• Journal of Korean Society of Water and Wastewater
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• v.36 no.2
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• pp.81-95
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• 2022

The present study was performed to investigate the effects of NH₃-N and nitrifying microorganisms on the increased BOD of downstream of the Yeongsan river in Gwangju. Water samples were collected periodically from the 13 sampling sites of rivers from April to October 2021 to monitor water qualities. In addition, the trends of nitrogenous biochemical oxygen demand (NBOD) and microbial clusters were analyzed by adding different NH₃-N concentrations to the water samples. The monitoring results showed that NH₃-N concentration in the Yeongsan river was 22 times increased after the inflow of discharged water from the Gwangju 1st public sewage treatment plant (G-1-PSTP). Increased NH₃-N elevated NBOD levels through the nitrification process in the river, consequently, it would attribute to the increase of BOD in the Yeongsan river. Meanwhile, there was no proportional relation between NBOD and NH₃-N concentrations. However, there was a significant difference in NBOD occurrence by sampling sites. Specifically, when 5 mg/L NH₃-N was added, NBOD of the river sample showed 2-4 times higher values after the inflow of discharged water from G-1-PSTP. Therefore, it could be thought other factors such as microorganisms influence the elevated NBOD levels. Through next-generation sequencing analysis, nitrifying microorganisms such as Nitrosomonas, Nitroga, and Nitrospira (Genus) were detected in rivers samples, especially, the proportion of them was the highest in river samples after the inflow of discharged water from G-1-PSTP. These results indicated the effects of nitrifying microorganisms and NH₃-N concentrations as important limiting factors on the increased NBOD levels in the rivers. Taken together, comprehensive strategies are needed not only to reduce the NH₃-N concentration of discharged water but also to control discharged nitrifying microorganisms to effectively reduce the NBOD levels in the downstream of the Yeongsan river where discharged water from G-1-PSTP flows.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.2
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• pp.79-85
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• 2012

In this study, Application of sequencing batch reactor (SBR) process for RO retentate treatment was performed. Efficiency of treatment by load and temperature variation was tested. The SBR process was operated two types as HRT per one cycle was 8 and 12 hours, respectively. Methanol was injected for an effective denitrificaion owing to low C/N ratio of the RO retentate. TN removal efficiency of the SBR process was relatively stable at the change of flow-rate and temperature. The optimum time cycle of SBR process was 2 cycle/day for TN removal, and in the case of 3 cycle/day, the effluent TN concentration was found under the effluent quality standard. In the result of assessment, the application of SBR process for RO retentate treatment was effective and could be utilized to design for the wastewater treatment plant. The specific nitrification rate (SNR) and specific denitrification rate (SDNR) were $0.043{\sim}0.066kg\;NH_3-N/kg\;MLVSS{\cdot}day$ and $0.096{\sim}0.287kg\;NH_3^--N/kg\;MLVSS{\cdot}day$, respectively. The derived kinetic could be applied for design to the aerobic and anoxic tank in the RO retentate treatment.

• Journal of Korean Society on Water Environment
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• v.16 no.4
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• pp.501-512
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• 2000

This study was carried out to develop the new process for RBC process which is capable of nutrient removal and to obtain its design parameters for Sludge Settling Type Rotating Biological Contactors by comparing RBC with RBC combined with HBR (Hanmee Bio-Reactor). To achieve more than 90% of organic removal efficiency, organic loading rate less than $6.0g\;BOD/m^2/d$ is recommended. Nitrification rate was about 90% at $6.0g\;BOD/m^2/d$. TN removal efficiency of RBC+HBR was higher than those of RBC1 and RBC2. TN removal efficiency at condition of $5.0g\;BOD/m^2/d$ was about 60% in RBC1. When BOD loading rate was $6.0g\;BOD/m^2/d$. TN removal efficiencies in RBC2 and RBC+HBR were about 70%, 80%, respectively. TP removal efficiency was more than about 67% for RBC1, about 63% for RBC2 and about 71 % for RBC+HBR at the same loading rate. From the blank experiment to observe removal efficiency in the first stage, it can be known that COD removal efficiency was about 30% and suspend solids settling rate was about 45%. It was proved that RBC+HBR is much better in sludge dewatering than RBC.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.13 no.1
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• pp.233-241
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• 1993

This study was conducted to characterise the sidestream from municipal wastewater treatment plants and its effects on the main treatment process. The flow rates and waste strengthes from each unit processes were measured and analysed, and finally determined its characteristics through the mass balance techniques. A laboratory scale completely mixed activated sludge was operated at $20^{\circ}C$ and fed in pulse with the sidestream to simulate the actual operating conditions. The study results indicated that the flow rates of sidestream ranged from 1.2 to 1.8 percent of the influent flow. However, the organic and nutrient loading rates could be increased to about 20 to 30 percent at an average, but 40 to 70 percent at a peak condition. It appears that the impurities from the sidestreams were not easily settled and resulted in lower primary efficiency. Consequently, it increased the organic loading rates to the aeration tank and the efficiencies were decreased at least about 10 percent at an average in comparison to the ordinary condition without the sidestream. With the peak condition, the efficiencies could not reach more than 80 percent for the organic removal and 50 percent for the nitrification.

• Journal of Korean Society of Water and Wastewater
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• v.18 no.1
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• pp.37-48
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• 2004

The purpose of this study was to evaluate adaptability of external carbon source using GPS-X program in pilot plant composed with 2-stage denitrification process. The result from analysis of pilot plant operation and GPS-X simulation showed that effluent concentration could be simulated similarly by modifying operation conditions, such as DO concentration, C/N ratio and other calibrated parameter. In order to satisfy the standard of the effluent water quality on T-N of 20mg/L, it required approximately 3.1 of C/N ratio and 50% of nitrogen removal efficiency when influent T-N is 36.9mg/L. To maintain the stable water quality of the receiving water, the effluent T-N concentration should be less than 10-15mg/L and the appropriate C/N ratio to remove nitrogen was 4.27-6.82. The analysis of sensitivity to kinetic coefficient and reaction constant showed that $Y_H$ and ${\mu}_{mAUT}$ were most sensitive to nitrate and ammonia nitrogen, relatively and sensitivity coefficient of their were 1.32, 1.98. It was concluded that as $Y_H$ decreased and ${\mu}_{mAUT}$ increased, the reaction rates of denitrification and nitrification increased and the removal efficiencies of $NO_3{^-}-N$ and $NH_4{^+}-N$ improved.

• Journal of Korean Society of Water and Wastewater
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• v.28 no.2
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• pp.161-170
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• 2014

It is essential to decrease energy consumption and excess sludge to economically operate sewage treatment plant. This becomes more important along with a ban on sea dumping and exhaustion of resource. Therefore, many researchers have been study on energy consumption reduction and strategies for minimization of excess sludge production from the activated sludge process. The aeration cost account for a high proportion of maintenance cost because sufficient air is necessary to keep nitrifying bacteria activity of which the oxygen affinity is inferior to that of heterotrophic bacteria. Also, additional costs are incurred to stabilize excess sludge and decrease the volume of sludge. There were anoxic, aerobic, membrane, deairation and concentration zone in this MBR process. Continuous aeration was provided to prevent membrane fouling in membrane zone and intermittent aeration was provided in aerobic zone through ammonia sensor. So, there was the minimum oxygen to remove $NH_4-N$ below limited quantity that could be eliminated in membrane zone. As the result of this control, energy consumption of aeration system declined by between 10.4 % and 19.1 %. Besides, we could maintain high MLSS concentration in concentration zone and this induced the microorganisms to be in starved condition. Consequentially, the amount of excess sludge decrease by about 15 %.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.4
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• pp.438-444
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• 2005

This study is to install the flexible vertical in order to separate not only the time but also the space in the single reactor by opening and closing the flexible vertical, and to intensify the aerobic, anaerobic and anoxic reactions by reducing the time to activate the microorganism for nitrification, denitrification, release of organic phosphate and luxury uptake of ortho-phosphate. Eventually the result of this study obtained each 90.9%, 76.4% for the removal efficiency of total nitrogen and phosphate. Also, content rate of phosphate at excess sludge was higher $25{\sim}30%$ for SBR reactor with the flexible verticals than existing SBR process. It would be concluded that SBR reactor with flexible verticals is promising for nitrogen and phosphate removal conditions than conventional SBR processes.

• Korean Journal of Materials Research
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• v.15 no.3
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• pp.166-171
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• 2005

Fe-6Al-9Si(N) alloy powders were synthesized by hybrid process of chemical nitrification and mechanical milling. The nitriding treatment on Fe-6Al-9Si alloy powders formed $\gamma'-Fe_4N$ phase on the powders surface. The nitriding-treated powders were pulverized by horizontal high-energy ball milling machine. The longer ball milling time tended to reduce the size of alloy powders. In ball milling for 36h, extremely fine powders with about $7\~9wt\%$ nitrogen were obtained. Through X-ray diffraction analysis on the powders, it was found out that the longer milling time caused a disappearance of the crystallinity of $\alpha-Fe$ in the powders. TEM study confirmed that the powders is comprised of a few tens nano-meter sized crystals, including $\alpha-Fe$ phase with partially $\gamma'-Fe_4N$ phase. Hysteresis curves of the synthesized powders measured by VSM revealed lower saturation magnetization and higher coercivity, which seemed to be attributed to nitrogen-impregnation and severe residual stress developed during the high energy milling. Microstructure observation on the powder annealed at 873 K for 1 h showed 10 to 20 nm sized $\alpha-Fe$ crystal. Such a enhanced crystallinity significantly increased the magnetization and decreased the coercivity, which was attributed to not only the crystallinity but also residual stress relaxation.

• 한국생물공학회:학술대회논문집
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• 2005.10a
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• pp.450-455
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• 2005

To treat wastewater efficiently by a one-step process of nitrogen removal, a new strain of $N_2-producing$ bacteria from $NH{_4}{^+}$ under an aerobic condition was isolated and identified. By 16S-rDNA analysis, the isolate was identified as Enterobacter asburiae with 96% similarity. The isolate shows that the capacity of $N_2$ production under an oxic condition was approximately three times higher than that under an anoxic condition. The optimal conditions (pH, temperature and C/N ratio) of the immobilized isolate for $N_2$ production were found to be 7.0, $30^{\circ}C$ and 5, respectively. Under all the optimum reaction conditions, the removal efficiency of $COD_{Cr}$ and TN reached 56.1 and 60.9%, respectively. The removal rates of $COD_{Cr}$ and TN were highest for the first 2.5 hrs (with the removal $COD_{Cr}$ ratios of 32.1), and afterwards the rates decreased as reaction proceeded. For application of the immobilized isolate to a practical process of ammonium removal, a continuous bioreactor system exhibited a satisfactory performance at HRT of 12.1 hr, in which the effluent concentrations of $NH{_4}{^+}-N$ was measured to be 15.4 mg/L with its removal efficiency of 56.0%. The maximum removal rate of $NH{_4}{^+}-N$ reached 1.6 mg $NH{_4}{^+}-N/L/hr$ at HRT of 12.1 hr (with N loading rate of 0.08 $Kg-N/m^3-carrier/d)$. As a result, the application of the immobilized isolate appears a viable alternative to the nitrification-denitrification processes.

• Journal of Korean Society on Water Environment
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• v.22 no.4
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• pp.678-686
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• 2006

The feasibility of the high-hydrophilic biofilter was examined for application in rural wastewater treatment in Korea. The intermittent trickling biofiter was developed for wastewater treatment of media and examined instantaneous wetting water and immersional wetting water. Melamin foam absorbed 120 times it's weight in water and maintained wetting status than other materials. These characteristics are improvement for application in rural areas showing large variance of amount of influent. The biofilter process was effective in treating organic pollutants; mean removal efficiencies of $BOD_5$ and TSS were above 80%. The average SS concentrations of effluent was showed below $10mg/L^{-1}$ and meet guidelines in special regions, however, the average concentration of $BOD_5$ was about $20mg/L^{-1}$. The removals of T-N and T-P were relatively less effective and removal efficiencies were below 40%. It might meet the guidelines for T-P because of low levels of influent T-P concentration. However, the T-N concentration were too high and further treatment is required. The effluent concentration of $NH_4-N$ showed a significant reduction rate about 43.8%, but part of $NH_4-N$ was transformed to $NO_2-N$ and $NO_3-N$ inside the biofilter through nitrification process. The effluent concentration of org-P was removed about 78.8% of influent concentration by filtration. Considering stable performance and effective removal of pollutant in wastewater, low maintenance, and cost-effectiveness, the hydrophilic biofilter system was thought to be an effective and feasible alternative for decentralized rural areas.