• Title/Summary/Keyword: nitrogen depletion

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OPTIMIZATION OF VARIABLES AFFECTING CORROSION RESISTANCE OF VACUUM SINTERED STAINLESS STEELS

  • Klar, Erhard;Samal, Prasan
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 1995.11a
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    • pp.9-9
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    • 1995
  • MATERIAL AND PROCESS VARIABLES THAT STRONGLY AFFECT THE CORROSION RESISTANCE OF PA4 STAINLESS STEELS, INCLUDE : ALLOY COMPOSITION, POWDER CLEANLINESS, NITROGEN, OXYGEN AND GARBON CONTENTS, CHROMIUM DEPLETION DUE TO SURFACE EVAPORATION AND SINTERED DENSITY. THE OPTIMUM PROCESS PARAMETERS FOR DELUBRICATION AND SINTERING THAT RESULT IN LOWEST LEVELS OF NITROGEN, OXYGEN AND CARBON AND MINIMUM LEVELS OF CHROMIUM DEPLETION WILL BE PRESENTED, FOR A NUMBER OF AUSTENTIC AND FERRITIC STAINLESS STEELS. THE EFFECT OF SINTERED DENSITY ON THE CORROSION RESISTANCE OF BOTH AUSTENITIC AND FERRITIC GRADES OF STAINLESS STEEL WILL ALSO BE COVERED.

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High Temperature Gas Nitriding of Fe-20Mn-12Cr-1Cu Damping Alloy (Fe-20Mn-12Cr-1Cu 제진합금의 고온가스 질화처리)

  • Sung, Jee-Hyun;Kim, Yeong-Hee;Sung, Jang-Hyun;Kang, Chang-Yong
    • Journal of the Korean Society for Heat Treatment
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    • v.26 no.3
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    • pp.105-112
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    • 2013
  • The microstructural changes of Fe-20Mn-12Cr-1Cu alloy have been studied during high temperature gas nitriding (HTGN) at the range of $1000^{\circ}C{\sim}1150^{\circ}C$ in an atmosphere of nitrogen gas. The mixed microstructure of austenite and ${\varepsilon}$-martensite of as-received alloy was changed to austenite single phase after HTGN treatment at the nitrogen-permeated surface layer, however the interior region that was not affected nitrogen permeation remained the structure of austenite and ${\varepsilon}$-martensite. With raising the HTGN treatment temperature, the concentration and permeation depth of nitrogen, which is known as the austenite stabilizing element, were increased. Accordingly, the depth of austenite single phase region was increased. The outmost surface of HTGN treated alloy at $1000^{\circ}C$ appeared Cr nitride. And this was in good agreement with the thermodynamically calculated phase diagram. The grain growth was delayed after HTGN treatment temperature ranges of $1000^{\circ}C{\sim}1100^{\circ}C$ due to the grain boundary precipitates. For the HTGN treatment temperature of $1150^{\circ}C$, the fine grain region was shown at the near surface due to the grain boundary precipitates, however, owing to the depletion of grain boundary precipitates, coarse grain was appeared at the depth far from the surface. This depletion may come from the strong affinity between nitrogen and substitutional element of Al and Ti leading the diffusion of these elements from interior to surface. Because of the nitrogen dissolution at the nitrogen-permeated surface layer by HTGN treatment, the surface hardness was increased above 150 Hv compared to the interior region that was consisted with the mixed microstructure of austenite and ${\varepsilon}$-martensite.

Enhancement of $\beta$-D-Glucans Production by Agaricus blazei Murill by Nitrogen Supplementation

  • NA JEONG-GEOL;KIM HYUN-HAN;CHUN GIE-TAEK;CHANG YONG KEUN;LEE SANG JONG;CHUNG YEON HO
    • Journal of Microbiology and Biotechnology
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    • v.15 no.6
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    • pp.1388-1391
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    • 2005
  • Temporal changes of cell growth pattern and intracellular content of $\beta$-D-glucans were investigated with off-gas data in Agaricus blazei culture where glucose was intermittently fed. It was observed that the time point of carbon source depletion coincided with the point of sudden drop in the carbon dioxide evolution rate (CER), and that the sole supplementation of glucose was not enough to maintain active cell growth and glucan content. On the other hand, when yeast extract, a typical nitrogen source, was supplemented together with glucose when the CER suddenly dropped because of carbon source depletion, an active cell growth could be maintained until the end of the culture and the glucan content did not decrease with culture time, significantly enhancing glucan productivity.

Investigating the Impact of Best Management Practices on Nonpoint Source Pollution from Agricultural Lands

  • ;Saied Mostaghimi
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.32 no.E
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    • pp.1-19
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    • 1990
  • Abstract Over the last several decades, crop production in the United States increased largely due to the extensive use of animal waste and fertilizers as plant nutrient supplements, and pesticides for crops pests and weed control. Without the application of animal waste best management, the use of animal waste can result in nonpoint source pollution from agricultural land area. In order to increase nutrient levels and decrease contamination from agricultural lands, nonpoint source pollution is responsible for water quality degradation. Nonpoint source pollutants such as animal waste, ferilizers, and pesticides are transported primarily through runoff from agricultural areas. Nutrients, primarily nitrogen and phosphorus, can be a major water quality problem because they cause eutrophic algae growth. In 1985, it was presented that Watershed/Water Quality Monitoring for Evaluation BMP Effectiveness was implemented for Nomini Creek Watershed, located in Westmoreland County, Virginia. The watershed is predominantly agricultural and has an aerial extent of 1505 ha of land, with 43% under cropland, 54% under woodland, and 3% as homestead and roads. Rainfall data was collected at the watershed from raingages located at sites PNI through PN 7. Streams at stations QN I and QN2 were being measured with V-notch weirs. Water levels at the stream was measured using an FW-l Belfort (Friez FWl). The water quality monitoring system was designed to provide comprehensive assessment of the quality of storm runoff and baseflow as influenced by changes in landuse, agronomic, and cultural practices ill the watershed. As this study was concerned with the Nomini Creek Watershed, the separation of storm runoff and baseflow measured at QNI and QN2 was given by the master depletion curve method, and the loadings of baseflow and storm runoff for TN (Total Nitrogen) and TP (Total Phosphorus) were analyzed from 1987 through 1989. The results were studied for the best management practices to reduce contamination and loss of nutrients, (e.g., total nitrogen and total phosphorus) by nonpoint source pollution from agricultural lands.

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The Study on Envionmental Characteristics of Chungju Reservoir (충주호의 환경특성에 관한연구)

  • 사성오;정영도;김학성
    • Journal of environmental and Sanitary engineering
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    • v.13 no.3
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    • pp.1-8
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    • 1998
  • Chungju reservoir is a multipurpose dam lake located at the upstream of Nm Han river and known as having the biggest watershed and the second water volume in korea. Conclusions are made as follows. 1. Environmental characteristics of the reservoir appear to be as follows. Chungju reservoir has long hydaulic retention time, 60-160 days. Water column has oxygen depletion zone in hypolimnion. Chungju reservoir is found to be in the midst of eutrophication. Chlorophyll-a and other physical parameters are found to be significantly dependent. 2. Nitrogen to phosphorus ratio was 50-350 for the water samples taken from the reservoir in 1996. It is very important clue for water quality management in relation to phytoplankton growing kinetics. Variations in chlorophyll-a contents appear to be related closely to total phosphorus concentration.

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Nitrogenase Derepression and Associated Metabolism in a Microaerophilic Cyanobacterium, Plectonema boryanum

  • Pandey, Kapil Deo;Sukla, Sarkar;Naz, Shaheen;Smita, Chaturvedi;Ajaikumar, Kashyap
    • Journal of Microbiology and Biotechnology
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    • v.11 no.2
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    • pp.179-185
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    • 2001
  • Nitrate grown cells of cyanobacterium Plectonema boryanum, transferred to nitrogen stress, evolved nitrogenase catalyzed $H_2$ under microaerophilic condition. Nitrogen ($N_2$) in gs phase, low light intensity, and reducing substances in incubation phase stimulated $N_2$fixation ($H_2\;evolution$). Cyanobacterium grew slowly under microaerobic condition with a low intracellular ammonia pool. Nitrogen sources (${NO_3}^-,{NH_4}^+,\;and\;CH_3NH_3$) inhibited nitrogenase and glutamine synthetase (GS) transferase activity, and methylamine behaved like an ammonical nitrogen source. Depletion of molybdenum (Mo) and addition of tungsten (W) in the incubation medium inhibited $H_2$ evolution, Cyanobacterium was able to take up nitrate and expressed nitrate reductase (NR) activity under microaerophilic condition at an extremely slow rate.

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Improved Production of Curdlan with Concentrated Cells of Agrobacterium sp.

  • Jung, Dae-Young;Cho, Young-Su;Chung, Chung-Han;Jung, Dai-Il;Kim, Kwang;Lee, Jin-Woo
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.6 no.2
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    • pp.107-111
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    • 2001
  • The addition of a limited concentration of yeast extract to a minimal salt medium (MSM) enhanced cell growth and increased the production of curdlan whereas nitrogen-limitation was found to be essential for the higher production of curdlan by Agrobacterium sp. ATCC 31749. As the amount of the inoculum increased, the cell growth as well as the production of curdlan also increased in the MSM without a nitrogen source. The cell growth and production of curdlan increased as the initial pH of the medium decreased as low as 5.0. The conversion rate and concentration of curdlan from 2% (w/v) glucose in the MSM with concentrated cells under nitrogen deletion was 67% and 13.4 g/L, respectively. The highest conversion rate of curdlan under the conditions optimized in this study was 71% when the glucose concentrations was 1% (w/v).

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Decolorization of Poly R-478 Dye by Coriolus versicolor IFO 30388 (구름버섯(Coriolus versicolor IFO 30388)에 의한 Poly R-478 염료의 탈색)

  • Yoon, Kyung-Ha
    • Korean Journal of Microbiology
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    • v.32 no.3
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    • pp.182-185
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    • 1994
  • Effects of nitrogen and carbon sources on the decolorization rate of poly R-478 dye by a white rot basidiomycete Coriorus versicolor IFO 30388 were examined. The fungus exhibited 87.2% of decolorization rate when it was cultured in the state of stationary in a nitrogen-limited medium (pH 4.5) which contained 2.0% glucose, 0.04% ammonium tartrate, 0.02% poly R-478 dye, 2% $KH_2PO_4$, 0.5% $MgSO_4{\cdot}7H_2O$, 0.1% $CaCl_2{\cdot}2H_2O$, 0.002% thiamine-HCl and 10 mM 2,2 dimethylsuccinate (sodium) at $28^{\circ}C$ for 10 days. Decolorization of the dye occurred in the presence of nitrogen source in the medium and decolorization rate increased rapidly after depletion of $NH_4^+$ from the medium.

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Effect of C/N Ratio on the Production of Poly(3-hydroxyalkanoates) by the Methylotroph Paracoccus denitrificans

  • Kim, Byung-Ki;Yoon, Sung-Chul;Nam, Jae-Do;Lenz, Robert-W.
    • Journal of Microbiology and Biotechnology
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    • v.7 no.6
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    • pp.391-396
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    • 1997
  • Two series of carbon sources, linear primary $C_1$~$C_9$ alcohols and linear $C_2$~$C_{10}$ monocarboxylic acids were tested for PHA synthesis in Paracoccus denitrificans. The results showed that the growth-associated synthesis of PHA could be referred only to the carbon sources with odd number of carbon except methanol. For all carbon sources with even number of carbon, nitrogen limitation was required to induce PHA synthesis in P. denitrificans. Poly(3-hydroxyvalerate)[P(3HV)] homopolymer was synthesized from $C_5$, $C_7$, and $C_9$ while growing in the presence of nitrogen, but the nitrogen depletion in the later growth period incorporated 3-hydroxybutyrate(3HB) unit into the polymer chain. The optimum C/N ratio for P(3HV) homopolymer production was found to be 10 when the strain was grown on 10 ml/l of valeric acid for 96 h. P. denitrificans synthesized P(3HB-co-3HV) copolymers from n-hexanoic and n-octanoic acid. The microstructural characterics of the P(3HB-co-3HV) copolymer from n-propanol was investigated using $^13C$-nuclear magnetic resonance spectroscopy, showing a structural heterogeneity.

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The Characteristics of SBR Treatment with Different Types of Piggery Wastewater (축산폐수성상에 따른 SBR 처리특성)

  • Jun, Byong-Hee;Poo, Kyung-Min;Kim, Yang-Hoon;Im, Jeong-Hoon;Kim, Chang-Won
    • Journal of Korean Society on Water Environment
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    • v.18 no.4
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    • pp.435-440
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    • 2002
  • A pilot scale SBR (effective volume, $20m^3$) for the treatment of piggery wastewater treatment was performed with three different kinds of wastewater; fermenter effluent, scraper type and slurry type. The react phase in SBR was performed by sub-cycle operation consisting of repeated short cycle of anoxic-aerobic step. The fermenter effluent was characterized by the rapid nitrification and $NO_X-N$ accumulation due to depletion of organic matter in wastewater. The scraper type wastewater showed appropriate nitrogen removal efficiency, however, a poor response capacity for high loading rate often resulted in increased nitrogen concentration in effluent. Moreover, severe P release was the most serious problem in scraper type wastewater. SBR treated slurry type wastewater with high nitrogen removal efficiency to satisfy effluent quality requirement. It was thought that high concentration of organic matter in slurry made it possible to uptake P during SBR operation, where P concentration of 140mgP/l was decreased to 8mgP/l. As results, SBR was suitable to treat slurry type wastewater which has been discharged to the ocean till now.