• 제목/요약/키워드: nitrogen cycle

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초전도변압기의 계통적용을 위한 예상 시장진입가격 추정 (Evaluate the expected price of HTS transformer for introducing into korean power system)

  • 김종율;이승렬;윤재영
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 추계학술대회 논문집 전력기술부문
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    • pp.176-178
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    • 2004
  • HTS (High Temperature Superconducting) Transformer has the several useful characteristics in the viewpoints of technical and economical. Especially, an HTS transformer replaces the copper wire coils in a conventional transformer with lower loss HTS wire In addition, inexpensive, environmentally benign liquid nitrogen replaces the conventional oil as the electrical insulation (dielectric) and provides the necessary cooling for the HTS transformer Therefore, the Life-cycle cost of an HTS transformer is much more attractive than conventional because it is more energy efficient, lighter in weight, smaller in size, and environmentally compliant. HTS transformer can be the best way to replace with conventional transformer in the future. In this paper, we investigate the expected price of HTS transformer to have a merit in viewpoint of economic aspect. First, life-cycle cost of conventional transformer is calculated and based on this, the expected price of HTS transformer is evaluated, which HTS transformer is competitive against conventional transformer.

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Catalytic Isomerization of Allyic Alcohols to Carbonyl Compounds with Rh(ClO$_4$)(CO)(PPh$_3)_2$ and [Rh(CO)(PPh$_3)_3$]ClO$_4$

  • 신종식;박정한;김충일
    • Bulletin of the Korean Chemical Society
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    • 제10권1호
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    • pp.102-103
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    • 1989
  • Four coordinated rhodium(Ⅰ) complexes, Rh($ClO_4$)(CO)$(PPh_3)_2$ and [$Rh(CO)(PPh_3)_3$]$ClO_4$(2) catalyze the iosmerization of allylic alcohols to the corresponding carbonyl compounds at room temperature under nitrogen. The isomerization is faster with 2 than with 1, which is understood in terms of relative ease of the last step of the catalytic cycle, the reductive elimination of enol. Relative rates of the isomerization with 1 and 2 for different allylic alcohols are also explained by the relative ease of the enol elimination step in part. The first step of the catalytic cycle, the complex formation of the allylic alcohol through the ${\pi}-system$ of the olefinic group of the allylic alcohol and the following step, formation of hydridoallyl complex also seem to affect the overall rate of the isomerization.

초전도변압기 시장진입가격 예측을 통한 경제성 분석 (Economic Evaluation of HTS Transformer by Predicting Market Penetration Price)

  • 김종율;이승렬;윤재영
    • 대한전기학회논문지:전력기술부문A
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    • 제53권9호
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    • pp.507-512
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    • 2004
  • HTS (High Temperature Superconducting) Transformer has the several useful characteristics in the viewpoints of technical and economical. Especially, an HTS transformer replaces the copper wire coils in a conventional transformer with lower loss HTS wire. In addition, inexpensive, environmentally benign liquid nitrogen replaces the conventional oil as the electrical insulation (dielectric) and provides the necessary cooling for the HTS transformer Therefore, the Life-cycle cost of an HTS transformer is much more attractive than conventional because it is more energy efficient, lighter in weight, smaller in size, and environmentally compliant. HTS transformer can be the best way to replace with conventional transformer in the future. In these days, companies world-wide have conducted researches on HTS transformer. A development project for a 154kV HTS transformer is proceeding at a research center and university in Korea. In this paper, we investigate the expected price of HTS transformer to have a merit in viewpoint of economic aspect. First, life-cycle cost of conventional transformer is calculated and based on this, the expected price of HTS transformer is evaluated. which HTS transformer is competitive against conventional transformer.

蟾津江 河口 干潟地 水質의 年間變化 (Seasonal Variations of Chemical Composition of the Estuary Water in Guang Yang Inlet from Mar. 1961 to Feb. 1962)

  • 원종훈
    • 대한화학회지
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    • 제6권2호
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    • pp.176-197
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    • 1962
  • Seasonal variations of chemical constituents of estuarine water at a definite station of the tidal flat in Guang Yang inlet have been determined for two days a month. The range and mean of the annual variations are as follows:Tidal variations through a year are as follows:1. Although the tidal value of pH is almost constant during one tidal cycle, it raises abruptly 0.1-0.2 intervals of pH value during the first period of flood.2. The lower values of chlorinity, magnesium and calcium contents have been determined the nearer the slack after ebb, and slightly higher during the first period of flood tide than the last of ebb. The tidal change of calcium contents is more remarkable than of magnesium.3. The higher per cent saturation values of dissolved oxygen, sometimes higher than 100 per cent, re determined the nearer the slack after ebb.4. The total nitrogen contents, relatively poor, varies accidentally during one tidal cycle, whereas phosphate-P and silicate-Si are rich at the slack after ebb and increase proportionally to the mixing percentage of fresh water. The average values, 52.2 and 18.5 of Si/P and N/P are greater than of the normal.5. The acid soluble iron contents, lower in winter than in summer, is also varies accidentally during one tidal cycle and the magnitude of the variation is large.6. The chemical composition considered from the value of Ca/Cl or Mg/Cl of estuarine water varies according to the chlorinity even at the high chlorinity of 18-19%.

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LNG 냉열을 이용한 공기액화분리시스템의 시뮬레이션 및 공정 해석 (Process Analysis and Simulation for System of Air Liquefaction Separation Using LNG Cold Energy)

  • 한단비;백영순
    • 한국수소및신에너지학회논문집
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    • 제30권3호
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    • pp.276-281
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    • 2019
  • The process of separating oxygen and nitrogen from the air is mainly performed by electric liquefaction, which consumes a lot of electricity, resulting in higher operating costs. On the other hand, when used for cold energy of LNG, electric power can be reduced compared to the electric Linde cycle. Currently, LNG cold energy is used in the cold refrigeration warehouse, separation of air-liquefaction, and LNG cold energy generation in Japan. In this study, the system using LNG cold energy and the Linde cycle process system were simulated by PRO/II simulators, respectively, to cool the elevated air temperature from the compressor to about $-183^{\circ}C$ in the air liquefaction separation process. The required amount of electricity was compared with the latent heat utilization fraction of LNG, the LNG supply pressure, and the LNG cold energy usage. At the air flow rate of $17,600m^3/h$, the power source unit of the Linde cycle system was $0.77kWh/m^3$, compared with $0.3kWh/m^3$.

Aspartate-glutamate carrier 2 (citrin): a role in glucose and amino acid metabolism in the liver

  • Milan Holecek
    • BMB Reports
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    • 제56권7호
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    • pp.385-391
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    • 2023
  • Aspartate-glutamate carrier 2 (AGC2, citrin) is a mitochondrial carrier expressed in the liver that transports aspartate from mitochondria into the cytosol in exchange for glutamate. The AGC2 is the main component of the malate-aspartate shuttle (MAS) that ensures indirect transport of NADH produced in the cytosol during glycolysis, lactate oxidation to pyruvate, and ethanol oxidation to acetaldehyde into mitochondria. Through MAS, AGC2 is necessary to maintain intracellular redox balance, mitochondrial respiration, and ATP synthesis. Through elevated cytosolic Ca2+ level, the AGC2 is stimulated by catecholamines and glucagon during starvation, exercise, and muscle wasting disorders. In these conditions, AGC2 increases aspartate input to the urea cycle, where aspartate is a source of one of two nitrogen atoms in the urea molecule (the other is ammonia), and a substrate for the synthesis of fumarate that is gradually converted to oxaloacetate, the starting substrate for gluconeogenesis. Furthermore, aspartate is a substrate for the synthesis of asparagine, nucleotides, and proteins. It is concluded that AGC2 plays a fundamental role in the compartmentalization of aspartate and glutamate metabolism and linkage of the reactions of MAS, glycolysis, gluconeogenesis, amino acid catabolism, urea cycle, protein synthesis, and cell proliferation. Targeting of AGC genes may represent a new therapeutic strategy to fight cancer.

돼지 수정란이식의 현황과 문제점 (Advances and Problems of Embryo Transfer in Swine)

  • 박창식
    • 한국수정란이식학회지
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    • 제5권2호
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    • pp.11-22
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    • 1990
  • Remarkable progress has recently been made in embryo transfer technology, resulting in the birth of IVF and nuclear transfer offsprings in swine. However, further progress of the technology to (I) make a safe, effective and economic estrual-cycle synchronization compound, (2) regulate each step of sperm capacitation (3) induce monospermic fertilization, (4) in vitro grow and mature oocytes, (5) fertilize the oocytes efficently, (6) culture the oocytes to the blastocyst stage in defined media, (7) produce multiply copies of embryos with superior genetic merit, (8) preselect the sex of these superior offsprings, and (9) preserve embryos by freezing and storage in liquid nitrogen is required before this promising technology is applied routinely to swine for practical use.

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질소순환에서 미생물의 역할

  • 유익동
    • 미생물과산업
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    • 제14권3호
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    • pp.23-26
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    • 1988
  • 자연계에 있어서 질소는 대기중의 분자상질소를 비롯하여 초산, 암모니아와 같은 무기태질소, 단백질, 핵산 등의 유기태질소 등 다양한 형태로 존재하며 생물권내에서 흡수, 고정, 대사, 분해되는 등 다양한 순환을 거듭하고 있다. 대기중의 분자상질소는 Rhizobium, Azotobacter, Klebsielle, Clostridium, Blue-green algae 및 광합성세균 등에 의해 고장되어 암모니아의 형태로 환원된다. 한편 대부분의 식물들은 초산이나 암모니아 형태의 질소를 흡수 동화하여 핵산, 단백질을 만들고 이들 구성물은 사후 암모니아로 재분해 된다. 또한 동식물의 유체내지는 배설물들도 각기 분해되어 암모니아의 형태로 변화되는데 이와같은 일련의 질소순환(nitrogen cycle)은 초화세균, 탈질세균 내지는 질소고정균등 대부분의 미생물에 의해 크게 지배를 받고 있다.

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Effectiveness analysis of pre-cooling methods on hydrogen liquefaction process

  • Yang, Yejun;Park, Taejin;Kwon, Dohoon;Jin, Lingxue;Jeong, Sangkwon
    • 한국초전도ㆍ저온공학회논문지
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    • 제22권3호
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    • pp.20-24
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    • 2020
  • The purpose of this analytic study is to design and examine an efficient hydrogen liquefaction cycle by using a pre-cooler. The liquefaction cycle is primarily comprised of a pre-cooler and a refrigerator. The fed hydrogen gas is cooled down from ambient temperature (300 K) to the pre-cooling coolant temperature (either 77 K or 120 K approximately) through the pre-cooler. There are two pre-cooling methods: a single pre-coolant pre-cooler and a cascade pre-cooler which uses two levels of pre-coolants. After heat exchanging with the pre-cooler, the hydrogen gas is further cooled and finally liquefied through the refrigerator. The working fluids of the potential pre-cooling cycle are selected as liquid nitrogen and liquefied natural gas. A commercial software Aspen HYSYS is utilized to perform the numerical simulation of the proposed liquefaction cycle. Efficiency is compared with respect to the various conditions of the heat exchanging part of the pre-cooler. The analysis results show that the cascade method is more efficient, and the heat exchanging part of the pre-coolers should have specific UA ratios to maximize both spatial and energy efficiencies. This paper presents the quantitative performance of the pre-cooler in the hydrogen liquefaction cycle in detail, which shall be useful for designing an energy-efficient liquefaction system.