damage. ${\beta}$-Carbolines, deprenyl and antioxidants depressed the formation of nitric oxide and melanin in dopamine-treated PC12 cells. The results suggest that cell death due to dopamine PC12 cells is mediated by caspase-8, -9 and -3. Unlike deprenyl, ${\beta}$-carbolines may attenuate the dopamineinduced cell death in PC12 cells by suppressing change in the mitochondrial membrane permeability through inhibition of the toxic action of reactive oxygen and nitrogen species.