• 제목/요약/키워드: nitrification process

검색결과 262건 처리시간 0.021초

호흡률을 이용한 연속회분식반응조의 질산화 공정 해석 (Nitrification process analysis by respirometry in a sequencing batch reactor)

  • 김동한;김성홍
    • 상하수도학회지
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    • 제33권1호
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    • pp.55-62
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    • 2019
  • The respirometric technique has been used to analyze the nitrification process in a sequencing batch reactor(SBR) treating municipal wastewater. Especially the profile of the respiration rate very well expressed the reaction characteristics of nitrification. As the nitrification process required a significant amount of oxygen for nitrogen oxidation, the respiration rate due to nitrification was high. The maximum nitrification respiration rate, which was about $50mg\;O_2/L{\cdot}h$ under the period of sufficient nitrification, was related directly to the nitrification reaction rate and showed the nitrifiers activity. The growth rate of nitrifiers is the most critical parameter in the design of the biological nutrient removal systems. On the basis of nitrification kinetics, the maximum specific growth rate of nitrifiers in the SBR was estimated as $0.91d^{-1}$ at $20^{\circ}C$, and the active biomass of nitrifiers was calculated as 23 mg VSS/L and it was about 2% of total biomass.

Low Temperature Effects on the Nitrification in a Nitrogen Removal Fixed Biofilm Process Packed with SAC Media

  • Jang, Se-Yong;Byun, Im-Gyu
    • 한국환경과학회지
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    • 제22권1호
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    • pp.1-6
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    • 2013
  • A fixed biofilm reactor system composed of anaerobic, anoxic(1), anoxic(2), aerobic(1) and aerobic(2) reactor was packed with synthetic activated ceramic (SAC) media and adopted to reduce the inhibition effect of low temperature on nitrification activities. The changes of nitrification activity at different wastewater temperature were investigated through the evaluation of temperature coefficient, volatile attached solid (VAS), specific nitrification rate and alkalinity consumption. Operating temperature was varied from 20 to $5^{\circ}C$. In this biofilm system, the specific nitrification rates of $15^{\circ}C$, $10^{\circ}C$ and $5^{\circ}C$ were 0.972, 0.859 and 0.613 when the specific nitrification rate of $20^{\circ}C$ was assumed to 1.00. Moreover the nitrification activity was also observed at $5^{\circ}C$ which is lower temperature than the critical temperature condition for the microorganism of activated sludge system. The specific amount of volatile attached solid (VAS) on media was maintained the range of 13.6-12.5 mg VAS/g media at $20{\sim}10^{\circ}C$. As the temperature was downed to $5^{\circ}C$, VAS was rapidly decreased to 10.9 mg VAS/g media and effluent suspended solids was increased from 3.2 mg/L to 12.0 mg/L due to the detachment of microorganism from SAC media. And alkalinity consumption was lower than theoretical value with 5.23 mg as $CaCO_3$/mg ${NH_4}^+$-N removal at $20^{\circ}C$. Temperature coefficient (${\Theta}$) of nitrification rate ($20^{\circ}C{\sim}5^{\circ}C$) was 1.033. Therefore, this fixed film nitrogen removal process showed superior stability for low temperature condition than conventional suspended growth process.

양식 수처리를 위한 생물막 공정에서 질산화 영향인자에 대한 고찰 (A Study of Nitrification Kinetics in the Biofilter Process for Aquaculture Water Treatment: A Review)

  • 박노백;박미선;이진환;명정인
    • 한국수산과학회지
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    • 제46권6호
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    • pp.675-681
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    • 2013
  • There have been many studies on biofilter process regarding satisfactory water quality and the operational conditions of Recirculating Aquaculture Systems (RAS). For effective nitrification processes, it is necessary to dynamically identify and apply nitrifying microorganisms. Physical, chemical and biological processes concerning biofilms can be applied and influential factors including substrate, dissolved oxygen concentrations, organic matter, temperature, pH, alkalinity, salinity and mixing velocity intensity need to be considered. Also, designing and managing the process based on the dynamic interpretation of these factors are prerequisites for engineering applications of the biofilter process. This paper draws on current literature on the kinetics of nitrification of biofilms in the biofilter process. Influential factors for nitrification are crucial during the biofilter process and are expected to be critical in informing the design and operation of recirculating aquaculture systems.

수리학적 체류시간에 따른 부유성장 미생물을 이용한 공정과 하이브리드 공정의 유기물, 질소 및 인 제거 특성 비교 (Comparison of Removal Characteristics of Organic Matter, Nitrogen and Phosphorus in Suspended-Growth and Hybrid Processes with Hydraulic Retention Time)

  • 류홍덕;이상일
    • 대한환경공학회지
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    • 제28권1호
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    • pp.15-25
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    • 2006
  • 본 연구는 도시하수 처리시 부유성장 미생물만을 이용하는 MLE(Modified Ludzack-Ettinger) 공정과 부유 및 부착 미생물을 동시에 활용하는 하이브리드(hybrid)형 공정인 M-Dephanox(Modified-Dephanok) 공정의 유기물, 질소 및 인 제거효율을 수리학적 체류시간에 따라 상호 비교 검토하고자 하였다. H-Dephanox 공정은 기존 Dephanox 공정의 단점을 극복하기 위하여 고안된 공정으로서 기존 Dephanox 공정에 비해 탈질 효율을 증가시킬 수 있도록 고안되었다. 수리학적 체류시간에 따른 유기물, 질소 및 인 제거효율을 관찰한 결과 하이브리드 공정인 H-Dephanox 공정이 MLE 공정에 비해 높은 제거효율이 관찰되었으며, 특히 질산화의 경우 수리학적 체류시간이 6, 5, 4, 3.5 hr으로 짧아짐에 따라 MLE 공정이 M-Dephanox 공정에 비해 질산화 영향을 더 심하게 받는 것으로 나타났다. M-Dephanox 공정의 질화반응조에서의 암모니아성 질소 제거 효율은 질산화 반응조의 HRT 1.59 hr에서 약 92%를 나타내 매우 짧은 수리학적 체류시간에서도 질산화 반응이 원활하게 일어나는 것을 관찰 할 수 있었으며, 질산화 반응조로 유입되는 유기물의 영향을 심하게 받는 것으로 관찰되었다. 질산화 반응조에서의 HRT 단축은 전체 공정의 HRT도 줄이는 결과를 가져옴을 관찰 할 수 있었다.

부착성 미생물을 이용한 질산화 및 탈질특성에 관한 연구 (Study on the Characteristics of Nitrification and Denitrification using Attached Microorganism)

  • 권문선;이의신
    • 상하수도학회지
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    • 제8권3호
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    • pp.19-25
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    • 1994
  • In this research, characteristics of nitrification and denitrification using the microorganism attached on sponge and plates were examined. The denitrification and nitrification performance were investigated under the anaerobic and aerobic condition for about 2 months. Because the basins of denitrification and nitrification were connected in series, wastewater was flowed from denitrification basin to nitrification one. The 90% of influent flowrate was returned from nitrification basin to denitrification one. Most of organic material was removed in nitrification basin, wherease the only exact amount of organics required in denitrification process was removed in denitrification one. This experiment resulted in that heterotrophic bacteria existing in aerobic basin governed the removal efficiency of organic compounds. In case the influent BOD concentration into nitrification basin was 80mg/l, it did not affect to accumulation of nitrifying bacteria, the balance of heterotrophic bacteria was proved to be an important factor in nitrification/denitrification method such as anaerobic and aerobic cycling type.

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질산화-탈질 연계공정에서 질소화합물 및 기능성 유전자 거동 (Dynamics of Nitrogen Compounds and Functional Genes in a Nitrification-Denitrification Coupling Process)

  • 권지현;박형주;이윤영;조경숙
    • 한국미생물·생명공학회지
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    • 제48권1호
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    • pp.72-78
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    • 2020
  • The dynamics of nitrogen compounds and RNA-based functional genes were characterized in the nitrification-denitrification coupling process. For the removal of residual ammonium, intermittent aeration was introduced in the denitrification reactor. N2O production was not observed in both reactors. In both reactors, the nitrifying genes (achaeal-amoA, bacterial-amoA and hor) and denitrifying genes (narG, nirK, norB and nosZ) had a copy number of 3.92 × 102-7.25 × 105 and 2.85 × 102-3.06 × 104 per ng of DNA, respectively. These results suggest that denitrification and nitrification reactions occur in both the nitrification and denitrification reactors, respectively. Therefore, the coupling process is a promising one for the conversion of ammonium to nitrogen without generating N2O.

호흡률에 기반한 연속회분식반응조의 포기공정 제어 (Aeration control based on respirometry in a sequencing batch reactor)

  • 김동한;김성홍
    • 상하수도학회지
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    • 제32권1호
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    • pp.11-18
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    • 2018
  • As the sequencing batch reactor process is a time-oriented system, it has advantages of the flexibility in operation for the biological nutrient removal. Because the sequencing batch reactor is operated in a batch system, respiration rate is more sensitive and obvious than in a continuous system. The variation of respiration rate in the process well represented the characteristics of biological reactions, especially nitrification. The respiration rate dropped rapidly and greatly with the completion of nitrification, and the maximum respiration rate of nitrification showed the activity of nitrifiers. This study suggested a strategy to control the aeration of the sequencing batch reactor based on respirometry. Aeration time of the optimal aerobic period required for nitrification was daily adjusted according to the dynamics of respiration rate. The aeration time was mainly correlated with influent nitrogen loadings. The anoxic period was extended through aeration control facilitating a longer endogenous denitrification reaction time. By respirometric aeration control in the sequencing batch reactor, energy saving and process performance improvement could be achieved.

CNR공법의 체류시간에 따른 도시하수의 질소제거 (The Nitrogen Removal of Municipal Wastewater with HRT using CNR Process)

  • 김영규;양익배;김인배
    • 한국환경보건학회지
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    • 제26권3호
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    • pp.98-102
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    • 2000
  • The aim of this study was to evaluate on the removal effect of total nitrogen in municipal wastewater by decreasing hydraulic retention time(HRT) from 6 hour to 4 hour on CNR process. CNR-A(Cilia Nutrient Removal) is the process combining A2/O process with cilium media of H2L corporation. The removal efficiencies for T-N were 63.1% in A-1 reactor, and 73.5% in A-2 reactor and 77.0% in A-3 reactor. The specific nitrification(g-NH3-N/g-MLVSS.d) of Oxic in CNR-A process was 0.07-0.32. The specific denitrification in Anoxic and the specific nitrification inOxic was higher in HRT 4 hour because of optimum F/M ratio.

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다공성 미디어를 충진한 혐기-호기 반응조를 이용한 하수고도처리에 관한 연구 (Advanced Wastewater Treatment Using Anoxic-Aerobic Reactor Filled with Porous Media)

  • 김동하
    • 상하수도학회지
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    • 제21권1호
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    • pp.83-89
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    • 2007
  • A biological anoxic-aerobic reactor filled with porous media was operated in lab scale for the advanced wastewater treatment. The experiments were conducted for 6 months with three HRTs (4, 6, 8hr) and temperature of $23{\sim}25^{\circ}C$. Some other experimental conditions were as follows; nitrification reactor (MLSS 4,500mg/L, DO 3.3mg/L, $23{\sim}28^{\circ}C$), denitrification reactor(MLSS 8,000mg/L, ORP -100mV, Temp.$19{\sim}23^{\circ}C$). Average removal efficiencies of SS, $BOD_5$, $COD_{Cr}$, T-N, and T-P were 97.8%, 95.5%, 94.5%, 80.2%, and 60.6%, respectively. The reactor filled with porosity media showed stable removal capacity for organics and nutrients. Fast and complete nitrification and denitrification were accomplished. Maintaining high MLSS with porous media in the nitrification and denitrification reactor appears to enhance the nitrogen removal process. For the higher T-P removal, some coagulant addition process will be needed.

회전원판법을 적용한 Modified Dephanox 공정의 하수처리특성 (Characteristics of Wastewater Treatment in Applying RBC Modified Dephanox Process)

  • 강민구;김금용;류홍덕;이상일
    • 대한환경공학회지
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    • 제32권5호
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    • pp.477-486
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    • 2010
  • 본 연구는 생물학적 폐수처리공정의 하나인 회전원판법(RBC)을 이용하여 질산화 반응을 향상 시키는 목적으로 수행되었다. 그 일환으로 회전원판법(RBC)에 의한 질산화반응의 향상을 평가하기 위해서 본 연구에서는 Modified Dephanox 공정에 회전원판법(RBC)를 적용하여 연구를 수행 하였다. 회전원판법(RBC)을 이용한 공정의 가장 두드러진 특징은 질산화 반응조 안으로 질산화반응에 방해인자로 작용하는 고농도의 부유성 고형물(suspended solid)이 유입되어도 질산화반응을 원활히 수행할 수 있다는 데 있다. 게다가 공정의 운영결과 TCOD 제거 효율은 유입 TCOD 부하율이 0.04~0.1 kg/$day{\cdot}m^3$ 일 때는 약 90%이상의 TCOD 제거효율이 나타났다. T-N 제거효율은 약 75% 정도로 실험실규모의 공정운영에도 불구하고 높은 제거효율이 관찰되었다. 또한 인 의 경우 ${PO_4}^{3-}$-P 및 T-P 제거효율은 유입 ${PO_4}^{3-}$-P 및 T-P 부하율이 증가할수록 제거효율은 증가하는 경향을 나타내고 있다. 결론적으로 Modified Dephanox 공정에서 독립질산화 반응을 수행하는 회전원판법(RBC)의 이용은 높은 질산화반응을 수행할 뿐만 아니라 유입되는 부유성 고형물(suspended solid)의 영향을 최소화하여 안정적인 처리효율을 나타내는 시스템이다.